摘要:
A silver halide emulsion which exhibits high sensitivity, high contrast, little sensitivity variation with humidity conditions at the time of exposure, and excellent reciprocity law properties at high illumination intensities. Also, a method of preparing the emulsion in a stable manner, and a silver halide color photographic photosensitive material and an image forming method that use the emulsion. The emulsion includes a mesoionic compound having a thiolate structure or a protonated thiolate structure, and the emulsion is sensitized by an Au (III) compound. The emulsion preferably contains an oxidatively dimerized form of a mesoionic compound having a thiolate structure, and a silver chloride content of at least 90 mol %.
摘要:
A silver halide emulsion which exhibits high sensitivity, high contrast, little sensitivity variation with humidity conditions at the time of exposure, and excellent reciprocity law properties at high illumination intensities. Also, a method of preparing the emulsion in a stable manner, and a silver halide color photographic photosensitive material and an image forming method that use the emulsion. The emulsion includes a mesoionic compound having a thiolate structure or a protonated thiolate structure, and the emulsion is sensitized by an Au (III) compound. The emulsion preferably contains an oxidatively dimerized form of a mesoionic compound having a thiolate structure, and a silver chloride content of at least 90 mol %.
摘要:
A silver halide emulsion chemically sensitized by at least one compound having a bond of anionic chalcogenide to gold(I) cation and capable of releasing a gold-chalcogen anion species and a method for chemically sensitizing a silver halide emulsion, comprising adding at least one compound having a bond of anionic chalcogenide to gold(I) cation and capable of releasing a gold-chalcogen anion species are disclosed.
摘要:
A process for producing a lightsensitive silver halide emulsion comprising silver halide grains, wherein the emulsion contains tabular silver halide grains in an amount of at least 50% of the total projected area of all the silver halide grains, the average iodine content of all the silver halide grains is at least 2 mol %, and the tabular silver halide grains have at least 10 dislocation lines per grain, wherein the process comprises (step 1) set fourth below, and the process comprises a step of performing chemical sensitization so that a selenium sensitizer is added in an amount of 2.5×10−6 to 5×10−5 mol/mol silver and comprises a step of performing spectral sensitization (step 1) performing the spectral sensitization in which a spectral sensitizer is added in the presence of 50 ppm or less of calcium, magnesium and strontium, followed by adding at least one water-soluble salt of a metal selected from the group consisting of calcium, magnesium and strontium, so that the concentration of calcium, magnesium and strontium becomes 100-2500 ppm, and then the chemical sensitization is started.
摘要:
A silver halide photographic material comprises a silver halide emulsion layer provided on a support. In the photographic material of the present invention, the silver halide emulsion layer contains a tellurium compound represented by the formula (I) or (II): ##STR1## in which each of R.sup.11 and R.sup.12 is --OR.sup.13, --NR.sup.14 R.sup.15, --SR.sup.16 or hydrogen; R.sup.11 and R.sup.12 may be combined with each other to form a heterocyclic ring; each of R.sup.21 and R.sup.22 is an alkyl, alkenyl, alkynyl, aralkyl, aryl or heterocyclic group, --OR.sup.23, --NR.sup.24 R.sup.25, --SR.sup.26 or hydrogen; R.sup.21 and R.sup.22 may be combined with each other to form a heterocyclic ring; each of X.sup.1 and X.sup.2 is oxygen, sulfur or .dbd.NR.sup.17 ; each of X.sup.3 and X.sup.4 is oxygen, sulfur or .dbd.NR.sup.27 ; each of R.sup.13, R.sup.14, R.sup.15, R.sup.16, R.sup.17, R.sup.23, R.sup.24, R.sup.25, R.sup.26 and R.sup.27 is an alkyl, alkenyl, alkynyl, aralkyl, aryl or heterocyclic group or hydrogen; R.sup.14 and R.sup.15 may be combined with each other to form a heterocyclic ring; and R.sup. 24 and R.sup.25 may be combined with each other to form a heterocyclic ring.
摘要翻译:卤化银照相材料包括设置在载体上的卤化银乳剂层。 在本发明的照相材料中,卤化银乳剂层含有由式(I)或(II)表示的碲化合物:其中R11和R12各自为-OR13,-NR14R15,-SR16或 氢; R 11和R 12可以相互结合形成杂环; R 21和R 22各自为烷基,烯基,炔基,芳烷基,芳基或杂环基,-OR 23,-NR 24 R 25,-SR 26或氢; R 21和R 22可以相互结合形成杂环; X1和X2各自为氧,硫或= NR17; X3和X4各自为氧,硫或= NR27; R 13,R 14,R 15,R 16,R 17,R 23,R 24,R 25,R 26和R 27中的每一个是烷基,烯基,炔基,芳烷基,芳基或杂环基或氢; R 14和R 15可以相互结合形成杂环; 并且R 24和R 25可以彼此结合形成杂环。
摘要:
A method for processing a silver halide photographic material which comprises processing an imagewise exposed silver halide photographic material with a processing solution having a fixing ability containing (1) a thiosulfate As disclosed, wherein said processing solution having a fixing ability further contains at least one of (2) at least one compound selected from the group consisting of a bisulfite and a sulfite, and a compound represented by formula (A'): ##STR1## wherein R'.sub.1, R'.sub.2, R'.sub.3, R'.sub.4 and R'.sub.5 each represents a hydrogen atom or a substituent other than a hydroxyl group or a group containing a hydroxyl group, provided that at least one of R'.sub.1 to R'.sub.5 is at least one of a sulfo group and a group constaining a sulfo group and (3) at least one bisulfite addition product of a compound represented by formula (A'). In the method, a fixing solution having a pH of from 5.0 to 9.0 or a bleach-fixing solution with improved stability over time during continuous processing and exhibiting excellent desilvering performance is used. The method provides an image showing a reduced increase in stain with time and realizes improvements of the working environment.
摘要:
An electromagnetic shielding film for plasma display which is excellent in electromagnetic shielding characteristics for effectively shielding electromagnetic waves, near infrared rays, stray light, external light, and the like and even when stored under a wet heat condition, is small in change of color tint and good in adhesion, with a blackening layer hardly peeled away, is provided by a transparent electromagnetic shielding film including a transparent support having thereon a conductive metal layer in a pattern-like state having an electromagnetic shielding ability and having a surface covered by a blackening layer, with the blackening layer made of an alloy of nickel and zinc in a nickel/zinc mass ratio of from 0.5 to 50.
摘要:
A light-transmitting electromagnetic wave shielding film which is a conductive silver thin film with a metallic silver portion formed on a support in a meshy state, wherein the metallic silver portion formed in the meshy state has a line width of 18 μm or less, an opening rate of 85% or more, an Ag content of 80 to 100% by mass and a surface resistance value of 5 Ω/sq or less. This light-transmitting electromagnetic wave shielding film has characteristic features that it has a high electromagnetic wave shielding property and a high transparency at the same time and the meshy portion is black.
摘要:
To provide a light transmitting electromagnetic wave shielding film which achieves both of excellent electromagnetic wave shielding properties and an excellent near infrared ray cutting function.A light transmitting electromagnetic wave shielding film has a metallic silver part and a light transmitting part, which are formed by exposing an emulsion layer containing a silver salt emulsion formed on a support and then developing, wherein the light transmitting electromagnetic wave shielding film has infrared ray shielding properties.
摘要:
An electromagnetic shielding film for plasma display which is excellent in electromagnetic shielding characteristics for effectively shielding electromagnetic waves, near infrared rays, stray light, external light, and the like and even when stored under a wet heat condition, is small in change of color tint and good in adhesion, with a blackening layer hardly peeled away, is provided by a transparent electromagnetic shielding film including a transparent support having thereon a conductive metal layer in a pattern-like state having an electromagnetic shielding ability and having a surface covered by a blackening layer, with the blackening layer made of an alloy of nickel and zinc in a nickel/zinc mass ratio of from 0.5 to 50.