公开(公告)号：US09670415B2

公开(公告)日：2017-06-06

申请号：US13605701

申请日：2012-09-06

Applicant: Bilge Yilmaz ,  Ulrich Berens ,  Vijay Narayanan Swaminathan ,  Ulrich Müller ,  Gabriele Iffland ,  Laszlo Szarvas

Inventor： Bilge Yilmaz ,  Ulrich Berens ,  Vijay Narayanan Swaminathan ,  Ulrich Müller ,  Gabriele Iffland ,  Laszlo Szarvas

IPC: C01B39/54 ,  C01B39/48 ,  B01J29/70 ,  B01J29/85 ,  B01J29/86 ,  B01J29/87 ,  C10G3/00 ,  C10G11/05 ,  C07C1/20 ,  C10G25/03 ,  C10G11/18 ,  B01D53/94

CPC classification number: C10G3/49 ,  B01D53/9413 ,  B01D53/9436 ,  B01D2255/50 ,  B01J29/70 ,  B01J29/7015 ,  B01J29/85 ,  B01J29/86 ,  B01J29/87 ,  B01J2229/183 ,  C01B39/48 ,  C01B39/54 ,  C07C1/20 ,  C07C2529/70 ,  C10G11/05 ,  C10G11/18 ,  C10G25/03 ,  C10G2300/405 ,  Y02C20/10 ,  C07C11/02

Abstract: The present invention relates to a process for the preparation of a zeolitic material having a structure comprising YO2 and optionally comprising X2O3, preferably comprising YO2 and X2O3, wherein said process comprises the steps of (1) providing a mixture comprising one or more ammonium compounds of which the ammonium cation has the formula (I): [R1R2NR3R4]+  (I) and further comprising one or more sources for YO2 and one or more sources for X2O3; (2) crystallizing the mixture provided in (1); wherein Y is a tetravalent element, and X is a trivalent element, and wherein in formula (I) R1 and R2 are independently from one another derivatized or underivatized methyl, and R3 and R4 are independently from one another derivatized or underivatized (C3-C5)alkyl, and wherein the molar ratio of ammonium cation having the formula (I) to Y in the mixture provided in step (1) and crystallized in step (2) is equal to or greater than 0.25.

公开(公告)号：US09334171B2

公开(公告)日：2016-05-10

申请号：US13163377

申请日：2011-06-17

Applicant: Bilge Yilmaz ,  Ulrich Müller ,  Meike Pfaff ,  Hermann Gies ,  Feng-Shou Xiao ,  Takashi Tatsumi ,  Xinhe Bao ,  Weiping Zhang ,  Dirk de Vos ,  Hiroyuki Imai ,  Bin Xie ,  Haiyan Zhang

Inventor： Bilge Yilmaz ,  Ulrich Müller ,  Meike Pfaff ,  Hermann Gies ,  Feng-Shou Xiao ,  Takashi Tatsumi ,  Xinhe Bao ,  Weiping Zhang ,  Dirk de Vos ,  Hiroyuki Imai ,  Bin Xie ,  Haiyan Zhang

IPC: C01B39/48 ,  B01J29/70 ,  C01B39/46 ,  B01J20/18 ,  B01J20/28 ,  C07C1/20 ,  C10G3/00 ,  C10G11/18 ,  C10G25/03 ,  C01B37/02 ,  B01D53/94

CPC classification number: C01B39/46 ,  B01D53/9418 ,  B01D2251/2067 ,  B01D2253/108 ,  B01D2253/3425 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/9207 ,  B01D2257/402 ,  B01D2257/404 ,  B01D2257/406 ,  B01D2258/012 ,  B01J20/186 ,  B01J20/28011 ,  B01J20/2803 ,  B01J20/28042 ,  B01J20/28057 ,  B01J29/70 ,  B01J2229/186 ,  C01B37/02 ,  C01B39/48 ,  C01P2006/12 ,  C07C1/20 ,  C07C2529/70 ,  C07C2529/80 ,  C10G3/49 ,  C10G11/18 ,  C10G25/03 ,  C10G2300/405 ,  C10G2300/70 ,  Y02C20/10 ,  Y02P20/153 ,  Y02P20/52 ,  Y02P30/20

Abstract: A process for the production of a zeolitic material having an LEV-type framework structure comprising YO2 and optionally comprising X203, wherein said process comprises preparing a mixture comprising one or more sources for YO2, one or more solvents, and optionally comprising seed crystals; and crystallizing the mixture; wherein Y is a tetravalent element, and X is a trivalent element, and wherein the crystallized mixture contains 0.1 wt.-% or less, more preferably 0.01 wt.-% or less of one or more metals M based on 100 wt.-% of YO2, wherein even more preferably the crystallized mixture contains no metal M, wherein M stands for sodium and/or potassium, wherein preferably M stands for the group of alkali and alkaline earth metals.

Abstract translation: 一种制备具有包含YO 2和任选地包含X 2 O 3的LEV型骨架结构的沸石材料的方法，其中所述方法包括制备包含一种或多种YO 2，一种或多种溶剂和任选地包含晶种的源的混合物; 并使混合物结晶; 其中Y是四价元素，X是三价元素，并且其中所述结晶混合物含有基于100重量％的0.1重量％或更少，更优选0.01重量％或更少的一种或多种金属M， 的YO 2，其中甚至更优选结晶的混合物不含金属M，其中M代表钠和/或钾，其中优选M代表碱金属和碱土金属。

公开(公告)号：US09334170B2

公开(公告)日：2016-05-10

申请号：US13616834

申请日：2012-09-14

Applicant: Bilge Yilmaz ,  Ulrich Müller ,  Feng-Shou Xiao ,  Takashi Tatsumi ,  Dirk de Vos ,  Xinhe Bao ,  Weiping Zhang ,  Hermann Gies ,  Hiroyuki Imai ,  Bart Tijsebaert ,  Limin Ren ,  Chengguan Yang

Inventor： Bilge Yilmaz ,  Ulrich Müller ,  Feng-Shou Xiao ,  Takashi Tatsumi ,  Dirk de Vos ,  Xinhe Bao ,  Weiping Zhang ,  Hermann Gies ,  Hiroyuki Imai ,  Bart Tijsebaert ,  Limin Ren ,  Chengguan Yang

IPC: C01B39/00 ,  B01J29/85 ,  B01J37/02 ,  B01J29/00 ,  B01J29/84 ,  B01J29/83 ,  C01B39/54 ,  C01B37/08 ,  C01B39/48 ,  B01J29/70 ,  B01J35/00 ,  B01J35/02 ,  B01J35/10 ,  C07C1/20 ,  C10G11/18 ,  C10G3/00 ,  B01D53/02 ,  B01D53/94

CPC classification number: C01B39/00 ,  B01D53/02 ,  B01D53/9418 ,  B01D2255/2025 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/2092 ,  B01D2255/2094 ,  B01D2255/50 ,  B01J29/005 ,  B01J29/7015 ,  B01J29/83 ,  B01J29/84 ,  B01J29/85 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1066 ,  B01J37/02 ,  B01J37/0221 ,  B01J37/023 ,  B01J2229/62 ,  C01B37/08 ,  C01B39/48 ,  C01B39/54 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2006/12 ,  C07C1/20 ,  C07C2529/85 ,  C10G3/49 ,  C10G11/18 ,  Y02P20/52 ,  Y02P30/20 ,  C07C11/02

Abstract: The present invention relates to a process for the preparation of a zeolitic material having a CHA framework structure, said zeolitic material comprising zeolite crystals having a core-shell structure, wherein said process comprises the steps of (1) providing a mixture comprising one or more sources for Z2O5, one or more sources for X2O3, optionally one or more structure directing agents, and seed crystals having a CHA framework structure, wherein the CHA framework structure of the seed crystals comprises YO2, X2O3, and optionally Z2O5, and wherein the seed crystals have a diameter of 450 nm or greater; (2) crystallizing the mixture provided in (1) to afford zeolite crystals comprising a core of seed crystal provided in step (1) and a shell crystallized on the seed crystal; wherein Z is a pentavalent element, Y is a tetravalent element, and X is a trivalent element.

Abstract translation: 本发明涉及一种制备具有CHA骨架结构的沸石材料的方法，所述沸石材料包含具有核 - 壳结构的沸石晶体，其中所述方法包括以下步骤：（1）提供包含一种或多种 Z 2 O 5的源，X 2 O 3，任选的一种或多种结构导向剂的一种或多种来源，以及具有CHA骨架结构的晶种，其中晶种的CHA骨架结构包含YO 2，X 2 O 3和任选的Z 2 O 5，并且其中所述种子 晶体的直径为450nm以上; （2）使（1）中提供的混合物结晶，得到包含步骤（1）中提供的晶种核心的沸石晶体和在晶种上结晶的壳; 其中Z为五价元素，Y为四价元素，X为三价元素。

公开(公告)号：US09260062B2

公开(公告)日：2016-02-16

申请号：US13063168

申请日：2009-09-09

Applicant: Rolf Kamps ,  Ulrich Müller

Inventor： Rolf Kamps ,  Ulrich Müller

IPC: H04N7/00 ,  H04N7/18 ,  B60R11/04 ,  B60R11/00

CPC classification number: B60R11/04 ,  B60R2011/0094

Abstract: An image detection system having a camera unit for detecting images of the outside area of a motor vehicle, and a protection element that can be moved from a closed position to an open position by a mechanism through a drive. At least one lens of the camera unit is located behind the protection element inaccessible from the outside when the protection element is located in the closed position. At least the lens is released by the protection element for image detection in the open position. At least the camera unit with the mechanism and the protection element is disposed in a first module and the drive is provided in a second module separate from the first module. The first and second modules are mechanically connected to one another by at least one actuation element so that the drive drives the mechanism by way of the actuation element.

Abstract translation: 一种图像检测系统，其具有用于检测机动车辆的外部区域的图像的摄像单元，以及能够通过驱动机构通过机构从关闭位置移动到打开位置的保护元件。 当保护元件位于关闭位置时，照相机单元的至少一个透镜位于保护元件后面不能从外部进入的位置。 至少透镜由打开位置的图像检测用保护元件释放。 至少具有机构的摄像机单元和保护元件设置在第一模块中，并且驱动器设置在与第一模块分离的第二模块中。 第一和第二模块通过至少一个致动元件彼此机械连接，使得驱动器通过致动元件驱动机构。

公开(公告)号：US09242241B2

公开(公告)日：2016-01-26

申请号：US13501811

申请日：2010-10-11

Applicant: Ivor Bull ,  Ulrich Müller ,  Bilge Yilmaz

Inventor： Ivor Bull ,  Ulrich Müller ,  Bilge Yilmaz

IPC: B01J29/06 ,  B01J35/00 ,  B01J29/84 ,  B01J29/83 ,  B01J29/064 ,  B01J29/70 ,  B01J29/72 ,  B01D53/94 ,  B01J29/072 ,  B01J29/76 ,  B01J37/00 ,  B01J37/10 ,  B01J29/85

CPC classification number: B01J29/76 ,  B01D53/9409 ,  B01D53/9418 ,  B01D53/9459 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/904 ,  B01D2257/402 ,  B01D2257/404 ,  B01D2257/406 ,  B01D2258/012 ,  B01J29/064 ,  B01J29/072 ,  B01J29/70 ,  B01J29/72 ,  B01J29/83 ,  B01J29/84 ,  B01J29/85 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/10 ,  B01J2229/186 ,  B01J2229/36 ,  Y02C20/10

Abstract: Aspects of the present invention relates to a copper containing Levyne molecular sieve having a silica to alumina mole ratio less than 30 and a Cu:Al atomic ratio less than 0.45, wherein the Levyne molecular sieve retains at least 60% of its surface area after exposure to a temperature of from about 750° C. to about 950° C. in the present of up to 10 volume percent water vapor for a time ranging from about 1 to about 48 hours.

Abstract translation: 本发明的方面涉及二氧化硅与氧化铝的摩尔比小于30且Cu:Al原子比小于0.45的含铜Levyne分子筛，其中Levyne分子筛在曝光后保持其表面积的至少60％ 在约10体积％的水蒸气中存在约750℃至约950℃的温度，时间范围为约1至约48小时。

公开(公告)号：US09181145B2

公开(公告)日：2015-11-10

申请号：US13438408

申请日：2012-04-03

Applicant: Bilge Yilmaz ,  Ulrich Müller ,  Faruk Özkirim ,  Dirk de Vos ,  Feng-Shou Xiao ,  Takashi Tatsumi ,  Xinhe Bao ,  Weiping Zhang ,  Hermann Gies ,  Hiroyuki Imai ,  Bart Tijsebaert

Inventor： Bilge Yilmaz ,  Ulrich Müller ,  Faruk Özkirim ,  Dirk de Vos ,  Feng-Shou Xiao ,  Takashi Tatsumi ,  Xinhe Bao ,  Weiping Zhang ,  Hermann Gies ,  Hiroyuki Imai ,  Bart Tijsebaert

IPC: C07C2/66

CPC classification number: C07C2/66 ,  C07C2529/70 ,  C07C15/073 ,  C07C15/02

Abstract: The present invention relates to a process for the alkylation of an organic compound comprising: (a) providing a catalyst comprising one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YO2 and optionally comprises X2O3, wherein Y is a tetravalent element, and X is a trivalent element, (b) contacting the catalyst with one or more alkylatable organic compounds in the presence of one or more alkylating agents in one or more reactors for obtaining one or more alkylated organic compounds, wherein the one or more zeolitic materials is obtainable from a synthetic process which does not employ an organotemplate as structure directing agent.

Abstract translation: 本发明涉及一种有机化合物的烷基化方法，包括：（a）提供包含一种或多种具有BEA骨架结构的沸石材料的催化剂，其中所述BEA骨架结构包含YO 2并且任选地包含X 2 O 3，其中Y是 四价元素，X是三价元素，（b）在一个或多个烷基化剂存在下，在一个或多个烷基化剂存在下使催化剂与一种或多种可烷基化的有机化合物接触，以获得一种或多种烷基化有机化合物，其中所述一种或多种烷基化有机化合物， 更多的沸石材料可以从不使用有机模板作为结构导向剂的合成方法获得。

公开(公告)号：US09096616B2

公开(公告)日：2015-08-04

申请号：US13542971

申请日：2012-07-06

Applicant: Natalia Trukhan ,  Ulrich Müller

Inventor： Natalia Trukhan ,  Ulrich Müller

IPC: C07F3/06

CPC classification number: C07F3/06

Abstract: Described is a process for preparing a porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, where the at least one metal ion is a zinc ion and the at least one at least bidentate organic compound is based on 2-methylimidazole, which comprises the steps (a) addition of a first water-based solution comprising zinc ions to a second water-based solution comprising 2-methylimidazole, with a suspension being formed after addition of the second solution; (b) addition of a third solution comprising a strong base to the suspension formed in step (a).

Abstract translation: 描述了一种制备多孔金属 - 有机骨架的方法，所述多孔金属 - 有机骨架包含至少一种与至少一种金属离子配位的至少二齿有机化合物，其中所述至少一种金属离子是锌离子，并且所述至少一种至少二齿有机化合物 是基于2-甲基咪唑，其包括以下步骤：（a）在包含2-甲基咪唑的第二水性溶液中加入包含锌离子的第一水性溶液，在加入第二溶液后形成悬浮液; （b）向步骤（a）中形成的悬浮液中加入包含强碱的第三溶液。

公开(公告)号：US08609879B2

公开(公告)日：2013-12-17

申请号：US12837962

申请日：2010-07-16

Applicant: Joaquim Henrique Teles ,  Hans-Georg Göbbel ,  Peter Baβler ,  Philip Kampe ,  Kai Gumlich ,  Christian Bartosch ,  Ulrich Müller ,  Richard Jacubinas ,  Natalia Trukhan ,  Meinolf Weidenbach ,  Martin Cogswell

Inventor： Joaquim Henrique Teles ,  Hans-Georg Göbbel ,  Peter Baβler ,  Philip Kampe ,  Kai Gumlich ,  Christian Bartosch ,  Ulrich Müller ,  Richard Jacubinas ,  Natalia Trukhan ,  Meinolf Weidenbach ,  Martin Cogswell

IPC: C07C255/00

CPC classification number: C07D301/12 ,  B01D17/0208 ,  B01D17/047 ,  Y02P20/582

Abstract: A method for separating acetonitrile from water, comprising (i) providing a stream S1 containing at least 95 wt.-%, based on the total weight of S1, acetonitrile and water, wherein the weight ratio of acetonitrile: water is greater than 1; (ii) adding a stream P, comprising at least 95 wt.-% C3, based on the total weight of stream P, to S1 to obtain a mixed stream S2, C3 being propene optionally admixed with propane with a minimum weight ratio of propene: propane of 7:3; (iii) subjecting S2 to a temperature of 92° C. at most and a pressure of at least 10 bar, obtaining a first liquid phase L1 essentially consisting of C3, acetonitrile, and water, and a second liquid phase L2 essentially consisting of water and acetonitrile wherein the weight ratio of acetonitrile: water in L2 is less than 1; (iv) separating L1 from L2.

Abstract translation: 一种从水中分离乙腈的方法，包括（i）提供基于S1的总重量，乙腈和水的至少95重量％的流S1，其中乙腈：水的重量比大于1; （ii）将基于流P的总重量的至少95重量％C 3的流P加入到S1中，以获得混合物流S2，将任选地与丙烷混合的丙烯以最小重量比的丙烯 ：丙烷7：3; （iii）使S2达到最多92℃的温度和至少10巴的压力，得到基本上由C3，乙腈和水组成的第一液相L1和基本上由水组成的第二液相L2 乙腈，其中乙腈：水的重量比小于1; （iv）将L1与L2分离。

公开(公告)号：US08524932B2

公开(公告)日：2013-09-03

申请号：US13249943

申请日：2011-09-30

Applicant: Emi Leung ,  Ulrich Müller ,  Natalia Trukhan ,  Hendrick Mattenheimer ,  Gerhard Cox ,  Stefan Blei

Inventor： Emi Leung ,  Ulrich Müller ,  Natalia Trukhan ,  Hendrick Mattenheimer ,  Gerhard Cox ,  Stefan Blei

IPC: C07F5/06

CPC classification number: C07F5/069

Abstract: The present invention relates to a process for preparing a porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, where the at least one metal ion is based on an aluminum ion and the at least one at least bidentate organic compound is based on fumaric acid, by reacting at least one aluminum compound with at least fumaric acid in an alkaline aqueous medium, optionally in the presence of at least one base, at a temperature in the range from 20° C. to 100° C. at an absolute pressure of not more than 2 bar for from 0.2 to 4 hours.

Abstract translation: 本发明涉及一种制备多孔金属 - 有机骨架的方法，其包含与至少一种金属离子配位的至少一种至少二齿的有机化合物，其中所述至少一种金属离子基于铝离子，并且所述至少一种 至少二齿有机化合物是基于富马酸，在至少一种碱的存在下，在至少一种碱的存在下，在20℃的温度下使至少一种铝化合物与至少富马酸在碱性水性介质中反应。 至100℃，绝对压力不超过2巴0.2至4小时。

公开(公告)号：US20130064758A1

公开(公告)日：2013-03-14

申请号：US13606614

申请日：2012-09-07

Applicant: Bilge Yilmaz ,  Ulrich Müller ,  Faruk Özkirim ,  Meike Pfaff ,  Mike Haas ,  Feng-Shou Xiao

Inventor： Bilge Yilmaz ,  Ulrich Müller ,  Faruk Özkirim ,  Meike Pfaff ,  Mike Haas ,  Feng-Shou Xiao

IPC: C01B39/00

CPC classification number: C01B39/46 ,  C01B39/02 ,  C01B39/30

Abstract: The present invention relates to an organotemplate-free synthetic process for the production of a zeolitic material comprising YO2 and X2O3, wherein said process comprises the steps of (1) preparing a mixture comprising seed crystals, one or more sources for YO2, one or more sources for X2O3, and one or more solvents; (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material comprising YO2 and X2O3 as a crystallization product; wherein Y is a tetravalent element, and X is a trivalent element, andwherein at least a portion of the mother liquor obtained in step (2) is recycled to step (1) as a source for YO2, optionally after concentration of the mother liquor.

Abstract translation: 本发明涉及一种用于生产包含YO 2和X 2 O 3的沸石材料的无有机模板合成方法，其中所述方法包括以下步骤：（1）制备包含晶种的混合物，一种或多种YO2源，一种或多种 X2O3和一种或多种溶剂的来源; （2）使步骤（1）中获得的混合物结晶，得到包含YO 2和X 2 O 3作为结晶产物的沸石材料; 其中Y是四价元素，X是三价元素，并且其中步骤（2）中获得的至少一部分母液作为YO2源再循环到步骤（1），任选地在母液浓缩之后 。