摘要:
The present invention comprises wrinkled polymer particle comprising a polyester-containing particle having a surface covered with at least one wrinkle comprising folds, ridges, crevices and channels. The present invention further comprises a method of forming wrinkled polyester-containing particles comprising preparing a mixture of an organic phase and an aqueous phase, said mixture comprising an unsaturated precursor polyester, a water immiscible organic solvent, at least one organic-soluble ethylenically unsaturated monomer, and initiator, subjecting said mixture to high energy emulsification, initiating crosslinking of said polyester after emulsification, and removing said water immiscible organic solvent to recover wrinkled polyester-containing particles.
摘要:
Various imaging members including lithographic imaging members can be prepared by applying to a support, an aqueous formulation comprising one or more imaging components to form an imaging layer. Over the imaging layer is directly applied a non-aqueous inverse emulsion comprising highly hydrophilic, water-swellable microgel particles dispersed in a water-immiscible organic solvent to form a protective layer. This protective layer provides physical durability but it is still readily removed during or after imaging with water or fountain solutions.
摘要:
Water-soluble or water-dispersible branched or unbranched cationic epoxy compounds comprise a backbone having covalently attached thereto two or more epoxy moieties and one or more of the same or different organoonium moieties. The backbone comprises at least 25 weight % oxygen.
摘要:
An imaging member, such as a negative-working printing plate or on-press cylinder, comprises latex polymer-carbon black composite particles. Such imaging members can be prepared with a hydrophilic imaging layer comprised of a heat-sensitive hydrophilic polymer having ionic moieties and the latex polymer-carbon black composite particles as a photothermal conversion material. The latex polymer-carbon black composite particles can be formulated in water or water-miscible solvents without agglomeration with other components such as charged polymers.
摘要:
An imaging member, such as a negative-working printing plate, can be prepared using a hydrophilic heat-sensitive imaging layer comprised of a hydrophilic heat-sensitive, crosslinked vinyl polymer containing recurring organoonium groups. The imaging member can also include a photothermal conversion material such as carbon black or an infrared radiation absorbing dye. The heat-sensitive polymer has recurring units containing an organoammonium, organophosphonium or organosulfonium group that reacts to provide increased oleophilicity (ink receptivity) in response to heat. Heat is preferably generated by laser irradiation in the IR region of the electromagnetic spectrum. The heat-sensitive polymer is considered “switchable” in response to heat. The imaging member can be used in printing methods without the usual wet processing steps.
摘要:
An imaging member is prepared by applying to a support a heat-sensitive imaging layer which comprises at least one heat-sensitive polymer capable of undergoing transformation from a hydrophilic to hydrophobic state or hydrophobic to hydrophilic state, wherein the transformation occurs such that the activation energy Ea and the Arrhenius pre-exponential factor A associated with the transformation simultaneously fulfill the relationships: ln (A).gtoreq.0.4 Ea+8.84 and ln (A).ltoreq.1.69 Ea-14.37. The imaging member is useful in processless thermal lithographic printing.
摘要:
The present invention relates to a loaded particle comprising at least one fluorescent dye, and in particular, a fluorescent dye with a large Stokes shift. The invention further relates to a method for producing an loaded latex particle, loaded with a fluorescent dye having a large stokes shift. In addition, the present invention relates to latex particles loaded with fluorescent dyes that are organic solvent soluble and insoluble in water. In a preferred embodiment, when the dyes are loaded into the water soluble latex particle, an increase is observed in quantum yield of fluorescence as compared to the quantum yield of the dye in aqueous solvent.
摘要:
Combustible core-shell particles have a nitro-resin core that is covered by an addition polymer shell in a weight ratio of from 20:1 to 0.2:1 (core:shell). The shell polymer is derived from one or more ethylenically unsaturated polymerizable monomers that are represented by the following Structure I: CH2═C(R)-X (I) wherein R is hydrogen or methyl, and X is any monovalent moiety except a phenyl group. These combustible core-shell particles are particularly useful in thermal imaging materials such as “direct-write” printing plate precursors.
摘要:
Water-compatible branched or unbranched epoxy compounds comprise a backbone having covalently attached two or more epoxy moieties and one or more of the same or different sulfonate or thiosulfate moieties.
摘要:
The present invention relates to a method of forming porous particles comprising preparing a mixture of an organic phase and an aqueous phase comprising an unsaturated polyester, a water immiscible organic solvent, at least one organic-soluble ethylenically unsaturated monomer, and initiator, subjecting said mixture to high energy emulsification, initiating crosslinking of said polyester after emulsification, removing said water immiscible organic solvent to recover porous polyester particles.