公开(公告)号：US4892922A

公开(公告)日：1990-01-09

申请号：US287814

申请日：1988-12-21

申请人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  Wayne P. Pruett ,  Samuel D. Hilbert

发明人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  Wayne P. Pruett ,  Samuel D. Hilbert

IPC分类号： C08G63/668 ,  C08G63/685 ,  C08G63/688

CPC分类号： C08G63/668 ,  C08G63/6854 ,  C08G63/6884

摘要： Colored polyester compositions useful for molding into articles such as food containers, beverage bottles, cured structural plastics and the like comprising molding grade polyester such as a linear, thermoplastic polyester having reacted therewith or copolymerized therein the residue of a 7-amino-2H-1-benzopyran-2-one compound or a 7-amino-2H-1-benzopyran-2-imine compound, said residue absorbing radiation in the range of about 400 to 450 nm and being non-extractable from said polymer and stable under polymer formation and processing conditions.

摘要翻译： 可用于模制成诸如食品容器，饮料瓶，固化的结构塑料等制品的着色聚酯组合物包括成型级聚酯，例如与其反应的线性热塑性聚酯或其中共聚有7-氨基-2H-1 - 苯并吡喃-2-酮化合物或7-氨基-2H-1-苯并吡喃-2-亚胺化合物，所述残余物吸收在约400至450nm范围内的辐射，并且不能从所述聚合物中萃取并且在聚合物形成下是稳定的 和加工条件。

公开(公告)号：US4749773A

公开(公告)日：1988-06-07

申请号：US78433

申请日：1987-07-27

申请人： Max A. Weaver ,  Wayne P. Pruett ,  Samuel D. Hilbert ,  Clarence A. Coates, Jr.

发明人： Max A. Weaver ,  Wayne P. Pruett ,  Samuel D. Hilbert ,  Clarence A. Coates, Jr.

IPC分类号： C08G63/44 ,  C08G63/54 ,  C08G63/685 ,  C08G64/04 ,  C08G64/12 ,  C08G63/76 ,  C08G69/44

CPC分类号： C08G64/12 ,  C07C255/00 ,  C07C317/00 ,  C08G63/54 ,  C08G63/6858 ,  C08G64/045

摘要： A composition useful for molding into articles such as food containers, soft drink bottles, cured structural plastics and the like, comprising molding grade linear or unsaturated polyester or polycarbonate having reacted or copolymerized therein a total of from 100 to about 800 ppm, of the residue of one or a mixture of methine reactants of the formula ##STR1## wherein R.sup.1 is hydrogen or an unsubstituted or substituted alkyl, alkenyl, cycloalkyl or aryl radical;A.sup.1 is an unsubstituted or substituted phenylene radical;A.sup.2 is an unsubstituted or substituted 1,4-phenylene radical;R.sup.2 is hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical;R.sup.3 is cyano or ##STR2## and R.sup.4 is one of the substituents which R.sup.3 can represent or an unsubstituted or substituted carbamoyl, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, aryl or aromatic heterocyclic radicals.The methine residues are present in the polymer as an integral part of the polymer chain and absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are non-extractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.

摘要翻译： 可用于模制成诸如食品容器，软饮料瓶，固化的结构塑料等的制品的组合物，其包含在其中反应或共聚合总计为100至约800ppm的残余物的成型级线性或不饱和聚酯或聚碳酸酯 其中R 1是氢或未取代或取代的烷基，链烯基，环烷基或芳基的一种或者下式的次甲基化合物的混合物： A1是未取代或取代的亚苯基; A2是未取代或取代的1,4-亚苯基; R2是氢或未取代或取代的烷基，环烷基或芳基; R 3是氰基或R 4是R 3可以代表的取代基之一或未取代或取代的氨基甲酰基，烷酰基，芳酰基，烷基磺酰基，芳基磺酰基，芳基或芳族杂环基。 次甲基残基作为聚合物链的组成部分存在于聚合物中，并吸收约250至约390nm范围内的紫外线辐射。 残余物不能从聚合物中萃取，并且在制备和加工聚合物的条件下是稳定的。

公开(公告)号：US4749774A

公开(公告)日：1988-06-07

申请号：US78434

申请日：1987-07-27

申请人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  Wayne P. Pruett ,  Samuel D. Hilbert

发明人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  Wayne P. Pruett ,  Samuel D. Hilbert

IPC分类号： C08F299/04 ,  C08F283/01 ,  C08G63/44 ,  C08G63/46 ,  C08G63/52 ,  C08G63/68 ,  C08G63/685 ,  C08G64/04 ,  C08L67/02 ,  C08G63/76 ,  C08G69/44

CPC分类号： C07C255/00 ,  C08G63/52 ,  C08G63/6858 ,  C08G64/045

摘要： Composition useful for molding into articles which as food containers, beverage bottles, cured structural plastics and the like comprising molding grade linear or unsaturated polyester or polycarbonate having reacted therewith or copolymerized therein the residue of one or more poly-methine compounds having the formula: ##STR1## wherein each R.sup.1 is independently selected from cyano, carboxy, alkenyloxycarbonyl, or a substituted or unsubstituted alkoxycarbonyl, cycloalkoxoycarbonyl or aryloxycarbonyl radical;each R.sup.2 is independently selected from one of the groups specified for R.sup.1 or an unsubstituted or substituted aryl, carbamoyl, alkanoyl, cycloalkanoyl, aroyl, alkylsulfonyl, cycloalkylsulfonyl, arylsulfonyl or aromatic, heterocyclic radical;each R.sup.3 is independently selected from hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical;A.sup.1 and A.sup.2 are independently selected from 1,4-phenylene radicals; andL is an organic linking group bonded by non-oxo carbon atoms to the oxygen atoms adjacent to L; provided the poly-methine compound bears at least one substituent that is reactive with one of the monomers from which the condensation polymer is derived.The polymethine residues are present in the polymer as an integral part of the polymer chain and absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are non-extractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.

公开(公告)号：US4892923A

公开(公告)日：1990-01-09

申请号：US287819

申请日：1988-12-21

申请人： Max A. Weaver ,  Wayne P. Pruett ,  Samuel D. Hilbert ,  Clarence A. Coates, Jr.

发明人： Max A. Weaver ,  Wayne P. Pruett ,  Samuel D. Hilbert ,  Clarence A. Coates, Jr.

IPC分类号： C08G63/123 ,  C08G63/187 ,  C08G63/197 ,  C08G63/685

CPC分类号： C08G63/187 ,  C08G63/123 ,  C08G63/197 ,  C08G63/6854

摘要： Disclosed are compositions useful for molding into articles such as food containers, beverage bottles, cured structural plastics and the like comprising a polyester such as a linear, thermo-plastic polyester having reacted or copolymerized therein the residue of a 3H-naphtho[2,1-b]pyran-3-one or 3H-naphtho[2,1-b]pyran-3-imine compound. The naphthopyran compounds and residues are stable at the high temperatures at which the polymers are prepared and absorb radiation in the range of 350 to 450 nm.

摘要翻译： 公开了可用于模制成诸如食品容器，饮料瓶，固化的结构塑料等的制品的组合物，其包括在其中反应或共聚有3H-萘并[2,1 -b]吡喃-3-酮或3H-萘并[2,1-b]吡喃-3-亚胺化合物。 萘并吡喃化合物和残余物在制备聚合物的高温下是稳定的，并且吸收在350至450nm范围内的辐射。

公开(公告)号：US4808677A

公开(公告)日：1989-02-28

申请号：US153635

申请日：1988-02-08

申请人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  Wayne P. Pruett ,  Samuel D. Hilbert

发明人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  Wayne P. Pruett ,  Samuel D. Hilbert

IPC分类号： C08G63/685 ,  C09B69/10 ,  C08G63/20

CPC分类号： C09B69/109 ,  C08G63/685

摘要： Disclosed are colored compositions useful for molding into articles such as food containers, beverage bottles, cured structural plastics and the like comprising condensation polymer having reacted therewith or copolymerized therein a coloring amount of the residue of a colorant compound having the formula; ##STR1## wherein R.sup.1 is ##STR2## carbonyl halide or an unsubstituted or substituted carbocyclic or hetrocyclic aryl radical;R.sup.2 is hydrogen or an unsubstituted or substituted alkyl or acyl radical;R.sup.3 is any of the substituents which R.sup.1 may represent; andA.sup.1 and A.sup.2 each is the residue of a fused benzene ring; whereinR.sup.4 is hydrogen, allyl or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical; andR.sup.5 is hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical; provided the colorant compound bears at least one substituent that is reactive with one of the monomers from which the condensation polymer is derived.The colorant compound residues are present in the polymer chain and impart a red color to the polymer. The residues are nonextractable from the polymer and stable at the condition at which the polymers are prepared and processed.

摘要翻译： 公开了可用于模制成诸如食品容器，饮料瓶，固化的结构塑料等制品的着色组合物，其包含与其反应或与其共聚的具有下式的着色剂化合物的着色量的缩聚物; 或者其中R 1为羰基卤或未取代或取代的碳环或杂环芳基的“IMAGE”或“IMAGE” R2是氢或未取代或取代的烷基或酰基; R3是R1可以表示的任何取代基; A1和A2各自为稠合苯环的残基; 其中R4是氢，烯丙基或未取代或取代的烷基，环烷基或芳基; 并且R 5是氢或未取代或取代的烷基，环烷基或芳基; 只要着色剂化合物具有至少一个与衍生缩合聚合物的单体之一反应的取代基。 着色剂化合物残基存在于聚合物链中并赋予聚合物红色。 残余物不可聚合，并且在制备和加工聚合物的条件下是稳定的。

公开(公告)号：US4950732A

公开(公告)日：1990-08-21

申请号：US125031

申请日：1987-11-24

申请人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  Wayne P. Pruett ,  Samuel D. Hilbert

发明人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  Wayne P. Pruett ,  Samuel D. Hilbert

IPC分类号： C08F299/04 ,  C07C67/00 ,  C07C253/00 ,  C07C255/38 ,  C07C255/40 ,  C08F283/01 ,  C08G63/16 ,  C08G63/18 ,  C08G63/40 ,  C08G63/52 ,  C08G63/68 ,  C08G63/685 ,  C08G64/00 ,  C08G64/04

CPC分类号： C08G64/04 ,  C08G63/52 ,  C08G63/6858

摘要： A composition useful for molding into articles such as food containers, soft drink bottles, cured structural plastics and the like, comprising molding or fiber grade linear or unsaturated polyester or polycarbonate having copolymerized therein a total of from 1.0 to about 5,000 ppm, of the reactant residue moieties of one or a mixture of bis-methine reactants of the formulaM.sup.1 .dbd.HC--Ar.sup.1 --CH.dbd.M.sup.2whereinAr.sup.1 is an unsubstituted or substituted 1,4-phenylene radical; andM.sup.1 and M.sup.2 are the same or different and each is a disubstituted methylene group having the structure ##STR1## wherein R.sup.1 is ##STR2## and R.sup.2 is ##STR3## wherein R.sup.3 is hydrogen, allyl or an unsubstituted or substituted alkyl, cycloalkyl or phenyl radical;X is a divalent alkylene, cycloalkylene or phenylene radical or a combination thereof which may include within the divalent chain one or two atoms or radicals selected from ##STR4## wherein R.sup.6 is an unsubstituted or substituted alkyl, cycloalkyl or phenyl radical;R.sup.4 is a group that is reactive with one of the monomers from which the condensation polymer is prepared;Ar.sup.2 is an unsubstituted or substituted phenylene or heterocyclic arylene radical;R.sup.5 is hydrogen, R.sup.4 or --X--R.sup.4 ;wherein the bis-methine moiety absorbs radiation significantly in the range of 250 to 390 nm and is non-extractable from said polymer and is stable under the conditions the polymer is prepared or processed.

公开(公告)号：US5091501A

公开(公告)日：1992-02-25

申请号：US594460

申请日：1990-10-04

申请人： Max A. Weaver ,  Samuel D. Hilbert ,  Wayne P. Pruett ,  Clarence A. Coates, Jr.

发明人： Max A. Weaver ,  Samuel D. Hilbert ,  Wayne P. Pruett ,  Clarence A. Coates, Jr.

IPC分类号： C07D311/16 ,  C08G63/668 ,  C08G63/68

CPC分类号： C07D311/16 ,  C08G63/668 ,  C08G63/68

摘要： This invention provides a process for producing 2H-1-benzopyran-2-ones (coumarins) from optionally-substituted o-halocinnamic acids or esters under polyester-forming conditions. When the coumarins contain appropriately reactive functional groups, and desired monomers are present, a colored or UV-absorbing coumarin/polyester copolymer is provided in one step.

摘要翻译： 本发明提供了在聚酯形成条件下从任选取代的邻卤代甲酰胺酸或酯生产2H-1-苯并吡喃-2-酮（香豆素）的方法。 当香豆素含有适当的反应性官能团并且存在所需的单体时，在一个步骤中提供着色或UV吸收香豆素/聚酯共聚物。

公开(公告)号：US4882412A

公开(公告)日：1989-11-21

申请号：US287815

申请日：1988-12-21

申请人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  Wayne P. Pruett ,  Samuel D. Hilbert

发明人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  Wayne P. Pruett ,  Samuel D. Hilbert

IPC分类号： C08G63/668 ,  C08G63/685 ,  C08G63/688

CPC分类号： C08G63/6884 ,  C08G63/668 ,  C08G63/6854

摘要： Composition useful for molding into articles such as food containers, beverage bottles, cured structural plastics and the like comprising molding grade polyester such as a linear, thermoplastic polyester having reacted therewith or copolymerized therein the residue of a 7-oxy-2H-1-benzopyran-2-one compound or a 7-oxy-2H-1-benzopyran-2-imine compound, said residue absorbing radiation in the range of about 330 to 380 nm and being non-extractable from said polymer and stable under polymer formation and processing conditions.

摘要翻译： 用于模塑成诸如食品容器，饮料瓶，固化的结构塑料等的制品的组合物包括成型级聚酯，例如与其反应的线性热塑性聚酯或其中共聚有7-氧基-2H-1-苯并吡喃的残余物 -2-酮化合物或7-氧基-2H-1-苯并吡喃-2-亚胺化合物，所述残余物吸收在约330至380nm范围内的辐射并且不能从所述聚合物中萃取并且在聚合物形成和加工下是稳定的 条件。

公开(公告)号：US4845188A

公开(公告)日：1989-07-04

申请号：US233790

申请日：1988-08-19

申请人： Max A. Weaver ,  Wayne P. Pruett ,  Samuel D. Hilbert ,  Clarence A. Coates, Jr.

发明人： Max A. Weaver ,  Wayne P. Pruett ,  Samuel D. Hilbert ,  Clarence A. Coates, Jr.

IPC分类号： C07C323/62 ,  C08G63/688 ,  C08G63/91 ,  C08G64/04

CPC分类号： C08G64/045 ,  C08G63/6888

摘要： A composition useful for molding into articles such as food containers, soft drink bottles, cured structural plastics and the like, comprising molding grade linear or unsaturated polyester or polycarbonate having reacted or copolymerized therein the residue of one or a mixture of methine reactants of the formula ##STR1## whereinR.sup.1 is an unsubstituted or substituted alkyl, cycloalkyl or aryl radical;A is an unsubstituted or substituted 1,4-phenylene radical;R.sup.2 is hydrogen or an unsubstituted or substituted alkyl, alkenyl, cycloalkyl or aryl radical;R.sup.3 is cyano, ##STR2## or an unsubstituted or substituted carbamoyl, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, aryl or aromatic heterocyclic radicals. The methine residues are present in the polymer as an integral part of the polymer chain and absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are non-extractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.

公开(公告)号：US4826903A

公开(公告)日：1989-05-02

申请号：US158819

申请日：1988-02-22

申请人： Max A. Weaver ,  Samuel D. Hilbert ,  Wayne P. Pruett ,  Clarence A. Coates, Jr.

发明人： Max A. Weaver ,  Samuel D. Hilbert ,  Wayne P. Pruett ,  Clarence A. Coates, Jr.

IPC分类号： C07D277/64 ,  C07C69/732 ,  C07C69/78 ,  C07C255/41 ,  C07C307/02 ,  C07C309/65 ,  C07C309/66 ,  C07C309/73 ,  C07C317/44 ,  C07C323/52 ,  C07C333/08 ,  C07D235/12 ,  C07D263/56 ,  C07D271/10 ,  C08G63/12 ,  C08G63/54 ,  C08G63/68 ,  C08G63/685 ,  C08G63/688 ,  C08G64/04 ,  C08K5/00 ,  C08G63/52 ,  C08K5/47 ,  C08K5/42 ,  C08K5/34 ,  C08K5/10

CPC分类号： C08G64/045 ,  C08G63/54 ,  C08G63/68 ,  C08K5/005

摘要： Composition useful for molding into articles such as food containers, beverage bottles, cured structural plastics and the like comprising molding grade linear or unsaturated polyester or polycarbonate (a) containing a mono-4-acryloxystyryl or bis-4-acyloxystyryl compound or (b) having reacted therewith or copolymerized therein a styryl residue derived from a mono-4-acryloxystyryl or bis-4-acyloxystyryl compound, having the formula ##STR1## wherein R.sup.4 and R.sup.5 represent the acyl radical and the other radicals are as defined in the specification.Preferred compositions comprise a linear polyester containing a styryl residue as an integral part of the polymer chain. The styryl residues absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are non-extractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.

摘要翻译： 包含成型级线性或不饱和聚酯或含有单-4-丙烯酰氧基苯乙烯基或双-4-酰氧基苯乙烯基化合物的聚碳酸酯（a）的成型物可用于成型为食品容器，饮料瓶，固化的结构塑料等制品，或（b） 与其反应或在其中共聚衍生自具有式“IMAGE”+ TR“IMA”的单-4-丙烯酰氧基苯乙烯基或双-4-酰氧基苯乙烯基化合物的苯乙烯基残基，其中R 4和R 5表示酰基，而其它基团为 在规范中定义。 优选的组合物包含含有作为聚合物链的组成部分的苯乙烯基残基的线性聚酯。 苯乙烯基残基吸收约250至约390nm范围内的紫外线辐射。 残余物不能从聚合物中萃取，并且在制备和加工聚合物的条件下是稳定的。