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公开(公告)号：US5364691A
公开(公告)日：1994-11-15
申请号：US490854
申请日：1990-03-09
摘要： This invention relates to radiation curable alk-1-enyloxy carbonate reaction products of a hydroxylated compound having the formula A-ROH and a dialk-1-enyloxy carbonate having the formula ##STR1## wherein R is a polymeric radical selected from the group of polyester, polyacetal, polyurethane, polyether, and polycarbonate, said polymers containing from about 10 to 50 repeating monomer units;A' is a terminating moiety and is hydrogen, lower alkyl or hydroxy;R' is hydrogen or lower alkyl;B is a linear, branched or cyclic divalent radicalhaving from 2 to 12 carbon atoms and is selected from the group of alkylene, mono or poly alkoxylated alkylene, alkenylene, alkynylene, arylene, alkarylene and aralkylene radicals, which radicals are optionally substituted with halo, lower alkyl, cyano, nitro or alkoxy and m has a value of from 1 to 10. The products of this invention are defined by the formula: ##STR2## wherein A' is a terminating moiety and is hydrogen, lower alkyl or ##STR3##
摘要翻译： 本发明涉及具有式A-ROH的羟基化化合物和具有式“IMAGE”的二烷基-1-烯氧基碳酸酯的可辐射固化的烷-1-烯氧基碳酸酯反应产物，其中R是选自聚酯的聚合基 聚缩醛，聚氨酯，聚醚和聚碳酸酯，所述聚合物含有约10至50个重复单体单元; A'为终止部分，为氢，低级烷基或羟基; R'是氢或低级烷基; B是具有2至12个碳原子的直链，支链或环状二价基团，并且选自亚烷基，单或多烷氧基化亚烷基，亚烯基，亚炔基，亚芳基，亚烷基和亚芳基，其基团任选被卤素 ，低级烷基，氰基，硝基或烷氧基，m的值为1至10.本发明的产物由下式定义：其中A'为终止部分，为氢，低级烷基或 图像>
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公开(公告)号：US5159098A
公开(公告)日：1992-10-27
申请号：US579511
申请日：1990-09-10
IPC分类号： C07C271/12 , C07C271/20
CPC分类号： C07C271/20 , C07C271/12
摘要： The invention relates to alk-1-enyloxy carbamates selected from the group having the formulae ##STR1## wherein R is a saturated or unsaturated, monovalent or divalent hydrocarbon radical having from 1 to 50 carbon atoms and is optionally substituted with halo, alkyleneoxy, hydroxy, or a combination of said radicals; Y is --O-- or --OCO--O--; X is hydrogen or methyl; R' and R" are each independently hydrogen, alkyl, aryl, aralkyl or alkaryl; m has a value of from 2 to 6 and n has a value of from 0 to 25. The invention also relates to the use of these alk-1-enyloxy carbamates as reactive diluents in cationically induced radiation curing of epoxy, vinyl ether, urethane monomers or oligomers and others.
摘要翻译： 本发明涉及选自具有下式的基团的烯-1-烯氧基氨基甲酸酯：其中R是具有1至50个碳原子的饱和或不饱和的一价或二价烃基，并且是 任选地被卤素，亚烷氧基，羟基或所述基团的组合取代; Y是-O-或-OCO-O-; X是氢或甲基; R'和R“各自独立地为氢，烷基，芳基，芳烷基或烷芳基; m的值为2至6，n的值为0至25.本发明还涉及这些烷-1-烯氧基氨基甲酸酯作为反应性稀释剂在环氧树脂，乙烯基醚，氨基甲酸酯的阳离子诱导辐射固化中的用途 单体或低聚物等。
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公开(公告)号：US5262449A
公开(公告)日：1993-11-16
申请号：US936470
申请日：1992-08-28
CPC分类号： C07D317/36 , C09D4/00
摘要： This invention relates to a coating composition which can be cured by exposure to radiation energy in the presence of a cationic photoinitiator. The composition comprises a mixture of between about 1 and about 75 wt. % of a reactive vinyl or alk-1-enyl ether cyclocarbonate having the formula ##STR1## wherein R is hydrogen or lower alkyl; R' is C.sub.2 to C.sub.4 alkylene; n has a value of from 0 to 4 and n' has a value of from 1 to 4 and between about 99 and about 25 wt. % of a polymerizable compound containing an onium salt initiator which is normally insoluble in said polymerizable compound or a mixture thereof. The invention also relates to the use of the composition as a protective coating on a substrate.
摘要翻译： 本发明涉及可在阳离子光引发剂存在下通过暴露于辐射能固化的涂料组合物。 组合物包含约1至约75wt。 ％的具有式“IMAGE”的反应性乙烯基或烷-1-烯基醚环碳酸酯，其中R是氢或低级烷基; R'是C 2至C 4亚烷基; n具有0至4的值，n'具有1至4的值和约99至约25重量％的值。 通常不溶于所述可聚合化合物或其混合物的含有鎓盐引发剂的可聚合化合物的％。 本发明还涉及组合物在基材上作为保护涂层的用途。
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公开(公告)号：US5036112A
公开(公告)日：1991-07-30
申请号：US470488
申请日：1990-01-26
CPC分类号： C09D4/00
摘要： This invention relates to a cross-linkable, cationic radiation curable composition comprising (a) a non-volatile vinyl ether, epoxide, acrylate or an oligomer thereof (b) a cationic photoinitiator and (c) a divinyl ether polyacetal oligomer having the formula ##STR1## wherein n has a value of from 1 to 50;X is uniformly sulfur or oxygen;R is C.sub.2 to C.sub.4 alkeneoxy alkylene, poly(alkyleneoxy) alkylene, or a branched, linear or cyclic C.sub.2 to C.sub.20 alkylene andR' is phenylene, diphenylene methane, diphenylene propane, xylylene, tolylene, or a branched, linear or cyclic C.sub.2 to C.sub.20 alkylene optionally substituted with an ether, ester, carbonate, carbamate, C.sub.2 to C.sub.4 alkyleneoxy alkylene or poly(C.sub.2 to C.sub.4 alkyleneoxy) alkylene radical. The invention also relates to the composition cured on a substrate.
摘要翻译： 本发明涉及可交联的阳离子可辐射固化组合物，其包含（a）非挥发性乙烯基醚，环氧化物，丙烯酸酯或其低聚物（b）阳离子光引发剂和（c）二乙烯基醚聚缩醛低聚物， IMAGE>其中n具有1至50的值; X均匀硫或氧; R为C 2至C 4烯氧基亚烷基，聚（亚烷基氧基）亚烷基或支链，直链或环状的C 2至C 20亚烷基，R'为亚苯基，二亚苯基甲烷，二亚苯基丙烷，亚二甲苯，甲苯或支链， 任选被醚，酯，碳酸酯，氨基甲酸酯，C 2至C 4亚烷氧基亚烷基或聚（C 2至C 4亚烷氧基）亚烷基取代的C 20亚烷基。 本发明还涉及在基材上固化的组合物。
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公开(公告)号：US5085795A
公开(公告)日：1992-02-04
申请号：US658722
申请日：1991-02-21
CPC分类号： C11D3/43 , C09D9/00 , C11D3/38618 , C11D3/3956 , C11D7/5013 , C11D7/267 , C11D7/3281
摘要： What is provided herein is a water-based, environmentally safe, stain-remover composition for effectively removing a wide variety of stains from fabrics consisting essentially of:(a) 5-20% by weight N-methylpyrrolidone (NMP),(b) 5-20% by weight .gamma.-butyrolactone (BLO),(c) 40-88% by weight water, and(d) 1-10% by weight surfactant, and, optionally,including a base-buffer to provide a pH in the range of about 7-11.
摘要翻译： 本文提供的是水性，环境安全的去污剂组合物，用于有效地从织物中除去各种污渍，其基本上由以下组成：（a）5-20重量％的N-甲基吡咯烷酮（NMP），（b） 5-20重量％的γ-丁内酯（BLO），（c）40-88重量％的水，和（d）1-10重量％的表面活性剂，和任选地包括碱缓冲液以提供pH 范围约7-11。
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17.发明授权N-pyrrolidonyl methyltriphenyl phosphonium salts and method for their preparation and use 失效N-吡咯烷酮基甲基三苯基鏻盐及其制备和使用方法
公开(公告)号：US4997952A
公开(公告)日：1991-03-05
申请号：US420767
申请日：1989-10-12
IPC分类号： C07F9/572
CPC分类号： C07F9/5721
摘要： A novel triphenylphosphonium salts of chloromethyl pyrrolidone having the formula: ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3 may be the same or different and may be hydrogen, lower alkyl, lower alkoxy, lower alkenyl, lower cycloalkyl, and lower carboalkoxy, phenyl, substituted phenyl, naphthyl, and substituted naphthyl, R.sub.4 is lower alkyl or phenyl and X is an anion. The compounds are useful in Wittig-type reactions and as phase transfer catalysts. A method for preparing the inventive compound is also disclosed.
摘要翻译： 具有下式的氯甲基吡咯烷酮的新型三苯基鏻盐：其中R 1，R 2和R 3可以相同或不同，并且可以是氢，低级烷基，低级烷氧基，低级烯基，低级环烷基和低级烷氧羰基，苯基， 取代的苯基，萘基和取代的萘基，R4是低级烷基或苯基，X是阴离子。 该化合物可用于Wittig型反应和相转移催化剂。 还公开了制备本发明化合物的方法。
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公开(公告)号：US5227509A
公开(公告)日：1993-07-13
申请号：US520042
申请日：1990-05-07
IPC分类号： C07B61/00 , C07C331/20
CPC分类号： C07B61/00 , C07C331/20
摘要： A method for preparing (R)X.sub.m-p A.sub.p by reacting (R)X.sub.m and MA in N-methylpyrrolidone and recovering the by-product MX as a precipitate wherein:X is halide;R contains from 1 to 8 carbon atoms, can be substituted or unsubstituted, and is straight or branched chain alkyl, cycloaliphatic, aralkyl, alkylene, alkenyl, alkenylene, alkynyl or alkynylene with the proviso that X is not attached to a carbon atom having a double bond;A.sup.- is a monovalent anion soft base selected from the group consisting of halide different from X, SCN.sup.-, SH.sup.-, SO.sub.3 H.sup.-, R.sub.2 PO.sub.4.sup.-, PF.sub.6.sup.-, and [SP(Z) (OR.sup.1).sub.2 ].sup.- wherein R.sup.1 is lower alkyl and z i sulfur or oxygen;M is an alkali metal or NH.sub.4.sup.+ ;m is an integer from 1 to 3 with the proviso that m is 1 or 2 when R has one carton; andP is an integer from 1 to m.
摘要翻译： 一种通过（R）Xm和MA在N-甲基吡咯烷酮中反应制备（R）Xm-pAp的方法，并回收作为沉淀物的副产物MX，其中X是卤化物; R包含1至8个碳原子，可以是取代或未取代的，并且是直链或支链烷基，脂环族，芳烷基，亚烷基，烯基，亚烯基，炔基或亚炔基，条件是X不连接到具有 双键; A-是选自不同于X，SCN-，SH-，SO 3 - ，R 2 PO 4 - ，PF 6 - 和[SP（Z）（OR 1）2] - 的卤素的一价阴离子软碱，其中R1较低 烷基和i硫或氧; M是碱金属或NH4 +; m是1至3的整数，条件是当R具有一个纸箱时，m为1或2; P为1〜m的整数。
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19.发明授权Controlled release N-substituted pyrrolidone esters and process for the use thereof 失效受控释放的N-取代的吡咯烷酮酯及其用途的方法
公开(公告)号：US5206386A
公开(公告)日：1993-04-27
申请号：US675367
申请日：1991-03-20
IPC分类号： C07D207/26 , C07D207/27
CPC分类号： C07D207/27
摘要： N-substituted cyclic lactam esters are made from biologically active organic acids and N-haloalkyl substituted cyclic lactam, preferably N-chloromethyl pyrrolidone. Such esters provide slow release of the organic acids in situ through slow hydrolysis of the ester to release the organic acid and the N-alkyl substituted cyclic lactam. The esters are useable for delivering a large variety of biologically active organic acids in slow release fashion to target organisms and promote effective long term therapeutic treatment. In particular, an ester made from acetyl salicyclic acid and chloromethyl pyrrolidone provides a vehicle for dermal penetration and slow release of aspirin for long term treatment.
摘要翻译： N-取代的环状内酰胺酯由生物活性有机酸和N-卤代烷基取代的环状内酰胺，优选N-氯甲基吡咯烷酮制成。 这种酯通过缓慢水解酯释放有机酸和N-烷基取代的环状内酰胺，从而提供了原位缓慢释放有机酸。 酯可用于以缓释方式将大量各种各样的生物活性有机酸递送至靶生物并促进有效的长期治疗治疗。 特别地，由乙酰水杨酸和氯甲基吡咯烷酮制成的酯提供用于长期治疗的阿司匹林的皮肤渗透和缓慢释放的载体。
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20.发明授权Stable matrix emulsion concentrates and stable aqueous and/or organic solvent compositions containing biocides 有权稳定的基质乳液浓缩物和含有杀生物剂的稳定的含水和/或有机溶剂组合物公开(公告)号：US09560847B2
公开(公告)日：2017-02-07
申请号：US10990995
申请日：2004-11-17
CPC分类号： A01N25/04 , A01N47/12 , A01N43/653 , A01N2300/00
摘要： A stable matrix emulsion concentrate of a biocide, e.g. 3-iodopropynyl-2-butyl carbamate (IPBC) and/or a triazole fungicide, and stable aqueous and/or organic solvent formulations thereof, i.e. dilutable in water and/or an organic solvent are provided, which are particularly useful for treating wood products to provide protection against microorganisms and insects.
摘要翻译： 一种杀生物剂的稳定的基质乳液浓缩物，例如 提供3-碘丙炔基-2-丁基氨基甲酸酯（IPBC）和/或三唑杀真菌剂，以及其稳定的水和/或有机溶剂制剂，即在水和/或有机溶剂中可稀释，其特别适用于处理木制品 提供防止微生物和昆虫的保护。
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