Wrinkled polyester particles
    11.
    发明授权
    Wrinkled polyester particles 有权
    皱纹聚酯颗粒

    公开(公告)号:US07128972B2

    公开(公告)日:2006-10-31

    申请号:US10208344

    申请日:2002-07-30

    IPC分类号: B32B5/16

    摘要: The present invention comprises wrinkled polymer particle comprising a polyester-containing particle having a surface covered with at least one wrinkle comprising folds, ridges, crevices and channels. The present invention further comprises a method of forming wrinkled polyester-containing particles comprising preparing a mixture of an organic phase and an aqueous phase, said mixture comprising an unsaturated precursor polyester, a water immiscible organic solvent, at least one organic-soluble ethylenically unsaturated monomer, and initiator, subjecting said mixture to high energy emulsification, initiating crosslinking of said polyester after emulsification, and removing said water immiscible organic solvent to recover wrinkled polyester-containing particles.

    摘要翻译: 本发明包括起皱聚合物颗粒,其包含含有至少一个褶皱,脊,裂缝和通道的皱纹的表面的含聚酯的颗粒。 本发明还包括形成起皱的含聚酯的颗粒的方法,包括制备有机相和水相的混合物,所述混合物包含不饱和前体聚酯,水不混溶的有机溶剂,至少一种有机可溶性烯属不饱和单体 和引发剂,使所述混合物进行高能乳化,在乳化后引发所述聚酯的交联,并除去所述水不混溶的有机溶剂以回收起皱的含聚酯的颗粒。

    Heat-sensitive compositions and imaging member containing carbon black and methods of imaging and printing
    14.
    发明授权
    Heat-sensitive compositions and imaging member containing carbon black and methods of imaging and printing 失效
    含有炭黑的热敏组合物和成像构件以及成像和印刷方法

    公开(公告)号:US06660449B2

    公开(公告)日:2003-12-09

    申请号:US10083258

    申请日:2001-10-19

    IPC分类号: G03F7038

    摘要: An imaging member, such as a negative-working printing plate or on-press cylinder, comprises latex polymer-carbon black composite particles. Such imaging members can be prepared with a hydrophilic imaging layer comprised of a heat-sensitive hydrophilic polymer having ionic moieties and the latex polymer-carbon black composite particles as a photothermal conversion material. The latex polymer-carbon black composite particles can be formulated in water or water-miscible solvents without agglomeration with other components such as charged polymers.

    摘要翻译: 成像构件,例如负压印版或压印滚筒,包括胶乳聚合物 - 炭黑复合颗粒。 这样的成像构件可以由具有离子部分的热敏亲水性聚合物和胶乳聚合物 - 炭黑复合颗粒作为光热转化材料的亲水成像层制备。 胶乳聚合物 - 炭黑复合颗粒可以配制成水或水混溶性溶剂,而不与其它组分例如带电聚合物结合。

    Processless direct write printing plate having heat sensitive crosslinked vinyl polymer with organoonium group and methods of imaging and printing
    15.
    发明授权
    Processless direct write printing plate having heat sensitive crosslinked vinyl polymer with organoonium group and methods of imaging and printing 有权
    具有热敏性交联乙烯基聚合物与无机组的无过程直写式印版和成像和印刷方法

    公开(公告)号:US06190830B1

    公开(公告)日:2001-02-20

    申请号:US09309999

    申请日:1999-05-11

    IPC分类号: G03F7004

    CPC分类号: B41C1/1041 B41M5/368

    摘要: An imaging member, such as a negative-working printing plate, can be prepared using a hydrophilic heat-sensitive imaging layer comprised of a hydrophilic heat-sensitive, crosslinked vinyl polymer containing recurring organoonium groups. The imaging member can also include a photothermal conversion material such as carbon black or an infrared radiation absorbing dye. The heat-sensitive polymer has recurring units containing an organoammonium, organophosphonium or organosulfonium group that reacts to provide increased oleophilicity (ink receptivity) in response to heat. Heat is preferably generated by laser irradiation in the IR region of the electromagnetic spectrum. The heat-sensitive polymer is considered “switchable” in response to heat. The imaging member can be used in printing methods without the usual wet processing steps.

    摘要翻译: 可以使用由含有重复有机基团的亲水性热敏交联乙烯基聚合物构成的亲水性热敏成像层来制备成像构件,例如负性印刷版。 成像构件还可以包括光热转换材料,例如炭黑或红外辐射吸收染料。 热敏聚合物具有含有有机铵,有机鏻或有机锍基团的重复单元,其响应于热而反应以提供增加的亲油性(吸墨性)。 热量优选通过激光照射在电磁光谱的IR区域中产生。 热敏聚合物因热而被认为是“可切换的”。 成像构件可以用于印刷方法,而不需要通常的湿法处理步骤。

    Core-shell nitro-resin particles and method of preparation
    18.
    发明授权
    Core-shell nitro-resin particles and method of preparation 失效
    核壳硝基树脂颗粒及其制备方法

    公开(公告)号:US06986944B2

    公开(公告)日:2006-01-17

    申请号:US10441383

    申请日:2003-05-20

    申请人: Jeffrey W. Leon

    发明人: Jeffrey W. Leon

    IPC分类号: B32B5/16

    摘要: Combustible core-shell particles have a nitro-resin core that is covered by an addition polymer shell in a weight ratio of from 20:1 to 0.2:1 (core:shell). The shell polymer is derived from one or more ethylenically unsaturated polymerizable monomers that are represented by the following Structure I: CH2═C(R)-X  (I) wherein R is hydrogen or methyl, and X is any monovalent moiety except a phenyl group. These combustible core-shell particles are particularly useful in thermal imaging materials such as “direct-write” printing plate precursors.

    摘要翻译: 可燃核壳颗粒具有由加成聚合物壳覆盖的硝基树脂核心,其重量比为20:1至0.2:1(核:壳)。 壳聚合物衍生自由以下结构I表示的一种或多种烯键式不饱和可聚合单体:<?在线配方描述=“在线式”末端=“铅”→> CH 2 其中R是氢或甲基,X是任何单价基团,除了一个或多个 苯基。 这些可燃核壳颗粒在诸如“直写式”印版前体的热成像材料中特别有用。

    Method of preparation of porous polyester particles
    20.
    发明授权
    Method of preparation of porous polyester particles 有权
    多孔聚酯颗粒的制备方法

    公开(公告)号:US06780942B2

    公开(公告)日:2004-08-24

    申请号:US10027701

    申请日:2001-12-20

    IPC分类号: C08J326

    摘要: The present invention relates to a method of forming porous particles comprising preparing a mixture of an organic phase and an aqueous phase comprising an unsaturated polyester, a water immiscible organic solvent, at least one organic-soluble ethylenically unsaturated monomer, and initiator, subjecting said mixture to high energy emulsification, initiating crosslinking of said polyester after emulsification, removing said water immiscible organic solvent to recover porous polyester particles.

    摘要翻译: 本发明涉及一种形成多孔颗粒的方法,包括制备有机相和含有不饱和聚酯,水不混溶的有机溶剂,至少一种有机可溶性烯属不饱和单体和引发剂的水相的混合物,使所述混合物 高能乳化,在乳化后引发所述聚酯的交联,除去所述水不混溶的有机溶剂以回收多孔聚酯颗粒。