公开(公告)号：US11876268B2

公开(公告)日：2024-01-16

申请号：US17358168

申请日：2021-06-25

Applicant: Palo Alto Research Center Incorporated

Inventor： Elif Karatay ,  Kathryn F. Murphy ,  Mahati Chintapalli

IPC: H01M8/10 ,  H01M8/1067 ,  H01M8/1004 ,  H01M8/1041 ,  H01M8/1039 ,  H01M8/1081

CPC classification number: H01M8/1067 ,  H01M8/1004 ,  H01M8/1039 ,  H01M8/1041 ,  H01M8/1081 ,  H01M2300/0082 ,  H01M2300/0085

Abstract: A polymer electrolyte membrane includes an ion-conducting polymeric electrolyte material and platelets, distributed through the polymeric electrolyte material. The platelets have an aspect ratio of length to thickness of at least 2:1. The platelets are aligned generally parallel to a length of the membrane. The platelets can be functionalized with free radical scavengers, or other moieties, to extend the lifetime of the membrane or of a membrane electrode assembly incorporating the membrane.

公开(公告)号：US11670790B2

公开(公告)日：2023-06-06

申请号：US16694305

申请日：2019-11-25

Applicant: Robert Bosch GmbH

Inventor： Soo Kim ,  Jonathan Mailoa ,  Timothy Schultz ,  Nathan Craig ,  Uma Krishnamoorthy ,  Jake Christensen

IPC: H01M8/10 ,  H01M8/1004 ,  H01M4/86 ,  H01M4/92 ,  H01M8/1039 ,  H01M8/1041 ,  H01M4/88

CPC classification number: H01M8/1004 ,  H01M4/8605 ,  H01M4/8652 ,  H01M4/8825 ,  H01M4/92 ,  H01M8/1039 ,  H01M8/1041 ,  H01M2008/1095

Abstract: A fuel cell membrane electrode assembly including a polymer electrolyte membrane (PEM) and first and second electrodes. The PEM is situated between the first and second electrodes. The first electrode includes a first catalyst material layer including a first catalyst material and having first and second surfaces. The first electrode includes first and second material layers adjacent to the first and second surfaces, respectively, of the first catalyst material. The first material layer faces away from the PEM and the second material layer faces the PEM. The first material layer comprises a graphene-based material layer having a number of defects configured to mitigate dissolution of the first catalyst material through the first material layer.

公开(公告)号：US20170244125A1

公开(公告)日：2017-08-24

申请号：US15521676

申请日：2015-10-08

Applicant: NISSAN MOTOR CO., LTD. ,  NIPPON STEEL & SUMIKIN CHEMICAL CO., LTD.

Inventor： Shinichi TAKAHASHI ,  Tetsuya MASHIO ,  Norifumi HORIBE ,  Atsushi OHMA

IPC: H01M8/1004 ,  H01M8/1041 ,  H01M4/92 ,  H01M4/86 ,  H01M4/88

CPC classification number: H01M8/1004 ,  H01M4/8605 ,  H01M4/8652 ,  H01M4/8825 ,  H01M4/8828 ,  H01M4/92 ,  H01M4/926 ,  H01M8/1041 ,  H01M2008/1095

Abstract: The present invention relates to an electrode catalyst for fuel cell containing a catalyst carrier having carbon as a main component and a catalytic metal carried on the catalyst carrier, wherein the electrode catalyst for fuel cell has a ratio R′ (D′/G intensity ratio) of a peak intensity of D′ band (D′ intensity) measured in the vicinity of 1620 cm−1 to a peak intensity of G band (G intensity) measured in the vicinity of 1580 cm−1 by Raman spectroscopy of more than 0.6 and 0.8 or less, and satisfies at least one of the (a) to (d). According to the present invention, an electrode catalyst for fuel cell excellent in gas transportability is provided.

公开(公告)号：US20170012319A1

公开(公告)日：2017-01-12

申请号：US15273058

申请日：2016-09-22

Applicant: Ford Global Technologies, LLC

Inventor： Venkataramani ANANDAN ,  Andrew Robert DREWS

IPC: H01M10/0562 ,  H01M2/16 ,  H01M10/0525

CPC classification number: H01M10/0562 ,  G01N27/333 ,  H01M2/1653 ,  H01M6/187 ,  H01M8/1011 ,  H01M8/1041 ,  H01M8/1065 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/056 ,  H01M12/08 ,  H01M2008/1095 ,  H01M2300/0065 ,  H01M2300/0068 ,  Y02E60/128 ,  Y02E60/50 ,  Y02E60/523

Abstract: A solid state battery includes a flexible polymer sheet, and an array of solid state pillars supported by and extending through the sheet. Each of the pillars has an anode layer, a cathode layer adjacent, and an inorganic solid electrolyte (ISE) layer interposed between the anode and cathode layers.

Abstract translation: 固态电池包括柔性聚合物片材和由片材支撑并延伸穿过片材的固态支柱阵列。 每个支柱具有阳极层，邻近的阴极层和介于阳极层和阴极层之间的无机固体电解质（ISE）层。

公开(公告)号：US20150200413A1

公开(公告)日：2015-07-16

申请号：US14664598

申请日：2015-03-20

Applicant: TORAY INDUSTRIES, INC.

Inventor： Daisuke IZUHARA ,  Hiroshi TAIKO ,  Yuriko OKADA ,  Shinya ADACHI ,  Masataka NAKAMURA

IPC: H01M8/10

CPC classification number: H01M8/1041 ,  C08G65/4056 ,  C08J5/2256 ,  C08J2371/12 ,  H01B1/122 ,  H01M8/04197 ,  H01M8/1025 ,  H01M8/1072 ,  H01M8/1088 ,  H01M2008/1095 ,  H01M2300/0082 ,  Y02E60/523 ,  Y02P20/582 ,  Y02P70/56

Abstract: The present invention relates to a method for producing a polymer electrolyte molded article, which comprises forming a polymer electrolyte precursor having a protective group and an ionic group, and deprotecting at least a portion of protective groups contained in the resulting molded article to obtain a polymer electrolyte molded article. According to the present invention, it is possible to obtain a polymer electrolyte material and a polymer electrolyte molded article, which are excellent in proton conductivity and are also excellent in fuel barrier properties, mechanical strength, physical durability, resistance to hot water, resistance to hot methanol, processability and chemical stability. A polymer electrolyte fuel cell using a polymer electrolyte membrane, polymer electrolyte parts or a membrane electrode assembly can achieve high output, high energy density and long-term durability.

公开(公告)号：US08962216B2

公开(公告)日：2015-02-24

申请号：US13387320

申请日：2010-07-21

Applicant: Takuro Hirakimoto ,  Kazuaki Fukushima ,  Kenji Kishimoto

Inventor： Takuro Hirakimoto ,  Kazuaki Fukushima ,  Kenji Kishimoto

IPC: H01M8/10 ,  H01B1/12

CPC classification number: H01M8/1041 ,  H01B1/122 ,  H01M8/1011 ,  H01M8/1023 ,  H01M8/1032 ,  H01M8/1081 ,  H01M2300/0088 ,  Y02E60/523 ,  Y02P70/56

Abstract: An ion-conducting composite electrolyte membrane with strength improved without impairing ionic conductivity, and a fuel cell using the same are provided. The proton conductive composite electrolyte membrane includes an electrolyte which includes an ion-dissociating functional group and is made of a fullerene derivative or sulfonated pitch within a range of 5 wt % to 85 wt % both inclusive, and a binder which has a weight-average molecular weight of 550000 or over and a logarithmic viscosity of 2 dL/g or over, and is made of a fluorine-based polymer such as polyvinylidene fluoride and a copolymer of polyvinylidene fluoride and hexafluoropropylene within a range of 15 wt % to 95 wt % both inclusive.

Abstract translation: 提供了强度提高而不损害离子导电性的离子导电复合电解质膜，以及使用其的燃料电池。 质子传导复合电解质膜包括电解质，其包含离子解离官能团，并且由富勒烯衍生物或磺化沥青构成，其含量在5重量％至85重量％的范围内，并且具有重均分子量 分子量为550000以上，对数粘度为2dL / g以上，由聚偏氟乙烯等氟系聚合物和聚偏二氟乙烯与六氟丙烯的共聚物构成，为15重量％〜95重量％ 包括在内

公开(公告)号：US20140242477A1

公开(公告)日：2014-08-28

申请号：US14240784

申请日：2012-09-03

Applicant: Shinya Kikuzumi ,  Masahiro Mori

Inventor： Shinya Kikuzumi ,  Masahiro Mori

IPC: H01M8/10

CPC classification number: H01M8/1041 ,  D04H1/4318 ,  D04H1/728 ,  H01B1/122 ,  H01M2/1606 ,  H01M2/162 ,  H01M2/1666 ,  H01M2/1686 ,  H01M8/0289 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1067 ,  H01M8/1081 ,  H01M2008/1095 ,  H01M2300/0088 ,  Y02E60/521 ,  Y02P70/56

Abstract: An object of the present invention is to provide an electrolyte membrane that suppresses swelling and shrinkage caused by water retained in the electrolyte membrane for a solid polymer-type fuel cell, improves the durability of the electrolyte membrane, and obtains excellent power generation characteristics with a low resistance. The electrolyte membrane for a solid polymer-type fuel cell includes, as a reinforcing membrane, a nonwoven fabric composed of an electrolyte material and PVDF bicomponent fibers 2a, thereby improving the durability of the electrolyte membrane. Furthermore, the bicomponent fiber 2a has pores 23 that can effectively retain generated water, thereby improving battery performance under the condition of a low humidity.

Abstract translation: 本发明的目的在于提供一种电解质膜，其抑制固体聚合物型燃料电池的电解质膜中保留的水引起的溶胀和收缩，提高电解质膜的耐久性，并且可以获得优异的发电特性 低电阻。 作为固体高分子型燃料电池用电解质膜，由电解质材料和PVDF双组分纤维2a构成的无纺布作为增强膜，由此提高了电解质膜的耐久性。 此外，双组分纤维2a具有可以有效地保持生成的水的孔23，从而在低湿度的条件下提高电池性能。

公开(公告)号：US08501368B2

公开(公告)日：2013-08-06

申请号：US12567048

申请日：2009-09-25

Applicant: Jing-Pin Pan ,  Yueh-Wei Lin ,  Chung-Liang Chang ,  Li-Duan Tsai ,  Ya-Tin Hsu

Inventor： Jing-Pin Pan ,  Yueh-Wei Lin ,  Chung-Liang Chang ,  Li-Duan Tsai ,  Ya-Tin Hsu

IPC: H01M8/10

CPC classification number: H01M8/1039 ,  C08J5/2275 ,  C08J2300/202 ,  C08J2300/208 ,  C08L27/18 ,  C08L2205/04 ,  H01M8/1023 ,  H01M8/1041 ,  H01M8/1081 ,  Y02P70/56 ,  C08L79/085

Abstract: The disclosed forms a proton exchange membrane. First, multi-maleimide and barbituric acid are copolymerized to form a hyper-branched polymer. Next, the solvent of the sulfonated tetrafluoroethylene copolymer (Nafion) aqueous solution is replaced from water with dimethyl acetamide (DMAc). 10 to 20 parts by weight of the hyper-branched polymer is added to the 90 to 80 parts by weight of the Nafion in a DMAc solution, stood and heated to 50° C. to inter-penetrate the hyper-branched polymer and the Nafion. The heated solution is coated on a substrate, baked, and pre-treated to remove residue solvent for completing an inter-penetrated proton exchange membrane.

Abstract translation: 所公开的形成质子交换膜。 首先，将多马来酰亚胺和巴比妥酸共聚以形成超支化聚合物。 接着，用水与二甲基乙酰胺（DMAc）代替磺化四氟乙烯共聚物（Nafion）水溶液的溶剂。 将10〜20重量份的超支化聚合物加入到在DMAc溶液中的90至80重量份的Nafion中，并加热至50℃以相互渗透超支化聚合物和Nafion 。 将加热的溶液涂布在基材上，烘烤并预处理以除去残留溶剂以完成相互穿透的质子交换膜。

公开(公告)号：US20130157168A1

公开(公告)日：2013-06-20

申请号：US13720944

申请日：2012-12-19

Applicant: Samsung Electronics Co., Ltd.

Inventor： Pil-won HEO ,  Ki-hyun KIM ,  Seong-woo CHOI

IPC: H01M4/90 ,  H01M8/10

CPC classification number: H01M4/9008 ,  H01M8/10 ,  H01M8/103 ,  H01M8/1041 ,  H01M8/1044 ,  H01M8/1048

Abstract: A composition including a compound represented by Formula 1, an azole-based polymer, and at least one of compounds represented by Formula 2-7 according to the specification, a composite obtained from the composition, an electrode and electrolyte for a fuel cell that include the composition or the composite, and a fuel cell including the electrode or the electrolyte membrane: M11-aM2aPxOy  Formula 1 wherein, in Formula 1, M1 is a tetravalent element; M2 is at least one selected from the group including a monovalent element, a divalent element, and a trivalent element; 0≦a

Abstract translation: 一种组合物，其包含由式1表示的化合物，唑类聚合物和至少一种根据说明书的式2-7表示的化合物，由组合物获得的复合物，用于燃料电池的电极和电解质，其包括 该组合物或复合材料以及包含电极或电解质膜的燃料电池：M11-aM2aPxOyFormula 1其中，在式1中，M1是四价元素; M2是选自包括一价元素，二价元素和三价元素的基团中的至少一种; 0 @ a <1; x是从1.5到3.5的数字; y是从5到13的数字。

公开(公告)号：US20130122395A1

公开(公告)日：2013-05-16

申请号：US13675633

申请日：2012-11-13

Applicant: Samsung Electronics Co., Ltd.

Inventor： Ki-hyun KIM ,  Pil-won HEO ,  Chan-ho PAK ,  Seong-woo CHOI

IPC: H01M4/90 ,  H01M8/10

CPC classification number: H01M4/9008 ,  C08K5/13 ,  H01M4/8663 ,  H01M4/881 ,  H01M4/8817 ,  H01M8/1018 ,  H01M8/102 ,  H01M8/1041 ,  H01M2008/1095 ,  Y02P70/56

Abstract: A composition including a cross-linkable compound and at least one selected from compounds represented by Formula 1, a composite obtained from the composition, an electrode including the composition or the composite, a composite membrane including the composite, and a fuel cell including the composite membrane, wherein, in Formula 1, a and R are as defined in the specification.

Abstract translation: 一种组合物，其包含可交联化合物和选自由式1表示的化合物中的至少一种，由组合物获得的复合物，包含该组合物或复合物的电极，包含该复合材料的复合膜，以及包含该复合材料的燃料电池 膜，其中在式1中，a和R如说明书中所定义。