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    Synthesis of a tetraamido macrocycle ligand from a novel diamidodiol
    1.
    发明授权
    Synthesis of a tetraamido macrocycle ligand from a novel diamidodiol 失效
    从新型二酰氨基二醇合成四氨基大环配体

    公开(公告)号：US06384279B1

    公开(公告)日：2002-05-07

    申请号：US09943536

    申请日：2001-08-30

    申请人： James E. Deline ,  Michael M. Ott

    发明人： James E. Deline ,  Michael M. Ott

    IPC分类号： C07C23102

    CPC分类号： C07C233/18 ,  C07D257/02

    摘要： A new composition of matter for a diamidodiol and a method for preparing the diamidodiol. The exemplary diamidodiol has the formula C15H30N2O4 and is prepared by reacting a first quantity of 2-amino-2-methyl-1-propanol with a second quantity of a di-substituted malonyl dichloride (i.e., diethylmalonyl dichloride), preferably in ethyl acetate as solvent. A tetraamido macrocycle is prepared from the diamidodiol in two steps by oxidizing the diamidodiol to form a diacid followed by coupling using a known procedure of the diacid with an aryl diamine (e.g., 1,2-diaminobenzene) to yield the tetraamido macrocycle.

    摘要翻译： 二酰氨基二醇的新物质组合物和二酰胺二醇的制备方法。 示例性二酰氨基二醇具有式C 15 H 30 N 2 O 4，并且通过使第一量的2-氨基-2-甲基-1-丙醇与第二量的二取代丙二酰氯（即二乙基丙二酰氯）反应，优选在乙酸乙酯中反应制备，如 溶剂。 通过氧化二酰氨基二醇以形成二酸，然后使用二酸的已知方法与芳基二胺（例如1,2-二氨基苯）偶合，从二酰氨基二醇制备四酰氨基大环化合物，得到四酰胺大环化合物。

    Synthesis of a tetraamido macrocycle ligand from a novel diamidodiol
    2.
    发明授权
    Synthesis of a tetraamido macrocycle ligand from a novel diamidodiol 有权
    从新型二酰氨基二醇合成四氨基大环配体

    公开(公告)号：US06297400B1

    公开(公告)日：2001-10-02

    申请号：US09347435

    申请日：1999-07-02

    申请人： James E. Deline ,  Michael M. Ott

    发明人： James E. Deline ,  Michael M. Ott

    IPC分类号： C07C23303

    CPC分类号： C07C233/18 ,  C07D257/02

    摘要： A new composition of matter for a diamidodiol and a method for preparing the diamidodiol. The exemplary diamidodiol has the formula C15H30N2O4 and is prepared by reacting a first quantity of 2-amino-2-methyl-1-propanol with a second quantity of a di-substituted malonyl dichloride (i.e., diethylmalonyl dichloride), preferably in ethyl acetate as solvent. A tetraamido macrocycle is prepared from the diamidodiol in two steps by oxidizing the diamidodiol to form a diacid followed by coupling using a known procedure of the diacid with an aryl diamine (e.g., 1,2-diaminobenzene)to yield the tetraamido macrocycle.

    摘要翻译： 二酰氨基二醇的新物质组合物和二酰胺二醇的制备方法。 示例性二酰氨基二醇具有式C 15 H 30 N 2 O 4，并且通过使第一量的2-氨基-2-甲基-1-丙醇与第二量的二取代丙二酰氯（即二乙基丙二酰氯）反应，优选在乙酸乙酯中反应制备，如 溶剂。 通过氧化二酰氨基二醇以形成二酸，然后使用二酸的已知方法与芳基二胺（例如1,2-二氨基苯）偶合，从二酰氨基二醇制备四酰氨基大环化合物，得到四酰胺大环化合物。

    Synthesis of a tetraamido macrocycle ligand
    3.
    发明授权
    Synthesis of a tetraamido macrocycle ligand 失效
    四氨基大环配体的合成

    公开(公告)号：US6127536A

    公开(公告)日：2000-10-03

    申请号：US318410

    申请日：1999-05-25

    申请人： James E. Deline ,  Michael M. Ott ,  Kevin A. Klotter

    发明人： James E. Deline ,  Michael M. Ott ,  Kevin A. Klotter

    IPC分类号： C07D257/10 ,  C07D225/00

    CPC分类号： C07D257/10

    摘要： An improved synthesis for preparing a tetraamido-macrocyclic ligand, such as 5,6-Benzo-3,8,11,13-tetraoxo-2,2,9,9-tetramethyl-12,12-diethyl-1,4,7,10-tetraazacyclotridecane, H.sub.4, in greatly improved yield and in a commercially viable manner, comprising the steps of dissolving a quantity of a 1,2-bis(2-aminoalkanamido)benzene in a solution comprised of ethyl acetate and methylene chloride to yield a first reaction solution; dissolving a quantity of a malonyl dihalide in an ethyl acetate solution to yield a second reaction solution; adding the first reaction solution and the second reaction solution to a reaction vessel containing a third reaction solution comprised of refluxing ethyl acetate solution and an acid scavenger to form a reaction mixture; and isolating a solid product comprised of the tetraamido-macrocycle directly from the reaction mixture by filtration.

    摘要翻译： 用于制备四氨基 - 大环配体的改进的合成物，例如5,6-苯并-3,8,11,13-四氧代-2,2,9,9-四甲基-1,12,12-二乙基-1,4,7 ，10-四氮杂环十二烷，H4，以大大提高的产率和商业上可行的方式，包括以下步骤：将一定数量的1,2-双（2-氨基烷酰胺）苯溶解在由乙酸乙酯和二氯甲烷组成的溶液中以产生 第一反应溶液; 将一定数量的丙二酰二卤化物溶于乙酸乙酯溶液中以产生第二反应溶液; 将第一反应溶液和第二反应溶液加入到含有回流乙酸乙酯溶液和酸清除剂的第三反应溶液的反应容器中以形成反应混合物; 并通过过滤直接从反应混合物中分离由四氨基 - 大环化合物组成的固体产物。

    Liquid compositions containing N-alkyl ammonium acetonitrile salts
    5.
    发明授权
    Liquid compositions containing N-alkyl ammonium acetonitrile salts 失效
    含有N-烷基铵乙腈盐的液体组合物

    公开(公告)号：US6046150A

    公开(公告)日：2000-04-04

    申请号：US303009

    申请日：1999-04-30

    申请人： Clement K. Choy ,  James E. Deline ,  Lafayette D. Foland ,  Aram Garabedian, Jr. ,  Kevin A. Klotter ,  Michael J. Petrin ,  Martin J. Phillippi ,  William L. Smith

    发明人： Clement K. Choy ,  James E. Deline ,  Lafayette D. Foland ,  Aram Garabedian, Jr. ,  Kevin A. Klotter ,  Michael J. Petrin ,  Martin J. Phillippi ,  William L. Smith

    IPC分类号： C07D295/14 ,  C07D295/15 ,  C11D3/28 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  C11D17/04 ,  C11D17/08 ,  D06L3/02 ,  H04B7/06 ,  C11D17/00

    CPC分类号： C07D295/15 ,  C11D17/041 ,  C11D3/38618 ,  C11D3/3925 ,  C11D3/3947 ,  C11D3/42 ,  D06L3/021 ,  D06L3/026 ,  H04B7/0619

    摘要： The invention provides liquid cleaning or bleaching compositions containing compounds having the structure of Formula I ##STR1## wherein A is a saturated ring formed by five atoms in addition to the N.sub.1 atom, the five saturated ring atoms being four carbon atoms and a heteroatom, the substituent R.sub.1 bound to the N.sub.1 atom of the Formula I structure including either (a) a C.sub.1-24 alkyl or alkoxylated alkyl where the alkoxy is C.sub.2-4, (b) a C.sub.4-24 cycloalkyl, (c) a C.sub.7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C.sub.2-4, or (e) --CR.sub.2 R.sub.3 CN where R.sub.2 and R.sub.3 are each H, a C.sub.1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C.sub.2-4, the R.sub.2 and R.sub.3 substituents are each H, a C.sub.1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C.sub.2-4, and wherein Y is a generally anionic counterion and Z is in the range of 0 to 10. Additional, adjunct materials commonly found in liquid cleaning and bleaching compositions can be added.

    摘要翻译： 本发明提供了含有具有式I结构的化合物的液体清洗或漂白组合物，其中A是除N1原子以外的五个原子形成的饱和环，五个饱和环原子是四个碳原子和一个杂原子，取代基R 1结合 包括（a）C1-24烷基或烷氧基烷基，其中烷氧基是C2-4，（b）C4-24环烷基，（c）C7-24烷芳基，（d） ）重复或不重复的烷氧基或烷氧基化醇，其中烷氧基单元是C 2-4，或（e）-CR 2 R 3 CN，其中R 2和R 3各自为H，C 1-4烷基，环烷基或烷芳基，或重复或非重复烷氧基 或烷氧基化醇，其中烷氧基单元为C 2-4，R 2和R 3取代基各自为H，C 1-4烷基，环烷基或烷芳基，或重复或非重复烷氧基或烷氧基化醇，其中烷氧基单元为C 2-4， 并且其中Y是通常为阴离子的抗衡离子，Z在0至10的范围内。另外， 通常可以添加在液体清洗和漂白组合物中发现的辅助材料。

    N-alkyl ammonium acetonitrile salts, methods therefor and compositions therewith
    7.
    发明授权
    N-alkyl ammonium acetonitrile salts, methods therefor and compositions therewith 失效
    N-烷基铵乙腈盐，其方法和组合物

    公开(公告)号：US06764613B2

    公开(公告)日：2004-07-20

    申请号：US09849388

    申请日：2001-05-03

    申请人： Ulrich Annen ,  James E. Deline ,  Kevin A. Klotter ,  Michael Müller ,  Klaus Mundinger ,  Sarah A. Perkins ,  Martin J. Phillippi ,  Martin Scholtissek ,  Michael Schönherr ,  William L. Smith ,  Alfred G. Zielske

    发明人： Ulrich Annen ,  James E. Deline ,  Kevin A. Klotter ,  Michael Müller ,  Klaus Mundinger ,  Sarah A. Perkins ,  Martin J. Phillippi ,  Martin Scholtissek ,  Michael Schönherr ,  William L. Smith ,  Alfred G. Zielske

    IPC分类号： C09K300

    CPC分类号： C11D3/3925 ,  C07D295/15 ,  D06L4/12

    摘要： Substantially solid compositions are provided having therein a compound with the structure of Formula I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) —CR2R3C≡N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is a value in the range of 0 to 10, and wherein Y is monovalent or multivalent and is sulfate, bisulfate, tosylate, or mixtures of sulfate and bisulfate as counterion. These compositions have reduced water uptake due to the Formula I compound.

    摘要翻译： 其中提供了具有式I结构的化合物的基本固体组合物，其中A是除了N1原子之外由多个原子形成的饱和环，饱和环原子包括至少一个碳原子和至少一个O， S和N原子，与式I结构的N1原子结合的取代基R1包括（a）C1-24烷基或烷氧基为烷氧基的烷基，C2烷基，（b）C4-24环烷基，（ c）C7-24烷芳基，（d）重复或不重复的烷氧基或烷氧基化醇，其中烷氧基单元是C 2-4，或（e）-CR 2 R 3 C = N，其中R 2和R 3各自为H， ，环烷基或烷芳基，或重复或非重复烷氧基或烷氧基化醇，其中烷氧基单元为C 2-4，R 2和R 3取代基各为H，C 1-4烷基，环烷基或烷芳基，或重复或非重复烷氧基 或烷氧基化醇，其中烷氧基单元为C2-4，Z为0至10的范围内的值，并且其中Y为单价或mu 是硫酸盐，硫酸氢盐，甲苯磺酸盐，或硫酸盐和硫酸氢盐的混合物作为抗衡离子。 这些组合物由于式I化合物而降低了吸水率。