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公开(公告)号：US4048028A
公开(公告)日：1977-09-13
申请号：US698293
申请日：1976-06-22
Applicant: Karl Moeglich
Inventor： Karl Moeglich
CPC classification number: B01J20/28014 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/28004 , B01J20/3204 , B01J20/3236 , B01J20/3297 , C02F1/288 , C25B1/00 , B01J2220/42 , B01J2220/4825 , B01J2220/56 , B01J2220/58
Abstract: A sorbent particulate material, such as a metal hydroxide-coated sawdust, is made by passing a direct electric current between an anode of a metal capable of forming a flocculent hydroxide and a cathode in a turbulent electrolyte containing the dispersed particulate material, so as to form a metal hydroxide and deposit it on such material. Also described are filters made from the sorbent particulate material and processes of filtering or otherwise removing undesired components from liquid media by means of such product.
Abstract translation: 吸附剂颗粒材料，例如金属氢氧化物涂覆的锯屑，是通过在包含分散的颗粒材料的湍流电解质中将能够形成絮状氢氧化物的金属的阳极和阴极之间的直流电流传递到 形成金属氢氧化物并将其沉积在这种材料上。 还描述了由吸附剂颗粒材料制成的过滤器以及通过这种产品过滤或以其它方式从液体介质去除不期望的组分的过程。
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12.发明授权
公开(公告)号：US4021320A
公开(公告)日：1977-05-03
申请号：US616402
申请日：1975-09-24
Applicant: Karl Moeglich
Inventor： Karl Moeglich
IPC: C25B1/00
CPC classification number: C25B1/00
Abstract: The present invention relates to a method of electrochemically removing silver in the form of AgO from a photographic fixer solution containing silver ions without destroying the utility of the solution comprising the steps of applying alternating current having a frequency of between about 0.5 Hz and 800 Hz and a current density of between about 0.1 and 20 amperes per square inch across electrodes immersed in said solution to cause AgO to precipitate at the electrodes. The method can also be practiced above the range of about 20 amperes per square inch at the cost of destroying the utility of the solution. The method can also be used to remove silver in the form of AgO from other solutions.
Abstract translation: 本发明涉及一种从含有银离子的照相定影剂溶液中电化学去除AgO形式的银的方法，而不破坏该溶液的用途，该方法包括以下步骤：施加频率在约0.5Hz和800Hz之间的频率，以及 在浸入所述溶液中的电极之间的电流密度为约0.1至20安培/平方英寸，以使AgO在电极处沉淀。 该方法也可以在大约20安培/平方英寸的范围内实施，其代价是破坏溶液的效用。 该方法也可用于从其他溶液中除去AgO形式的银。
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Patent Agency Ranking
公开(公告)号：US4212724A
公开(公告)日：1980-07-15
申请号：US963940
申请日：1978-11-21
Applicant: Karl Moeglich
Inventor： Karl Moeglich
CPC classification number: A01K63/04 , C02F1/46114 , C02F9/00 , C02F1/463 , C02F1/4672
Abstract: The invention relates to an oxidation and coagulation apparatus and method especially suitable for use with aquariums (especially salt-water aquariums). Water is withdrawn from the aquarium by a pump, and is fed into the oxidizer and coagulator. The oxidizer and coagulator includes a chamber into which the pump discharges water under pressure, a plurality of electrodes disposed in the chamber and connected up to a source of e.m.f. (AC), a plurality of electrically conductive particles (e.g., graphite) disposed in the chamber, a structure for violently continuously circulating the particles within the chamber so that they continuously impact all of the electrodes, and structure for preventing movement of the electrically conductive particles out of the chamber. An outlet is provided from the chamber and a filter is provided for separating particles and coagulants from the water after discharge from the chamber, and then returning the now-purified water to the aquarium. The electrodes may be stainless steel, yet they will not rust even over extended operation in purifying salt water.
Abstract translation: 本发明涉及一种特别适用于水族箱（特别是盐水水族箱）的氧化和凝结装置和方法。 水通过泵从水族箱中取出，并进入氧化剂和凝结剂。 氧化剂和凝结器包括一个室，泵在压力下向其中排放水，多个电极设置在室中，并连接到一个源。 （AC），设置在室中的多个导电颗粒（例如石墨），用于使室内的颗粒剧烈连续循环的结构，使得它们连续地冲击所有电极，并且用于防止导电 颗粒离开室。 从室提供出口，并且提供过滤器用于在从室排出后从水中分离颗粒和凝结剂，然后将现净化水返回到水族箱中。 电极可以是不锈钢，即使在净化盐水时也不会生锈。
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公开(公告)号：US4094755A
公开(公告)日：1978-06-13
申请号：US663790
申请日：1976-03-04
Applicant: Karl Moeglich
Inventor： Karl Moeglich
CPC classification number: B01J8/42 , C02F1/46114 , C02F1/463 , C02F1/465 , C02F2001/46133 , C02F2201/4611 , C02F2201/46125 , C02F2201/4616 , C02F2301/024
Abstract: An improved method and apparatus for continuously agglomerating solids of colloidal size of larger suspended in a liquid is disclosed. The process comprises passing the liquid between spaced electrode plates in the presence of a fluidized bed of conductive particles, and subjecting said liquid suspension to an electric field from alternating current applied across said electrodes through the conductive particles of said bed. The turbulence of the particles in said bed has been found to improve conductivity and current efficiency, minimize electrode erosion, and by a mechanical, scrubbing action of the bed particles, minimize fouling or scaling of the electrodes so that the suspending forces of said solids are rapidly and efficiently broken. The agglomerated solids may then be separated from the liquid by conventional means such as skimming, settling, flotation and the like.
Abstract translation: 公开了一种改进的方法和装置，用于连续地附聚在液体中较大悬浮液的胶体尺寸的固体。 该方法包括在存在导电颗粒的流化床的情况下将液体通过间隔开的电极板，并且使所述液体悬浮液经由穿过所述电极穿过所述床的导电颗粒施加的交流电流进行电场。 已经发现，所述床中的颗粒的湍流改善了导电性和电流效率，使电极腐蚀最小化，并且通过床颗粒的机械洗涤作用，使电极的结垢或结垢最小化，使得所述固体的悬浮力为 快速有效地破碎。 然后可以通过常规方法例如撇取，沉降，浮选等将附聚的固体与液体分离。
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公开(公告)号：US4072596A
公开(公告)日：1978-02-07
申请号：US663791
申请日：1976-03-04
Applicant: Karl Moeglich
Inventor： Karl Moeglich
CPC classification number: C02F1/46 , C02F1/46114 , C02F1/4672 , C02F1/4676 , Y10S588/90
Abstract: A vessel is described for facilitating the removal of difficultly oxidizable impurities such as phenol and/or polychlorinated biphenyl from dilute aqueous solutions or dispersions. The vessel contains stacked, packed beds having characteristics of alternating high and low electrical conductivity with separately controlled pairs of electrodes for the two alternate types of beds. An aqueous solution containing contaminants is admitted to the vessel and passed through the successive beds wherein the solution or dispersion is subjected to an alternating current field for decomposition of the contaminants in the high resistivity beds and oxidization thereof in the lower resistivity beds by hydrogen peroxide produced by alternating current electrolysis of water. The preferred electrodes are hollow and water cooled. In addition, the bed is jacketed and cooling water is circulated through the jacket to maintain a more efficient, lower process temperature. The bed having lower resistivity includes conductive particles which may be graphite, and may include activated carbon or equivalent material. Said bed also contains non-conductive particles such particles being coated with catalysts. The catalyst may be an oxidation catalyst, such as the oxides of the metals of Groups IVa, Va, VIb, and VIIb, and specifically preferred are MnO.sub.2, Cr.sub. 2 O.sub.3, Bi.sub.2 O.sub.3 or PbO.sub.2. In the alternative, the catalyst may be a reduction catalyst such as oxides of nickel, iron and oxides of other Group VIII metals. The highly resistive bed is packed with said non-conductive particles only.
Abstract translation: 描述了用于促进从稀水溶液或分散体除去难以可氧化的杂质如苯酚和/或多氯联苯的容器。 容器包含具有交替的高和低导电性的堆叠的填充床，具有用于两种替代类型的床的单独控制的电极对。 含有污染物的水溶液进入容器并通过连续的床，其中溶液或分散体经受交流电场，用于分解高电阻率床中的污染物，并且通过产生过氧化氢在较低电阻率床中的氧化 通过交流电解电解水。 优选的电极是中空的并且水冷却。 此外，床被夹套，并且冷却水循环通过护套以保持更有效，更低的工艺温度。 具有较低电阻率的床包括可以是石墨的导电颗粒，并且可以包括活性炭或等效材料。 所述床还包含非导电颗粒，这些颗粒被催化剂涂覆。 催化剂可以是氧化催化剂，例如IVa，Va，VIb和VIIb族金属的氧化物，特别优选的是MnO 2，Cr 2 O 3，Bi 2 O 3或PbO 2。 在替代方案中，催化剂可以是还原催化剂，例如镍，铁的氧化物和其它VIII族金属的氧化物。 高电阻床仅用所述非导电颗粒填充。
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公开(公告)号：US4053378A
公开(公告)日：1977-10-11
申请号：US663792
申请日：1976-03-04
Applicant: Karl Moeglich , Graham L. Hodgetts
Inventor： Karl Moeglich , Graham L. Hodgetts
CPC classification number: C02F1/463 , C02F1/46 , C02F2301/024
Abstract: An improved method and apparatus for continuously agglomerating solids of colloidal size or larger suspended in a liquid is disclosed. The process comprises passing the liquid between spaced electrode plates in the presence of a fluidized bed of conductive particles, and subjecting said liquid suspension to an electric field from alternating current applied across said electrodes through the conductive particles of said bed. The turbulence of the particles in said bed has been found to improve conductivity and current efficiency, minimize electrode erosion, and by a mechanical, scrubbing action of the bed particles, minimize fouling or scaling of the electrodes so that the suspending forces of said solids are rapidly and efficiently broken. The agglomerated solids may then be separated from the liquid by conventional means such as skimming, settling, flotation and the like.
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17.发明授权
公开(公告)号：US4021319A
公开(公告)日：1977-05-03
申请号：US616121
申请日：1975-09-24
Applicant: Karl Moeglich
Inventor： Karl Moeglich
IPC: C25B1/00
CPC classification number: C25B1/00
Abstract: A method of electrolytically removing silver from a photographic fixer solution comprising the steps of placing the photographic fixer solution in a cell having an anode chamber and a cathode chamber, with said chamber being separated by a diaphragm having a pore size of between about 1.0 microns to 500 microns and applying a direct current across the anode and cathode to create a current density of between about 0.001 and 5 amperes per square inch at the cathode to thereby cause argentic oxide to precipitate at the cathode and an equivalent amount of elemental sulfur to precipitate at the anode. The cell is preferably maintained at a temperature of between about 20.degree. C. and 60.degree. C. The cell can be operated as a flow cell by maintaining a hydraulic head between the chambers to determine the flow across the diaphragm. When the cell is operated as a flow cell, a minimum specific amount of photographic fixer must be conveyed to the cell to prevent oxidation of sulfur and escape of SO.sub.2 gas.
Abstract translation: 一种从照相定影剂溶液中电解去除银的方法，包括以下步骤：将照相定影剂溶液放置在具有阳极室和阴极室的电池中，所述室由孔径为约1.0微米的隔膜分隔成 500微米，并在阳极和阴极上施加直流电流，以在阴极产生约0.001和5安培/平方英寸之间的电流密度，从而使氧化银在阴极处沉淀，并且等量的元素硫在 阳极。 电池优选保持在约20℃至60℃之间的温度。电池可以通过在室之间保持液压头来确定流过隔膜的流动来作为流动池来操作。 当电池作为流动池操作时，必须将最小量的照相定影剂输送到电池中以防止硫的氧化和SO2气体逸出。
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