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公开(公告)号：US06235218B1
公开(公告)日：2001-05-22
申请号：US09444041
申请日：1999-11-19
申请人： Ulrich Annen , James E. Deline , Lafayette D. Foland , Kevin A. Klotter , Josef Müller , Michael Müller , Klaus Mundinger , Martin A. Phillippi , Alfred Ruland , Wolfgang Schäfer , Gregor Schürmann , Rudi Widder , Alfred G. Zielske
发明人： Ulrich Annen , James E. Deline , Lafayette D. Foland , Kevin A. Klotter , Josef Müller , Michael Müller , Klaus Mundinger , Martin A. Phillippi , Alfred Ruland , Wolfgang Schäfer , Gregor Schürmann , Rudi Widder , Alfred G. Zielske
IPC分类号： C07D26530
CPC分类号： C11D3/3925 , C07D295/15
摘要： A process is provided for the preparation of a compound having the structure of Formula I The process includes reacting a heterocyclic amine with a monoaldehyde or a dialdehyde in a pH range of from about 8 to 14 and then quaternizing the so-reacted heterocyclic amine with an alkylating agent at a pH of not less than about 2. The use of pH control substantially prevents formation of an undesirable protonated reaction intermediate.
摘要翻译： 提供了一种制备具有式I结构的化合物的方法。该方法包括使杂环胺与约8至14的pH范围内的单醛或二醛反应，然后将如此反应的杂环胺与烷基化 在pH不低于约2的情况下，pH控制的使用基本上防止形成不期望的质子化反应中间体。
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公开(公告)号：US5591378A
公开(公告)日：1997-01-07
申请号：US271093
申请日：1994-07-06
CPC分类号： C11D3/3925
摘要： Substituted benzonitrile activators give excellent bleaching performance when combined with a peroxygen source and dissolved in solution. These substituted benzonitrile activators give best bleaching performance when the activators are multiply substituted with electron-withdrawing groups.
摘要翻译： 当与过氧源结合并溶解在溶液中时，取代的苄腈活化剂具有优异的漂白性能。 当活化剂被吸电子基团取代时，这些取代的苄腈活化剂具有最佳的漂白性能。
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公开(公告)号：US5707542A
公开(公告)日：1998-01-13
申请号：US720875
申请日：1996-10-03
CPC分类号： C11D3/3925
摘要： Substituted benzonitrile activators give excellent bleaching performance when combined with a peroxygen source and dissolved in solution. These substituted benzonitrile activators give best bleaching performance when the activators are multiply substituted with electron-withdrawing groups.
摘要翻译： 当与过氧源结合并溶解在溶液中时，取代的苄腈活化剂具有优异的漂白性能。 当活化剂被吸电子基团取代时，这些取代的苄腈活化剂具有最佳的漂白性能。
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公开(公告)号：US6127536A
公开(公告)日：2000-10-03
申请号：US318410
申请日：1999-05-25
IPC分类号： C07D257/10 , C07D225/00
CPC分类号： C07D257/10
摘要： An improved synthesis for preparing a tetraamido-macrocyclic ligand, such as 5,6-Benzo-3,8,11,13-tetraoxo-2,2,9,9-tetramethyl-12,12-diethyl-1,4,7,10-tetraazacyclotridecane, H.sub.4, in greatly improved yield and in a commercially viable manner, comprising the steps of dissolving a quantity of a 1,2-bis(2-aminoalkanamido)benzene in a solution comprised of ethyl acetate and methylene chloride to yield a first reaction solution; dissolving a quantity of a malonyl dihalide in an ethyl acetate solution to yield a second reaction solution; adding the first reaction solution and the second reaction solution to a reaction vessel containing a third reaction solution comprised of refluxing ethyl acetate solution and an acid scavenger to form a reaction mixture; and isolating a solid product comprised of the tetraamido-macrocycle directly from the reaction mixture by filtration.
摘要翻译： 用于制备四氨基 - 大环配体的改进的合成物，例如5,6-苯并-3,8,11,13-四氧代-2,2,9,9-四甲基-1,12,12-二乙基-1,4,7 ，10-四氮杂环十二烷，H4，以大大提高的产率和商业上可行的方式，包括以下步骤：将一定数量的1,2-双（2-氨基烷酰胺）苯溶解在由乙酸乙酯和二氯甲烷组成的溶液中以产生 第一反应溶液; 将一定数量的丙二酰二卤化物溶于乙酸乙酯溶液中以产生第二反应溶液; 将第一反应溶液和第二反应溶液加入到含有回流乙酸乙酯溶液和酸清除剂的第三反应溶液的反应容器中以形成反应混合物; 并通过过滤直接从反应混合物中分离由四氨基 - 大环化合物组成的固体产物。
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公开(公告)号：US5877315A
公开(公告)日：1999-03-02
申请号：US59112
申请日：1998-04-13
申请人： James E. Deline , Kevin A. Klotter
发明人： James E. Deline , Kevin A. Klotter
IPC分类号： C07D295/14 , C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06
CPC分类号： C07D295/15 , C11D3/38618 , C11D3/3925 , C11D3/3947 , C11D3/42 , D06L3/021 , D06L3/026 , H04B7/0619
摘要： Bleaching compositions are provided that comprise two nitrile groups where each nitrile is bonded to a quaternary nitrogen through a methylene unit. The quaternary nitrogens are part of a saturated ring. This saturated ring contains from two to eight atoms in addition to the quaternary nitrogen. A source of active oxygen will react with the nitriles for bleaching applications.
摘要翻译： 提供漂白组合物，其包含两个腈基团，其中每个腈通过亚甲基单元与季氮结合。 季氮是饱和环的一部分。 该饱和环除了季氮之外还含有2至8个原子。 活性氧源将与腈类反应，用于漂白应用。
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公开(公告)号：US06384279B1
公开(公告)日：2002-05-07
申请号：US09943536
申请日：2001-08-30
申请人： James E. Deline , Michael M. Ott
发明人： James E. Deline , Michael M. Ott
IPC分类号： C07C23102
CPC分类号： C07C233/18 , C07D257/02
摘要： A new composition of matter for a diamidodiol and a method for preparing the diamidodiol. The exemplary diamidodiol has the formula C15H30N2O4 and is prepared by reacting a first quantity of 2-amino-2-methyl-1-propanol with a second quantity of a di-substituted malonyl dichloride (i.e., diethylmalonyl dichloride), preferably in ethyl acetate as solvent. A tetraamido macrocycle is prepared from the diamidodiol in two steps by oxidizing the diamidodiol to form a diacid followed by coupling using a known procedure of the diacid with an aryl diamine (e.g., 1,2-diaminobenzene) to yield the tetraamido macrocycle.
摘要翻译： 二酰氨基二醇的新物质组合物和二酰胺二醇的制备方法。 示例性二酰氨基二醇具有式C 15 H 30 N 2 O 4，并且通过使第一量的2-氨基-2-甲基-1-丙醇与第二量的二取代丙二酰氯（即二乙基丙二酰氯）反应，优选在乙酸乙酯中反应制备，如 溶剂。 通过氧化二酰氨基二醇以形成二酸，然后使用二酸的已知方法与芳基二胺（例如1,2-二氨基苯）偶合，从二酰氨基二醇制备四酰氨基大环化合物，得到四酰胺大环化合物。
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公开(公告)号：US06297400B1
公开(公告)日：2001-10-02
申请号：US09347435
申请日：1999-07-02
申请人： James E. Deline , Michael M. Ott
发明人： James E. Deline , Michael M. Ott
IPC分类号： C07C23303
CPC分类号： C07C233/18 , C07D257/02
摘要： A new composition of matter for a diamidodiol and a method for preparing the diamidodiol. The exemplary diamidodiol has the formula C15H30N2O4 and is prepared by reacting a first quantity of 2-amino-2-methyl-1-propanol with a second quantity of a di-substituted malonyl dichloride (i.e., diethylmalonyl dichloride), preferably in ethyl acetate as solvent. A tetraamido macrocycle is prepared from the diamidodiol in two steps by oxidizing the diamidodiol to form a diacid followed by coupling using a known procedure of the diacid with an aryl diamine (e.g., 1,2-diaminobenzene)to yield the tetraamido macrocycle.
摘要翻译： 二酰氨基二醇的新物质组合物和二酰胺二醇的制备方法。 示例性二酰氨基二醇具有式C 15 H 30 N 2 O 4，并且通过使第一量的2-氨基-2-甲基-1-丙醇与第二量的二取代丙二酰氯（即二乙基丙二酰氯）反应，优选在乙酸乙酯中反应制备，如 溶剂。 通过氧化二酰氨基二醇以形成二酸，然后使用二酸的已知方法与芳基二胺（例如1,2-二氨基苯）偶合，从二酰氨基二醇制备四酰氨基大环化合物，得到四酰胺大环化合物。
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公开(公告)号：US6017464A
公开(公告)日：2000-01-25
申请号：US207797
申请日：1998-12-09
申请人： James E. Deline
发明人： James E. Deline
IPC分类号： C07D295/14 , C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06 , C09K3/00
CPC分类号： C07D295/15 , C11D3/38618 , C11D3/3925 , C11D3/3947 , C11D3/42 , D06L3/021 , D06L3/026 , H04B7/0619
摘要： Bleaching compositions are provided that comprise two nitrile groups where each nitrile is bonded to a quaternary nitrogen through a methylene unit. The quaternary nitrogens are part of a saturated ring. This saturated ring contains from two to eight atoms in addition to the quaternary nitrogen. A source of active oxygen will react with the nitrites for bleaching applications.
摘要翻译： 提供漂白组合物，其包含两个腈基团，其中每个腈通过亚甲基单元与季氮结合。 季氮是饱和环的一部分。 该饱和环除了季氮之外还含有2至8个原子。 活性氧源将与亚硝酸盐反应，用于漂白应用。
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