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    High temperature lubricating oil composition containing a silicon-tin-containing compound
    11.
    发明授权
    High temperature lubricating oil composition containing a silicon-tin-containing compound 失效
    含有含锡锡化合物的高温润滑油组合物

    公开(公告)号：US2937995A

    公开(公告)日：1960-05-24

    申请号：US70195757

    申请日：1957-12-11

    Applicant: GEN ELECTRIC

    Inventor： HOLDSTOCK NORMAN G ,  BROWN JR EDGAR D

    IPC: C07F7/08 ,  C07F7/22 ,  C08K5/57

    CPC classification number: C10M3/00 ,  C07F7/0836 ,  C07F7/2248 ,  C07F7/2252 ,  C08K5/57 ,  C10M2227/04 ,  C10M2227/06 ,  C10M2227/083 ,  C10M2229/02 ,  C10M2229/04 ,  C10M2229/041 ,  C10M2229/042 ,  C10M2229/043 ,  C10M2229/044 ,  C10M2229/05 ,  C10M2229/051 ,  C10N2210/04 ,  C10N2220/02 ,  C10N2230/08 ,  C10N2240/08 ,  C10N2240/12 ,  C10N2240/121 ,  C08L83/04

    Abstract: A lubricant comprises (1) a liquid polymeric organopolysiloxane having an average of 1,98-2,25 organic groups per silicon atom and (2) a minor proportion of a compound of formula : wherein m is O or a number up to 2 and R and R1 are aliphatic, alicyclic, aryl, aralkyl, alkaryl or heterocyclic radicles which may carry substituents such as halogen atoms. In examples, bis (trimethylsiloxy) dimethyl stannane is added to a methylchlorophenylpolysiloxane chain-stopped with trimethylsilyl groups and having inter-condensed dimethyl-siloxy groups and chlorinated phenyl-siloxy groups. The bis (trimethylsiloxy) dimethyl stannane is prepared by first reacting hexamethyl disiloxane with ammonium fluoride and sulphuric acid to give trimethyl fluorosilane and hydrolysing this to the corresponding silanol. The silanol is reacted with sodium to give trimethyl sodium silanolate which, on reaction with dimethyl tin dichloride, gives the bis (trimethyl siloxy) dimethyl stannane. Specification 586,187, 586,956 and 709,920 are referred to.ALSO:A lubricant, suitable for use under heavy load at elevated temperatures, comprises (1) a liquid polymeric organopolysiloxane having an average of 1.98-2.25 organic groups per silicon atom and (2) a minor proportion of a compound of formula: wherein m is 0 or a number up to 2 and R and R1 are aliphatic, alicyclic, aryl, aralkyl, alkaryl or heterocyclic radicles which may carry substituents such as halogen atoms. In examples, bis-(trimethylsiloxy) dimethyl stannane is added to organopolysiloxanes.

    Abstract translation: 一种润滑剂包括（1）每个硅原子平均具有1,98-2,25个有机基团的液体聚合有机聚硅氧烷和（2）少量下式的化合物：＆lt;形式：0847336 / IV（a）/ 1 >其中m是0或高达2的数，R和R 1是可携带取代基如卤素原子的脂族，脂环族，芳基，芳烷基，烷芳基或杂环基。 在实施例中，将双（三甲基甲硅烷氧基）二甲基锡烷加入到甲基氯苯基聚硅氧烷中，用三甲基甲硅烷基连接并具有稠合的二甲基甲硅烷氧基和氯代苯基 - 甲硅烷氧基。 二（三甲基甲硅烷氧基）二甲基锡烷是通过使六甲基二硅氧烷与氟化铵和硫酸反应得到三氟甲硅烷并将其水解成相应的硅烷醇来制备的。 硅烷醇与钠反应，得到三甲基硅烷醇钠，与二甲基二氯化锡反应，得到双（三甲基甲硅烷氧基）二甲基锡烷。 规格586,187,586956和709,920。适用于在高温下重负荷下使用的润滑剂包括（1）每硅原子平均具有1.98-2.25个有机基团的液体聚合物有机聚硅氧烷和（2）一种 较小比例的式：的化合物，其中m为0或至多2的数，R和R 1为脂族，脂环，芳基，芳烷基，烷芳基或杂环基，其可带有取代基例如 卤原子。 在实施例中，将双（三甲基甲硅烷氧基）二甲基锡烷加入到有机聚硅氧烷中。

    Alkali metal sulfate substituted organosiloxanes containing internal sulfate groups and process therefor
    13.
    发明授权
    Alkali metal sulfate substituted organosiloxanes containing internal sulfate groups and process therefor 失效
    含有内硫酸根的碱金属硫酸盐取代的有机硅氧烷及其工艺

    公开(公告)号：US3412129A

    公开(公告)日：1968-11-19

    申请号：US51609965

    申请日：1965-12-23

    Applicant: GEN ELECTRIC

    Inventor： HOLDSTOCK NORMAN G

    IPC: C07F7/08 ,  C08G77/00 ,  C08G77/48

    CPC classification number: C07F7/0856 ,  C08G77/00 ,  C08G77/48 ,  Y10S516/01

    Abstract: 1,154,479. Organosilicon polymers. GENERAL ELECTRIC CO. 14 Oct., 1966 [23 Dec., 1965], No. 46014/66. Headings C3S and C3T. Organosilicon polymers of the formula wherein M is Na or K, R is an alkyl radical of 1 to 3 C atoms, R 1 is a monovalent h.c. radical free of aliphatic unsaturation having not more than 7 C atoms, R 11 is H or R 1 , a = 3 to 8, x = 1 to 10, y = 0 to 150 and z = 0 to 150, can be made by reacting a sila-oxacycloalkane of the formula with from 0À5 to 1À1 moles per mole of silaoxacycloalkane of conc.H 2 SO 4 or oleum, with subsequent neutralization of the reaction product with a Na or K base. If desired, a diorganopolysiloxane may be added as a coreactant. The first step of the reaction is effected at 0‹ to 100‹ C., and the neutralization is effected in an aqueous medium, preferably at room temperature, after which water is removed and the polymer is obtained by solvent extraction. Examples describe the above preparation of the polymers, and in Example (1) there is also obtained a disiloxane of the formula Uses: as cosmetic and general surfactants, and as self-emulsifying organosilicon materials.

    Lubricating oil composition containing a silicon-tin-containing compound
    15.
    发明授权
    Lubricating oil composition containing a silicon-tin-containing compound 失效
    含有含锡锡化合物的润滑油组合物

    公开(公告)号：US2937994A

    公开(公告)日：1960-05-24

    申请号：US70195657

    申请日：1957-12-11

    Applicant: GEN ELECTRIC

    Inventor： HOLDSTOCK NORMAN G

    IPC: C07F7/22 ,  C08G77/58

    CPC classification number: C07F7/2212 ,  C08G77/58 ,  C10M1/08 ,  C10M3/00 ,  C10M2207/282 ,  C10M2207/34 ,  C10M2207/40 ,  C10M2207/404 ,  C10M2219/108 ,  C10M2227/083 ,  C10M2229/02 ,  C10M2229/041 ,  C10M2229/05 ,  C10M2229/051 ,  C10N2220/02 ,  C10N2230/08 ,  C10N2240/08 ,  C10N2240/12 ,  C10N2240/121

    Abstract: A lubricant comprises a liquid lubricating material and a minor proportion of a compound of formula wherein n is a number up to 1000 and R and R1 are aliphatic, alicyclic, aryl, aralkyl, alkaryl or heterocyclic radicles, which may carry substituents such as halogen atoms. The lubricating material may be a mineral or vegetable oil or a synthetic lubricant such as a polysiloxane. In examples, bischloromethyltetramethyldisiloxane is converted to the corresponding di-Grignard reagent by reaction with magnesium and diethyl ether, and this Grignard reagent is reacted with dimethyl tin dichloride. The reaction product is employed as an additive for mineral oil, polysiloxanes or di (2-ethylhexyl) sebacate (together with thiodiphenylamine as rust inhibitor and a methyl silicone oil as foam inhibitor). Specifications 586,187, 586,956 and 709,920 are referred to.ALSO:A lubricant, especially suitable for use under heavy load at high temperatures, comprises a liquid lubricating material and a minor proportion of a compound of formula: wherein n is a number up to 1000 and R and R1 are aliphatic, alicyclic, aryl, aralkyl, alkaryl or heterocyclic radicles, which may carry substituents such as halogen atoms. The lubricating material may be a mineral or vegetable oil or a synthetic lubricant such as a polysiloxane. In examples, bischloromethyltetramethyldisiloxane is converted to the corresponding di-Grignard reagent by reaction with magnesium and diethyl ether, and this Grignard reagent is reacted with dimethyl tin dichloride. The reaction product is employed as an additive for mineral oil, polysiloxanes or di(2-ethylhexyl) sebacate (together with thiodiphenylamine as rust inhibitor and a methyl silicone oil as foam inhibitor). Specifications 586,187, 586,956 and 709,920 are referred to.

    Abstract translation: 润滑剂包括液体润滑材料和少量式（FORM：0847335 / IV（a）/ 1）的化合物，其中n是高达1000的数，R和R 1是脂族，脂环族，芳基，芳烷基，烷芳基 或杂环基团，其可以携带取代基如卤素原子。 润滑材料可以是矿物或植物油或合成润滑剂如聚硅氧烷。 在实施例中，通过与镁和二乙醚反应将双氯甲基四甲基二硅氧烷转化为相应的二格氏试剂，并将该格氏试剂与二氯甲烷二氯化锡反应。 反应产物用作矿物油，聚硅氧烷或癸二酸二（2-乙基己基）酯（与硫代二苯胺作为防锈剂和甲基硅油作为抑泡剂）的添加剂。 特别适用于高温重载下使用的润滑剂包括液体润滑材料和少量下列化合物：的化合物， 其中n是高达1000的数，R和R 1是脂族，脂环，芳基，芳烷基，烷芳基或杂环基，其可以带有取代基如卤原子。 润滑材料可以是矿物或植物油或合成润滑剂如聚硅氧烷。 在实施例中，通过与镁和二乙醚反应将双氯甲基四甲基二硅氧烷转化为相应的二格氏试剂，并将该格氏试剂与二氯甲烷二氯化锡反应。 反应产物用作矿物油，聚硅氧烷或癸二酸二（2-乙基己基）酯（与硫代二苯胺作为防锈剂和甲基硅油作为抑泡剂）的添加剂。 参考规格586,187,586956和709,920。

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