Method for separating triethanolamin from a mixture obtainable by ammonia and ethylene oxide reaction
    11.
    发明授权
    Method for separating triethanolamin from a mixture obtainable by ammonia and ethylene oxide reaction 有权
    从由氨和环氧乙烷反应获得的混合物中分离三乙醇胺的方法

    公开(公告)号:US07279602B2

    公开(公告)日:2007-10-09

    申请号:US10573498

    申请日:2004-10-02

    IPC分类号: C07C209/84 C07C209/86

    CPC分类号: C07C213/10 C07C215/12

    摘要: Process for separating triethanolamine continuously by distillation from a mixture of monoethanolamine, diethanolamine and triethanolamine together with ethanolamine ethers and water obtained by reaction of ammonia with ethylene oxide in the liquid phase under superatmospheric pressure and at elevated temperature, in which the mixture is distilled in two stages. The low-boiling fraction and the high-boiling fraction are taken off and discharged in the first stage and the intermediate-boiling fraction comprising >99.4% by weight of triethanolamine and

    摘要翻译: 通过蒸馏从单乙醇胺,二乙醇胺和三乙醇胺的混合物中连续分离三乙醇胺的方法以及乙醇胺醚和水,其通过在超大气压和升高的温度下在液相中将氨与环氧乙烷反应而获得,其中将混合物在两 阶段 在第一阶段中将低沸点馏分和高沸点馏分取出并排出,在第二阶段中蒸馏出包含> 99.4重量%的三乙醇胺和<0.2重量%的二乙醇胺的中间沸点馏分。 混合物的蒸馏优选在连接到该塔或在分隔壁塔中的第一塔和第二塔中进行。

    Method for separating triethanolamin from a mixture obtainable by ammonia and ethylene oxide reaction
    16.
    发明申请
    Method for separating triethanolamin from a mixture obtainable by ammonia and ethylene oxide reaction 有权
    从由氨和环氧乙烷反应获得的混合物中分离三乙醇胺的方法

    公开(公告)号:US20060293541A1

    公开(公告)日:2006-12-28

    申请号:US10573498

    申请日:2004-10-02

    IPC分类号: C07C213/10

    CPC分类号: C07C213/10 C07C215/12

    摘要: Process for separating triethanolamine continuously by distillation from a mixture of monoethanolamine, diethanolamine and triethanolamine together with ethanolamine ethers and water obtained by reaction of ammonia with ethylene oxide in the liquid phase under superatmospheric pressure and at elevated temperature, in which the mixture is distilled in two stages. The low-boiling fraction and the high-boiling fraction are taken off and discharged in the first stage and the intermediate-boiling fraction comprising >99.4% by weight of triethanolamine and

    摘要翻译: 通过蒸馏从单乙醇胺,二乙醇胺和三乙醇胺的混合物中连续分离三乙醇胺的方法以及乙醇胺醚和水,其通过在超大气压和升高的温度下在液相中将氨与环氧乙烷反应而获得,其中将混合物在两 阶段 在第一阶段中将低沸点馏分和高沸点馏分取出并排出,在第二阶段中蒸馏出包含> 99.4重量%的三乙醇胺和<0.2重量%的二乙醇胺的中间沸点馏分。 混合物的蒸馏优选在连接到该塔或在分隔壁塔中的第一塔和第二塔中进行。

    Process for the preparation of triethylenediamine (TEDA) from ethylenediamine
    19.
    发明授权
    Process for the preparation of triethylenediamine (TEDA) from ethylenediamine 有权
    从乙二胺制备三亚乙基二胺(TEDA)的方法

    公开(公告)号:US07115742B2

    公开(公告)日:2006-10-03

    申请号:US10359244

    申请日:2003-02-06

    IPC分类号: C07D487/04

    CPC分类号: C07D487/08 Y02P20/582

    摘要: A process for the preparation of triethylenediamine (TEDA) by reaction of ethylenediamine (EDA) in the presence of a zeolite catalyst, wherein the zeolite catalyst contains one or more metals M in oxidation states II, III or IV as oxides. The desired molar ratio of SiO2 to metal oxide of the zeolite catalyst depends on the oxidation state of the metal M as specified herein. The reaction temperature is from 250 to 500° C. TEDA is an important basic chemical and is used, among other things, in the preparation of pharmaceuticals and plastics, in particular as a catalyst in the preparation of polyurethanes.

    摘要翻译: 一种在沸石催化剂存在下通过乙二胺(EDA)反应制备三亚乙基二胺(TEDA)的方法,其中沸石催化剂含有一种或多种氧化态为II,III或IV的金属M作为氧化物。 沸石催化剂所需的SiO 2与金属氧化物的摩尔比取决于金属M的氧化态,如本文所述。 反应温度为250-500℃.TEDA是重要的基础化学品,尤其用于制备药物和塑料,特别是作为制备聚氨酯的催化剂。

    Decoloration and color stabilization of TEDA solution
    20.
    发明授权
    Decoloration and color stabilization of TEDA solution 失效
    TEDA溶液的脱色和颜色稳定

    公开(公告)号:US07074926B2

    公开(公告)日:2006-07-11

    申请号:US10765988

    申请日:2004-01-29

    IPC分类号: C07D487/00

    CPC分类号: C07D487/08

    摘要: The present invention relates to a process for preparing TEDA solutions comprising a solvent selected from the group consisting of polyhydric alcohols and ethers of polyhydric alcohols. The process comprises passing gaseous TEDA into the solvent and subsequently treating the solutions with one or more suitable adsorbents. This gives solutions which have only low color numbers and are color-stable on storage. The solutions can be used as such in preferred applications of TEDA, preferably polyurethane production.

    摘要翻译: 本发明涉及一种制备TEDA溶液的方法,其包含选自多元醇和多元醇醚的溶剂。 该方法包括将气态TEDA通入溶剂中,随后用一种或多种合适的吸附剂处理溶液。 这给出了仅具有低颜色数量且在存储时颜色稳定的解决方案。 该溶液可以原样用于TEDA,优选聚氨酯生产。