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11.发明申请公开(公告)号：US20110237825A1
公开(公告)日：2011-09-29
申请号：US12998845
申请日：2009-11-16
IPC分类号： C07C69/02
CPC分类号： C07C51/12 , B01J29/22 , B01J29/24 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J37/0009 , B01J37/0201 , B01J2229/42 , C07C67/37 , C07C53/08 , C07C69/14
摘要： A process for the carbonylation of dimethyl ether and/or methanol with carbon monoxide to produce methyl acetate and/or acetic acid in the presence of a catalyst formed by compositing a mordenite loaded with silver and/or copper, with an inorganic oxide binder.
摘要翻译： 在通过将负载有银和/或铜的丝光沸石复合而形成的催化剂与无机氧化物粘合剂的存在下，用一氧化碳羰基化二甲醚和/或甲醇以制备乙酸甲酯和/或乙酸的方法。
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12.发明申请公开(公告)号：US20110218356A1
公开(公告)日：2011-09-08
申请号：US12998684
申请日：2009-10-08
CPC分类号： C07C67/37 , B01J29/18 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1061 , B01J35/109 , B01J37/0009 , B01J37/08 , B01J2229/42 , C07C51/12 , C07C53/08 , C07C69/14
摘要： A process for the preparation of methyl acetate and/or acetic acid by carbonylating dimethyl ether and/or methanol with carbon monoxide in the presence of a catalyst, which catalyst is a H-mordenite bound with a mesoporous binder selected from silicas, aluminas, silica-aluminas, magnesium silicates and magnesium aluminum silicates.
摘要翻译： 一种通过在催化剂存在下用一氧化碳羰基化二甲醚和/或甲醇来制备乙酸甲酯和/或乙酸的方法，该催化剂是与介孔粘合剂结合的H-丝光沸石，所述介孔粘合剂选自二氧化硅，氧化铝，二氧化硅 铝酸镁，硅酸镁和硅酸镁铝。
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公开(公告)号：US5877348A
公开(公告)日：1999-03-02
申请号：US992106
申请日：1997-12-17
CPC分类号： C07C51/12
摘要： A process for the production of acetic acid by carbonylating with carbon monoxide methanol and/or a reactive derivative thereof in a carbonylation reactor containing a liquid reaction composition comprising an iridium carbonylation catalyst, methyl iodide co-catalyst, a finite concentration of water, acetic acid, methyl acetate and at least one promoter wherein the water concentration is at or below that at which the maximum in the graph of carbonylation rate versus water concentration occurs and there is employed in the liquid reaction composition a co-promoter selected from alkali metal iodides, alkaline earth metal iodides, metal complexes capable of generating I.sup.-, salts capable of generating I.sup.-, and mixtures of two or more thereof.
摘要翻译： 一种通过在一氧化碳甲醇和/或其活性衍生物中羰基化反应生产乙酸的方法，所述羰基化反应器含有含有铱羰基化催化剂，甲基碘助催化剂，有限浓度的水，乙酸 ，乙酸甲酯和至少一种助催化剂，其中水浓度等于或低于羰基化速率对水浓度图中的最大值，并且在液体反应组合物中使用选自碱金属碘化物， 碱土金属碘化物，能够产生I-的金属络合物，能够产生I-的盐，以及其两种或更多种的混合物。
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公开(公告)号：US08524954B2
公开(公告)日：2013-09-03
申请号：US12998639
申请日：2009-11-10
IPC分类号： C07C29/152 , C07C29/157 , C07C27/06
CPC分类号： C07C29/151 , C07C29/149 , C07C51/12 , Y02P20/582 , C07C31/08 , C07C31/04 , C07C53/08
摘要： The present invention relates to a process for producing methanol and ethanol, wherein the methanol is produced from synthesis gas and the ethanol is produced via the hydrogenation of an ethanoic acid feed; characterized in that the hydrogenation of the ethanoic acid feed is carried out within the same alcohol synthesis unit and in the presence of the same catalyst(s) that is used to produce the methanol from the synthesis gas and wherein the feed introduced to the alcohol synthesis unit comprises synthesis gas and ethanoic acid.
摘要翻译： 本发明涉及一种生产甲醇和乙醇的方法，其中甲醇由合成气生产，乙醇通过乙酸进料的氢化生产; 其特征在于，所述乙酸进料的氢化在相同的醇合成单元内进行，并且在用于从合成气生产甲醇的相同催化剂的存在下进行，并且其中引入醇合成的进料 单元包括合成气和乙酸。
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15.发明授权公开(公告)号：US08450521B2
公开(公告)日：2013-05-28
申请号：US12998684
申请日：2009-10-08
CPC分类号： C07C67/37 , B01J29/18 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1061 , B01J35/109 , B01J37/0009 , B01J37/08 , B01J2229/42 , C07C51/12 , C07C53/08 , C07C69/14
摘要： Process for preparing methyl acetate and/or acetic acid by contacting a carbonylatable reactant selected from dimethyl ether and methanol with carbon monoxide in the presence of a catalyst. The catalyst is a H-mordenite bound with a mesoporous binder selected from silicas, aluminas, silica-aluminas, magnesium silicates and magnesium aluminum silicates.
摘要翻译： 在催化剂存在下使选自二甲醚和甲醇的羰基化反应物与一氧化碳接触来制备乙酸甲酯和/或乙酸的方法。 催化剂是与选自二氧化硅，氧化铝，二氧化硅 - 氧化铝，硅酸镁和硅酸镁铝的介孔粘合剂结合的H-丝光沸石。
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公开(公告)号：US20110224462A1
公开(公告)日：2011-09-15
申请号：US12998639
申请日：2009-11-10
IPC分类号： C07C29/157 , C07C27/06 , C07C29/152
CPC分类号： C07C29/151 , C07C29/149 , C07C51/12 , Y02P20/582 , C07C31/08 , C07C31/04 , C07C53/08
摘要： The present invention relates to a process for producing methanol and ethanol, wherein the methanol is produced from synthesis gas and the ethanol is produced via the hydrogenation of an ethanoic acid feed; characterised in that the hydrogenation of the ethanoic acid feed is carried out within the same alcohol synthesis unit and in the presence of the same catalyst(s) that is used to produce the methanol from the synthesis gas and wherein the feed introduced to the alcohol synthesis unit comprises synthesis gas and ethanoic acid.
摘要翻译： 本发明涉及一种生产甲醇和乙醇的方法，其中甲醇由合成气生产，乙醇通过乙酸进料的氢化生产; 其特征在于，所述乙酸进料的氢化在相同的醇合成单元内进行，并且在用于从合成气生产甲醇的相同催化剂的存在下进行，并且其中引入醇合成的进料 单元包括合成气和乙酸。
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公开(公告)号：US08536369B2
公开(公告)日：2013-09-17
申请号：US12451004
申请日：2008-04-23
IPC分类号： C07C67/37
摘要： Process for producing methyl acetate by carbonylating a dimethyl ether feed with carbon monoxide under substantially anhydrous conditions in the presence of a mordenite catalyst which has been ion-exchanged or otherwise loaded with at least one of silver and copper. The mordenite is also ion-exchanged or otherwise loaded with platinum in an amount in the range 0.05 to 10 mol % relative to aluminum.
摘要翻译： 在已经离子交换或以其它方式装载银和铜中的至少一种的丝光沸石催化剂的存在下，在基本无水条件下用一氧化碳羰基化二甲醚进料来生产乙酸甲酯的方法。 丝光沸石也以相对于铝的0.05至10mol％的量离子交换或以其它方式装载铂。
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公开(公告)号：US20100121098A1
公开(公告)日：2010-05-13
申请号：US12451004
申请日：2008-04-23
IPC分类号： C07C67/36 , B01J29/068 , C07C51/093
摘要： Production of methyl acetate by carbonylating a dimethyl ether feed with carbon monoxide under substantially anhydrous conditions, in the presence of a mordenite catalyst which contains copper and/or silver and 0.05 to 10 mol % platinum relative to aluminium.
摘要翻译： 在含有铜和/或银的丝光沸石催化剂和相对于铝的0.05至10mol％的铂的存在下，在基本无水的条件下，用一氧化碳羰基化二甲醚进料生产乙酸甲酯。
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公开(公告)号：US07915446B2
公开(公告)日：2011-03-29
申请号：US10563920
申请日：2004-06-23
申请人： Anthony Haynes , David John Law , Andrew Miller , George Ernest Morris , Marc John Payne , John Glenn Sunley
发明人： Anthony Haynes , David John Law , Andrew Miller , George Ernest Morris , Marc John Payne , John Glenn Sunley
IPC分类号： C07C51/16
CPC分类号： B01J23/468 , C07C51/12 , C07C53/08
摘要： A catalyst and process for the production of acetic acid by the carbonylation of methanol and/or a reactive derivative thereof. The catalyst system comprises an iridium carbonylation catalyst, methyl iodide co-catalyst, optionally at least one of ruthenium, osmium, rhenium, zinc, gallium, tungsten, cadmium, mercury and indium and at least one non-hydrohalogenoic acid promoter. The non-hydrohalogenoic acid may be an oxoacid, a superacid and/or a heteropolyacid.
摘要翻译： 用于通过甲醇和/或其反应性衍生物的羰基化生产乙酸的催化剂和方法。 催化剂体系包括铱羰基化催化剂，甲基碘助催化剂，钌，锇，铼，锌，镓，钨，镉，汞和铟中的至少一种和至少一种非氢卤酸促进剂。 非氢卤酸可以是含氧酸，超酸和/或杂多酸。
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公开(公告)号：US5663430A
公开(公告)日：1997-09-02
申请号：US460537
申请日：1995-06-02
申请人： George Ernest Morris , Stephen James Smith , John Glenn Sunley , Robert John Watt , Bruce Leo Williams
发明人： George Ernest Morris , Stephen James Smith , John Glenn Sunley , Robert John Watt , Bruce Leo Williams
摘要： In a process for purifying a carboxylic acid fraction obtained by liquid phase carbonylation of an alkyl alcohol and/or its reactive derivative in which volatile iridium- and/or volatile co-promoter contaminants are converted to involatile forms by contacting with an iodide in the absence of carbon monoxide or at a partial pressure less than that of the carbonylation reaction. The involatile contaminants are then separated from the carboxylic acid.
摘要翻译： 在通过烷基醇和/或其反应性衍生物的液相羰基化获得的羧酸级分的纯化方法中，其中挥发性铱和/或挥发性共助催化剂污染物通过在不存在下与碘化物接触而转化为非挥发性形式 的一氧化碳或分压低于羰基化反应的分压。 然后将非挥发性污染物与羧酸分离。
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