公开(公告)号：US08258071B2

公开(公告)日：2012-09-04

申请号：US10587854

申请日：2005-01-13

Applicant: Younes Bouizi ,  Valentin Valtchev ,  Loiec Rouleau ,  Nicolas Bats ,  Laurent Simon

Inventor： Younes Bouizi ,  Valentin Valtchev ,  Loiec Rouleau ,  Nicolas Bats ,  Laurent Simon

IPC: B01J29/06

CPC classification number: B01J37/0246 ,  B01J29/035 ,  B01J29/084 ,  B01J29/7007 ,  B01J29/80 ,  B01J35/023 ,  B01J2229/62

Abstract: The invention relates to a catalyst that comes in the form of grains, each grain consisting of a core covered by at least one external layer, the core consisting of an acidic porous solid and having a size of between 0.1 micron and 0.4 millimeter, in which the external layer has a uniform thickness with a uniformity criterion C, which is less than 0.30, whereby said uniformity criterion C is defined as being equal to an average, on a number N of catalyst grain samples, of the ratio of the difference between the maximum thickness, Eimax, of the external layer and the minimum thickness, Eimin, of this same layer to the average of these two thicknesses Eimax and Eimin.

Abstract translation: 本发明涉及一种呈颗粒形式的催化剂，每个颗粒由至少一层外层覆盖的芯组成，芯由酸性多孔固体组成，尺寸为0.1微米至0.4毫米，其中 外层具有均匀的厚度，其均匀性标准C小于0.30，其中所述均匀性标准C被定义为等于催化剂颗粒样品数目N上的平均值 最大厚度，Eimax以及最小厚度Eimin，与该两个厚度Eimax和Eimin的平均值相同。

公开(公告)号：US20120205286A1

公开(公告)日：2012-08-16

申请号：US13345041

申请日：2012-01-06

Applicant: Jeremy FRANCIS ,  Laurent Simon ,  Emmanuelle Guillon ,  Nicolas Bats ,  Avelino Corma ,  Christophe Pichon

Inventor： Jeremy FRANCIS ,  Laurent Simon ,  Emmanuelle Guillon ,  Nicolas Bats ,  Avelino Corma ,  Christophe Pichon

IPC: C10G65/12 ,  B01J29/04 ,  C10G47/06

CPC classification number: B01J29/146 ,  B01J29/166 ,  B01J35/002 ,  B01J35/0066 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/0205 ,  B01J37/20 ,  B01J2229/14 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  C10G49/08 ,  C10G2300/301 ,  C10G2300/4018

Abstract: Process for hydrocracking and/or hydrotreatment of hydrocarbon feeds utilizing a catalyst comprising at least one hydro-dehydrogenating element of group VIB and of non-precious group VIII used alone or mixed, and a support comprising at least one porous mineral matrix and at least one dealuminated USY zeolite having an overall silicon-to-aluminium atomic ratio comprised between 2.5 and 10, a fraction by weight of extra-network aluminium atom greater than 10% relative to the total mass of the aluminium present in the zeolite, a mesopore volume measured by nitrogen porosimetry greater than 0.07 ml.g−1, and a crystal parameter a0 of the elemental mesh greater than 24.28 Å, in which a quantity of the element nickel comprised between 0.5 and 3% by weight relative to the total mass of the zeolite is deposited on said USY zeolite and in which said catalyst is in the sulphide form.

Abstract translation: 使用包含至少一种单独或混合使用的VIB族和非贵重族VIII的加氢脱氢元素的催化剂，以及包含至少一种多孔矿物基质和至少一种多孔矿物基质的载体来加氢裂化和/或加氢处理烃进料的方法 具有2.5至10的整体硅 - 铝原子比的脱铝USY沸石，相对于存在于沸石中的铝的总质量大于10％的网络外铝原子的重量百分比，测量的中孔体积 通过氮气孔隙度法大于0.07ml.g-1，并且元素网的晶体参数a0大于24.28，其中元素镍的量相对于沸石的总质量为0.5-3重量％ 沉积在所述USY沸石上，其中所述催化剂为硫化物形式。

公开(公告)号：US20110192765A1

公开(公告)日：2011-08-11

申请号：US13057781

申请日：2009-07-29

Applicant: Emmanuelle Guillon ,  Laurent Simon

Inventor： Emmanuelle Guillon ,  Laurent Simon

IPC: C10G47/02 ,  B01J29/076 ,  B01J29/072 ,  C10G49/08 ,  C07C4/02 ,  C10G45/00 ,  C10G65/00 ,  C07C7/00

CPC classification number: B01J29/76 ,  B01J21/04 ,  B01J21/12 ,  B01J29/78 ,  B01J37/0009 ,  B01J37/20 ,  B01J2229/20 ,  B01J2229/42 ,  C01B39/48 ,  C10G47/16 ,  C10G47/20 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018

Abstract: The present invention relates to a catalyst comprising at least one IZM-2 zeolite, at least one amorphous matrix, at least one hydro-dehydrogenating element selected from the group formed by the elements from group VIB and from group VIII of the periodic table and excluding platinum and palladium. The catalyst also optionally contains a controlled quantity of at least one doping element selected from phosphorus, boron and silicon, optionally at least one element from group VB of the periodic table of the elements, and optionally a group VIIA element. The invention also relates to hydrocracking and hydrotreatment processes implementing this catalyst.

Abstract translation: 本发明涉及包含至少一种IZM-2沸石，至少一种无定形基质，至少一种加氢脱氢元素的催化剂，所述至少一种加氢脱氢元件选自由元素周期表中VIB族和VIII族元素形成的基团，不包括 铂和钯。 催化剂还任选地含有受控量的至少一种选自磷，硼和硅的掺杂元素，任选地包含元素周期表第VB族中的至少一种元素，以及任选的第VIIA族元素。 本发明还涉及实施该催化剂的加氢裂化和加氢处理方法。

公开(公告)号：US20110172482A1

公开(公告)日：2011-07-14

申请号：US12994194

申请日：2009-04-28

Applicant: Amandine Cabiac ,  Alexandra Chaumonnot ,  Laurent Simon

Inventor： Amandine Cabiac ,  Alexandra Chaumonnot ,  Laurent Simon

IPC: C07C2/02 ,  B01J21/06 ,  B01J35/10 ,  B01J29/04 ,  B01J29/18 ,  B01J29/65 ,  B01J29/70 ,  B01J21/02 ,  B01J21/04 ,  B01J21/16 ,  B01J21/14 ,  B01J27/182 ,  B01J21/18

CPC classification number: C07C2/12 ,  B01J29/041 ,  B01J29/06 ,  B01J29/40 ,  B01J29/7007 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/0045 ,  B01J2229/42 ,  C07C2529/40 ,  C07C2529/70 ,  C10G50/00

Abstract: A catalyst that comprises at least one binder and at least one crystallized material with hierarchized and organized porosity in the fields of microporosity and mesoporosity is described, whereby said crystallized material consists of at least two elementary spherical particles, each of said particles comprising a mesostructured silicon-oxide-based matrix that has a mesopore diameter of between 1.5 and 30 nm and that has microporous and crystallized walls with a thickness of between 1 and 60 nm, whereby said elementary spherical particles have a maximum diameter of 200 microns. Said catalyst is used in a process for oligomerization of an olefinic feedstock that contains hydrocarbon molecules that have 2 to 12 carbon atoms per molecule.

Abstract translation: 描述了一种催化剂，其包含至少一种粘合剂和至少一种在微孔和中孔性的领域中具有分级和有组织的孔隙率的结晶材料，由此所述结晶材料由至少两个基本球形颗粒组成，每个所述颗粒包含介孔结构的硅 基于氧化物的基质，其中孔直径在1.5至30nm之间，并且具有厚度在1至60nm之间的微孔和结晶壁，由此所述基本球形颗粒的最大直径为200微米。 所述催化剂用于含有每分子具有2至12个碳原子的烃分子的烯烃原料低聚的方法。

公开(公告)号：US20110155633A1

公开(公告)日：2011-06-30

申请号：US12903587

申请日：2010-10-13

Applicant: Laurent SIMON ,  Christophe Bouchy

Inventor： Laurent SIMON ,  Christophe Bouchy

IPC: C10G65/12 ,  C10G47/20 ,  C10G49/08

CPC classification number: C10G47/18 ,  C10G2/30 ,  C10G45/62 ,  C10G45/64 ,  C10G47/20 ,  C10G65/12

Abstract: The invention relates to a process for the production of middle distillates from a paraffinic feedstock that is produced by Fischer-Tropsch synthesis, implementing a hydrocracking/hydroisomerization catalyst that comprises at least one hydro-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table and a substrate that comprises at least one zeolite that has at least one series of channels of which the opening is defined by a ring with 12 oxygen atoms modified by a) a stage for introducing at least one alkaline cation that belongs to group IA or IIA of the periodic table, b) a stage for treatment of said zeolite in the presence of at least one molecular compound that contains at least one silicon atom, c) at least one stage for partial exchange of said alkaline cations by NH4+ cations such that the remaining content of alkaline cations in the modified zeolite at the end of stage c) is such that the alkaline cation/aluminum molar ratio is between 0.2:1 and 0.01:1, and d) at least one heat treatment stage.

Abstract translation: 本发明涉及一种由费 - 托合成生产的石蜡原料生产中间馏分的方法，其实施加氢裂化/加氢异构化催化剂，该加氢裂化/加氢异构化催化剂包含至少一种加氢脱氢金属，其选自由 元素周期表VIB族和VIII族的金属和至少一种具有至少一个通道系列的沸石的基质，该沸石的开口由具有12个氧原子的环所限定，该氧原子被a） 至少一种属于周期表的IA或IIA族的碱性阳离子，b）在至少一种含有至少一个硅原子的分子化合物的存在下，用于处理所述沸石的阶段，c）至少一个用于 通过NH 4 +阳离子部分交换所述碱性阳离子，使得在阶段c）结束时改性沸石中碱性阳离子的剩余含量使得碱性阴离子 铝/铝摩尔比为0.2:1至0.01:1，和d）至少一个热处理阶段。

公开(公告)号：US20110124936A1

公开(公告)日：2011-05-26

申请号：US12994213

申请日：2009-04-28

Applicant: Amandine Cabiac ,  Alexandra Chaumonnot ,  Laurent Simon

Inventor： Amandine Cabiac ,  Alexandra Chaumonnot ,  Laurent Simon

IPC: C07C2/24 ,  C07C2/08

CPC classification number: B01J29/40 ,  B01J29/06 ,  B01J35/023 ,  B01J35/08 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/0045 ,  B01J2229/62 ,  C07C2/12 ,  C07C2529/40 ,  C07C2529/70 ,  C10G50/00 ,  C10G2300/1088 ,  C10G2300/1092 ,  C10G2300/4018 ,  C10G2400/22

Abstract: A process for oligomerization of an olefinic feedstock that contains olefinic hydrocarbon molecules that have 2 to 10 carbon atoms per molecule is described, whereby said process comprises bringing said feedstock into contact with a catalyst that comprises at least one amorphous material with hierarchized and organized porosity and consists of at least two elementary spherical particles, each of said particles comprising a mesostructured silicon-oxide-based matrix that has a mesopore diameter of between 1.5 and 30 nm and that exhibits amorphous and microporous walls with a thickness of between 1 and 50 nm, whereby said elementary spherical particles have a maximum diameter of 200 microns.

Abstract translation: 描述了含有每分子具有2-10个碳原子的烯属烃分子的烯烃原料的低聚方法，其中所述方法包括使所述原料与包含至少一种具有分级和组织的孔隙率的至少一种无定形材料的催化剂接触， 由至少两个基本球形颗粒组成，每个所述颗粒包含介孔结构的基于氧化硅的基质，其中孔直径在1.5至30nm之间，并且具有介于1和50nm之间的无定形和微孔壁， 由此所述基本球形颗粒的最大直径为200微米。

公开(公告)号：US20110120910A1

公开(公告)日：2011-05-26

申请号：US12942315

申请日：2010-11-09

Applicant: Laurent Simon ,  Emmanuelle Guillon ,  Christophe Bouchy

Inventor： Laurent Simon ,  Emmanuelle Guillon ,  Christophe Bouchy

IPC: C10G69/02 ,  C10G47/20 ,  C10G35/04

CPC classification number: C10G45/62 ,  B01J29/106 ,  B01J29/126 ,  B01J29/166 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/108 ,  B01J37/0009 ,  B01J2229/16 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  C10G45/64 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/04 ,  C10G2400/08 ,  Y02P30/20

Abstract: This invention describes a process for the production of middle distillates from a paraffinic feedstock that is produced by Fischer-Tropsch synthesis, implementing a hydrocracking/hydroisomerization catalyst that comprises at least one hydro-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table and a substrate that comprises at least one dealuminified Y zeolite that has an initial overall atomic ratio of silicon to aluminum of between 2.5 and 20, a starting extra-lattice aluminum atom fraction by weight that is greater than 10%, relative to the total mass of aluminum that is present in the zeolite, a starting mesopore volume that is measured by nitrogen porosimetry that is greater than 0.07 ml.g−1, and a starting crystalline parameter ao of the elementary mesh of between 24.38 Å and 24.30 Å, whereby said zeolite is modified by a) a basic treatment stage consisting in mixing said dealuminified Y zeolite with a basic aqueous solution, and at least one heat treatment stage c).

Abstract translation: 本发明描述了一种由费 - 托合成生产的石蜡原料生产中间馏分的方法，其实施加氢裂化/加氢异构化催化剂，其包含至少一种加氢脱氢金属，其选自由 元素周期表VIB族和VIII族的金属以及包含至少一种脱铝Y沸石的底物，其具有硅与铝的初始总原子比为2.5至20，起始晶格间铝原子级分的重量比为 相对于存在于沸石中的铝的总质量大于10％，通过氮气孔率法测量的起始中孔体积大于0.07ml.g-1，并且初级晶体参数ao为初级 筛网在24.38埃至24.30埃之间，由此所述沸石通过以下步骤进行改性：a）将所述脱铝Y沸石w 碱性水溶液和至少一个热处理阶段c）。

公开(公告)号：US20110108460A1

公开(公告)日：2011-05-12

申请号：US12942487

申请日：2010-11-09

Applicant: Laurent SIMON ,  Emmanuelle Guillon ,  Antoine Daudin

Inventor： Laurent SIMON ,  Emmanuelle Guillon ,  Antoine Daudin

IPC: C10G65/02

CPC classification number: C10G3/45 ,  B01J23/883 ,  B01J29/084 ,  B01J29/146 ,  B01J29/166 ,  B01J37/10 ,  B01J2229/16 ,  B01J2229/22 ,  B01J2229/36 ,  B01J2229/38 ,  B01J2229/42 ,  C10G3/46 ,  C10G3/49 ,  C10G3/50 ,  C10G3/54 ,  C10G45/64 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2400/04 ,  C10G2400/08 ,  Y02P30/20

Abstract: This invention describes a process for treatment of feedstocks obtained from a renewable source implementing—in one hydroisomerization stage—a catalyst that comprises at least one hydro-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table and a substrate that comprises at least one dealuminified Y zeolite that has an initial overall atomic ratio of silicon to aluminum of between 2.5 and 20, a fraction by weight of an initial extra-network aluminum atom that is greater than 10%, relative to the total mass of aluminum that is present in the zeolite, an initial mesopore volume that is measured by nitrogen porosimetry that is greater than 0.07 ml·g−1, and an initial crystalline parameter ao of the unit cell mesh of between 24.38 Å and 24.30 Å, whereby said zeolite is modified by a) a basic treatment stage that consists of the mixing of said dealuminified Y zeolite with a basic aqueous solution, and at least one heat treatment stage c).

Abstract translation: 本发明描述了一种处理从可再生来源获得的原料的方法，该可再生来源实施了一个加氢异构化阶段 - 催化剂，该催化剂包含至少一种选自由VIB族金属和VIII族金属形成的基团的加氢脱氢金属 和包含至少一种脱铝Y沸石的底物，所述脱铝Y沸石的硅与铝的初始总原子比为2.5至20，初始超网络铝原子的重量百分比大于10％ ，相对于存在于沸石中的铝的总质量，通过氮气孔率法测量的初始中孔体积大于0.07ml·g-1，并且单元孔网的初始结晶参数ao在24.38 所述沸石通过以下步骤进行改性：a）碱性处理阶段，其由所述脱铝Y沸石与碱性水溶液的混合组成， 至少一个热处理阶段c）。

公开(公告)号：US20110108459A1

公开(公告)日：2011-05-12

申请号：US12942351

申请日：2010-11-09

Applicant: Laurent SIMON ,  Emmanuelle Guillon

Inventor： Laurent SIMON ,  Emmanuelle Guillon

IPC: C10G65/12 ,  C10G47/20 ,  C01B39/00 ,  B01J29/04

CPC classification number: C01B39/00 ,  B01J29/084 ,  B01J29/146 ,  B01J29/166 ,  B01J35/10 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/10 ,  B01J37/20 ,  B01J2229/16 ,  B01J2229/22 ,  B01J2229/36 ,  B01J2229/38 ,  B01J2229/40 ,  C10G45/08 ,  C10G45/12 ,  C10G47/20 ,  C10G65/12 ,  C10G2300/1007 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018 ,  C10G2400/02 ,  C10G2400/04

Abstract: The present invention describes a hydrocracking and/or hydrotreatment process using a catalyst comprising an active phase containing at least one hydrogenating/dehydrogenating component selected from the group VIB elements and the non-precious elements of group VIII of the periodic table, used alone or in a mixture, and a support comprising at least one dealuminated zeolite Y having an overall initial atomic ratio of silicon to aluminium between 2.5 and 20, an initial weight fraction of extra-lattice aluminium atoms greater than 10%, relative to the total weight of aluminium present in the zeolite, an initial mesopore volume measured by nitrogen porosimetry greater than 0.07 ml·g−1 and an initial crystal lattice parameter a0 between 24.38 Å and 24.30 Å, said zeolite being modified by a) a stage of basic treatment comprising mixing said dealuminated zeolite Y with a basic aqueous solution, and at least one stage c) of thermal treatment.

Abstract translation: 本发明描述了使用催化剂的加氢裂化和/或加氢处理方法，所述催化剂包含活性相，所述活性相含有至少一种选自元素周期表中VIB族元素和VIII族非贵金属的氢化/脱氢组分， 混合物和包含至少一种脱铝沸石Y的载体，其具有2.5至20的硅与铝的总初始原子比，超晶格铝原子的初始重量分数相对于铝的总重量大于10％ 存在于沸石中，通过氮气孔隙度法测量的初始中孔体积大于0.07ml·g -1，初始晶格参数a0在24.38埃至24.30埃之间，所述沸石通过以下步骤进行修饰：a）碱性处理阶段，包括将所述 用碱性水溶液脱铝沸石Y和至少一个热处理阶段c）。

公开(公告)号：US07476773B2

公开(公告)日：2009-01-13

申请号：US11476203

申请日：2006-06-28

Applicant: Sylvain Louret ,  Vincent Coupard ,  Laurent Simon

Inventor： Sylvain Louret ,  Vincent Coupard ,  Laurent Simon

IPC: C07C2/00

CPC classification number: C10G50/00

Abstract: A process for preparing a gas oil cut comprises the following steps in succession: 1) oligomerizing an olefinic C2-C12 hydrocarbon cut, preferably C3-C7 and more preferably C3-C5; 2) separating the mixture of products obtained in step 1) into three cuts: a light cut containing unreacted C4 and/or C5 olefinic hydrocarbons, an intermediate cut having a T95 in the range 200-220° C. and a heavy cut comprising the complement; T95 being the temperature at which 95% by weight of product has evaporated, as determined in accordance with standard method ASTM D2887; 3) oligomerizing the intermediate cut obtained in the separation step; characterized in that in step 3), oligomerization is carried out in the presence of an olefinic C4 and/or C5 hydrocarbon cut in a weight ratio of intermediate cut to olefinic C4 and/or C5 cut in the range of 60/40 to 80/20.

Abstract translation: 一种制备瓦斯油切割的方法包括以下步骤：1）使烯烃C2-C12烃馏分低聚，优选C3-C7，更优选C3-C5; 2）将步骤1）中获得的产物的混合物分成三个切口：含有未反应的C 4和/或C 5烯烃的轻馏分，T95在200-220℃范围内的中间切口，以及包含 补充; T95是按照标准方法ASTM D2887测定的95重量％的产品蒸发的温度; 3）使分离步骤中获得的中间切片低聚; 其特征在于在步骤3）中，在中间切割的烯烃C4和/或C5切割重量比为60/40至80 /℃的烯烃C4和/或C5烃切割的存在下进行低聚， 20。