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公开(公告)号：US09201302B2
公开(公告)日：2015-12-01
申请号：US14044912
申请日：2013-10-03
CPC分类号： G03F7/033 , B41C1/1008 , B41C2210/04 , B41C2210/06 , B41C2210/24 , G03F7/0388 , G03F7/20
摘要： Negative-working lithographic printing plate precursors have improved bakeability and good shelf life and can be imaged using either UV or infrared radiation. These precursors have a negative-working imageable layer that has a unique polymeric binder comprising a polymeric backbone and further comprising at least (a) and (b) pendant groups distributed in random order along the polymeric backbone. The (a) pendant groups are ethylenically unsaturated polymerizable groups, and the (b) pendant groups are defined by Structures (I), (II), and (III) described in the disclosure.
摘要翻译： 负性平版印刷版前体具有改善的烘烤性和良好的保质期，并且可以使用UV或红外辐射成像。 这些前体具有负性可成像层，其具有包含聚合物主链的独特聚合物粘合剂，并且还包含至少（a）和（b）沿聚合物主链以随机顺序分布的侧基。 （a）侧基是烯属不饱和可聚合基团，（b）侧基由本发明中描述的结构（I），（II）和（III）定义。
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公开(公告)号：US08354216B2
公开(公告)日：2013-01-15
申请号：US12173220
申请日：2008-07-15
CPC分类号： G03F7/031 , B41C1/1008 , B41C1/1016 , B41C2201/02 , B41C2201/10 , B41C2201/12 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/08 , B41C2210/20 , B41C2210/22 , B41C2210/24 , B41C2210/266 , G03F7/033 , G03F7/092 , G03F7/3035
摘要： Negative-working imageable elements such as lithographic printing plate precursors, include a free-radically polymerizable component, an initiator composition that is capable of generating free radicals sufficient to initiate polymerization of the free-radically polymerizable component upon exposure to imaging radiation in the presence of a radiation absorbing compound, a radiation absorbing compound, an aerobic free radical inhibitor, optionally a polymeric binder that is not a free radically polymerizable component, and an anaerobic free radical inhibitor. The molar ratio of the anaerobic free radical inhibitor to the aerobic free radical inhibitor is at least 1:1. This combination of inhibitors provides increased shelf life and good latent image stability particularly when the element includes a polymeric topcoat layer that functions as an oxygen barrier.
摘要翻译： 负面工作的可成像元件如平版印刷版前体包括可自由基聚合的组分，引发剂组合物，其能够产生足够的自由基，以便在存在可见光辐射的情况下暴露于成像辐射时引发可自由基聚合的组分的聚合 辐射吸收化合物，辐射吸收化合物，需氧自由基抑制剂，任选的不是可自由基自由基组分的聚合物粘合剂和厌氧自由基抑制剂。 厌氧自由基抑制剂与好氧自由基抑制剂的摩尔比至少为1:1。 这种抑制剂的组合提供了增加的保质期和良好的潜影稳定性，特别是当元件包括用作氧阻隔层的聚合物顶涂层时。
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公开(公告)号：US20110086202A1
公开(公告)日：2011-04-14
申请号：US12575567
申请日：2009-10-08
CPC分类号： G03F7/031 , B41C1/1008 , B41C1/1016 , B41C2201/02 , B41C2210/04 , B41C2210/06 , B41C2210/22 , B41C2210/24 , B41C2210/266 , G03F7/105 , Y10T428/24479
摘要： Negative-working imageable elements can be imaged and processed to provide lithographic printing plates. These imageable elements are sensitive to infrared radiation but are insensitive to “white” light and thus can be more easily handled under white light conditions. These properties are possible by incorporating a filter dye having a λmax of from about 300 to about 500 nm into the imageable layer of the imageable elements.
摘要翻译： 可以对负面工作的可成像元件进行成像和处理以提供平版印刷版。 这些可成像元件对红外辐射敏感，但对“白”光不敏感，因此可以在白光条件下更容易处理。 通过将λmax为约300至约500nm的滤光染料掺入到可成像元件的可成像层中，这些性质是可能的。
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公开(公告)号：US20100233445A1
公开(公告)日：2010-09-16
申请号：US12403458
申请日：2009-03-13
CPC分类号： G03F7/092 , G03F7/11 , Y10T428/24802
摘要： Negative-working imageable element can be used to provide lithographic printing plates. The imageable element has a suitable radiation-sensitive imageable layer and a water-soluble overcoat disposed on the imageable layer. This overcoat comprises at least one poly(vinyl alcohol) having a saponification degree of at least 90%, an alkoxylation product of an alkanol, and either a 2-sulfonato succinic acid dialkylester or an alkoxylation product of a 1,4-butanediol.
摘要翻译： 负性可成像元件可用于提供平版印刷版。 可成像元件具有合适的辐射敏感可成像层和设置在可成像层上的水溶性外涂层。 该外涂层包含至少一种皂化度至少为90％的聚（乙烯醇），链烷醇的烷氧基化产物，2-磺酸丁二酸二烷基酯或1,4-丁二醇的烷氧基化产物。
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公开(公告)号：US08889341B2
公开(公告)日：2014-11-18
申请号：US13591559
申请日：2012-08-22
申请人： Saija Werner , Harald Baumann , Udo Dwars , Christopher D. Simpson , Axel Draber
发明人： Saija Werner , Harald Baumann , Udo Dwars , Christopher D. Simpson , Axel Draber
CPC分类号： B41C1/1008 , B41C1/1016 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/08 , B41C2210/24 , G03F7/028 , G03F7/11
摘要： A negative-working lithographic printing plate precursor comprises a negative-working radiation-sensitive imageable layer and an outermost layer comprising a vinyl alcohol copolymer comprising at least one unit of each of the (a), (b), and (c) recurring units, in any order, defined in the disclosure. The (c) recurring units are present in the vinyl alcohol copolymer in an amount of at least 0.5 mol %, based on the total recurring units. These precursors can be used to prepare lithographic printing plates either on-press or off-press after imaging using near-UV, visible, or infrared radiation.
摘要翻译： 负性平版印刷版前体包括负性辐射敏感可成像层和包含乙烯醇共聚物的最外层，所述乙烯醇共聚物包含（a），（b）和（c）重复单元中的每一个的至少一个单元 ，以任何顺序，在本公开中定义。 （c）重复单元基于总重复单元以至少0.5mol％的量存在于乙烯醇共聚物中。 这些前体可以用于在使用近紫外，可见或红外辐射成像后制备平版印刷版，其可以在成像之后按压或压制。
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公开(公告)号：US08426104B2
公开(公告)日：2013-04-23
申请号：US12575567
申请日：2009-10-08
CPC分类号： G03F7/031 , B41C1/1008 , B41C1/1016 , B41C2201/02 , B41C2210/04 , B41C2210/06 , B41C2210/22 , B41C2210/24 , B41C2210/266 , G03F7/105 , Y10T428/24479
摘要： Negative-working imageable elements can be imaged and processed to provide lithographic printing plates. These imageable elements are sensitive to infrared radiation but are insensitive to “white” light and thus can be more easily handled under white light conditions. These properties are possible by incorporating a filter dye having a λmax of from about 300 to about 500 nm into the imageable layer of the imageable elements.
摘要翻译： 可以对负面工作的可成像元件进行成像和处理以提供平版印刷版。 这些可成像元件对红外辐射敏感，但对“白”光不敏感，因此可以在白光条件下更容易处理。 这些性质可以通过将具有约300至约500nm的兰姆达克的过滤染料掺入到可成像元件的可成像层中。
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公开(公告)号：US08043787B2
公开(公告)日：2011-10-25
申请号：US12048452
申请日：2008-03-14
申请人： Gerhard Hauck , Celin Savariar-Hauck , Udo Dwars , Harald Baumann , Bernd Strehmel , Christopher D. Simpson
发明人： Gerhard Hauck , Celin Savariar-Hauck , Udo Dwars , Harald Baumann , Bernd Strehmel , Christopher D. Simpson
CPC分类号： G03F7/075 , B41C1/1008 , B41C1/1016 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/10 , B41C2210/20 , B41C2210/22 , B41C2210/24 , B41C2210/266 , G03F7/0047
摘要： Negative-working imageable elements are prepared with radiation-sensitive imageable layers that contain surface-modified silica particles such as fumed silica particles and sol-gel silica particles, that are present in an amount of from about 1 to about 40 weight %, have an average particle size of from about 1 to about 500 nm, have surface hydroxy groups, and have a carbon content of from about 0.5 to about 15 weight % that is derived from surface hydrophobic groups having 1 to 30 carbon atoms. The presence of the surface-modified silica particles provides improved abrasion resistance, reduced tackiness, and various other desired properties.
摘要翻译： 使用含有表面改性二氧化硅颗粒如热解法二氧化硅颗粒和溶胶 - 凝胶二氧化硅颗粒的辐射敏感可成像层制备负性可成像元件，其含量为约1至约40重量％，具有 具有约1至约500nm的平均粒度具有表面羟基，并且具有衍生自具有1至30个碳原子的表面疏水基团的约0.5至约15重量％的碳含量。 表面改性二氧化硅颗粒的存在提供了改进的耐磨性，降低的粘合性和各种其它期望的性能。
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公开(公告)号：US07858292B2
公开(公告)日：2010-12-28
申请号：US11949810
申请日：2007-12-04
申请人： Harald Baumann , Udo Dwars , Bernd Strehmel , Christopher D. Simpson , Celin Savariar-Hauck , Gerhard Hauck
发明人： Harald Baumann , Udo Dwars , Bernd Strehmel , Christopher D. Simpson , Celin Savariar-Hauck , Gerhard Hauck
CPC分类号： G03F7/033 , B41C1/1008 , B41C1/1016 , B41C2201/02 , B41C2201/14 , B41C2210/02 , B41C2210/04 , B41C2210/06 , B41C2210/22 , B41C2210/24 , B41C2210/262 , B41C2210/266 , Y10S430/121
摘要： Radiation-sensitive compositions and imageable elements include a polymeric or non-polymeric component in an imageable layer, which component includes 1H-tetrazole groups. The non-polymeric components can be radically polymerizable compounds. The polymeric components can have 1H-tetrazole groups that are pendant to the backbone. The use of such components in negative- or positive-working imageable elements provides high photospeed and improved developability for providing imaged and developed elements, such as lithographic printing plates that show improved chemical resistance and run length.
摘要翻译： 辐射敏感组合物和可成像元件包括可成像层中的聚合物或非聚合物组分，该组分包括1H-四唑基团。 非聚合物组分可以是可自由基聚合的化合物。 聚合物组分可具有垂直于主链的1H-四唑基团。 在负片或正性可成像元件中使用这样的组分可提供高的感光速度和改进的显影性，以提供成像和显影元件，例如显示改善的耐化学性和游程长度的平版印刷版。
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公开(公告)号：US20100015556A1
公开(公告)日：2010-01-21
申请号：US12173220
申请日：2008-07-15
CPC分类号： G03F7/031 , B41C1/1008 , B41C1/1016 , B41C2201/02 , B41C2201/10 , B41C2201/12 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/08 , B41C2210/20 , B41C2210/22 , B41C2210/24 , B41C2210/266 , G03F7/033 , G03F7/092 , G03F7/3035
摘要： Negative-working imageable elements such as lithographic printing plate precursors, include a free-radically polymerizable component, an initiator composition that is capable of generating free radicals sufficient to initiate polymerization of the free-radically polymerizable component upon exposure to imaging radiation in the presence of a radiation absorbing compound, a radiation absorbing compound, an aerobic free radical inhibitor, optionally a polymeric binder that is not a free radically polymerizable component, and an anaerobic free radical inhibitor. The molar ratio of the anaerobic free radical inhibitor to the aerobic free radical inhibitor is at least 1:1. This combination of inhibitors provides increased shelf life and good latent image stability particularly when the element includes a polymeric topcoat layer that functions as an oxygen barrier.
摘要翻译： 负面工作的可成像元件如平版印刷版前体包括可自由基聚合的组分，引发剂组合物，其能够产生足够的自由基，以便在存在可见光辐射的情况下暴露于成像辐射时引发可自由基聚合的组分的聚合 辐射吸收化合物，辐射吸收化合物，需氧自由基抑制剂，任选的不是可自由基自由基组分的聚合物粘合剂和厌氧自由基抑制剂。 厌氧自由基抑制剂与好氧自由基抑制剂的摩尔比至少为1:1。 这种抑制剂的组合提供了增加的保质期和良好的潜影稳定性，特别是当元件包括用作氧阻隔层的聚合物顶涂层时。
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公开(公告)号：US20090233227A1
公开(公告)日：2009-09-17
申请号：US12048452
申请日：2008-03-14
申请人： Gerhard Hauck , Celin Savariar-Hauck , Udo Dwars , Harald Baumann , Bernd Strehmel , Christopher D. Simpson
发明人： Gerhard Hauck , Celin Savariar-Hauck , Udo Dwars , Harald Baumann , Bernd Strehmel , Christopher D. Simpson
CPC分类号： G03F7/075 , B41C1/1008 , B41C1/1016 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/10 , B41C2210/20 , B41C2210/22 , B41C2210/24 , B41C2210/266 , G03F7/0047
摘要： Negative-working imageable elements are prepared with radiation-sensitive imageable layers that contain surface-modified silica particles such as fumed silica particles and sol-gel silica particles, that are present in an amount of from about 1 to about 40 weight %, have an average particle size of from about 1 to about 500 nm, have surface hydroxy groups, and have a carbon content of from about 0.5 to about 15 weight % that is derived from surface hydrophobic groups having 1 to 30 carbon atoms. The presence of the surface-modified silica particles provides improved abrasion resistance, reduced tackiness, and various other desired properties.
摘要翻译： 使用含有表面改性二氧化硅颗粒如热解法二氧化硅颗粒和溶胶 - 凝胶二氧化硅颗粒的辐射敏感可成像层制备负性可成像元件，其含量为约1至约40重量％，具有 具有约1至约500nm的平均粒度具有表面羟基，并且具有衍生自具有1至30个碳原子的表面疏水基团的约0.5至约15重量％的碳含量。 表面改性二氧化硅颗粒的存在提供了改进的耐磨性，降低的粘合性和各种其它期望的性能。
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