Abstract:
Disclosed is a fuel unit for a gas generator such as a hydrogen gas generator that can supply gas to a gas consuming system such as a fuel cell system. The fuel unit includes a housing containing a solid fuel composition and a heat producing material. The fuel composition contains gas releasing solid material that reacts to release gas when heated. The heat producing material reacts exothermically to produce heat. A plurality of quantities of the heat producing material are in thermal communication with corresponding portions of an unsegregated quantity the fuel composition such that, following initiation of a reaction of each quantity of the heat producing material, the quantity of heat producing material will heat the corresponding portion of the unsegregated quantity of the fuel composition, and the corresponding portion of the unsegregated quantity of the fuel composition will react to release a quantity of the gas.
Abstract:
The invention relates to methods of forming an alane-etherate complex and α-alane from the alane-etherate complex. The methods include reacting an alkyl halide with a metal alanate in a solvent including an ether. A tertiary amine may also be added to the reaction. The alane is collected after removal of the solvent and/or the tertiary amine. An electrospraying process can be used to remove the solvent.
Abstract:
A hydrogen generator and a fuel cell system including a fuel cell battery and the hydrogen generator. The hydrogen generator includes a cartridge, a housing with a cavity to removably contain the cartridge, and an initiation system. The cartridge includes a casing; a plurality of pellets including a hydrogen containing material; a plurality of solid heat transfer members in contact with but not penetrating the casing; a hydrogen outlet in the casing; and a hydrogen flow path from each pellet to the hydrogen outlet. A plurality of heating elements is disposed inside the housing. When the cartridge is in the cavity, each heating element is disposed so heat can be conducted from the heating element and through the casing and corresponding heat transfer member to initiate the release of hydrogen gas. The initiation system can selectively heat one or more pellets to release hydrogen gas as needed.
Abstract:
The invention relates to mixed metal borohydrides used for solid hydrogen storage. The mixed metal borohydrides are synthesized through solution synthesis using multiple metal borohydrides. First and second precursor solutions are prepared and combined to create a mixture in which the mixed metal borohydride is formed. The solvent is removed, leaving the mixed metal borohydride. The first precursor solution consisting essentially of lithium borohydride, and the second precursor solution consisting essentially of a borohydride compound containing one or more metal cations selected from the group of metals consisting of sodium, magnesium, calcium and titanium.