公开(公告)号：US4116952A

公开(公告)日：1978-09-26

申请号：US788217

申请日：1977-04-18

Applicant: Fabio Beffa ,  Gerhard Back ,  Eginhard Steiner

Inventor： Fabio Beffa ,  Gerhard Back ,  Eginhard Steiner

IPC: C09B45/00 ,  C09B55/00 ,  D06P1/10 ,  D06P1/13 ,  C09B45/06 ,  C09B45/26 ,  D06P3/32

CPC classification number: C09B45/00 ,  C09B55/001 ,  D06P1/10 ,  D06P1/13

Abstract: 1:2 Chromium complex dyes which contain one molecule of an azo or azomethine compound of the formula ##STR1## and one molecule of the azomethine compound of the formula ##STR2## COMPLEXED TO A CHROMIUM ATOM, IN WHICH FORMULAE A represents the radical of a diazo component of the benzene or naphthalene series, which carries the complex-forming group XH in ortho-position to the azo group,B represents the radical of a coupling component which couples in ortho-position to HX' or the radical of an aromatic o-hydroxyaldehyde,Z represents a nitrogen atom or the -CH group,X represents an oxygen atom or a -CO-O group,X' represents an oxygen atom, a NH group, a low molecular N-alkyl, N-aralkyl or N-aryl group, andR represents a substituted or unsubstituted aliphatic or cycloaliphatic radical,And the benzene ring a can carry a further fused benzene ring or can be substituted by halogen, nitro, alkyl and alkoxy, in particular by low molecular alkyl and alkoxy, and these compounds contain together 0 to 5 water-solubilizing groups and optionally a group of the formula--N.dbd.N--Ar--N.dbd.N--Ar' (3)and/or one to two groups of the formula--N.dbd.N--Ar" (4)wherein Ar, Ar' and Ar" represent an aromatic, carbocyclic or heterocyclic radical. These dyes are primarily suitable for dyeing natural and synthetic polyamide material.

公开(公告)号：US4083839A

公开(公告)日：1978-04-11

申请号：US712284

申请日：1976-08-06

Applicant: Gerhard Back ,  Fabio Beffa

Inventor： Gerhard Back ,  Fabio Beffa

IPC: C09B45/16

CPC classification number: C09B45/16

Abstract: Chromium complex dyes of the formula ##STR1## wherein Z is a nitro group or a chlorine atom, each of R and R.sub.1 is a phenyl radical which is optionally substituted by halogen, low molecular alkoxy, low molecular alkyl or nitro, one of the symbols X.sub.1, X.sub.2 and X.sub.3 is hydrogen and each of the others is hydrogen, a halogen atom, a nitro, methyl or methoxy group and Me.sup.+ is a cation. The dyes are suitable for dyeing and printing natural and synthetic polyamides to produce dyeings which are level and have good fastness to light, washing, fulling, decatizing and carbonizing.

Abstract translation: 式（Ⅰ）的铬络合物染料其中Z为硝基或氯原子，R和R 1各自为任选被卤素，低分子烷氧基，低分子烷基或硝基取代的苯基，一个 符号X 1，X 2和X 3为氢，并且各自为氢，卤素原子，硝基，甲基或甲氧基，Me +为阳离子。 染料适用于染色和印刷天然和合成聚酰胺，以生产水平且具有良好的耐光牢度，洗涤，充满，脱脂和碳化的染色。

公开(公告)号：US4053462A

公开(公告)日：1977-10-11

申请号：US711199

申请日：1976-08-04

Applicant: Fabio Beffa ,  Gerhard Back

Inventor： Fabio Beffa ,  Gerhard Back

IPC: C09B45/16 ,  D06P1/36 ,  D06P3/04 ,  D06P3/32 ,  D06P1/10 ,  D06P3/24

CPC classification number: C09B45/16 ,  D06P1/36 ,  D06P3/046 ,  D06P3/32

Abstract: Chromium complex dyes which, in the form of their free acid, have the formula ##STR1## wherein one X represents the sulphonic acid group and the other X represents the nitro group, Y is a sulfone or sulfonamide group and Z is an acyl group. The dyes are suitable for dyeing natural and synthetic polyamides to produce dyeings which are level and have good fastness to light, perspiration, fulling, decatizing and carbonizing.

公开(公告)号：US4013630A

公开(公告)日：1977-03-22

申请号：US663019

申请日：1976-03-02

Applicant: Fabio Beffa ,  Gerhard Back

Inventor： Fabio Beffa ,  Gerhard Back

IPC: C09B45/16 ,  C09B45/06 ,  C09B45/26 ,  D06P1/10

CPC classification number: D06P1/10 ,  C09B45/06

Abstract: Chromium complex dyes of the formula ##STR1## WHEREIN Z represents a phenyl radical, an alkyl radical of 4 to 12 carbon atoms, a cycloalkyl radical of 5 to 9 carbon atoms or an aralkyl radical of 7 to 12 carbon atoms,S.sub.1 represents hydrogen, halogen, alkyl of 1 to 5 carbon atoms, alkoxy of 1 to 2 carbon atoms, nitro, alkanoylamino of 2 to 3 carbon atoms or alkoxycarbonylamino of 2 to 3 carbon atoms,S.sub.2 represents hydrogen, alkyl of 1 to 5 carbon atoms, alkanoylamino or alkoxycarbonylamino, each of 2 to 3 carbon atoms,Me.sup.+ represents a cation, andAr represents the radical of an aromatic or a heterocyclic diazo component which contains 1 to 3 SO.sub.3 H groups and is optionally further substituted by carboxy, halogen, alkyl of 1 to 5 carbon atoms, alkoxy of 1 to 2 carbon atoms or nitro.

Abstract translation: 式（VIII）的铬复合染料代表苯基，4-12个碳原子的烷基，5至9个碳原子的环烷基或7-12个碳原子的芳烷基，S1代表氢， 卤素，1至5个碳原子的烷基，1至2个碳原子的烷氧基，2至3个碳原子的硝基，烷酰基氨基或2至3个碳原子的烷氧基羰基氨基，S2表示氢，1至5个碳原子的烷基，烷酰基氨基或 烷氧基羰基氨基，2至3个碳原子，Me +表示阳离子，Ar表示含有1至3个SO 3 H基团并任选进一步被羧基，卤素，烷基取代的芳族或杂环重氮组分的基团 1至5个碳原子的烷氧基或1至2个碳原子的烷氧基或硝基。

公开(公告)号：US5001227A

公开(公告)日：1991-03-19

申请号：US669942

申请日：1984-11-09

Applicant: Hans U. Schutz ,  Ulrich Schlesinger ,  Gerhard Back

Inventor： Hans U. Schutz ,  Ulrich Schlesinger ,  Gerhard Back

IPC: C09B62/012 ,  C09B62/095 ,  C09B62/255 ,  C09B62/477

CPC classification number: C09B62/477 ,  C09B62/095

Abstract: The invention relates to chromium complexes of the formula ##STR1## in which L is H.sub.2 O, NH.sub.3, R.sub.2 --OH, R.sub.2 --NH.sub.2, (R.sub.2).sub.2 NH, (R.sub.2).sub.3 N or pyridine, wherein R.sub.2 is C.sub.1-6 -alkyl unsubstituted or substituted by halogen, C.sub.1-4 -alkoxy or amino, B is 8-hydroxyquinoline, 5-chloro-8-hydroxyquinoline, 5-hydroxyacridine, 6-hydroxy-4,7-phenanthroline, pyridine-2-carboxylic acid, 8-carboxyquinoline, 5,7-dibromo-8-hydroxyquinoline, o-hydroxyaniline, o-hydroxynaphthylamine, proline, glycine, serine, aspartic acid or R.sub.1 --CH(NH.sub.2)--COOH, wherein R.sub.1 is C.sub.1-6 -alkyl unsubstituted or substituted by halogen, C.sub.1-4 -alkoxy or amino, D is benzene or naphthalene, Y is the nitrogen atom or the CH group, K, in the event that Y is the nitrogen atom, is naphthol, naphthylamine, 5-pyrazolone, 5-aminopyrazole, 1-phenyl- or 1-naphthyl-5-aminopyrazole, 1-phenyl- or 1-naphthyl-5-pyrazolone, 2,6-dihydroxy-3-cyano- or -3-carboxamido-4-alkylpyridine, 6-hydroxypyrid-2-one, acetoacetanilide, benzoylacetanilide or phenol, or, in the event that Y is the CH group K is o-hydroxybenzaldehyde or o-hydroxynaphthaldehyde, D and K independently of each other are unsubstituted or substituted by C.sub.1-5 -alkyl, C.sub.1-4 -alkoxy, acylamino having 1 to 6 carbon atoms, benzoylamino, amino, monoalkylamino or dialkylamino each having 1 to 4 carbon atoms, phenylamino, alkoxycarbonyl having 1 to 4 carbon atoms in the alkoxy, radical, nitro, cyano, trifluoromethyl, halogen, sulfamoyl, carbamoyl, ureido, hydroxyl, C.sub.1-4 -alkylsulfonyl, carboxyl, sulfomethyl, phenylazo or naphthylazo, and D and K contain the --(CO).sub.0-1 --O-- and --[O or N(R)]-- adjacent to the --N.dbd.Y-- and R is hydrogen, C.sub.1-4 -alkyl or phenyl, Ka is a cation, X is acryloyl, monohalogenoacryloyl, dihalogenoacryloyl, trihalogenoacryloyl, monohalogenomethacryloyl, dihalogenomethacryloyl, trihalogenomethacryloyl, monohalogenopropionyl, dihalogenopropionyl, phenylsulfonylpropionyl, methylsulfonylpropionyl, vinylsulfonyl, .beta.-chloroethylsulfonyl, .beta.-sulfatoethylsulfonyl, monohalogenopyrimidyl, dihalogenopyrimidyl, trihalogenopyrimidyl, monohalogenotriazinyl, dihalogenotriazinyl, X is bonded to D, K or B, D and K, D and B or K and B directly or via ##STR2## or --CH.sub.2 --N(R)--, m is 1, 2 or 3 and n is 1 or 2. These chromium complexes are suitable for dyeing nitrogen-containing or hydroxy-containing materials and they produce level dyeings having good all-round fastness properties.

公开(公告)号：US4818248A

公开(公告)日：1989-04-04

申请号：US102942

申请日：1987-09-30

Applicant: Gerhard Back ,  Walter Mosimann

Inventor： Gerhard Back ,  Walter Mosimann

IPC: D06P1/36 ,  D06P1/10 ,  D06P1/607 ,  D06P1/673 ,  D06P3/06 ,  D06P3/14 ,  D06P3/16 ,  D06P3/20 ,  D06P3/24 ,  C09B67/24

CPC classification number: D06P3/06 ,  D06P1/6076 ,  D06P1/6735 ,  D06P3/16 ,  D06P3/241 ,  Y10S8/917

Abstract: The present invention relates to a process for dyeing natural or synthetic polyamide fibre material from an aqueous liquor with dyes, in the presence of an alkali metal salt or an ammonium salt and in the presence of an assistant, which process comprises dyeing said fibre material with at least one sulfonated 1:1 metal complex dye or with a mixture containing at least one sulfonated 1:1 metal complex dye and at least one sulfonated metal-free dye, in the presence of 10 to 45 percent by weight of an alkali fluorosilicate or ammonium fluorosilicate or a mixture thereof, based on the amount of the 1:1 metal complex dye employed, and in the presence of an assistant at a pH value of 3 to 5.The process of the invention is suitable for dyeing natural or synthetic polyamide materials to give non-skittery and level dyeings of good fastness properties.

Abstract translation: 本发明涉及一种使用染料，在碱金属盐或铵盐存在下，在助剂的存在下从含水液体中染色天然或合成聚酰胺纤维材料的方法，该方法包括用所述纤维素材料 至少一种磺化的1:1金属络合物染料或含有至少一种磺化的1:1金属络合物染料和至少一种磺化金属的染料的混合物，在10至45重量％的氟硅酸盐存在下，或 基于所使用的1:1金属络合物染料的量，以及在pH值为3至5的助剂存在下，氟硅酸铵或其混合物。本发明的方法适用于染色天然或合成聚酰胺 材料赋予无纺布和水平染色牢度好的坚牢度。

公开(公告)号：US4680385A

公开(公告)日：1987-07-14

申请号：US717733

申请日：1985-03-28

Applicant: Gerhard Back

Inventor： Gerhard Back

IPC: C09B45/14 ,  C09B45/16 ,  C09B45/20 ,  C09B55/00 ,  C09B45/06 ,  D06P1/10 ,  D06P3/24

CPC classification number: C09B45/20 ,  C09B45/16 ,  C09B55/00

Abstract: Metal complex dyes that produce level, fast dyeings on textile materials are provided according to the formula ##STR1## wherein: D is a benzene, naphthalene or heterocyclic radical of a diazo component;Y is nitrogen or --CH;K is the radical of a coupling component if Y is nitrogen, or an o-hydroxyaldehyde radical if Y is --CH;Ka is a cation;Me is chromium or cobalt;Z.sub.1 is --O-- or --COO-- ortho to N.dbd.YZ.sub.2 is --O-- or --NR vicinal to N.dbd.Y, wherein R is hydrogen or a C.sub.1 -C.sub.4 alkyl or phenyl radical;R.sub.1 is a direct bond or a C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkenyl, or aryl radical or heterocyclic radial containing 1 to 3 sulfur, oxygen or nitrogen atoms;R.sub.2 is hydrogen or C.sub.1 -C.sub.8 -alkyl or aryl radical;R.sub.3 is hydrogen or a C.sub.1 -C.sub.8 alkyl, aryl or amino radical, or a heterocyclic radical containing 1 to 3 sulfur, oxygen or nitrogen atoms;V is a direct bond or oxygen;Q is oxygen or sulfur; andw is 0 or 1.

Abstract translation: 根据下式提供在纺织材料上产生水平，快速染色的金属络合染料，其中：D是重氮组分的苯，萘或杂环基; Y是氮或-CH; 如果Y是氮，K是偶联组分的基团，如果Y是-CH，则是邻羟基醛基; 嘉是阳离子; 我是铬或钴; Z 1是-O-或-COO-邻，N = Y Z2是-O-或-NR邻近于N = Y，其中R是氢或C1-C4烷基或苯基; R1是直接键或C1-C8-烷基，C1-C8-烯基或芳基或含有1至3个硫，氧或氮原子的杂环; R2是氢或C1-C8-烷基或芳基; R 3是氢或C 1 -C 8烷基，芳基或氨基，或含有1至3个硫，氧或氮原子的杂环基; V是直接键或氧; Q是氧或硫; w为0或1。

公开(公告)号：US4813972A

公开(公告)日：1989-03-21

申请号：US105344

申请日：1987-10-07

Applicant: Hans U. Schutz ,  Ulrich Schlesinger ,  Gerhard Back

Inventor： Hans U. Schutz ,  Ulrich Schlesinger ,  Gerhard Back

IPC: C09B62/44 ,  C09B62/002 ,  C09B62/012 ,  C09B62/04 ,  C09B62/095 ,  C09B62/20 ,  C09B62/255 ,  C09B62/465 ,  C09B62/477 ,  C09B62/503 ,  C09B62/515 ,  D06P1/382 ,  D06P1/384 ,  C09B62/01 ,  D06P1/38 ,  D06P3/10

CPC classification number: C09B62/477 ,  C09B62/012 ,  Y10S8/917 ,  Y10S8/918 ,  Y10S8/924

Abstract: The invention relates to chromium complexes of the formula ##STR1## in which A is the radical of a dicyclically metallizable azo or azomethine dye, B is the radical of a potentially at least bidentate bianionic complexible organic compound which contains no azo or azomethine group, L is a colorless monofunctional ligand, X is a fibre-reactive radical, Ka is a cation, K is 0 or 1, m is 1, 2 or 3, n is 1 or 2, and the X radical and the SO.sub.3.sup..crclbar. Ka group are each bonded to the radicals A and B, to a process for preparing the chromium complexes of the formula (1), and to a combined preparation and dyeing process.

Abstract translation: 本发明涉及式（1）的铬配合物，其中A是双环可金属化的偶氮或偶氮甲碱染料的基团，B是不含偶氮或偶氮甲碱的潜在至少二齿双键络合的有机化合物的基团 基团，L是无色单官能配体，X是纤维反应性基团，Ka是阳离子，K是0或1，m是1,2或3，n是1或2，X基团和SO 3（ - ）Ka基团各自键合到基团A和B，与制备式（1）的铬络合物的方法以及组合的制备和染色方法。

公开(公告)号：US4623358A

公开(公告)日：1986-11-18

申请号：US737112

申请日：1985-05-23

Applicant: Gerhard Back ,  Walter Mosimann

Inventor： Gerhard Back ,  Walter Mosimann

IPC: C09B45/02 ,  C09B45/00 ,  C09B67/22 ,  C09B67/24 ,  D06P1/10 ,  D06P1/673 ,  D06P3/06 ,  D06P3/24

CPC classification number: D06P3/06 ,  C09B67/0046 ,  C09B67/0072 ,  D06P1/6735 ,  Y10S8/917 ,  Y10S8/924

Abstract: The invention relates to a process for dyeing natural or synthetic polyamide fibre material levelly from an aqueous liquor, with 1:1 metal complex dyes which contain sulfo groups, in the presence of an alkali metal salt or an ammonium salt and optionally in the presence of an assistant, which comprises carrying out dyeing in the presence of an alkali metal fluoride or ammonium fluoride, of an alkali metal fluorosilicate or ammonium fluorosilicate, or of an alkali metal fluoroborate or ammonium fluoroborate, at a pH in the range from 3 to 7.The process of this invention is suitable for dyeing natural or synthetic polyamide material in level shades of good fastness properties.

Abstract translation: 本发明涉及一种从含水液体中以1:1碱金属盐或铵盐存在下含有磺基的1：1金属络合物染料和任选地在 助剂，其包括在碱金属氟化物或氟化铵存在下，在3至7的pH范围内进行氟化硅酸氟化钼或氟硅酸铵或氟代硼酸碱金属或氟硼酸铵的染色。 本发明的方法适用于以良好的牢度性能的水平色调染色天然或合成聚酰胺材料。

公开(公告)号：US4431583A

公开(公告)日：1984-02-14

申请号：US183892

申请日：1980-09-04

Applicant: Gerhard Back

Inventor： Gerhard Back

IPC: C09B29/44 ,  C09B45/00 ,  C09B45/14 ,  C09B45/16 ,  D06P3/32 ,  C09B45/20 ,  D06P3/24

CPC classification number: C09B45/00 ,  D06P3/326

Abstract: 1:2 Cobalt complex dyes of azo compounds of the formula ##STR1## wherein D is a phenyl or naphthyl radical which is substituted by sulphonic acid groups, halogen atoms, alkyl, alkoxy, nitro, cyano, acylamino or arylazo groups or is unsubstituted, and R is a hydrogen atom, a sulpho group, a halogen atom or a methyl group, and wherein the total number of sulpho groups present is 1 to 3. The dyes are suitable for dyeing polyamide materials such as wool, silk, synthetic polyamides and leather, particularly the latter. The dyes give full brown shades of good covering power with excellent fastness to light.

Abstract translation: 1：2式（1）的偶氮化合物的钴络合物染料其中D是被磺酸基团，卤素原子，烷基，烷氧基，硝基，氰基，酰氨基或芳基偶氮基取代的苯基或萘基，或 未取代，R为氢原子，磺基，卤原子或甲基，其中存在的磺基的总数为1〜3。该染料适用于染色聚酰胺材料如羊毛，丝绸， 合成聚酰胺和皮革，特别是后者。 染色剂具有良好的遮盖力的全棕色色调，具有优异的耐光牢度。