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公开(公告)号：US5288889A
公开(公告)日：1994-02-22
申请号：US60537
申请日：1993-05-13
申请人： Toshio Takago , Shinichi Sato , Hitoshi Kinami , Noriyuki Koike
发明人： Toshio Takago , Shinichi Sato , Hitoshi Kinami , Noriyuki Koike
IPC分类号： C07F7/18 , C08G65/02 , C08G65/04 , C08G65/32 , C08G65/333 , C08G65/336 , C08G65/48 , C09K3/00 , C09K3/18 , C07F7/10
CPC分类号： C08G65/33306 , C07F7/184 , C08G65/336
摘要： A fluorinated organic silicon compound of a structure having a fluorinated polyether group in its backbone and an isopropenoxysilyl group attached at either end forms a compliant coating on the surface of any substrate such as silicone rubber which is effective in imparting water and oil repellency and stain resistance to silicone rubber surface.
摘要翻译： 在其主链上具有氟化聚醚基团的结构的氟化有机硅化合物和任一端连接的异丙烯氧基甲硅烷基在任何基材例如硅橡胶的表面上形成柔顺涂层，其有效地赋予拒水拒油性和抗污性 到硅橡胶表面。
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公开(公告)号：US5241096A
公开(公告)日：1993-08-31
申请号：US961369
申请日：1992-10-15
IPC分类号： C07F7/18 , C08G77/22 , C08G77/24 , C08K5/5419 , C08L83/04
CPC分类号： C07F7/1896
摘要： A fluorine-containing organosilicon compound according to the present invention is expressed by the general formula: ##STR1## wherein Rf is a perfluoropolyether group having 3 to 17 carbon atoms, R is an alkylene group having 1 to 6 carbon atoms or an ether group expressed by the general formula:--R.sup.1 --O--R.sup.2 --wherein R.sup.1 and R.sup.2 may be the same or different and are each alkylene groups having 1 to 6 carbon atoms. The fluorine-containing organosilicon compound is highly useful as a curing agent for organopolysiloxane compositions that are condensation curable at room temperature.
摘要翻译： 根据本发明的含氟有机硅化合物由以下通式表示：其中Rf是具有3至17个碳原子的全氟聚醚基团，R是具有1至6个碳原子的亚烷基或表示的醚基团 通式为：-R 1 -O-R 2 - ，其中R 1和R 2可以相同或不同，并且各自是具有1至6个碳原子的亚烷基。 含氟有机硅化合物作为在室温下可缩合固化的有机聚硅氧烷组合物的固化剂是非常有用的。
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公开(公告)号：US5239034A
公开(公告)日：1993-08-24
申请号：US739428
申请日：1991-08-02
CPC分类号： C08L83/14
摘要： Silicone rubber compositions, of the addition curable type, comprise as a base polymer a vinyl-containing organopolysiloxane having a tetraorganosilethylenesiloxane unit of the following general formula: ##STR1## wherein R.sup.1 to R.sup.4 are each a monovalent hydrocarbon group of from 1 to 10 carbon atoms. The silicone rubber composition gives a cured product having high strength, for example, a tensile strength of 30 kg/cm.sup.2 or above, without compounding fillers or reinforcing agents.
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公开(公告)号：US5200440A
公开(公告)日：1993-04-06
申请号：US606870
申请日：1990-10-31
申请人： Toshio Takago , Hiroshi Inomata , Shinichi Sato , Hitoshi Kinami
发明人： Toshio Takago , Hiroshi Inomata , Shinichi Sato , Hitoshi Kinami
CPC分类号： C09C1/3081 , C07F7/1844 , C07F7/1852 , C08K9/06 , C01P2006/12
摘要： An organosilicone-treated silica obtained by treating(A) a silica powder having a specific surface area of at least 50 m.sup.2 /g with(B) a triorgano(1-alkoxyvinyloxy)silane having the formula (I): ##STR1## wherein R.sup.1 is a monovalent hydrocarbon group or an ether linkage-containing organic group, and R.sup.2 are each a substituted or unsubstituted monovalent hydrocarbon group or an ether linkage-containing organic group. The invention also discloses an organopolysiloxane composition containing the organosilicone-treated silica and a process preparing the composition. The organosilicone-treated silica is of high quality, containing no substance with disagreeable smell or corrosiveness which has been by-produced heretofore. Hence, the composition containing the silica is free from pseudocrosslinking such as structuring or crepe hardening.
摘要翻译： 通过（B）具有式（I）的三有机（1-烷氧基乙烯基氧基）硅烷处理（A）比表面积至少为50m 2 / g的二氧化硅粉末得到的经有机硅氧烷处理的二氧化硅： ）其中R1是一价烃基或含醚键的有机基团，R 2各自是取代或未取代的一价烃基或含醚键的有机基团。 本发明还公开了含有机硅氧烷处理的二氧化硅的有机聚硅氧烷组合物和制备该组合物的方法。 有机硅氧烷处理的二氧化硅是高品质的，不含有迄今为止副产生的具有令人不愉快的气味或腐蚀性的物质。 因此，含有二氧化硅的组合物没有伪交联，例如结构化或起皱硬化。
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公开(公告)号：US5399754A
公开(公告)日：1995-03-21
申请号：US233802
申请日：1994-04-26
CPC分类号： C07C51/58
摘要： A process of producing a perfluorocarboxylic acid fluoride having the formula (1): ##STR1## wherein n is an integer of at least 2, comprising effecting oligomerization of hexafluoropropylene oxide in the presence of an alkali metal fluoride a sulfone or a mixture of a sulfone with an ether having the formula (2):CH.sub.3 O(CH.sub.2 CH.sub.2 O).sub.m CH.sub.3 (2)where m is an integer of 2 to 6. This process makes it possible to improve production yield of hexafluoropropylene oxide oligomers remarkably, and to raise a reaction temperature for the oligomerization, as compared with conventional methods, thereby shortening reaction time therefor.
摘要翻译： 一种制备具有式（1）的全氟羧酸氟化物的方法：其中n是至少为2的整数，包括在碱金属氟化物a砜或混合物存在下进行六氟环氧丙烷的低聚反应 具有式（2）的醚的砜：CH 3 O（CH 2 CH 2 O）m CH 3（2）其中m是2至6的整数。该方法可以显着提高六氟环氧丙烷低聚物的产率，并提高 与常规方法相比，用于低聚的反应温度，从而缩短了其反应时间。
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6.发明授权Room temperature curable organopolysiloxane composition and cured product of the same 失效室温可固化的有机聚硅氧烷组合物和固化产物相同
公开(公告)号：US5314981A
公开(公告)日：1994-05-24
申请号：US37322
申请日：1993-03-26
申请人： Toshio Takago , Shinichi Sato , Hitoshi Kinami , Hirokazu Yamada
发明人： Toshio Takago , Shinichi Sato , Hitoshi Kinami , Hirokazu Yamada
摘要： A room temperature curable organopolysiloxane composition comprising: (A) 100 parts by weight of a diorganopolysiloxane blocked by hydroxyl group at both terminal ends of its molecule, (B) from 0.5 to 30 parts by weight of an organosilicon compound having at least three silicon-bonded hydrolyzable groups in its molecule or a partially hydrolyzed product of the organosilicon compound, (C) from 0.1 to 15 parts by weight of an alkoxysilane having the following general formula (1): ##STR1## wherein R.sup.1 and R.sup.2 are each an unsubstituted or substituted monovalent hydrocarbon group of from 1 to 8 carbon atoms, R.sup.3 is a divalent hydrocarbon group of from 1 to 8 carbon atoms which may contain an amide linkage (--CONH--) or ether oxygen linkage, Rf is a divalent perfluoroalkylene group or a divalent perfluoropolyether group, and n is an integer from 1 to 3, and a cured product of the composition. The composition and the cured product thereof ensure lessened contamination on surfaces of the cured product and in the surroundings, and permit easy removal of fungi, if any, from surfaces of the cured product.
摘要翻译： 一种室温可固化的有机聚硅氧烷组合物，其包含：（A）100重量份在其分子的两个末端被羟基封端的二有机聚硅氧烷，（B）0.5至30重量份的具有至少三个硅 - 其分子中的键合可水解基团或有机硅化合物的部分水解产物，（C）0.1至15重量份具有以下通式（1）的烷氧基硅烷：其中R 1和R 2各自为 1至8个碳原子的未取代或取代的一价烃基，R 3是可含有酰胺键（-CONH-）或醚氧键的1至8个碳原子的二价烃基，Rf是二价全氟亚烷基 或二价全氟聚醚基，n为1〜3的整数，以及所述组合物的固化物。 组合物和其固化产物确保了固化产物表面和周围环境中污染物的减少，容易从固化产物的表面除去真菌（如果有的话）。
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公开(公告)号：US5214177A
公开(公告)日：1993-05-25
申请号：US769483
申请日：1991-10-01
申请人： Masayuki Oyama , Toshio Takago , Hideki Fujii , Hitoshi Kinami
发明人： Masayuki Oyama , Toshio Takago , Hideki Fujii , Hitoshi Kinami
IPC分类号： C07F7/12
CPC分类号： C07F7/12
摘要： Fluorinated organic silicon compound of the general formula: ##STR1## wherein R is an alkyl group having 1 to 6 carbon atoms, n is an integer of from 1 to 6, and m is equal to 1, 2 or 3 are novel and useful as treating agents and intermediates for the synthesis of fluorinated cyclic organic silicon compounds. The fluorinated organic silicon compounds are prepared by reacting a chlorosilane with a fluorinated olefin.
摘要翻译： 具有以下通式的氟化有机硅化合物：其中R是具有1至6个碳原子的烷基，n是1至6的整数，m等于1,2或3是新的 并且可用作合成氟化环状有机硅化合物的处理剂和中间体。 氟化有机硅化合物通过氯硅烷与氟化烯烃反应制备。
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公开(公告)号：US5210253A
公开(公告)日：1993-05-11
申请号：US961361
申请日：1992-10-15
CPC分类号： C07F7/12 , C07F7/1836
摘要： Fluorine-containing organosilicon compound according to the present invention is expressed by the general formula: ##STR1## wherein Rf is a perfluoropolyether group having 3 to 17 carbon atoms, R is an alkylene group having 1 to 6 carbon atoms or a group of the general formula, --R.sup.2 --O--R.sup.3 --, wherein R.sup.2 and R.sup.3 may be the same or different and are each alkylene groups having 1 to 6 carbon atoms. The present compound is useful as a curing catalyst for organo-polysiloxane compounds that are condensation curable at room temperature. The compositions added with the fluorine-containing organosilicon compound have excellent characteristics such as water and oil repellencies, chemical resistance and contamination resistance and offer a variety of uses such as high performance sealing, coating and electric insulating materials.
摘要翻译： 根据本发明的含氟有机硅化合物由以下通式表示：其中Rf是具有3至17个碳原子的全氟聚醚基团，R是具有1至6个碳原子的亚烷基或一般的基团 R 2 -O-R 3 - ，其中R 2和R 3可以相同或不同，并且各自是具有1至6个碳原子的亚烷基。 本发明化合物可用作在室温下可缩合固化的有机聚硅氧烷化合物的固化催化剂。 加入含氟有机硅化合物的组合物具有防水拒油性，耐化学性和耐污染性等优异特性，并提供高性能密封，涂层和电绝缘材料等各种用途。
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公开(公告)号：US5196560A
公开(公告)日：1993-03-23
申请号：US720705
申请日：1991-06-25
CPC分类号： C07F7/14
摘要： Fluorine-containing dimethylchlorosilanes are prepared by reacting an ethylene compound having a fluorine-containing organic group with dimethylchlorosilane in the presence of a rhodium complex, for instance RhCl(PPh.sub.3) (Ph: phenyl group), as a catalyst. The use of a rhodium complex as a catalyst enables preparation in high yield of the fluorine-containing dimethylchlorosilane, which has been heretofore obtainable only in low yields.
摘要翻译： 含氟二甲基氯硅烷是通过在铑络合物例如RhCl（PPh 3）（Ph：苯基））作为催化剂的存在下使具有含氟有机基团的乙烯化合物与二甲基氯硅烷反应来制备的。 使用铑配合物作为催化剂使得能够以高产率制备含氟二甲基氯硅烷，其迄今为止仅以低收率获得。
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公开(公告)号：US5416183A
公开(公告)日：1995-05-16
申请号：US209066
申请日：1994-03-11
IPC分类号： C08G69/40 , C08G69/42 , C08L77/00 , C08L83/04 , C08L83/05 , C08L83/16 , C09K3/10 , C08G69/48 , C08G77/62
CPC分类号： C08L83/16
摘要： A room temperature curable composition comprising:(A) a fluorine-containing organosilicon compound having the formula (1):R.sup.2 --NHCO--[Rf.sup.1 --CONH--R.sup.1 --Q--R.sup.1 --NHCO].sub.a --Rf.sup.1 --CONH--R.sup.2 (1) wherein a is an integer of 0 or more, Rf.sup.1 is a perfluoroalkylene group or perfluoropolyether group, R.sup.1 is a divalent hydrocarbon group, R.sup.2 is a monovalent aliphatic unsaturated hydrocarbon group, and Q is a particular organosilicon group,(B) an organohydrogenpolysiloxane containing at least two Si--H groups in its molecule, and(C) a platinum family metal compound, the component (B) being contained such that the Si--H groups are contained in an amount of 0.5 to 5.0 moles per mole of the aliphatic unsaturated hydrocarbon group contained in the composition. The composition produces a cured product having good solvent resistance, chemical resistance, heat resistance and cold resistance.
摘要翻译： 一种室温固化性组合物，包括：（A）具有式（1）的含氟有机硅化合物：R2-NHCO- [Rf1-CONH-R1-Q-R1-NHCO] a-Rf1-CONH-R2（1） 其中a为0以上的整数，Rf 1为全氟亚烷基或全氟聚醚基，R 1为二价烃基，R 2为一价脂族不饱和烃基，Q为特定的有机硅基，（B）有机氢聚硅氧烷， 在其分子中至少有两个Si-H基团，和（C）铂族金属化合物，包含组分（B），使得每摩尔脂族不饱和单元含有0.5-5.0摩尔的Si-H基团 烃基包含在组合物中。 该组合物产生具有良好耐溶剂性，耐化学性，耐热性和耐寒性的固化产物。
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