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公开(公告)号:US10647841B2
公开(公告)日:2020-05-12
申请号:US15504233
申请日:2015-08-21
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Sudhin Datta , Xin Chen , Abdul M. Jangda , Rohan A. Hule , Jan Kalfus
IPC: C08L23/14
Abstract: Disclosed is a thermoplastic polyolefin composition useful in automotive components comprising at least a polypropylene having a melting point temperature (Tm) of greater than 130° C. and a melt flow rate (230° C./2.16 kg) within the range from 10 g/10 min to 80 g/10 min; an amorphous ethylene-propylene copolymer comprising within the range from 40 wt % to 80 wt % ethylene derived units and having a melt flow rate (230° C./2.16 kg) within the range from 0.1 g/10 min to 20 g/10 min; and a propylene-based elastomer having within the range from 5 to 25 wt % ethylene derived units and having a Tm of less than 110° C. The composition only partially breaks or there is no break at −29° C. (ASTM D256) with Notched Izod Force of between 10 to 40 ft-lb/in2 at 22° C. (533 to 2,132 J/m2), and between 1.0 to 12 ft-lb/in2 at −29° C. (53 to 636 J/m2).
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公开(公告)号:US20190330460A1
公开(公告)日:2019-10-31
申请号:US16379372
申请日:2019-04-09
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Lubin Luo , Xin Chen , Yen-Hao Lin , Anupriya Jain , Matthew S. Bedoya , Medrado M. Leal , Rebecca C. Savage , Rachel G. Terry , Sergey Yakovlev
Abstract: Heterophasic copolymers of propylene and an alpha olefin comonomer having a matrix phase and a fill phase, particularly, a heterophasic copolymer having a high fill phase content (greater than or equal to 50%), are provided herein. Polymerization methods and catalyst systems for producing such heterophasic copolymers are also provided.
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公开(公告)号:US20180186982A1
公开(公告)日:2018-07-05
申请号:US15724401
申请日:2017-10-04
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Xin Chen , Sudhin Datta
IPC: C08L23/12
CPC classification number: C08L23/12 , C08L2205/02 , C08L2205/03 , C08L2205/06 , C08L23/16 , C08K3/34
Abstract: This invention relates to a thermoplastic polyolefin composition with (a) 45 wt % to 70 wt % of a polypropylene having 70 wt % or more units derived from propylene, having a melting point temperature of greater than 130° C. and a melt flow rate from 2 to 80 g/10 min; (b) 20 wt % to 30 wt % of a bimodal ethylene-propylene copolymer comprising: (i) 80 wt % to 90 wt % of an amorphous ethylene-propylene copolymer having about 30 wt % or more units derived from ethylene; (ii) 5 wt % to 15 wt % of a semi-crystalline ethylene-propylene copolymer having 70 wt % or more units derived from ethylene; and (iii) 1 wt % to 5 wt % of a propylene-based elastomer having within the range from 5 wt % to 25 wt % ethylene derived units and having a melting point temperature of less than 110° C. and a Mw/Mn within the range from 2.0 to 4.0.
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公开(公告)号:US20180030257A1
公开(公告)日:2018-02-01
申请号:US15551819
申请日:2015-03-27
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Jie Hui Xu , Xin Chen
IPC: C08L23/14
CPC classification number: C08L23/14 , B29C45/0001 , C08L2205/02 , C08L2205/035 , C08L23/10
Abstract: The present invention is related to a grip composition comprising 5 to 10 wt % of a polymer blend modifier, having a weight average molecular weight of 10,000 to 100,000 g/mole, 65 to 75 wt % of a propylene-based elastomer, having a weight average molecular weight of 100,000 to 300,000 g/mole, and a mineral powder. The polymer blend modifier comprises a first propylene-based polymer and a second propylene-based polymer, where the first and second propylene-based polymers are different and are individually selected from a homopolymer of propylene or a copolymer of propylene and ethylene or a C4 to C10 alpha-olefin. The composition further comprises 5 to 10 wt % of a propylene polymer, which is a homopolymer of propylene or a copolymer of propylene units with from 0.5 to 4 wt % ethylene or C4 to C10 alpha-olefin comonomer derived units.
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公开(公告)号:US20180002352A1
公开(公告)日:2018-01-04
申请号:US15629586
申请日:2017-06-21
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: John R. Hagadorn , Patrick J. Palafox , Peijun Jiang , Yaohua Gao , Xin Chen , Georgy P. Goryunov , Mikhail I. Sharikov , Dmitry V. Uborsky , Alexander Z. Voskoboynikov
Abstract: Quinolinyldiamido transition metal complexes are disclosed for use in alkene polymerization to produce multimodal polyolefins.
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公开(公告)号:US20200239677A1
公开(公告)日:2020-07-30
申请号:US16793075
申请日:2020-02-18
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Sudhin Datta , Xin Chen , Abdul M. Jangda , Rohan A. Hule , Jan Kalfus
Abstract: Disclosed is a thermoplastic polyolefin composition useful in automotive components comprising at least a polypropylene having a melting point temperature (Tm) of greater than 130° C. and a melt flow rate (230° C./2.16 kg) within the range from 10 g/10 min to 80 g/10 min; an amorphous ethylene-propylene copolymer comprising within the range from 40 wt % to 80 wt % ethylene derived units and having a melt flow rate (230° C./2.16 kg) within the range from 0.1 g/10 min to 20 g/10 min; and a propylene-based elastomer having within the range from 5 to 25 wt % ethylene derived units and having a Tm of less than 110° C. The composition only partially breaks or there is no break at −29° C. (ASTM D256) with Notched Izod Force of between 10 to 40 ft-lb/in2 at 22° C. (533 to 2,132 J/m2), and between 1.0 to 12 ft-lb/in2 at −29° C. (53 to 636 J/m2).
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公开(公告)号:US10208140B2
公开(公告)日:2019-02-19
申请号:US15629586
申请日:2017-06-21
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: John R. Hagadorn , Patrick J. Palafox , Peijun Jiang , Yaohua Gao , Xin Chen , Georgy P. Goryunov , Mikhail I. Sharikov , Dmitry V. Uborsky , Alexander Z. Voskoboynikov
Abstract: Quinolinyldiamido transition metal complexes are disclosed for use in alkene polymerization to produce multimodal polyolefins.
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公开(公告)号:US20170233566A1
公开(公告)日:2017-08-17
申请号:US15503018
申请日:2015-08-04
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Sudhin Datta , Rohan A. Hule , Xin Chen , Feng Li
CPC classification number: C08L23/12 , C08J3/005 , C08J2323/12 , C08J2423/12 , C08L23/10 , C08L2203/14 , C08L2203/30 , C08L2205/025 , C08L2205/03 , C08F110/06 , C08F2500/06 , C08F2500/17 , C08F2/001 , C08F2500/12 , C08F2500/04 , C08F2500/05
Abstract: A bimodal polypropylene composition of at least a high molecular weight, predominantly isotactic, narrow molecular weight distribution polypropylene having a heat of fusion of 70 to 100 J/g, and a low molecular weight, predominantly isotactic, narrow molecular weight distribution polypropylene having a heat of fusion of 70 to 100 J/g, wherein the high molecular weight polymer and low molecular weight polymer are sufficiently miscible to impart a single glass transition temperature and a single melting point to the polymer blend, has improved processibility and stiffness compared to a single narrow molecular weight distribution isotactic polypropylene of the average of the components.
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19.
公开(公告)号:US20220081528A1
公开(公告)日:2022-03-17
申请号:US17419062
申请日:2020-01-13
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Antonios K. Doufas , Hang Dong , Krishnan Anantha Narayana Iyer , Oscar O. Chung , Xin Chen , Michael J. Goncy , John A. Bowers , Kathy B. Cabrera , Porter C. Shannon , Christopher S. Breiner
Abstract: Foam pellets comprising a thermoplastic vulcanizate (TPV) and thermo-expandable microspheres, the foam pellet having a specific gravity of 0.2 to 1.0 and the TPV being composed of an at least partially vulcanized rubber component and a thermoplastic component. The foam pellets may be subsequently processed to form various foam articles without the need to include a foaming agent during processing.
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公开(公告)号:US11104784B2
公开(公告)日:2021-08-31
申请号:US16793075
申请日:2020-02-18
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Sudhin Datta , Xin Chen , Abdul M. Jangda , Rohan A. Hule , Jan Kalfus
Abstract: Disclosed is a thermoplastic polyolefin composition useful in automotive components comprising at least a polypropylene having a melting point temperature (Tm) of greater than 130° C. and a melt flow rate (230° C./2.16 kg) within the range from 10 g/10 min to 80 g/10 min; an amorphous ethylene-propylene copolymer comprising within the range from 40 wt % to 80 wt % ethylene derived units and having a melt flow rate (230° C./2.16 kg) within the range from 0.1 g/10 min to 20 g/10 min; and a propylene-based elastomer having within the range from 5 to 25 wt % ethylene derived units and having a Tm of less than 110° C. The composition only partially breaks or there is no break at −29° C. (ASTM D256) with Notched Izod Force of between 10 to 40 ft-lb/in2 at 22° C. (533 to 2,132 J/m2), and between 1.0 to 12 ft-lb/in2 at −29° C. (53 to 636 J/m2).
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