公开(公告)号：US20190240901A1

公开(公告)日：2019-08-08

申请号：US16318763

申请日：2017-07-21

Applicant: DSM IP Assets B.V.

Inventor： Johan Franz Gradus Antonius JANSEN ,  Rudolfus Antonius Theodorus Maria VAN BENTHEM ,  Paulus Franciscus Anna BUIJSEN ,  Franciscus Johannes Marie DERKS ,  Mark Petrus Franciscus PEPELS ,  Alfred Jean Paul BUCKMANN

IPC: B29C64/165 ,  C08F290/06 ,  C08F220/18 ,  C08F2/48 ,  C08K3/013 ,  C08L75/02 ,  C08L75/14 ,  B29C64/393 ,  B29C64/291

CPC classification number: B29C64/165 ,  B29C64/393 ,  B33Y10/00 ,  B33Y70/00 ,  C08F216/125 ,  C08F220/18 ,  C08F290/06 ,  C08F290/061 ,  C08G18/227 ,  C08G18/3206 ,  C08G18/4211 ,  C08G18/672 ,  C08G18/73 ,  C08G18/755 ,  C08G18/8016 ,  C08K5/14 ,  C08K5/17 ,  C08L67/06 ,  C08L75/14 ,  C08G18/42

Abstract: A method of forming a three-dimensional object comprises the steps of forming a layer of a particulate composition, selectively depositing a liquid composition onto the layer of the particulate composition in accordance with computer data corresponding to the shape of at least a portion of a three-dimensional object, and repeating the steps a plurality of times to form a three-dimensional object. The particulate composition comprises a plurality of first particles that comprise a resin component comprising a first resin, the first resin comprising a first resin polymerizable group. Either or both of the particulate composition and the liquid composition comprise an initiator capable of initiating polymerization of at least the first resin. At least the first resin undergoes melting and polymerization in a plurality of the locations where the liquid composition has been selectively deposited.

公开(公告)号：US20190240900A1

公开(公告)日：2019-08-08

申请号：US16318754

申请日：2017-07-21

Applicant: DSM IP Assets B.V

Inventor： Johan Franz Gradus Antonius JANSEN ,  Rudolfus Antonius Theodorus Maria VAN BENTHEM ,  Paulus Franciscus Anna BUIJSEN ,  Franciscus Johannes Marie DERKS ,  Mark Petrus Franciscus PEPELS ,  Alfred Jean Paul BUCKMANN

IPC: B29C64/165 ,  C08F216/12 ,  C08F220/18 ,  C08F290/06 ,  C08K5/14 ,  C08K5/17 ,  C08L75/14 ,  C08L67/06

CPC classification number: B29C64/165 ,  B29C64/393 ,  B33Y10/00 ,  B33Y70/00 ,  C08F216/125 ,  C08F220/18 ,  C08F290/06 ,  C08F290/061 ,  C08G18/227 ,  C08G18/3206 ,  C08G18/4211 ,  C08G18/672 ,  C08G18/73 ,  C08G18/755 ,  C08G18/8016 ,  C08K5/14 ,  C08K5/17 ,  C08L67/06 ,  C08L75/14 ,  C08G18/42

Abstract: A method of forming a three-dimensional object comprises the steps of forming a layer of a particulate composition, selectively depositing a liquid composition onto the layer of the particulate composition in accordance with computer data corresponding to the shape of at least a portion of a three-dimensional object, initiating polymerization, and repeating the steps a plurality of times to form a three-dimensional object. The particulate composition comprises a plurality of first particles that comprise a resin component comprising a first resin, the first resin comprising a first resin polymerizable group, the first resin polymerizable group comprising a carbon-carbon double bond directly attached to an electron withdrawing group, a thermal radical initiator dispersed or dissolved in the resin component, and a retardant dispersed or dissolved in the resin component.

公开(公告)号：US20160264817A1

公开(公告)日：2016-09-15

申请号：US15026340

申请日：2014-11-21

Applicant: DSM IP ASSETS B.V.

Inventor： Jozef Johannes Catherina Jacobus BOONEN ,  Johan Franz Gradus Antonius JANSEN ,  Jacob Leendert DE HAAS ,  Petrus Henricus Marinus WELLENBERG ,  Gerrit Johannes DE LANGE ,  Kurt VAN DURME ,  Hugo Gerrit Barend RENKEMA

IPC: C09D167/06

CPC classification number: C09D167/06 ,  C08F220/10 ,  C09D4/00

Abstract: The invention relates to thermosetting powder coating compositions comprising an unsaturated resin comprising ethylenic unsaturations and a thermal radical initiator comprising a first thermal radical initiator, wherein the first thermal radical initiator is a methyl-substituted benzoyl peroxide abbreviated herein as MBPO. The invention further relates to a process for making said thermosetting powder coating composition and processes for coating an article with said thermosetting powder coating composition. The invention further relates to a cured thermosetting powder coating composition derived upon curing of the thermosetting powder coating composition of the invention. The invention further relates to an article having coated thereon said thermosetting powder coating composition as well as to an article having coated and cured thereon said thermosetting powder coating composition. The invention further relates to the use of said thermosetting powder coating composition, to the use of an article having coated thereon said thermosetting powder coating composition and to the use of an article having coated and cured thereon said thermosetting powder coating composition. The invention further relates to cured thermosetting powder coating compositions derived upon curing of the thermosetting powder coating compositions comprising an unsaturated resin comprising ethylenic unsaturations and a first thermal radical initiator, said first thermal radical initiator being methyl-substituted benzoyl peroxide, abbreviated herein as MBPO. The invention further relates to the use of MBPO for thermosetting powder coating compositions and especially wherein the thermosetting powder coating compositions are heat-curable at low temperatures on heat-sensitive articles.

Abstract translation: 本发明涉及热固性粉末涂料组合物，其包含包含烯属不饱和基团的不饱和树脂和包含第一热自由基引发剂的热自由基引发剂，其中第一热自由基引发剂是本文缩写为甲基取代的苯甲酰基作为MBPO。 本发明还涉及制备所述热固性粉末涂料组合物的方法和用所述热固性粉末涂料组合物涂覆制品的方法。 本发明还涉及一种固化的本发明的热固性粉末涂料组合物固化的热固性粉末涂料组合物。 本发明还涉及在其上涂覆有所述热固性粉末涂料组合物的制品以及在其上涂覆和固化的所述热固性粉末涂料组合物的制品。 本发明还涉及所述热固性粉末涂料组合物在使用其上涂覆有所述热固性粉末涂料组合物的制品的用途，以及使用其上涂覆和固化的所述热固性粉末涂料组合物的用途。 本发明还涉及固化的热固性粉末涂料组合物，该组合物包含含有烯属不饱和基团的不饱和树脂和第一热自由基引发剂，所述第一热自由基引发剂为甲基取代的过氧化苯甲酰，本文缩写为MBPO。 本发明还涉及MBPO用于热固性粉末涂料组合物的用途，特别是其中热固性粉末涂料组合物在低温下对热敏性物品是可热固化的。