公开(公告)号：US20240336043A1

公开(公告)日：2024-10-10

申请号：US18293804

申请日：2021-10-22

Applicant: Dow Global Technologies LLC

Inventor： Bo Liu ,  Feng Chen ,  Zhe Zhou ,  Wesley R. Mariott ,  Chuan C. He

IPC: B32B27/08 ,  B32B27/32

CPC classification number: B32B27/08 ,  B32B27/32 ,  B32B2250/03 ,  B32B2250/242 ,  B32B2307/72

Abstract: A multilayer film comprising at least three layers including (a) at least a first polyolefin layer, wherein the at least first polyolefin layer comprises a first outer layer of the multilayer film: (b) at least a second polyolefin layer, wherein the at least second polyolefin layer comprises a core layer of the multilayer film; and (c) at least a third polyolefin layer, wherein the at least third polyolefin layer comprises a second outer layer (or other layer such as a sealant layer) of the multilayer film: wherein the layers are as described.

公开(公告)号：US20200024380A1

公开(公告)日：2020-01-23

申请号：US16338164

申请日：2017-09-29

Applicant: Dow Global Technologies LLC

Inventor： Lixin Sun ,  Zhe Zhou ,  Edmund M. Carnahan ,  Kim L. Walton

IPC: C08F210/02 ,  C08F4/659

Abstract: The present disclosure relates to a capped, multi- or dual-headed chain composition comprising derivatives of a strained olefin. The present disclosure further relates to a process for synthesizing the capped, multi- or dual-headed composition by using an organometallic compound and a co-catalyst in the presence of a catalyst precursor and a strained olefm. The present disclosure further relates to use of the compositions, as well as the process to make the same, in olefin polymerization.

公开(公告)号：US20190225724A1

公开(公告)日：2019-07-25

申请号：US16314283

申请日：2017-06-30

Applicant: Dow Global Technologies LLC

Inventor： Juan Tuberquia ,  Colin LiPiShan ,  Zhe Zhou

IPC: C08F210/18 ,  G01N33/44 ,  G01N24/08

Abstract: A composition comprising an ethylene/alpha-olefin/non-conjugated polyene, and wherein the ethylene/alpha-olefin/O non-conjugated polyene comprises the following property: a “13C NMR % iCB Peak Area,” which is the {[(13C NMR peak area from 34.4 ppm to 34.6 ppm) divided by (the 13C NMR sum integral area from 160.0 to 100.0 and from 60.0 ppm to 0.00 ppm)]×100}, that is >0.010%, as determined by 13C NMR.

公开(公告)号：US20150315385A1

公开(公告)日：2015-11-05

申请号：US14649663

申请日：2013-12-10

Applicant: Dow Global Technologies LLC

Inventor： Nicole L. Wagner ,  David J. Brennan ,  Matthew D. Miller ,  Pramod D. Patil ,  Subrata Sen ,  Zhe Zhou

IPC: C08L95/00

CPC classification number: C08K5/18 ,  C08K5/05 ,  C08K5/17 ,  C08K5/315 ,  C08L2205/06 ,  C08L2555/40 ,  C08L2555/60 ,  C08L2555/74 ,  Y10T137/0318 ,  C08L95/00

Abstract: A bitumen transport composition is provided comprising bitumen, a diluent in an amount of 24 weight percent or less and an additive wherein the additive is a mono-alcohol, a mono-nitrile, an amine or mixtures thereof. Also provided is a method to make the bitumen transport composition. Also provided is a method to transport the bitumen transport composition.

Abstract translation: 提供的沥青输送组合物包括沥青，24重量％或更少的稀释剂和添加剂，其中所述添加剂是单醇，单腈，胺或其混合物。 还提供了制造沥青输送组合物的方法。 还提供了运输沥青输送组合物的方法。

公开(公告)号：US20240010779A1

公开(公告)日：2024-01-11

申请号：US18254956

申请日：2021-12-16

Applicant: Dow Global Technologies LLC ,  Northwestern University

Inventor： Evelyn Auyeung ,  Rhett A. Baillie ,  Thomas Wesley Karjala, JR. ,  Zhe Zhou ,  Jeffrey C. Munro ,  Colin Li Pi Shan ,  Phillip D. Hustad ,  Tobin J. Marks ,  Yanshan Gao

IPC: C08F297/08

CPC classification number: C08F297/083

Abstract: A process to form a composition comprising an ethylene/vinylarene multiblock interpolymer, said process comprising polymerizing, in a single reactor, a mixture comprising ethylene, a vinylarene, and optionally an alpha-olefin, in the presence of at least the following a)-c): a) a first metal complex selected from the following Formula (A), as described herein: b) a second metal complex selected from the following Formula (B), as described herein, and c) a chain shuttling agent selected from the following: a dialkyl zinc, a trialkyl aluminum, or a combination thereof. A composition comprising an ethylene/vinylarene multiblock interpolymer comprising at least one polymer structure selected from: -(AR)-(AP)-(AR)-(AP)- (Structure 1), or (AR)-(AP)-(AR)-(AP) (Structure 2); where each (AR) segment independently comprises, in polymerized form, ethylene, >10 mol % of the vinylarene and optionally an alpha-olefin, and wherein each (AP) segment independently comprises, ethylene, optionally ≤10 mol % vinylarene and optionally the alpha-olefin.

公开(公告)号：US20230058913A1

公开(公告)日：2023-02-23

申请号：US17788856

申请日：2020-12-23

Applicant: Dow Global Technologies LLC

Inventor： Stacy L. Pesek ,  Jeffrey C. Munro ,  Zhe Zhou ,  Andrew J. Young ,  Anthony J. Castelluccio ,  Thomas Wesley Karjala, Jr.

IPC: C08F297/08

Abstract: The present disclosure provides a process. In an embodiment, the process includes contacting ethylene and octene under polymerization conditions at a temperature greater than 125° C. with a catalyst system comprising (i) a first polymerization catalyst having the structure of Formula (III), a second polymerization catalyst having the structure of Formula (I), and (iii) a chain shuttling agent. The process includes forming an ethylene/octene multi-block copolymer having a normalized OOO triad content greater than 0.25. The present disclosure provides the resultant composition produced by the process. In an embodiment, the composition includes an ethylene/octene multi-block copolymer having a normalized OOO triad content greater than 0.25.

公开(公告)号：US20220073656A1

公开(公告)日：2022-03-10

申请号：US16338267

申请日：2017-09-29

Applicant: Dow Global Technologies LLC

Inventor： Lixin Sun ,  Zhe Zhou ,  Jaclyn Murphy ,  Edmund M. Carnahan

IPC: C08F10/14 ,  C08F4/659

Abstract: The present disclosure relates to a process for synthesizing a multi- or dual-headed composition by using an alpha,omega-diene and an organometallic compound in the presence of a catalyst precursor. The present disclosure further relates to use of the compositions, as well as the process to make the same, in olefin polymerization.

公开(公告)号：US09908956B2

公开(公告)日：2018-03-06

申请号：US15216473

申请日：2016-07-21

Applicant: Dow Global Technologies LLC

Inventor： Lawrence J. Effler ,  Teresa P. Karjala ,  Mehmet Demirors ,  Nilesh R. Savargaonkar ,  Selim Bensason ,  Zhe Zhou

IPC: C08F2/06 ,  C08F210/16 ,  C08L23/20 ,  C08J3/20 ,  C08J5/18 ,  C08L23/08 ,  C08K5/524 ,  C08F10/02 ,  C08L23/06 ,  C08K5/134 ,  C08K5/52

CPC classification number: C08F210/16 ,  C08F2/06 ,  C08F10/02 ,  C08J3/201 ,  C08J5/18 ,  C08J2323/06 ,  C08J2323/08 ,  C08K5/134 ,  C08K5/52 ,  C08K5/524 ,  C08L23/06 ,  C08L23/08 ,  C08L23/0815 ,  C08L23/20 ,  C08F210/14 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/17

Abstract: An ethylene/α-olefin copolymer comprising units derived from ethylene; and units derived from at least one α-olefin; wherein the ethylene/α-olefin copolymer has a density in the range of from 0.90 to 0.94 g/cc; a melt index (I2) in the range of from 0.05 to 50 dg/min; an Mw/Mn of from 3 to 5; and from 300 to 500 vinyl unsaturations per 1,000,000 carbon atoms in the ethylene/α-olefin copolymer is provided. Also provided is a process for producing an ethylene/α-olefin copolymer comprising: (1) polymerizing ethylene and one or more α-olefins in a polymerization reactor; (2) thereby producing an enhanced melt strength ethylene/α-olefin copolymer having from 300 to 500 vinyl unsaturation units per 1,000,000 carbon atoms, a density in the range of from 0.90 to 0.94 g/cc; a melt index (I2) in the range of from 0.05 to 50 dg/min; and a Mw/Mn of from 3 to 5.

公开(公告)号：US20160326283A1

公开(公告)日：2016-11-10

申请号：US15216473

申请日：2016-07-21

Applicant: Dow Global Technologies LLC

Inventor： Lawrence J. Effler ,  Teresa P. Karjala ,  Mehmet Demirors ,  Nilesh R. Savargaonkar ,  Selim Bensason ,  Zhe Zhou

IPC: C08F210/16 ,  C08K5/52 ,  C08K5/134

CPC classification number: C08F210/16 ,  C08F2/06 ,  C08F10/02 ,  C08J3/201 ,  C08J5/18 ,  C08J2323/06 ,  C08J2323/08 ,  C08K5/134 ,  C08K5/52 ,  C08K5/524 ,  C08L23/06 ,  C08L23/08 ,  C08L23/0815 ,  C08L23/20 ,  C08F210/14 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/17

Abstract: An ethylene/α-olefin copolymer comprising units derived from ethylene; and units derived from at least one α-olefin; wherein the ethylene/α-olefin copolymer has a density in the range of from 0.90 to 0.94 g/cc; a melt index (I2) in the range of from 0.05 to 50 dg/min; an Mw/Mn of from 3 to 5; and from 300 to 500 vinyl unsaturations per 1,000,000 carbon atoms in the ethylene/α-olefin copolymer is provided. Also provided is a process for producing an ethylene/α-olefin copolymer comprising: (1) polymerizing ethylene and one or more α-olefins in a polymerization reactor; (2) thereby producing an enhanced melt strength ethylene/α-olefin copolymer having from 300 to 500 vinyl unsaturation units per 1,000,000 carbon atoms, a density in the range of from 0.90 to 0.94 g/cc; a melt index (I2) in the range of from 0.05 to 50 dg/min; and a Mw/Mn of from 3 to 5.

Abstract translation: 包含衍生自乙烯的单元的乙烯/α-烯烃共聚物; 和衍生自至少一种α-烯烃的单元; 其中所述乙烯/α-烯烃共聚物的密度在0.90至0.94g / cc的范围内; 熔体指数（I 2）在0.05至50dg / min的范围内; Mw / Mn为3至5; 并且提供了乙烯/α-烯烃共聚物中每100万个碳原子的300-500个乙烯基不饱和度。 还提供了一种生产乙烯/α-烯烃共聚物的方法，包括：（1）在聚合反应器中聚合乙烯和一种或多种α-烯烃; （2），由此产生具有每1,000,000个碳原子具有300-500个乙烯基不饱和单元的增强的熔融强度乙烯/α-烯烃共聚物，密度在0.90-0.94g / cc范围内; 熔体指数（I 2）在0.05至50dg / min的范围内; Mw / Mn为3〜5。