公开(公告)号：US20120171576A1

公开(公告)日：2012-07-05

申请号：US13110924

申请日：2011-05-19

申请人： Li-Duan Tsai ,  Yueh-Wei Lin ,  Jason Fang ,  Cheng-Liang Cheng ,  Jing-Pin Pan ,  Tsung-Hsiung Wang

发明人： Li-Duan Tsai ,  Yueh-Wei Lin ,  Jason Fang ,  Cheng-Liang Cheng ,  Jing-Pin Pan ,  Tsung-Hsiung Wang

IPC分类号： H01M10/056

CPC分类号： H01M10/052 ,  H01M10/0567 ,  H01M2300/0025

摘要： A non-aqueous electrolyte including a lithium salt, an organic solvent, and an electrolyte additive is provided. The electrolyte additive is a meta-stable state nitrogen-containing polymer formed by reacting Compound (A) and Compound (B). Compound (A) is a monomer having a reactive terminal functional group. Compound (B) is a heterocyclic amino aromatic derivative as an initiator. A molar ratio of Compound (A) to Compound (B) is from 10:1 to 1:10. A lithium secondary battery containing the non-aqueous electrolyte is further provided. The non-aqueous electrolyte of this disclosure has a higher decomposition voltage than a conventional non-aqueous electrolyte, such that the safety of the battery during overcharge or at high temperature caused by short-circuit current is improved.

公开(公告)号：US08304117B2

公开(公告)日：2012-11-06

申请号：US12003599

申请日：2007-12-28

申请人： Yueh-Wei Lin ,  Tsung-Hsiung Wang ,  Jing-Pin Pan ,  Chang-Rung Yang ,  Jung-Mu Hsu

发明人： Yueh-Wei Lin ,  Tsung-Hsiung Wang ,  Jing-Pin Pan ,  Chang-Rung Yang ,  Jung-Mu Hsu

IPC分类号： H01M6/04

CPC分类号： H01M10/0565 ,  H01M10/052 ,  H01M2300/004

摘要： A gel polymer electrolyte precursor and a rechargeable cell comprising the same are provided. The gel polymer electrolyte precursor comprises a bismaleimide monomer or bismaleimide oligomer, a compound having formula (I): a non-aqueous metal salt electrolyte, a non-protonic solvent, and a free radical initiator, wherein the bismaleimide oligomer is prepared by reaction of barbituric acid and bismaleimide, X comprises oxygen, organic hydrocarbon compounds, organic hydrocarbon oxide compounds, oligomers or polymers, n is 2 or 3, and A independently comprises wherein m is 0˜6, X comprises hydrogen, cyano, nitro or halogen, and R1 independently comprises hydrogen or C1˜4 alkyl.

摘要翻译： 提供了一种凝胶聚合物电解质前体和包含该前体的可充电电池。 凝胶聚合物电解质前体包含双马来酰亚胺单体或双马来酰亚胺低聚物，具有式（I）的化合物：非水金属盐电解质，非质子溶剂和自由基引发剂，其中双马来酰亚胺低聚物通过 巴比妥酸和双马来酰亚胺，X包括氧，有机烃化合物，有机烃氧化物，低聚物或聚合物，n为2或3，A独立地包含其中m为0-6，X为氢，氰基，硝基或卤素，以及 R 1独立地包括氢或C 1-4烷基。

公开(公告)号：US08008360B2

公开(公告)日：2011-08-30

申请号：US12418534

申请日：2009-04-03

申请人： Chung-Liang Chang ,  Jing-Pin Pan ,  Tsung-Hsiung Wang ,  Yueh-Wei Lin ,  Ya-Tin Hsu

发明人： Chung-Liang Chang ,  Jing-Pin Pan ,  Tsung-Hsiung Wang ,  Yueh-Wei Lin ,  Ya-Tin Hsu

IPC分类号： B01J49/00

CPC分类号： C08G83/005 ,  C08J5/2275 ,  C08J2327/18 ,  C08J2400/202 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1044 ,  H01M8/1072 ,  H01M8/1081 ,  Y02P70/56

摘要： A proton exchange membrane and method for formation the same is disclosed. When forming the proton exchange membrane, first, a bismaleimide and barbituric acid are copolymerized to form a hyper-branched polymer. Next, the solvent of the sulfonated tetrafluorethylene copolymer (Nafion) aqueous solution is replaced with dimethyl acetamide (DMAc). 10 to 15 parts by weight of the hyper-branched polymer is added to 90 to 85 parts by weight of the Nafion in the DMAc solution, stood and heated to 50° C. for inter-penetration of the hyper-branched polymer and the Nafion. The heated solution is coated on a substrate, baked, and pre-treated to remove residue solvent to complete formation of the proton exchange membrane.

摘要翻译： 公开了质子交换膜及其形成方法。 当形成质子交换膜时，首先将双马来酰亚胺和巴比妥酸共聚以形成超支化聚合物。 接着，用二甲基乙酰胺（DMAc）代替磺化四氟乙烯共聚物（Nafion）水溶液的溶剂。 将10〜15重量份的超支化聚合物加入到在DMAc溶液中的90至85重量份的Nafion中，并加热至50℃，以使超支化聚合物和Nafion的相互渗透 。 将加热的溶液涂覆在基材上，烘烤并预处理以除去残留溶剂以完成质子交换膜的形成。

公开(公告)号：US20080160404A1

公开(公告)日：2008-07-03

申请号：US12003599

申请日：2007-12-28

申请人： Yueh-Wei Lin ,  Tsung-Hsiung Wang ,  Jing-Pin Pan ,  Chang-Rung Yang ,  Jung-Mu Hsu

发明人： Yueh-Wei Lin ,  Tsung-Hsiung Wang ,  Jing-Pin Pan ,  Chang-Rung Yang ,  Jung-Mu Hsu

IPC分类号： H01M10/40

CPC分类号： H01M10/0565 ,  H01M10/052 ,  H01M2300/004

摘要： A gel polymer electrolyte precursor and a rechargeable cell comprising the same are provided. The gel polymer electrolyte precursor comprises a bismaleimide monomer or bismaleimide oligomer, a compound having formula (I): , a non-aqueous metal salt electrolyte, a non-protonic solvent, and a free radical initiator, wherein the bismaleimide oligomer is prepared by reaction of barbituric acid and bismaleimide, X comprises oxygen, organic hydrocarbon compounds, organic hydrocarbon oxide compounds, oligomers or polymers, n is 2 or 3, and A independently comprises wherein m is 0˜6, X comprises hydrogen, cyano, nitro or halogen, and R1 independently comprises hydrogen or C1˜4 alkyl.

摘要翻译： 提供了一种凝胶聚合物电解质前体和包含该前体的可充电电池。 凝胶聚合物电解质前体包含双马来酰亚胺单体或双马来酰亚胺低聚物，具有式（I）的化合物：非水金属盐电解质，非质子溶剂和自由基引发剂，其中双马来酰亚胺低聚物通过反应 的巴比妥酸和双马来酰亚胺，X包括氧，有机烃化合物，有机烃氧化物，低聚物或聚合物，n为2或3，A独立地包含其中m为0〜6，X为氢，氰基，硝基或卤素， R 1和R 2独立地包括氢或C 1-4烷基。

公开(公告)号：US09005842B2

公开(公告)日：2015-04-14

申请号：US12546004

申请日：2009-08-24

申请人： Tsung-Hsiung Wang ,  Jing-Pin Pan ,  Wen-Chin Lee ,  Yueh-Wei Lin ,  Ya-Tin Hsu ,  Chung-Liang Chang ,  Chih-Jer Shih

发明人： Tsung-Hsiung Wang ,  Jing-Pin Pan ,  Wen-Chin Lee ,  Yueh-Wei Lin ,  Ya-Tin Hsu ,  Chung-Liang Chang ,  Chih-Jer Shih

IPC分类号： H01M8/10 ,  C08G73/12 ,  C08J5/22 ,  C08L79/08 ,  H01M4/92

CPC分类号： H01M8/1041 ,  C08G73/12 ,  C08J5/2256 ,  C08J2371/12 ,  C08J2400/202 ,  C08L79/085 ,  H01M4/92 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1048 ,  Y02E60/521

摘要： Proton exchange membrane compositions having high proton conductivity are provided. The proton exchange membrane composition includes a hyper-branched polymer, wherein the hyper-branched polymer has a DB (degree of branching) of more than 0.5. A polymer with high ion conductivity is distributed uniformly over the hyper-branched polymer, wherein the hyper-branched polymer has a weight ratio equal to or more than 5 wt %, based on the solid content of the proton exchange membrane composition.

摘要翻译： 提供了具有高质子传导性的质子交换膜组合物。 质子交换膜组合物包括超支化聚合物，其中超支化聚合物具有大于0.5的DB（支化度）。 具有高离子电导率的聚合物均匀地分布在超支化聚合物上，其中基于质子交换膜组合物的固体含量，超支化聚合物的重量比等于或大于5重量％。

公开(公告)号：US08034260B2

公开(公告)日：2011-10-11

申请号：US12425007

申请日：2009-04-16

申请人： Yueh-Wei Lin ,  Ya-Tin Hsu ,  Tsung-Hsiung Wang ,  Jing-Pin Pan ,  Meng-Chin Tsui

发明人： Yueh-Wei Lin ,  Ya-Tin Hsu ,  Tsung-Hsiung Wang ,  Jing-Pin Pan ,  Meng-Chin Tsui

IPC分类号： H01B1/00 ,  H01B1/02 ,  H01L31/00

CPC分类号： H01G9/2009 ,  H01G9/2031 ,  H01G9/2059 ,  Y02E10/542

摘要： Disclosed is a gel electrolyte for a photosensitive dye and method for manufacturing the same. First, bismaleimide and barbituric acid are dissolved in Brönsted base solution to form a gelling additive. Subsequently, the gelling additive is added into an ionic liquid electrolyte. The liquid electrolyte is then gelled at room temperature to form a gel electrolyte for the photosensitive dye utilized in dye sensitized solar cells. In addition, barbituric acid is further added into the gelling additive to enhance the gelling rate of the ionic liquid electrolyte.

摘要翻译： 公开了一种感光性染料用凝胶电解质及其制造方法。 首先，将双马来酰亚胺和巴比妥酸溶于Brönsted碱溶液中以形成胶凝添加剂。 随后，将胶凝添加剂加入到离子液体电解质中。 然后将液体电解质在室温下凝胶化以形成用于染料敏化太阳能电池中的感光染料的凝胶电解质。 此外，进一步向胶凝添加剂中加入巴比妥酸以提高离子液体电解质的胶凝速率。

公开(公告)号：US07875204B2

公开(公告)日：2011-01-25

申请号：US11889817

申请日：2007-08-16

申请人： Jing-Pin Pan ,  Chang-Rung Yang ,  Fu-Ming Wang ,  Jung-Mu Hsu ,  Yueh-Wei Lin

发明人： Jing-Pin Pan ,  Chang-Rung Yang ,  Fu-Ming Wang ,  Jung-Mu Hsu ,  Yueh-Wei Lin

IPC分类号： H01M10/0565

CPC分类号： H01M10/4235 ,  H01B1/122 ,  H01M10/0567 ,  H01M10/0568 ,  H01M2300/0082

摘要： A flame retarding polymer electrolyte composition containing maleimides includes a modified maleimide; a lithium salt; and at least one ionic solution in a ratio of at least 2 wt % relative to the total weight of the composition. By using the hyperbranched dendrimer-like structure of the modified maleimide as grafted skeleton for polymer electrolytes, the electrolyte composition can encapsulate an electrolytic solution continuously, thus preventing the exudation of the electrolytic solution and increasing the stability of lithium ionic conduction. Since the ionic solution is nonflammable, the safety of batteries are further enhanced when the polymer electrolyte composition is used as polymer electrolyte for a lithium secondary battery.

摘要翻译： 含有马来酰亚胺的阻燃聚合物电解质组合物包括改性马来酰亚胺; 锂盐; 和至少一种离子溶液，其比例相对于组合物的总重量为至少2重量％。 通过使用改性马来酰亚胺的超支化树枝状大分子结构作为聚合物电解质的接枝骨架，电解质组合物可以连续包封电解液，从而防止电解液的渗出和提高锂离子传导的稳定性。 由于离子溶液是不可燃的，当将聚合物电解质组合物用作锂二次电池的聚合物电解质时，电池的安全性进一步增强。

公开(公告)号：US08124282B2

公开(公告)日：2012-02-28

申请号：US11964772

申请日：2007-12-27

申请人： Jing-Pin Pan ,  Chang-Rung Yang ,  Tsung-Hsiung Wang ,  Yueh-Wei Lin ,  Pin-Chi Chiang ,  Jung-Mu Hsu

发明人： Jing-Pin Pan ,  Chang-Rung Yang ,  Tsung-Hsiung Wang ,  Yueh-Wei Lin ,  Pin-Chi Chiang ,  Jung-Mu Hsu

IPC分类号： H01M6/18

CPC分类号： H01M10/0567 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/4235

摘要： A nonaqueous electrolyte having maleimide additives and rechargeable cells employing the same are provided. The nonaqueous electrolyte having maleimide additives comprises an alkali metal electrolyte, a nonaqueous solvent, and maleimide additives. Specifically, the maleimide additives comprise maleimide monomer, bismaleimide monomer, bismaleimide oligomer, or mixtures thereof. The maleimide additives comprise functional groups, such as a maleimide double bond, phenyl group carboxyl, or imide, enhancing the charge-discharge efficiency, safety, thermal stability, chemical stability, flame-resistance, and lifespan of the secondary cells of the invention.

摘要翻译： 提供具有马来酰亚胺添加剂的非水电解质和使用该非水电解质的可充电电池。 具有马来酰亚胺添加剂的非水电解质包括碱金属电解质，非水溶剂和马来酰亚胺添加剂。 具体地，马来酰亚胺添加剂包括马来酰亚胺单体，双马来酰亚胺单体，双马来酰亚胺低聚物或其混合物。 马来酰亚胺添加剂包括官能团，例如马来酰亚胺双键，苯基羧基或酰亚胺，提高本发明的二次电池的充电 - 放电效率，安全性，热稳定性，化学稳定性，阻燃性和寿命。

公开(公告)号：US07560194B2

公开(公告)日：2009-07-14

申请号：US11304708

申请日：2005-12-16

申请人： Yueh-Wei Lin ,  Jing-Pin Pan ,  Mao-Sung Wu ,  Jyh-Tsung Lee ,  Jung-Mu Hsu ,  Jung-Cheng Lin

发明人： Yueh-Wei Lin ,  Jing-Pin Pan ,  Mao-Sung Wu ,  Jyh-Tsung Lee ,  Jung-Mu Hsu ,  Jung-Cheng Lin

IPC分类号： H01M10/40

CPC分类号： H01M10/0565 ,  C08J5/20 ,  C08K5/3415 ,  H01B1/122 ,  H01M10/0525 ,  H01M10/0569 ,  H01M2300/0085

摘要： The present invention is directed to a gel polymer electrolyte for use in rechargeable polymer secondary batteries and a precursor composition thereof. The precursor composition can be injected into an aluminum shell of a battery cell, which undergoes in-situ heating polymerization by heating and forms a gel polymer electrolyte penetrating a partition membrane therein. The precursor composition contains (meth)acrylic (acrylate) monomers and a modified bismaleimide oligomer resulting from a reaction of barbituric acid and bismaleimide.

摘要翻译： 本发明涉及用于可再充电聚合物二次电池的凝胶聚合物电解质及其前体组合物。 可以将前体组合物注入电池单元的铝壳中，通过加热进行原位加热聚合，形成透过其中的隔膜的凝胶聚合物电解质。 前体组合物含有（甲基）丙烯酸（丙烯酸酯）单体和由巴比妥酸和双马来酰亚胺反应得到的改性双马来酰亚胺低聚物。

公开(公告)号：US20080160418A1

公开(公告)日：2008-07-03

申请号：US11964772

申请日：2007-12-27

申请人： Jing-Pin Pan ,  Chang-Rung Yang ,  Tsung-Hsiung Wang ,  Yueh-Wei Lin ,  Pin-Chi Chiang ,  Jung-Mu Hsu

发明人： Jing-Pin Pan ,  Chang-Rung Yang ,  Tsung-Hsiung Wang ,  Yueh-Wei Lin ,  Pin-Chi Chiang ,  Jung-Mu Hsu

IPC分类号： H01M10/40

CPC分类号： H01M10/0567 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/4235

摘要： A nonaqueous electrolyte having maleimide additives and rechargeable cells employing the same are provided. The nonaqueous electrolyte having maleimide additives comprises an alkali metal electrolyte, a nonaqueous solvent, and maleimide additives. Specifically, the maleimide additives comprise maleimide monomer, bismaleimide monomer, bismaleimide oligomer, or mixtures thereof. The maleimide additives comprise functional groups, such as a maleimide double bond, phenyl group carboxyl, or imide, enhancing the charge-discharge efficiency, safety, thermal stability, chemical stability, flame-resistance, and lifespan of the secondary cells of the invention.

摘要翻译： 提供具有马来酰亚胺添加剂的非水电解质和使用该非水电解质的可充电电池。 具有马来酰亚胺添加剂的非水电解质包括碱金属电解质，非水溶剂和马来酰亚胺添加剂。 具体地，马来酰亚胺添加剂包括马来酰亚胺单体，双马来酰亚胺单体，双马来酰亚胺低聚物或其混合物。 马来酰亚胺添加剂包括官能团，例如马来酰亚胺双键，苯基羧基或酰亚胺，提高本发明的二次电池的充电 - 放电效率，安全性，热稳定性，化学稳定性，阻燃性和寿命。