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公开(公告)号：US6160074A
公开(公告)日：2000-12-12
申请号：US984188
申请日：1997-12-03
IPC分类号： C08G65/00 , C08G65/336 , C08G77/24 , C08G77/48 , C08L71/00 , C08L83/05 , C08L83/14 , C08L101/06
CPC分类号： C08G65/336 , C08G65/007
摘要： The invention provides a fluorine-containing curable composition comprising (A) a linear perfluoro compound having at least two alkenyl groups in its molecule and a divalent perfluoroalkylene or perfluoropolyether structure in its backbone, (B) a fluorinated organohydrogenpolysiloxane having at least four hydrosilyl groups in its molecule and a divalent perfluoro structure in its backbone, and (C) a platinum catalyst.
摘要翻译： 本发明提供一种含氟可固化组合物，其包含（A）在其分子中具有至少两个烯基的直链全氟化合物及其主链中的二价全氟亚烷基或全氟聚醚结构，（B）具有至少四个氢化甲硅烷基的氟化有机氢聚硅氧烷 其分子和其主链中的二价全氟结构，和（C）铂催化剂。
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公开(公告)号：US5705586A
公开(公告)日：1998-01-06
申请号：US494566
申请日：1995-06-22
IPC分类号： C07C235/08 , C07D295/185 , C07F7/21 , C08G65/00 , C08G65/336 , C08G69/42 , C08G77/46 , C08L83/08 , C08G77/26
CPC分类号： C07D295/185 , C07C235/08 , C07F7/21 , C08G65/007 , C08G65/336 , C08G69/42 , C08G77/46 , C08L83/08
摘要： Novel organic fluorine compounds are of formula (1): ##STR1## wherein R.sup.1 and R.sup.2 are monovalent hydrocarbon groups, Q.sup.1 is a group of formula (2) or (3): ##STR2## wherein R.sup.3 is a divalent hydrocarbon group which may have an intervening oxygen, nitrogen or silicon atom, R.sup.4 and R.sup.5 are divalent hydrocarbon groups, Rf.sup.1 is a divalent perfluoroalkylene or perfluoropolyether group, and letter a is an integer of 0-10. A curable composition comprising (A) a fluorinated amide compound having at least two aliphatic unsaturated groups of formula (1), (B) a fluorinated organohydrogensiloxane containing at least one monovalent perfluoroalkyl ether or perfluoroalkyl group and at least two hydrosilyl groups, and (C) a platinum group compound cures into elastomers solvent and chemical resistance.
摘要翻译： 新的有机氟化合物具有式（1）：其中R 1和R 2是一价烃基，Q 1是式（2）或（3）的基团：其中R 1和R 2是一价烃基， 3）其中R3是可以具有中间的氧，氮或硅原子的二价烃基，R4和R5是二价烃基，Rf1是二价全氟亚烷基或全氟聚醚基，而字母a是0-10的整数。 一种可固化组合物，其包含（A）具有至少两个式（1）的脂族不饱和基团的氟化酰胺化合物，（B）含有至少一个一价全氟烷基醚或全氟烷基和至少两个氢化甲硅烷基的氟化有机氢硅氧烷和（C ）铂族化合物固化成弹性体溶剂和耐化学性。
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公开(公告)号：US5380811A
公开(公告)日：1995-01-10
申请号：US70223
申请日：1993-06-02
CPC分类号： C08L83/14
摘要： A room temperature curable fluorine-containing organopolysiloxane composition comprising:(A) a fluorine-containing organosilicon compound having the general formula (1):R.sup.2 --NHCO--[Rf--CONH--R.sup.1 --Q--R.sup.1 --NHCO].sub.a --Rf--CONH--R.sup.2 (1) wherein a is an integer of 0 or more, Rf is a divalent perfluoroalkylene group or a divalent perfluoropolyether group, R.sup.1 is a divalent hydrocarbon group, R.sup.2 is a monovalent aliphatic unsaturated group-containing hydrocarbon group, and Q is a divalent siloxane group(B) a hydrogenorganopolysiloxane containing at least two Si--H groups in its molecule, and(C) a platinum family metal catalyst. The cured product of this composition exhibits good solvent resistance against non-polar solvents as well as polar solvents, in addition to good chemical resistance, heat resistance, release properties and water repellency.
摘要翻译： 一种室温固化型含氟有机聚硅氧烷组合物，其包含：（A）具有通式（1）的含氟有机硅化合物：R2-NHCO- [Rf-CONH-R1-Q-R1-NHCO] a-Rf-CONH -R2（1）其中a为0以上的整数，Rf为二价全氟亚烷基或二价全氟聚醚基，R 1为二价烃基，R 2为含脂肪族不饱和基团的一价烃基，Q为 二价硅氧烷基（B）分子中含有至少两个Si-H基团的氢有机聚硅氧烷，（C）铂族金属催化剂。 该组合物的固化产物除了具有良好的耐化学性，耐热性，脱模性和防水性外，对非极性溶剂以及极性溶剂表现出良好的耐溶剂性。
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公开(公告)号：US08143359B2
公开(公告)日：2012-03-27
申请号：US12620782
申请日：2009-11-18
IPC分类号： C08F30/08
CPC分类号： C07F7/081
摘要： The purpose of the present invention is to provide an organic silicon compound which has a vinyl group more reactive than those of the conventional organic silicon compounds and can be bonded with another compound.The present organic silicon compound is represented by the following formula (1), wherein R1 is, independently of each other, a vinyl group or an alkyl group having 1 to 4 carbon atoms, R2 is an alkylene group having 3 to 6 carbon atoms, and R3 is, independently of each other, a hydrogen atom or an alkyl group having 1 to 4 carbon atoms and optionally substituted with one or more fluorine atoms.
摘要翻译： 本发明的目的是提供一种有机硅化合物，其具有比常规有机硅化合物更具反应活性的乙烯基，并可与另一种化合物结合。 本发明的有机硅化合物由下式（1）表示，其中R 1彼此独立地为乙烯基或具有1至4个碳原子的烷基，R 2为具有3至6个碳原子的亚烷基， 并且R 3彼此独立地为氢原子或具有1至4个碳原子并且任选被一个或多个氟原子取代的烷基。
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公开(公告)号：US5117026A
公开(公告)日：1992-05-26
申请号：US723980
申请日：1991-07-01
申请人： Hirofumi Kishita , Kouichi Yamaguchi , Hideki Fujii , Shuji Suganuma , Yoshikazu Saito , Shinichi Sato , Kenichi Fukuda , Nobuyuki Kobayashi
发明人： Hirofumi Kishita , Kouichi Yamaguchi , Hideki Fujii , Shuji Suganuma , Yoshikazu Saito , Shinichi Sato , Kenichi Fukuda , Nobuyuki Kobayashi
IPC分类号： C07F7/12
CPC分类号： C07F7/12
摘要： The synthesis and use of a fluorine-containing organic silicon compound represented by: ##STR1## wherein each R.sup.1 independently represents a monovalent hydrocarbon group of 1-10 carbon atoms, and each R.sup.2 independently represents a monovalent hydrocarbon group of 1-10 carbon atoms or a CH.sub.2 CH.sub.2 Rf group, such that at least one R.sup.2 is CH.sub.2 CH.sub.2 Rf, wherein Rf is a perfluoroalkyl group of 1-10 carbon atoms; the compounds of formula (I) are useful in the preparation of fluorine-containing polysilethylenesiloxanes having excellent solvent-resisting and surface-lubricating properties.
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公开(公告)号：US20100160588A1
公开(公告)日：2010-06-24
申请号：US12620782
申请日：2009-11-18
IPC分类号： C08F130/08 , C07F7/10
CPC分类号： C07F7/081
摘要： The purpose of the present invention is to provide an organic silicon compound which has a vinyl group more reactive than those of the conventional organic silicon compounds and can be bonded with another compound.The present organic silicon compound is represented by the following formula (1), wherein R1 is, independently of each other, a vinyl group or an alkyl group having 1 to 4 carbon atoms, R2 is an alkylene group having 3 to 6 carbon atoms, and R3 is, independently of each other, a hydrogen atom or an alkyl group having 1 to 4 carbon atoms and optionally substituted with one or more fluorine atoms.
摘要翻译： 本发明的目的是提供一种有机硅化合物，其具有比常规有机硅化合物更具反应活性的乙烯基，并可与另一种化合物结合。 本发明的有机硅化合物由下式（1）表示，其中R 1彼此独立地为乙烯基或具有1至4个碳原子的烷基，R 2为具有3至6个碳原子的亚烷基， 并且R 3彼此独立地为氢原子或具有1至4个碳原子并且任选被一个或多个氟原子取代的烷基。
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公开(公告)号：US5281695A
公开(公告)日：1994-01-25
申请号：US883195
申请日：1992-05-14
CPC分类号： C08G65/321 , C07C43/126
摘要： The present compound is a novel perfluoropolyether represented by the following general formula: ##STR1## wherein m is an integer of 1 to 3 and n is an integer of 2 to 6. This compound is quite useful as an inert liquid used as a heat transfer mediums in the filed of electronic materials.
摘要翻译： 本发明化合物是由以下通式表示的新型全氟聚醚：其中m为1至3的整数，n为2至6的整数。该化合物作为用作传热的惰性液体是非常有用的 媒体在电子材料领域。
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18.发明授权Perfluoropolyether rubber composition and ion-conducting polymer electrolyte membrane 有权全氟聚醚橡胶组合物和离子导电高分子电解质膜公开(公告)号：US07838616B2
公开(公告)日：2010-11-23
申请号：US11924181
申请日：2007-10-25
IPC分类号： C08G77/12
CPC分类号： C08L71/02 , C08G65/007 , C08G2650/48 , C08J5/2275 , C08J5/2281 , C08J2371/02 , C08J2383/08 , H01M8/1027 , H01M8/103 , H01M8/1037 , H01M8/1039 , H01M8/1072 , Y02P70/56 , C08L83/00
摘要： A perfluoropolyether rubber composition is useful for forming a polymer electrolyte membrane, comprising (A) an alkenyl-containing perfluoropolyether, (B) a silicon-oxygen crosslinked structure having ionic conduction, and (C) a peroxide crosslinker. The silicon-oxygen crosslinked structure is obtained by simultaneously effecting oxidation and hydrolysis on an organoxysilane having an epoxy group and an organoxysilane having a mercapto group for thereby converting the mercapto group into a sulfonic group, and neutralizing the resulting sulfonic group-containing siloxane with a nitrogen-containing compound.
摘要翻译： 全氟聚醚橡胶组合物可用于形成聚合物电解质膜，其包含（A）含烯基的全氟聚醚，（B）具有离子导电性的硅 - 氧交联结构和（C）过氧化物交联剂。 通过在具有环氧基的有机氧基硅烷和具有巯基的有机氧基硅烷上同时进行氧化和水解，从而将巯基转化为磺酸基，并将所得的含磺酸基的硅氧烷中和，得到硅 - 氧交联结构 含氮化合物。
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公开(公告)号：US5118828A
公开(公告)日：1992-06-02
申请号：US723317
申请日：1991-06-28
申请人： Toshio Takago , Hirofumi Kishita , Shinichi Sato , Hitoshi Kinami , Shuji Suganuma , Koichi Yamaguchi , Kenichi Fukuda , Hirokazu Yamada
发明人： Toshio Takago , Hirofumi Kishita , Shinichi Sato , Hitoshi Kinami , Shuji Suganuma , Koichi Yamaguchi , Kenichi Fukuda , Hirokazu Yamada
IPC分类号： C07F7/08
CPC分类号： C07F7/0841
摘要： The fluorine-containing organosilicon compound of the present invention is represented by the following formula: ##STR1## wherein Rf is a perfluoroalkyl group. This compound is quite useful as a raw material for the production of polysilethylenesiloxanes excellent in solvent resistance.
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公开(公告)号：US08865820B2
公开(公告)日：2014-10-21
申请号：US13048133
申请日：2011-03-15
IPC分类号： C09J183/07 , C08G77/08 , C08G65/336 , C08G65/00 , C08L83/16 , C08G77/12
CPC分类号： C08L83/16 , C08G65/007 , C08G65/336 , C08G77/12 , C08L2666/14
摘要： A fluorine-containing curable composition which is less viscous, and which can produce a cured article having excellent heat resistance, chemical resistance, solvent resistance, and mechanical strength is provided. The fluorine-containing curable composition comprises (a) 100 parts by weight of a straight chain fluorine-containing polymer having at least two alkenyl groups per molecule represented by the following formula (1): said polymer having a number average molecular weight of 1,000 to 100,000; (b) a fluorine-containing organosilicon compound having at least 2 hydrogen atoms bonded to the silicon atom per molecule at an amount such that molar ratio of hydrosilyl group (SiH group) in the component (b) to the alkenyl group in the component (a) is in the range of 0.4 to 5.0; (c) a catalytic amount of a hydrosilylation catalyst; and (d) 1 to 100 parts by weight of a silica filler.
摘要翻译： 提供了一种粘度较低并且可以制造具有优异的耐热性，耐化学性，耐溶剂性和机械强度的固化制品的含氟可固化组合物。 含氟可固化组合物包含（a）100重量份的由下式（1）表示的每分子具有至少两个烯基的直链含氟聚合物：所述聚合物的数均分子量为1,000〜 100,000; （b）具有至少2个氢原子的含氟有机硅化合物，每分子与硅原子键合，其量使得组分（b）中的氢化甲硅烷基（SiH基）与组分（b）中烯基的摩尔比 a）在0.4至5.0的范围内; （c）催化量的氢化硅烷化催化剂; 和（d）1至100重量份的二氧化硅填料。
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