公开(公告)号：US06326123B1

公开(公告)日：2001-12-04

申请号：US09370316

申请日：1999-08-09

申请人： Paul R. West ,  Jeffery A. Gurney ,  John E. Walls

发明人： Paul R. West ,  Jeffery A. Gurney ,  John E. Walls

IPC分类号： G03F7004

CPC分类号： B41C1/1008 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  Y10S430/106 ,  Y10S430/127 ,  Y10S430/145

摘要： A positive image can be obtained from a positive-working element that is sensitive to infrared radiation. The element comprises an imaging layer containing an alkali-soluble reactive resin (such as a phenolic resin), an infrared radiation absorbing compound, a thermochemical acid generating compound, and a dissolution inhibitor that has acid-cleavable C—O—C groups. Upon laser exposure, a Bronsted acid is generated which then breaks the bonds of the C—O—C groups, allowing the exposed regions of the reactive resin to be solubilized in an alkaline developer solution.

摘要翻译： 可以从对红外线辐射敏感的正电极元件获得正像。 该元件包括含有碱溶性反应性树脂（例如酚醛树脂），红外辐射吸收化合物，热化学产酸化合物和具有酸可裂解C-O-C基团的溶解抑制剂的成像层。 激光曝光后，产生布朗斯台德酸，然后破坏C-O-C基团的键，允许反应性树脂的暴露区域溶解在碱性显影剂溶液中。

公开(公告)号：US4946373A

公开(公告)日：1990-08-07

申请号：US366115

申请日：1989-06-14

申请人： John E. Walls ,  Carlos Tellechea

发明人： John E. Walls ,  Carlos Tellechea

IPC分类号： G03F7/095

CPC分类号： G03F7/0955

摘要： This invention relates to a radiation polymerizable composition for use in a photographic element such as a lithographic printing plate comprising in admixture(a) a polymeric binder;(b) a photoinitiator;(c) a diazonium salt; and(d) a photopolymerizable mixture of(i) a polyfunctional acrylic monomer having from 3 to 6 unsaturated groups; and(ii) a monofunctional acrylic monomer having 1 unsaturated group.

摘要翻译： 本发明涉及用于照相材料如平版印刷版的可辐射聚合组合物，其包含（a）聚合物粘合剂; （b）光引发剂; （c）重氮盐; 和（d）（i）具有3至6个不饱和基团的多官能丙烯酸单体的可光聚合混合物; 和（ii）具有1个不饱和基团的单官能丙烯酸类单体。

公开(公告)号：US4772538A

公开(公告)日：1988-09-20

申请号：US762090

申请日：1985-08-02

申请人： John E. Walls ,  Frank C. Pagano

发明人： John E. Walls ,  Frank C. Pagano

IPC分类号： G03F7/033 ,  G03C1/70

CPC分类号： G03F7/033 ,  Y10S430/11 ,  Y10S430/121 ,  Y10S430/123 ,  Y10S522/904

摘要： This invention relates to a radiation polymerizable composition for use in a photographic element such as a lithographic printing plate comprising in admixture(a) a binder resin having the general formula--A--B--C-- wherein a plurality of each of components A, B and C occur in ordered or random sequence in the resin and wherein A is present in said resin at about 5% to about 20% by weight and comprises groups of the formula ##STR1## B is present in said resin at about 4% to about 30% by weight and comprises groups of the formula ##STR2## and C is present in said resin at about 50% to about 91% by weight and comprises acetal groups consisting of groups of the formulae ##STR3## where R is lower alkyl or hydrogen, and wherein said group I is present in component C from about 75% to about 85%, group II is present in component C from about 3% to about 5%; and group III is present in component C from about 10% to about 22%;(b) a photoinitiator;(c) a photopolymerizable mixture of(1) a polyethoxylate diacrylate monomer; and(2) an oligomeric amine diacrylate.

摘要翻译： 本发明涉及用于照相材料如平版印刷版的可辐射聚合组合物，其包含（a）具有通式-ABC的粘合剂树脂，其中多个组分A，B和C各自出现在 树脂中有序或无序的序列，其中A以约5重量％至约20重量％存在于所述树脂中，并且包含下式的基团B以约4重量％至约30重量％存在于所述树脂中 并且包含式（IMAGE）的基团，并且C以约50％至约91％（重量）的量存在于所述树脂中，并且包含由下式的组构成的缩醛基：（I） （III）其中R是低级烷基或氢，并且其中组I中存在的组I为约75％至约85％，组II中存在的组II为约3％至约5％; 组分C中组III存在约10％至约22％; （b）光引发剂; （c）（1）聚乙氧基化二丙烯酸酯单体的光聚合混合物; 和（2）低聚胺二丙烯酸酯。

公开(公告)号：US4707437A

公开(公告)日：1987-11-17

申请号：US924383

申请日：1986-10-29

申请人： John E. Walls ,  Carlos Tellechea ,  Major S. Dhillon

发明人： John E. Walls ,  Carlos Tellechea ,  Major S. Dhillon

IPC分类号： G03F7/033 ,  G03C1/76

CPC分类号： G03F7/033 ,  Y10T428/31667 ,  Y10T428/31692 ,  Y10T428/31797 ,  Y10T428/31855

摘要： This invention relates to a radiation polymerizable composition for use in a photographic element such as a lithographic printing plate comprising in admixture(a) a binder resin having the general formula--A--B--C-- wherein a plurality of each of components A, B and C occur in ordered or random sequence in the resin and wherein A is present in said resin at about 5% to about 20% by weight and comprises groups of the formula ##STR1## B is present in said resin at about 4% to about 30% by weight and comprises groups of the formula ##STR2## and C is present in said resin at about 50% to about 91% by weight and comprises acetal groups consisting of groups of the formulae ##STR3## where R is lower alkyl or hydrogen, and wherein said group I is present in component C from about 75% to about 85%, group II is present in component C from about 3% to about 5%; and group III is present in component C from about 10% to about 22%.(b) a photoinitiator;(c) a diazonium salt; and(d) a photopolymerizable mixture of(i) an acrylic monomer having two or more unsaturated groups; and(ii) an oligomer which is prepared by reacting one molar equivalent of a substantially linear polymeric compound having an active hydrogen group at each end thereof with at least two molar equivalents of a diisocyanate compound so as to form a prepolymer having an isocyanate group at each end thereof; and subsequently reacting said prepolymer with at least two equivalents of an ethylenically unsaturated compound having an active hydrogen group to provide said prepolymer with unsaturation at each end thereof.

摘要翻译： 本发明涉及用于照相材料如平版印刷版的可辐射聚合组合物，其包含（a）具有通式-ABC的粘合剂树脂，其中多个组分A，B和C各自出现在 树脂中有序或无序的序列，其中A以约5重量％至约20重量％存在于所述树脂中，并且包含下式的基团B以约4重量％至约30重量％存在于所述树脂中 并且包含式（IMAGE）的基团，并且C以约50％至约91％（重量）的量存在于所述树脂中，并且包含由式（I）的基团组成的缩醛基，其中R是低级烷基或氢，并且其中所述 组I中组I的含量为约75％至约85％，组分C中组II为约3％至约5％; 组分C中组III存在约10％至约22％。 （b）光引发剂; （c）重氮盐; 和（d）（i）具有两个或更多个不饱和基团的丙烯酸类单体的光聚合混合物; 和（ii）低聚物，其通过使一摩尔当量的在其各端具有活性氢基团的基本上线性的聚合物与至少两摩尔当量的二异氰酸酯化合物反应制备，以便形成具有异氰酸酯基团的预聚物 其每端; 随后使所述预聚物与至少两当量的具有活性氢基团的烯键式不饱和化合物反应，以使所述预聚物在其每一末端具有不饱和键。

公开(公告)号：US4554236A

公开(公告)日：1985-11-19

申请号：US543566

申请日：1983-10-19

申请人： Trisha Bentley ,  John E. Walls ,  Major S. Dhillon

发明人： Trisha Bentley ,  John E. Walls ,  Major S. Dhillon

IPC分类号： G03F7/016 ,  G03C1/60 ,  G03C1/94

CPC分类号： G03F7/0166

摘要： This invention relates to light sensitive water soluble diazonium compound condensation products stabilized against degradation caused by heat and/or prolonged storage employing selected amino acids as stabilizers. The invention also relates to presensitized reproduction materials comprising the amino acid stabilized water soluble diazonium compound condensation products.

摘要翻译： 本发明涉及使用所选择的氨基酸作为稳定剂的由热和/或长期储存稳定的防止降解的光敏水溶性重氮化合物缩合产物。 本发明还涉及包含氨基酸稳定化的水溶性重氮化合物缩合产物的致敏复制材料。

公开(公告)号：US4533620A

公开(公告)日：1985-08-06

申请号：US519443

申请日：1983-08-02

申请人： John E. Walls ,  Thomas A. Dunder

发明人： John E. Walls ,  Thomas A. Dunder

IPC分类号： G03F7/016 ,  G03C1/52 ,  G03F7/021 ,  G03F7/038 ,  G03C1/54 ,  C07C113/04 ,  G03F7/08

CPC分类号： G03F7/021

摘要： Light sensitive condensed copolymers or multi-polymers of at least two distinct diazonium salts of the types specified herein. The product is characterized by high light speed, good shelf life and very good resistance to thermal and electrical degradation.

摘要翻译： 至少两种本文所述类型的不同重氮盐的光敏缩合共聚物或多聚物。 该产品的特点是光速高，保质期好，耐热和电气降解性好。

公开(公告)号：US4448873A

公开(公告)日：1984-05-15

申请号：US359460

申请日：1982-03-18

申请人： John E. Walls ,  Major S. Dhillon

发明人： John E. Walls ,  Major S. Dhillon

IPC分类号： G03F1/54 ,  G03F7/016 ,  G03C1/60 ,  G03C1/78

CPC分类号： G03F1/54 ,  G03F7/0166

摘要： A photographic element comprising a transparent support and a coating on the support comprising a diazonium composition having a light absorbency of about 45% or less, and a colorant composition, said coating having a light transmission of not more than about 0.1%.

摘要翻译： 一种照相元件，包括透明载体和载体上的涂层，其包含具有约45％或更小的光吸收率的重氮组合物和着色剂组合物，所述涂层具有不大于约0.1％的透光率。

公开(公告)号：US4399021A

公开(公告)日：1983-08-16

申请号：US359457

申请日：1982-03-18

申请人： Thomas N. Gillich ,  John E. Walls ,  Stanley F. Wanat ,  William J. Rozell

发明人： Thomas N. Gillich ,  John E. Walls ,  Stanley F. Wanat ,  William J. Rozell

IPC分类号： B41N3/03 ,  C25D11/06 ,  C25D11/12 ,  C25D11/10 ,  C25D11/24

CPC分类号： B41N3/034 ,  C25D11/06 ,  C25D11/12 ,  Y10S205/921

摘要： According to the invention there is provided an electrochemical process for applying a firmly bonded insoluble metal oxide-organic complex on a metal surface by employing the metal as anode and a water-soluble polybasic organic acid as electrolyte. The polybasic acid may be a polyphosphonic acid, polyphosphoric and polycarboxyl acid, or polysulfonic acid and is advantageously polymeric. Polyvinyl phosphonic acid (PVPA) is a preferred electrolyte. Repetitive cycle pulsed direct current is used. The insoluble metal oxide-organic complex formed is composed of anodic oxide combined with polyacid, which forms a protective layer on the metal of improved corrosion resistance. The metal oxide-organic complex is well-suited to bond light sensitive coatings thereto. The metal may be steel, aluminum or magnesium.

摘要翻译： 根据本发明，提供了一种通过使用金属作为阳极和水溶性多元有机酸作为电解质将金属表面上牢固结合的不溶性金属氧化物 - 有机络合物施加到电化学方法。 多元酸可以是多膦酸，多磷酸和聚羧酸或聚磺酸，并且有利地是聚合的。 聚乙烯基膦酸（PVPA）是优选的电解质。 使用重复循环脉冲直流电。 形成的不溶性金属氧化物 - 有机络合物由阳极氧化物与多元酸组合，其在金属上形成了改善的耐腐蚀性的保护层。 金属氧化物 - 有机络合物非常适用于将光敏涂层粘合到其上。 金属可以是钢，铝或镁。

公开(公告)号：US4388156A

公开(公告)日：1983-06-14

申请号：US333586

申请日：1981-12-23

申请人： Thomas N. Gillich ,  John E. Walls

发明人： Thomas N. Gillich ,  John E. Walls

IPC分类号： B41N3/03 ,  C25D9/02 ,  C25D11/00 ,  C25D11/10

CPC分类号： B41N3/034 ,  C25D11/00 ,  C25D11/10 ,  C25D9/02

摘要： The invention is directed to the electrochemical treatment of aluminum substrates in a non-aqueous solution of a polybasic organic acid to provide a surface complex which promotes the adhesion of subsequently applied coatings to said surface.

摘要翻译： 本发明涉及在多元有机酸的非水溶液中对铝基板进行电化学处理以提供表面复合物，其促进随后涂覆的涂层对所述表面的粘附。

公开(公告)号：US4381340A

公开(公告)日：1983-04-26

申请号：US298051

申请日：1981-08-31

申请人： John E. Walls

发明人： John E. Walls

IPC分类号： B41N3/08 ,  G03F7/32 ,  G03C5/00

CPC分类号： G03F7/32

摘要： A developer suitable for machine and hand processing may now be made which accomplishes the aforementioned objects which is an aqueous solution comprising 2-propoxyethanol as a detackifying agent, an adjuvant solvent, a nonionic surfactant with a hydrophile-lipophile balance over about 17, and an inorganic salt. A developer/finisher may be prepared by adding thereto a water-soluble polymeric film former which is preferably polyvinyl pyrrolidone. A suspending agent, e.g. polyethylene glycol, is added to hand processing solutions.

摘要翻译： 现在可以进行适合于机器和手工处理的显影剂，其实现了上述目的，其是包含2-丙氧基乙醇作为防粘剂的水溶液，辅助溶剂，亲水亲油平衡超过约17的非离子表面活性剂，以及 无机盐。 可以通过向其中加入优选聚乙烯吡咯烷酮的水溶性聚合物成膜剂来制备显影剂/整理剂。 悬浮剂，例如 聚乙二醇加入到手工处理溶液中。