公开(公告)号：US10000610B2

公开(公告)日：2018-06-19

申请号：US14912161

申请日：2014-08-15

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, Jr. ,  Daryoosh Beigzadeh ,  Duane R. Romer ,  Thomas P. Clark ,  Peter Margl ,  Congcong Lu

IPC: C08G73/00 ,  C08G71/04 ,  C09D175/12 ,  C08G65/333

CPC classification number: C08G71/04 ,  C08G65/33306 ,  C08G65/33324 ,  C09D175/12

Abstract: A process to prepare polycarbamate comprising adding urea to a polyol in the presence of at least one catalyst selected from the group consisting of compounds having the following formula MmZn; wherein M is a divalent metal, and Z is an anionic functionality or a functionality capable of forming a covalent bond with M and wherein n times a valence number of Z equals X and m times two equals Y wherein the absolute value of X equals the absolute value of Y is provided. Also provided are a polycarbamate produced according to the process and a coating composition comprising the polycarbamate.

公开(公告)号：US20160200871A1

公开(公告)日：2016-07-14

申请号：US14912161

申请日：2014-08-15

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Xinrui Yu ,  Ylyong He ,  John W. Hull, JR. ,  Daryoosh Beigzadeh ,  Duane R. Romer ,  Thomas P. Clark ,  Peter Margl ,  Congcong Lu

IPC: C08G71/04 ,  C09D175/12

CPC classification number: C08G71/04 ,  C08G65/33306 ,  C08G65/33324 ,  C09D175/12

Abstract: A process to prepare polycarbamate comprising adding urea to a polyol in the presence of at least one catalyst selected from the group consisting of compounds having the following formula MmZn; wherein M is a divalent metal, and Z is an anionic functionality or a functionality capable of forming a covalent bond with M and wherein n times a valence number of Z equals X and m times two equals Y wherein the absolute value of X equals the absolute value of Y is provided. Also provided are a polycarbamate produced according to the process and a coating composition comprising the polycarbamate.

Abstract translation: 一种制备聚氨酯的方法，包括在至少一种选自具有下式MmZn的化合物的催化剂存在下将多元醇加入到多元醇中; 其中M是二价金属，Z是阴离子官能团或能够与M形成共价键的官能团，并且其中Z的数量等于X并且m倍的2倍等于Y，其中X的绝对值等于绝对值 提供了Y值。 还提供了根据该方法制备的聚氨酯和包含聚氨酯的涂料组合物。

公开(公告)号：US20160185713A1

公开(公告)日：2016-06-30

申请号：US14912157

申请日：2014-08-15

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull ,  Daryoosh Beigzadeh ,  Duane Romer ,  Thomas Clark ,  Peter Margi ,  Congcong Lu

IPC: C07C269/00 ,  C07C271/10 ,  C09D7/12

CPC classification number: C07C269/00 ,  C07C271/10 ,  C08G65/33303 ,  C08G65/33324 ,  C08G71/04 ,  C09D7/63 ,  C09D175/04

Abstract: A process to prepare polycarbamate comprising adding urea to a polyol in the presence of at least one catalyst selected from the group consisting of compounds having the following formula MmZn; wherein M is a trivalent metal, and Z is an anionic functionality or a functionality capable of forming a covalent bond with M and wherein n times a valence number of Z equals X and m times three equals Y wherein the absolute value of X equals the absolute value of Y is provided. Also provided are a polycarbamate produced according to the process and a coating composition comprising the polycarbamate.

Abstract translation: 一种制备聚氨酯的方法，包括在至少一种选自具有下式MmZn的化合物的催化剂存在下将多元醇加入到多元醇中; 其中M是三价金属，Z是阴离子官能团或能够与M形成共价键的官能团，并且其中Z的数量等于X，m的三倍等于Y，其中X的绝对值等于绝对值 提供了Y值。 还提供了根据该方法制备的聚氨酯和包含聚氨酯的涂料组合物。

公开(公告)号：US20160145466A1

公开(公告)日：2016-05-26

申请号：US14900106

申请日：2014-06-18

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Gary E. Spilman ,  Jeff R. Anderson ,  John N. Argyropoulos ,  Paul Foley ,  Xinrui Yu ,  John W. Hull ,  Congcong Lu ,  Daryoosh Beigzadeh

IPC: C09D175/12

CPC classification number: C09D175/12 ,  C09D161/24 ,  C09D167/00 ,  C09D167/08 ,  C08L67/08

Abstract: The instant invention provides a crosslinkable coating composition, and method of producing the same. The crosslinkable coating composition according to the present invention comprises: (a) one or more polycarbamates derived from one or more polyesters comprising the condensation reaction product of one or more polyols with one or more polyacids, wherein said one or more polyols comprise at least 25 percent by weight of one or more units having 4 or more hydroxyl groups; (b) one or more crosslinking agents; (c) one or more acid catalysts; and (d) optionally one or more organic solvents.

Abstract translation: 本发明提供一种可交联涂料组合物及其制备方法。 根据本发明的可交联涂料组合物包含：（a）一种或多种衍生自一种或多种聚酯的聚氨酯，其包含一种或多种多元醇与一种或多种多元酸的缩合反应产物，其中所述一种或多种多元醇包含至少25 一个或多个具有4个或更多个羟基的单元的重量百分比; （b）一种或多种交联剂; （c）一种或多种酸催化剂; 和（d）任选的一种或多种有机溶剂。

公开(公告)号：US20180265458A1

公开(公告)日：2018-09-20

申请号：US15986271

申请日：2018-05-22

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, JR. ,  Daryoosh Beigzadeh ,  Duane R. Romer ,  Thomas P. Clark ,  Peter Margl ,  Congcong Lu

IPC: C07C269/00 ,  C09D7/63 ,  C07C271/10 ,  C08G65/333 ,  C08G71/04 ,  C09D175/04

CPC classification number: C07C269/00 ,  C07C271/10 ,  C08G65/33303 ,  C08G65/33324 ,  C08G71/04 ,  C09D7/63 ,  C09D175/04

Abstract: A process to prepare polycarbamate comprising adding urea to a polyol in the presence of at least one catalyst selected from the group consisting of compounds having the following formula MmZn; wherein M is a trivalent metal, and Z is an anionic functionality or a functionality capable of forming a covalent bond with M and wherein n times a valence number of Z equals X and m times three equals Y wherein the absolute value of X equals the absolute value of Y is provided. Also provided are a polycarbamate produced according to the process and a coating composition comprising the polycarbamate.

公开(公告)号：US20180258224A1

公开(公告)日：2018-09-13

申请号：US15980769

申请日：2018-05-16

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, JR. ,  Daryoosh Beigzadeh ,  Duane R. Romer ,  Thomas P. Clark ,  Peter Margl ,  Congcong Lu

IPC: C08G71/04 ,  C08G65/333 ,  C09D175/12

Abstract: A process to prepare polycarbamate comprising adding urea to a polyol in the presence of at least one catalyst selected from the group consisting of compounds having the following formula MmZn; wherein M is a divalent metal, and Z is an anionic functionality or a functionality capable of forming a covalent bond with M and wherein n times a valence number of Z equals X and m times two equals Y wherein the absolute value of X equals the absolute value of Y is provided. Also provided are a polycarbamate produced according to the process and a coating composition comprising the polycarbamate.

公开(公告)号：US09822280B2

公开(公告)日：2017-11-21

申请号：US14900106

申请日：2014-06-18

Applicant: Dow Global Technologies LLC

Inventor： Gary E. Spilman ,  Jeff R. Anderson ,  John N. Argyropoulos ,  Paul Foley ,  Xinrui Yu ,  John W. Hull ,  Congcong Lu ,  Daryoosh Beigzadeh ,  Yiyong He

IPC: C08K5/05 ,  C08G69/44 ,  C08G73/10 ,  C08L77/00 ,  C08G63/02 ,  C09D175/12 ,  C09D167/00 ,  C09D167/08 ,  C09D161/24

CPC classification number: C09D175/12 ,  C09D161/24 ,  C09D167/00 ,  C09D167/08 ,  C08L67/08

Abstract: The instant invention provides a crosslinkable coating composition, and method of producing the same. The crosslinkable coating composition according to the present invention comprises: (a) one or more polycarbamates derived from one or more polyesters comprising the condensation reaction product of one or more polyols with one or more polyacids, wherein said one or more polyols comprise at least 25 percent by weight of one or more units having 4 or more hydroxyl groups; (b) one or more crosslinking agents; (c) one or more acid catalysts; and (d) optionally one or more organic solvents.

公开(公告)号：US09796815B2

公开(公告)日：2017-10-24

申请号：US13955507

申请日：2013-07-31

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, Jr. ,  Paul Foley

IPC: C08G71/04 ,  C08G65/333

CPC classification number: C08G71/04 ,  C08G65/33303

Abstract: A first process to produce polycarbamate comprising providing urea in liquid form; and adding the liquid urea to a polyol is provided. A second process for producing polycarbamate comprising adding solid urea to a polyol in liquid form to form a reaction mixture is provided. Also provided is a reaction product produced by the first process or second process.

公开(公告)号：US20160177033A1

公开(公告)日：2016-06-23

申请号：US14908843

申请日：2014-07-28

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Xinrui Yu ,  Yiyong He ,  Ronald H. Leng

IPC: C08G71/04 ,  B01J19/24

CPC classification number: C08G71/04 ,  B01J19/24 ,  B01J2219/00164 ,  B01J2219/24 ,  C08G65/33303 ,  C09D161/24 ,  C09D175/12

Abstract: A process to produce polycarbamate comprising providing urea in liquid form; and adding the urea in liquid form to a polyol in a reduced gradient profile to form polycarbamate product is provided. Also provided are: (a) a reaction product of the process and (b) an apparatus for operating the process.

Abstract translation: 一种生产聚氨酯的方法，包括以液体形式提供尿素; 并提供液体形式的脲以减少的梯度曲线形式制成多元醇以形成聚氨酯。 还提供了：（a）该方法的反应产物和（b）用于操作该方法的装置。

公开(公告)号：US20150038670A1

公开(公告)日：2015-02-05

申请号：US13955507

申请日：2013-07-31

Applicant: Dow Global Technologies LLC

Inventor： Xinrui Yu ,  Yiyong He ,  John W. Hull, JR. ,  Paul Foley

IPC: C08G71/04

CPC classification number: C08G71/04 ,  C08G65/33303

Abstract: A first process to produce polycarbamate comprising providing urea in liquid form; and adding the liquid urea to a polyol is provided. A second process for producing polycarbamate comprising adding solid urea to a polyol in liquid form to form a reaction mixture is provided. Also provided is a reaction product produced by the first process or second process.

Abstract translation: 生产聚氨酯的第一种方法，包括提供液态尿素; 并提供液态尿素至多元醇。 提供了生产聚氨酯的第二种方法，其包括将固体尿素加入到液体形式的多元醇中以形成反应混合物。 还提供了通过第一工艺或第二工艺生产的反应产物。