公开(公告)号：US09481789B2

公开(公告)日：2016-11-01

申请号：US14001391

申请日：2012-03-02

申请人： Masahiro Ichino ,  Manabu Kaneko ,  Kazuki Koga ,  Teppei Miura ,  Takuya Teranishi ,  Kiharu Numata ,  Kazutami Mitani ,  Tadao Samejima

发明人： Masahiro Ichino ,  Manabu Kaneko ,  Kazuki Koga ,  Teppei Miura ,  Takuya Teranishi ,  Kiharu Numata ,  Kazutami Mitani ,  Tadao Samejima

IPC分类号： C08J5/24 ,  C08L63/10 ,  C08G59/17 ,  C08G59/40 ,  C08K5/00

CPC分类号： C08L63/10 ,  B32B2305/076 ,  C08G59/1466 ,  C08G59/4021 ,  C08J5/24 ,  C08J2363/00 ,  C08J2363/10 ,  C08K5/0025 ,  Y10T428/27

摘要： The present invention relates to a method for producing a prepreg which contains reinforcing fibers and a matrix resin composition with the weight per square meter of the reinforcing fibers being 250-2,000 g/m2. The production method comprises the following steps (1)-(3): (1) a matrix resin composition blending step for obtaining a matrix resin composition by mixing an epoxy resin, a radically polymerizable unsaturated compound, an epoxy resin curing agent and a polymerization initiator that generates radicals, in said step the content of the radically polymerizable unsaturated compound relative to 100% by mass of the total of the epoxy resin and the radically polymerizable unsaturated compound being 10-25% by mass; (2) a matrix resin composition impregnating step; and (3) a surface viscosity increasing step.

摘要翻译： 本发明涉及含有增强纤维的预浸料坯的制造方法和每平方米加强纤维的重量为250〜2000g / m 2的基质树脂组合物。 制造方法包括以下步骤（1） - （3）：（1）通过混合环氧树脂，可自由基聚合的不饱和化合物，环氧树脂固化剂和聚合物来获得基质树脂组合物的基质树脂组合物混合步骤 在所述步骤中，自由基聚合性不饱和化合物的含量相对于环氧树脂和自由基聚合性不饱和化合物的总量的100质量％为10〜25质量％，生成自由基的引发剂; （2）基质树脂组合物浸渍步骤; 和（3）表面粘度增加步骤。

公开(公告)号：US08703244B2

公开(公告)日：2014-04-22

申请号：US12138729

申请日：2008-06-13

申请人： Shirou Asada ,  Hisao Koba ,  Akihiro Ito ,  Kazutami Mitani ,  Kimihiro Ikezaki ,  Koki Wakabayashi

发明人： Shirou Asada ,  Hisao Koba ,  Akihiro Ito ,  Kazutami Mitani ,  Kimihiro Ikezaki ,  Koki Wakabayashi

IPC分类号： B05D3/12

CPC分类号： C08K9/08 ,  B29B15/10 ,  B29C37/0075 ,  C08J5/24

摘要： A reinforced-fiber sheet impregnated with a matrix resin, a protective film having an irregular surface is applied to at least one surface of the reinforced-fiber sheet impregnated with the matrix resin such that the irregular surface faces the reinforced-fiber sheet. The thus-formed reinforced-fiber sheet covered with a protective film is kept at a temperature of 50-130° C. for four hours or more such that the viscosity of the impregnated resin is 100-10000 poise.

摘要翻译： 将浸渍有基质树脂的增强纤维片材，具有不规则表面的保护膜施加到浸渍有基质树脂的增强纤维片材的至少一个表面，使得不规则表面面向增强纤维片材。 将由保护膜覆盖的如此形成的增强纤维片材保持在50-130℃的温度下4小时以上，使得浸渍树脂的粘度为100-100泊。

公开(公告)号：US20130327479A1

公开(公告)日：2013-12-12

申请号：US14001391

申请日：2012-03-02

申请人： Masahiro Ichino ,  Manabu Kaneko ,  Kazuki Koga ,  Teppei Miura ,  Takuya Teranishi ,  Kiharu Numata ,  Kazutami Mitani ,  Tadao Samejima

发明人： Masahiro Ichino ,  Manabu Kaneko ,  Kazuki Koga ,  Teppei Miura ,  Takuya Teranishi ,  Kiharu Numata ,  Kazutami Mitani ,  Tadao Samejima

IPC分类号： C08L63/10

CPC分类号： C08L63/10 ,  B32B2305/076 ,  C08G59/1466 ,  C08G59/4021 ,  C08J5/24 ,  C08J2363/00 ,  C08J2363/10 ,  C08K5/0025 ,  Y10T428/27

摘要： The present invention relates to a method for producing a prepreg which contains reinforcing fibers and a matrix resin composition with the weight per square meter of the reinforcing fibers being 250-2,000 g/m2. The production method comprises the following steps (1)-(3): (1) a matrix resin composition blending step for obtaining a matrix resin composition by mixing an epoxy resin, a radically polymerizable unsaturated compound, an epoxy resin curing agent and a polymerization initiator that generates radicals, in said step the content of the radically polymerizable unsaturated compound relative to 100% by mass of the total of the epoxy resin and the radically polymerizable unsaturated compound being 10-25% by mass; (2) a matrix resin composition impregnating step; and (3) a surface viscosity increasing step.

摘要翻译： 本发明涉及含有增强纤维的预浸料坯的制造方法和每平方米加强纤维的重量为250〜2000g / m 2的基质树脂组合物。 制造方法包括以下步骤（1） - （3）：（1）通过混合环氧树脂，可自由基聚合的不饱和化合物，环氧树脂固化剂和聚合物来获得基质树脂组合物的基质树脂组合物混合步骤 在所述步骤中，自由基聚合性不饱和化合物的含量相对于环氧树脂和自由基聚合性不饱和化合物的总量的100质量％为10〜25质量％，生成自由基的引发剂; （2）基质树脂组合物浸渍步骤; 和（3）表面粘度增加步骤。

公开(公告)号：US20050101748A1

公开(公告)日：2005-05-12

申请号：US11016742

申请日：2004-12-21

申请人： Takashi Kaneko ,  Kazutami Mitani

发明人： Takashi Kaneko ,  Kazutami Mitani

IPC分类号： C08G59/38 ,  C08G59/50 ,  C08L63/00 ,  C08G59/04

CPC分类号： C08G59/38 ,  C08G59/5033 ,  C08L63/00 ,  Y10T428/24994

摘要： An epoxy resin composition according to the present invention is an epoxy resin composition with a viscosity at 25° C. of no more than 1000 mPa·s, incorporating (A) at least one of a bisphenol type epoxy resin (A1) and a phenol novolak type epoxy resin (A2), a polyvalent epoxy resin formed from a mononuclear aromatic backbone (B) and an aromatic amine curing agent (C), wherein a cured product produced by curing the epoxy resin composition displays a breaking elongation of at least, 5%. The epoxy resin composition has a low viscosity at room temperature which can be sustained with good stability for long periods. Furthermore, a cured product produced by curing the epoxy resin composition displays excellent heat resistance and mechanical characteristics, and is consequently ideally suited for use as a matrix resin for fiber reinforced composite materials.

摘要翻译： 根据本发明的环氧树脂组合物是在25℃下的粘度不超过1000mPa.s的环氧树脂组合物，其中（A）至少一种双酚型环氧树脂（A1）和苯酚 酚醛清漆型环氧树脂（A2），由单核芳香骨架（B）和芳香胺固化剂（C）形成的多价环氧树脂，其中通过固化环氧树脂组合物制备的固化产物至少显示出断裂伸长率， 5％。 环氧树脂组合物在室温下具有低粘度，可长时间保持良好的稳定性。 此外，通过固化环氧树脂组合物生产的固化产物显示出优异的耐热性和机械特性，因此理想地适合用作纤维增强复合材料的基质树脂。

公开(公告)号：US20130338266A1

公开(公告)日：2013-12-19

申请号：US13983088

申请日：2012-02-16

申请人： Masao Tomioka ,  Manabu Kaneko ,  Kazutami Mitani

发明人： Masao Tomioka ,  Manabu Kaneko ,  Kazutami Mitani

IPC分类号： C08L63/00 ,  C08L63/04

CPC分类号： C08L63/04 ,  C08G59/304 ,  C08G59/3272 ,  C08J5/24 ,  C08J2363/00 ,  C08J2363/04 ,  C08J2463/00 ,  C08J2463/04 ,  C08L63/00 ,  C08L2201/02 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/03

摘要： The present invention relates to an epoxy resin composition which comprises a phosphorus-containing modified epoxy resin (A) consisting of a compound (a) represented by Formula (a); a novolak epoxy resin (B); a hardener (C) for epoxy resins; and a metal hydroxide (D), wherein the content in mass % of the phosphorus-containing modified epoxy resin (A), CA, and the content in mass % of the metal hydroxide (D), CD, relative to the total amount of the epoxy resin composition, satisfy the following Formulas (1), (2), and (3): (1) 2.5CA+CD≧5; (2) 6≦CA≦40; and (3) 3≦CD≦30. This epoxy resin composition can give a composite material which has excellent flame retardancy even when neither a halogenated flame retardant, nor red phosphorus, nor a phosphoric acid ester is contained therein. According to the invention, it is also possible to provide a prepreg and a fiber-reinforced composite material obtained using the prepreg.

摘要翻译： 本发明涉及包含由式（a）表示的化合物（a）组成的含磷改性环氧树脂（A）的环氧树脂组合物。 酚醛清漆环氧树脂（B）; 环氧树脂用固化剂（C） 和金属氢氧化物（D），其中，所述含磷改性环氧树脂（A），CA的质量％含量和所述金属氢氧化物（D）的质量％的含量相对于所述金属氢氧化物的总量 环氧树脂组合物满足下列公式（1），（2）和（3）：（1）2.5CA + CD> = 5; （2）6 @ CA @ 40; 和（3）3 @ C​​D @ 30。 该环氧树脂组合物即使不含有卤化阻燃剂，也不含磷酸酯，也可以得到阻燃性优异的复合材料。 根据本发明，还可以提供使用预浸料获得的预浸料和纤维增强复合材料。

公开(公告)号：US06875825B2

公开(公告)日：2005-04-05

申请号：US10148873

申请日：2000-12-13

申请人： Takashi Kaneko ,  Kazutami Mitani

发明人： Takashi Kaneko ,  Kazutami Mitani

IPC分类号： C08G59/38 ,  C08G59/50 ,  C08L63/00 ,  B32B17/04 ,  B32B27/04 ,  C08L63/02 ,  C08L63/04

CPC分类号： C08G59/38 ,  C08G59/5033 ,  C08L63/00 ,  Y10T428/24994

摘要： A composition useful as a matrix for fiber-reinforced composites possesses a viscosity at 25° C. of no more than 1000 mPa's, and provides a cured product displays a breaking elongation of at least 5%. The composition comprises (A) at least one of a bisphenol epoxy resin (A1) and a phenol novolak type epoxy resin (A2), a polyvalent epoxy resin formed from a mononuclear aromatic backbone (B), and an aromatic amine curing agent (C).

摘要翻译： 用作纤维增强复合材料的基质的组合物在25℃下的粘度不超过1000mPa，并且提供固化产物显示至少5％的断裂伸长率。 组合物包含（A）双酚环氧树脂（A1）和苯酚酚醛清漆型环氧树脂（A2）中的至少一种，由单核芳香骨架（B）形成的多价环氧树脂和芳香族胺固化剂（C ）。

公开(公告)号：US20130330478A1

公开(公告)日：2013-12-12

申请号：US13985743

申请日：2012-02-16

申请人： Hisaya Ushiyama ,  Yasuhiro Fukuhara ,  Kazuki Koga ,  Tomoo Sano ,  Kazutami Mitani

发明人： Hisaya Ushiyama ,  Yasuhiro Fukuhara ,  Kazuki Koga ,  Tomoo Sano ,  Kazutami Mitani

IPC分类号： C09D163/00

CPC分类号： C09D163/00 ,  B29C70/443 ,  B29C70/48 ,  C08G59/4064 ,  C08G59/50 ,  C08G59/5033 ,  C08G59/56 ,  C08J5/24 ,  C08J2363/00

摘要： Provided is a method for producing a good epoxy resin composition for obtaining fiber-reinforced plastics. A production method for obtaining a fiber-reinforced composite material by impregnating a fiber assembly with an epoxy resin composition and then curing the epoxy resin composition, wherein the epoxy resin composition contains a component [A], a component [B] and a component [C] respectively satisfying the conditions described below. When the blending amount of the component [B] is set to b parts by mass and the blending amount of the component [C] is set to c parts by mass relative to 100 parts by mass of the component [A] contained in the epoxy resin composition, formula (2) is satisfied within the range of formula (1), formula (4) is satisfied within the range of formula (3), and formula (6) is satisfied within the range of formula (5).

摘要翻译： 提供一种制备用于获得纤维增强塑料的良好环氧树脂组合物的方法。 一种通过用环氧树脂组合物浸渍纤维组合物然后固化环氧树脂组合物来获得纤维增强复合材料的方法，其中环氧树脂组合物含有组分[A]，组分[B]和组分[ C]分别满足下述条件。 当将组分[B]的配合量设定为b质量份时，相对于100质量份的环氧树脂中含有的成分[A]，成分[C]的配合量为c质量份 在式（1）的范围内满足式（2），式（3）的范围内满足式（4），在式（5）的范围内满足式（6）。

公开(公告)号：US20080248204A1

公开(公告)日：2008-10-09

申请号：US12138729

申请日：2008-06-13

申请人： Shirou Asada ,  Hisao Koba ,  Akihiro Ito ,  Kazutami Mitani ,  Kimihiro Ikezaki ,  Koki Wakabayashi

发明人： Shirou Asada ,  Hisao Koba ,  Akihiro Ito ,  Kazutami Mitani ,  Kimihiro Ikezaki ,  Koki Wakabayashi

IPC分类号： B05D5/02

CPC分类号： C08K9/08 ,  B29B15/10 ,  B29C37/0075 ,  C08J5/24

摘要： The present invention relates to a prepreg which is free from the phenomenon that air is trapped between layers to generate voids, has good handling characteristics and can produce molded articles having any complicated shape and also relates to a method of producing the prepreg. A reinforced-fiber sheet is impregnated with a matrix resin so as to form a continuous resin layer at least in the inside thereof, and then, a protective film having an irregular surface is applied to at least one surface of the reinforced-fiber sheet impregnated with the matrix resin such that the irregular surface faces the reinforced-fiber sheet. In this state, the prepreg is allowed to leave at 30 to 60° C. under the atmosphere for 12 hours or more. The resulting prepreg (1) is provided with a continuous resin layer (3a) which exists therein, wherein at least one surface of one side of the prepreg is constituted of a resin-impregnated part (3b) where the impregnated resin substantially exists and a fiber part (2a) where no resin substantially exists.

摘要翻译： 本发明涉及一种预浸料坯，其没有空气被捕获在层之间以产生空隙的现象，具有良好的处理特性，并且可以生产具有任何复杂形状的模制品，并且还涉及制备预浸料的方法。 增强纤维片材用基质树脂浸渍，以便至少在其内部形成连续的树脂层，然后将具有不规则表面的保护膜施加到浸渍的增强纤维片材的至少一个表面上 基体树脂使得不规则表面面向增强纤维片材。 在这种状态下，允许预浸料在30〜60℃下在大气中离开12小时以上。 所得到的预浸料坯（1）上设置有存在于其中的连续树脂层（3a），其中预浸料坯一侧的至少一个表面由浸渍树脂基本存在的树脂浸渍部分（3b）构成 以及基本上不存在树脂的纤维部分（2a）。

公开(公告)号：US07230052B2

公开(公告)日：2007-06-12

申请号：US11016742

申请日：2004-12-21

申请人： Takashi Kaneko ,  Kazutami Mitani

发明人： Takashi Kaneko ,  Kazutami Mitani

IPC分类号： B32B17/04 ,  B32B27/04 ,  C08L63/02 ,  C08L63/04

CPC分类号： C08G59/38 ,  C08G59/5033 ,  C08L63/00 ,  Y10T428/24994

摘要： A composition useful as a matrix for fiber-reinforced composites possesses a viscosity at 25° C. of no more than 1000 mPa·s and provides a cured product displaying a breaking elongation of at least 5%. The composition comprises (A) at least one of a bisphenol epoxy resin (A1) and a phenol novolak epoxy resin (A2), a polyvalent epoxy resin formed from a mononuclear aromatic backbone (B), an aromatic amine curing agent (C), and a rubber (D).

摘要翻译： 用作纤维增强复合材料的基质的组合物在25℃下的粘度不超过1000mPa.s，并提供显示至少5％的断裂伸长率的固化产物。 该组合物包含（A）双酚环氧树脂（A1）和酚醛清漆环氧树脂（A2）中的至少一种，由单核芳香骨架（B），芳香胺固化剂（C）形成的多价环氧树脂， 和橡胶（D）。

公开(公告)号：US06828016B2

公开(公告)日：2004-12-07

申请号：US10742898

申请日：2003-12-23

申请人： Kazutami Mitani ,  Kazuya Goto

发明人： Kazutami Mitani ,  Kazuya Goto

IPC分类号： B32B1504

CPC分类号： B32B27/34 ,  B29B11/16 ,  B29C70/086 ,  B29C70/48 ,  B29L2009/00 ,  B32B3/22 ,  B32B5/26 ,  Y10T428/24612 ,  Y10T428/24744 ,  Y10T428/2476 ,  Y10T428/24851 ,  Y10T428/249924 ,  Y10T428/249953 ,  Y10T428/249994 ,  Y10T428/25 ,  Y10T428/253 ,  Y10T428/254 ,  Y10T428/269 ,  Y10T428/27 ,  Y10T428/2913 ,  Y10T428/2918 ,  Y10T428/2967

摘要： A preform can be molded by resin transfer molding and yields a composite material having excellent strength and excellent interlaminar debonding resistance. The preform, which is for producing a fiber-reinforced composite, comprises layers of laminated structure of a reinforcing material comprising reinforcement fibers and has, between these layers, a layer comprising a thermoplastic resin and having space so as not to inhibit a liquid resin from flowing therethrough. The preform is molded to yield a fiber-reinforced composite material.