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51 条记录 (耗时 0.028 秒)

    Catalyst in the form of grains comprising an acidic porous core surrounded by a uniform outer layer
    11.
    发明授权
    Catalyst in the form of grains comprising an acidic porous core surrounded by a uniform outer layer 失效
    包含由均匀外层包围的酸性多孔核的颗粒形式的催化剂

    公开(公告)号：US08258071B2

    公开(公告)日：2012-09-04

    申请号：US10587854

    申请日：2005-01-13

    申请人： Younes Bouizi ,  Valentin Valtchev ,  Loiec Rouleau ,  Nicolas Bats ,  Laurent Simon

    发明人： Younes Bouizi ,  Valentin Valtchev ,  Loiec Rouleau ,  Nicolas Bats ,  Laurent Simon

    IPC分类号： B01J29/06

    CPC分类号： B01J37/0246 ,  B01J29/035 ,  B01J29/084 ,  B01J29/7007 ,  B01J29/80 ,  B01J35/023 ,  B01J2229/62

    摘要： The invention relates to a catalyst that comes in the form of grains, each grain consisting of a core covered by at least one external layer, the core consisting of an acidic porous solid and having a size of between 0.1 micron and 0.4 millimeter, in which the external layer has a uniform thickness with a uniformity criterion C, which is less than 0.30, whereby said uniformity criterion C is defined as being equal to an average, on a number N of catalyst grain samples, of the ratio of the difference between the maximum thickness, Eimax, of the external layer and the minimum thickness, Eimin, of this same layer to the average of these two thicknesses Eimax and Eimin.

    摘要翻译： 本发明涉及一种呈颗粒形式的催化剂，每个颗粒由至少一层外层覆盖的芯组成，芯由酸性多孔固体组成，尺寸为0.1微米至0.4毫米，其中 外层具有均匀的厚度，其均匀性标准C小于0.30，其中所述均匀性标准C被定义为等于催化剂颗粒样品数目N上的平均值 最大厚度，Eimax以及最小厚度Eimin，与该两个厚度Eimax和Eimin的平均值相同。

    CATALYST IN THE FORM OF GRAINS COMPRISING AN ACIDIC POROUS CORE SURROUNDED BY A UNIFORM OUTER LAYER
    12.
    发明申请
    CATALYST IN THE FORM OF GRAINS COMPRISING AN ACIDIC POROUS CORE SURROUNDED BY A UNIFORM OUTER LAYER 失效
    颗粒形式的催化剂包含由均匀的外层包围的酸性多孔核心

    公开(公告)号：US20090036294A1

    公开(公告)日：2009-02-05

    申请号：US10587854

    申请日：2005-01-13

    申请人： Younes Bouizi ,  Valentin Valtchev ,  Loiec Rouleau ,  Nicolas Bats ,  Laurent Simon

    发明人： Younes Bouizi ,  Valentin Valtchev ,  Loiec Rouleau ,  Nicolas Bats ,  Laurent Simon

    IPC分类号： B01J29/04

    CPC分类号： B01J37/0246 ,  B01J29/035 ,  B01J29/084 ,  B01J29/7007 ,  B01J29/80 ,  B01J35/023 ,  B01J2229/62

    摘要： The invention relates to a catalyst that comes in the form of grains, each grain consisting of a core covered by at least one external layer, the core consisting of an acidic porous solid and having a size of between 0.1 micron and 0.4 millimeter, in which the external layer has a uniform thickness with a uniformity criterion C, which is less than 0.30, whereby said uniformity criterion C is defined as being equal to an average, on a number N of catalyst grain samples, of the ratio of the difference between the maximum thickness, Eimax, of the external layer and the minimum thickness, Eimin, of this same layer to the average of these two thicknesses Eimax and Eimin.

    摘要翻译： 本发明涉及一种呈颗粒形式的催化剂，每个颗粒由至少一层外层覆盖的芯组成，芯由酸性多孔固体组成，尺寸为0.1微米至0.4毫米，其中 外层具有均匀的厚度，其均匀性标准C小于0.30，其中所述均匀性标准C被定义为等于催化剂颗粒样品数目N上的平均值 最大厚度，Eimax以及最小厚度Eimin，与该两个厚度Eimax和Eimin的平均值相同。

    IM-13 crystallized solid and its process for preparation
    15.
    发明授权
    IM-13 crystallized solid and its process for preparation 失效
    IM-13结晶固体及其制备方法

    公开(公告)号：US08372376B2

    公开(公告)日：2013-02-12

    申请号：US12301889

    申请日：2007-05-10

    申请人： Philippe Caullet ,  Jean-Louis Paillaud ,  Nicolas Bats ,  Yannick Lorgouilloux

    发明人： Philippe Caullet ,  Jean-Louis Paillaud ,  Nicolas Bats ,  Yannick Lorgouilloux

    IPC分类号： C01B39/46 ,  C01B39/48

    CPC分类号： C01B39/06 ,  C01B37/00 ,  C01B37/005

    摘要： The invention relates to a crystallized solid, referred to by the name IM-13, which has an X-ray diffraction diagram as provided below. Said solid has a chemical composition that is expressed according to the general formula mXO2: nYO2: pZ2O3: qR: sF: wH2O, where R represents one or more organic radical(s), X represents one or more tetravalent element(s) different from germanium, Y represents germanium, Z represents at least one trivalent element, and F is fluorine.

    摘要翻译： 本发明涉及名称为IM-13的结晶固体，其具有如下提供的X射线衍射图。 所述固体具有根据通式mXO 2：n YO 2：pZ 2 O 3：qR：sF：wH 2 O表示的化学组成，其中R表示一个或多个有机基团，X表示一个或多个与以下不同的四价元素： 锗，Y表示锗，Z表示至少一种三价元素，F表示氟。

    IZM-3 CRYSTALLINE SOLID AND A PROCESS FOR ITS PREPARATION
    17.
    发明申请
    IZM-3 CRYSTALLINE SOLID AND A PROCESS FOR ITS PREPARATION 失效
    IZM-3结晶固体及其制备方法

    公开(公告)号：US20110009632A1

    公开(公告)日：2011-01-13

    申请号：US12744627

    申请日：2008-10-17

    申请人： Antoine Fecant ,  Nicolas Bats

    发明人： Antoine Fecant ,  Nicolas Bats

    IPC分类号： C07F7/30 ,  C07F7/02

    CPC分类号： C01B37/005 ,  C01B37/02 ,  C01P2002/72

    摘要： A crystalline solid designated IZM-3 is described which has the X ray diffraction diagram given below. Said solid has a chemical composition expressed as the anhydrous base in terms of moles of oxides by the formula aSiO2:bYO2:cR:dF, in which Y represents at least one tetravalent element other than silicon, R represents at least one organic nitrogen-containing species, and F is fluorine, a, b, c and d respectively representing the number of moles of SiO2, YO2, R and F and a is in the range 0.1 to 1, b is in the range 0 to 0.9, c is in the range 0.01 to 0.5 and d is in the range 0 to 0.5.

    摘要翻译： 描述了具有以下给出的X射线衍射图的称为IZM-3的结晶固体。 所述固体具有以氧化物的摩尔数表示为无水碱的化学组成，通过式aSiO 2 :bYO 2 :cR：dF，其中Y表示至少一种除硅以外的四价元素，R表示至少一种含有机氮 分别表示SiO 2，YO 2，R和F的摩尔数，a在0.1〜1的范围内，b在0〜0.9的范围内，c为 范围0.01〜0.5，d在0〜0.5的范围内。

    IM-12 crystallized solid and its process of preparation
    18.
    发明授权
    IM-12 crystallized solid and its process of preparation 有权
    IM-12结晶固体及其制备方法

    公开(公告)号：US07074385B2

    公开(公告)日：2006-07-11

    申请号：US10871700

    申请日：2004-06-21

    申请人： Bogdan Harbuzaru ,  Jean-Louis Paillaud ,  Joël Patarin ,  Nicolas Bats

    发明人： Bogdan Harbuzaru ,  Jean-Louis Paillaud ,  Joël Patarin ,  Nicolas Bats

    IPC分类号： C01B39/48

    CPC分类号： C01B37/005 ,  C01B39/06

    摘要： The invention relates to a crystallized solid, referred to by the name IM-12, which exhibits an x-ray diffraction diagram as provided below. Said solid exhibits a chemical composition that is expressed on an anhydrous base, in terms of oxide moles, by the formula XO2:m YO2:p Z2O3:q R2/nO, where R represents one or more cation(s) of valence n, X represents one or more different tetravalent element(s) of germanium, Y represents germanium, and Z represents at least one trivalent element.

    摘要翻译： 本发明涉及名称为IM-12的结晶固体，其显示如下所述的x射线衍射图。 所述固体表现出化学组成，其在无水碱上以氧化物摩尔数表示，通过式XO 2：m Y 2 2：p Z 2 其中R表示一个或多个n价阳离子，X表示一个或多个不同的四价元素， 的锗，Y表示锗，Z表示至少一种三价元素。

    Method for preparing organic/inorganic hybrid functionalized solids having a triazole ring
    20.
    发明授权
    Method for preparing organic/inorganic hybrid functionalized solids having a triazole ring 有权
    制备具有三唑环的有机/无机混合官能化固体的方法

    公开(公告)号：US08940905B2

    公开(公告)日：2015-01-27

    申请号：US13503292

    申请日：2010-10-06

    申请人： Marie Savonnet ,  David Farrusseng ,  Catherine Pinel ,  Delphine Bazer-Bachi ,  Nicolas Bats ,  Vincent Lecocq

    发明人： Marie Savonnet ,  David Farrusseng ,  Catherine Pinel ,  Delphine Bazer-Bachi ,  Nicolas Bats ,  Vincent Lecocq

    IPC分类号： C07F3/06 ,  C07F5/06 ,  C07F3/00 ,  C07F5/00

    CPC分类号： C07F5/069 ,  C07F3/003 ,  C07F5/003

    摘要： A process is described for the preparation of a functionalized hybrid solid with an organic-inorganic matrix, crystallized, bearing at least one reactive group based on a triazole ring, from a hybrid solid with an organic-inorganic matrix, MOF—NH2, comprising: i/ introduction, in a polar solvent S1, of said crystallized hybrid solid MOF—NH2, of at least one organic compound Q containing a nitride function N3 and at least one intermediate reagent R containing a nitrite function NO2, ii/ reaction of said reaction mixture, iii/ introduction in the reaction mixture of at least one reagent A bearing an alkyne function or an activated cyanide function, at least one Cu-based catalyst C and at least one polar solvent S2, iv/ reaction of said reaction mixture, v/ filtration and then washing and vi/ drying of said crystallized functionalized hybrid solid.

    摘要翻译： 描述了一种制备具有有机 - 无机基质的功能化混合固体的方法，该有机 - 无机基质结晶，具有至少一个基于三唑环的反应性基团，其与有机 - 无机基质MOF-NH 2的混合固体，包括： 在所述结晶的杂化固体MOF-NH 2的极性溶剂S1中引入至少一种含有氮化物官能N 3的有机化合物Q和至少一种含有亚硝酸盐功能NO 2的中间体试剂R，ii /所述反应的反应 混合物，iii /引入至少一种具有炔官能团或活性氰化物功能的试剂A的反应混合物，至少一种Cu基催化剂C和至少一种极性溶剂S2，iv /所述反应混合物的反应，v /过滤，然后洗涤和vi /干燥所述结晶的官能化混合固体。