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公开(公告)号:US20240077809A1
公开(公告)日:2024-03-07
申请号:US18300348
申请日:2023-04-13
Applicant: FUJIFILM Business Innovation Corp.
Inventor: Tomoya SASAKI , Ryosuke FUJII , Hiroko KOBAYASHI , Yuto OKAZAKI , Kosuke NARITA
CPC classification number: G03G5/056 , G03G5/047 , G03G5/0564 , G03G21/1814
Abstract: An electrophotographic photoreceptor includes a conductive substrate, and a lamination type photosensitive layer disposed on the conductive substrate and including a charge generation layer and a charge transport layer, in which the charge transport layer contains a charge transport material, at least one of a polyester resin (PEz) or a polycarbonate resin (PCz) that has at least one of a structure (Z1) represented by Formula (Z1) or a structure (Z2) represented by Formula (Z2) at at least one terminal, and a resin (X) that has at least one of a unit (X1) represented by Formula (X1) or a unit (X2) represented by Formula (X2), a mass proportion of the resin (X) in a total amount of the polyester resin (PEz), the polycarbonate resin (PCz), and the resin (X) in the charge transport layer is 0.5% by mass or greater and 30% by mass or less, and the charge transport layer has an average thickness of greater than 30 μm and less than 50 μm,
in Formula (Z1), Ar1 represents an aromatic ring that may have a substituent,
in Formula (Z2), Ar2 represents an aromatic ring that may have a substituent,
in Formula (X1), R101, R102, and R103 each independently represent a hydrogen atom or an alkyl group having 1 or more and 5 or less carbon atoms, L101 represents a single bond, an alkylene group having 1 or more and 5 or less carbon atoms, —O—, —C(═O)—, —C(═O)O—, an aromatic ring that may have a substituent, or a combination thereof, L102 represents a single bond, an alkylene group having 1 or more and 5 or less carbon atoms, —O—, —C(═O)—, —C(═O)O—, or a combination thereof, R104 and R105 each independently represent an alkyl group having 1 or more and 5 or less carbon atoms, n represents an integer of 0 or greater and 300 or less, R106, R107, and R108 each independently represent an alkyl group having 1 or more and 5 or less carbon atoms or —O—[Si(R109)(R110)O]m—Si(R111)(R112)(R113), R109, R110, R111, R12, and R113 each independently represent an alkyl group having 1 or more and 5 or less carbon atoms, and m represents an integer of 0 or greater and 20 or less,
in Formula (X2), R201, R202, and R203 each independently represent a hydrogen atom or an alkyl group having 1 or more and 5 or less carbon atoms, L201 represents a single bond, an alkylene group having 1 or more and 5 or less carbon atoms, —O—, —C(═O)—, —C(═O)O—, an aromatic ring that may have a substituent, or a combination thereof, L202 represents a single bond, an alkylene group having 1 or more and 5 or less carbon atoms, —O—, —C(═O)—, —C(═O)O—, or a combination thereof, and R204 is an alkyl group having 6 or more and 30 or less carbon atoms.-
公开(公告)号:US20240053689A1
公开(公告)日:2024-02-15
申请号:US18321800
申请日:2023-05-23
Applicant: FUJIFILM Business Innovation Corp.
Inventor: Yuto OKAZAKI , kosuke NARITA , Tomoya SASAKI , Hiroko KOBAYASHI , Ryosuke FUJII
IPC: G03G5/047 , G03G5/05 , C08G63/193 , C08G63/672 , G03G21/18
CPC classification number: G03G5/047 , G03G5/056 , C08G63/193 , C08G63/672 , G03G21/1803
Abstract: An electrophotographic photoreceptor includes a conductive substrate, and a lamination type photosensitive layer including a charge generation layer and a charge transport layer or a single layer type photosensitive layer that is a photosensitive layer disposed on the conductive substrate, in which the charge transport layer or the single layer type photosensitive layer is an outermost layer and contains a charge transport material and a binder resin containing a polyester resin having an aromatic ring, the charge transport layer or the single layer type photosensitive layer has an average thickness of 28 μm or greater and 50 μm or less, and a weight reduction ratio of the charge transport layer or the single layer type photosensitive layer from 30° C. to 175° C. in thermogravimetric analysis is 0.1% by mass or less.
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公开(公告)号:US20230288824A1
公开(公告)日:2023-09-14
申请号:US18181522
申请日:2023-03-09
Applicant: FUJIFILM Business Innovation Corp.
Inventor: Yuto OKAZAKI , Tomoya SASAKI , Ryosuke FUJII , Kohei HASHIMOTO , Hiroko KOBAYASHI , Kosuke NARITA
CPC classification number: G03G5/056 , G03G5/047 , C08G63/20 , C08G63/81 , G03G5/061446 , G03G21/1814
Abstract: An electrophotographic photoreceptor includes a conductive substrate, and a lamination type photosensitive layer disposed on the conductive substrate and including a charge generation layer and a charge transport layer, in which the charge transport layer contains a polyester resin having a structure represented by Formula (1) at a terminal and a charge transport material, and in a case where a weight-average molecular weight Mw of the polyester resin is defined as A (×10,000), a value of a ratio M1/M2 of a mass M1 of the charge transport material to a mass M2 of an entire charge transport layer is defined as Cs, and an average thickness of the charge transport layer is defined as Ds (μm), expressions of 7≤A≤40, 0.28≤Cs≤0.55, 27≤Ds≤50, and 5.0≤(A×Ds)/(Cs×100)≤70 are satisfied,
in Formula (1), nd represents an integer of 0 or greater and 4 or less, nd number of Rd's each independently represent a hydrocarbon group having 1 or more and 4 or less carbon atoms, L represents an ether bond or a —O—C(═O)— group, and * represent a bonding portion.-
公开(公告)号:US20230195003A1
公开(公告)日:2023-06-22
申请号:US18071516
申请日:2022-11-29
Applicant: FUJIFILM Business Innovation Corp.
Inventor: Tomoya SASAKI , Ryosuke FUJII , Kohei HASHIMOTO , Hiroko KOBAYASHI , Yuto OKAZAKI , Kosuke NARITA
IPC: G03G5/047 , G03G5/05 , C08G63/193 , G03G15/00
CPC classification number: G03G5/047 , G03G5/056 , C08G63/193 , G03G15/75
Abstract: An electrophotographic photoreceptor includes a conductive substrate, and a lamination type photosensitive layer disposed on the conductive substrate and including a charge generation layer and a charge transport layer, in which the charge transport layer contains a charge transport material and a polyester resin, and a mass proportion of a chemical substance (AA) represented by Formula (AA) in a total mass of the charge transport layer is 2,000 ppm or less.
In Formula (AA), X represents an organic group, and mAA represents an integer.-
公开(公告)号:US20220089829A1
公开(公告)日:2022-03-24
申请号:US17129286
申请日:2020-12-21
Applicant: FUJIFILM BUSINESS INNOVATION CORP.
Inventor: Tomoyo OKUBO , Shunsuke NOZAKI , Tomoya SASAKI , Hidekazu HIROSE
Abstract: A polyimide precursor solution, includes: a polyimide precursor; resin particles having a volume average particle diameter of 5 nm or more and 100 nm or less, and having a volume particle size distribution wherein a ratio of a volume frequency of resin particles having a particle diameter of 150 nm or more to a volume frequency of all of the resin particles in the polyimide precursor solution is 5% or less; and an aqueous solvent containing water.
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