公开(公告)号：US5580489A

公开(公告)日：1996-12-03

申请号：US377134

申请日：1995-01-23

申请人： Kenji Shinjo ,  Takao Takiguchi ,  Hiroyuki Kitayama ,  Kazuharu Katagiri ,  Masataka Yamashita ,  Takeshi Togano ,  Masahiro Terada ,  Junko Sato

发明人： Kenji Shinjo ,  Takao Takiguchi ,  Hiroyuki Kitayama ,  Kazuharu Katagiri ,  Masataka Yamashita ,  Takeshi Togano ,  Masahiro Terada ,  Junko Sato

IPC分类号： C07D271/10 ,  C07D285/12 ,  C09K19/34 ,  C09K19/42 ,  C09K19/46 ,  C07D239/02

CPC分类号： C07D271/10 ,  C07D285/12 ,  C09K19/345 ,  C09K19/3455 ,  C09K19/3463 ,  C09K19/348 ,  C09K19/3497 ,  C09K19/42 ,  C09K19/46

摘要： A ferroelectric chiral smectic liquid crystal composition, comprising at least one compound represented by the following formula (I): ##STR1## wherein R.sub.1 denotes a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent, R.sub.2 denotes a linear or branched alkyl group having 1-14 carbon atoms capable of having a substituent; X.sub.1 and X.sub.2 respectively denote a single bond, ##STR2## m is 0-7; and n is 0 or 1; and at least one compound represented by the following formula (II): ##STR3## wherein R.sub.3 denotes a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent; R.sub.4 denotes a linear alkyl group having 1-10 carbon atoms; X.sub.3 denotes a single bond, ##STR4## Y denotes ##STR5## and ##STR6## respectively denote ##STR7##

摘要翻译： 一种铁电手性近晶液晶组合物，其包含至少一种由下式（I）表示的化合物：其中R 1表示具有1-18个能够具有取代基的碳原子的直链或支链烷基，R2 表示具有能够具有取代基的具有1-14个碳原子的直链或支链烷基; X1和X2分别表示单键， m为0-7; 并且n为0或1; 和由下式（II）表示的至少一种化合物：其中R 3表示可具有取代基的具有1-18个碳原子的直链或支链烷基; R4表示具有1-10个碳原子的直链烷基; X3表示单键， Y表示

公开(公告)号：US5305131A

公开(公告)日：1994-04-19

申请号：US979812

申请日：1992-11-20

申请人： Masahiro Terada ,  Masataka Yamashita ,  Kazuharu Katagiri ,  Akio Yoshida ,  Shosei Mori ,  Syuji Yamada

发明人： Masahiro Terada ,  Masataka Yamashita ,  Kazuharu Katagiri ,  Akio Yoshida ,  Shosei Mori ,  Syuji Yamada

IPC分类号： C09K19/02 ,  C09K19/42 ,  C09K19/46 ,  G02F1/141 ,  G02F1/133

CPC分类号： G02F1/1416 ,  C09K19/0225 ,  C09K19/42 ,  C09K19/46

摘要： A liquid crystal device with a decreased temperature-dependence of response speed is obtained by using a liquid crystal composition having a temperature range where the composition assumes chiral smectic C phase. The temperature range of chiral smectic C phase includes a) a first temperature range where the liquid crystal composition shows a cone angle in chiral smectic C phase which increases on temperature decrease down to a mediate temperature, and b) a second temperature range, below the first temperature range, where the liquid crystal composition shows a cone angle in chiral smectic C phase which decreases on further temperature decrease below the mediate temperature.

摘要翻译： 通过使用具有组成为手性近晶C相的温度范围的液晶组合物，获得响应速度的温度依赖性降低的液晶装置。 手性近晶C相的温度范围包括a）第一温度范围，其中液晶组合物在手性近晶C相中显示锥角，其温度降低至中间温度时升高，以及b）第二温度范围，低于 第一温度范围，其中液晶组合物在手性近晶C相中显示锥角，其在进一步的温度降低到低于介质温度时降低。

公开(公告)号：US5250219A

公开(公告)日：1993-10-05

申请号：US863325

申请日：1992-04-02

申请人： Shosei Mori ,  Takao Takiguchi ,  Takashi Iwaki ,  Yoko Yamada ,  Takeshi Togano ,  Masataka Yamashita ,  Masahiro Terada ,  Kazuharu Katagiri

发明人： Shosei Mori ,  Takao Takiguchi ,  Takashi Iwaki ,  Yoko Yamada ,  Takeshi Togano ,  Masataka Yamashita ,  Masahiro Terada ,  Kazuharu Katagiri

IPC分类号： C07D239/26 ,  C07D239/28 ,  C07D239/34 ,  C09K19/34 ,  C09K19/46 ,  C09K19/30 ,  C09K19/52 ,  G02F1/13

CPC分类号： C07D239/26 ,  C07D239/28 ,  C07D239/34 ,  C09K19/3458 ,  C09K19/3463 ,  C09K19/46

摘要： A mesomorphic compound represented by the following formula (I): ##STR1## wherein R.sub.1 and R.sub.2 respectively denote a linear or branched alkyl group having 1-16 carbon atoms capable of having a substituent; Y.sub.1 denotes --COO--, --OCO--, --CH.sub.2 --or --OCH.sub.2 --; Z.sub.1 denotes a single bond, --O--, --COO--, --OCO-- or --OCOO--; and X denotes a halogen, cyano group or methyl group.

摘要翻译： 由下式（I）表示的介晶化合物：其中R 1和R 2分别表示可具有取代基的具有1-16个碳原子的直链或支链烷基; Y1表示-COO-，-OCO-，-CH2-或-OCH2-; Z 1表示单键，-O - ， - COO - ， - OCO-或-OCOO-; X表示卤素，氰基或甲基。

公开(公告)号：US5238601A

公开(公告)日：1993-08-24

申请号：US370909

申请日：1989-06-23

申请人： Kenji Shinjo ,  Takao Takiguchi ,  Hiroyuki Kitayama ,  Kazuharu Katagiri ,  Masahiro Terada ,  Takeshi Togano ,  Masataka Yamashita

发明人： Kenji Shinjo ,  Takao Takiguchi ,  Hiroyuki Kitayama ,  Kazuharu Katagiri ,  Masahiro Terada ,  Takeshi Togano ,  Masataka Yamashita

IPC分类号： C07D271/10 ,  C07D285/12 ,  C09K19/30 ,  C09K19/34 ,  C09K19/42

CPC分类号： C07D271/10 ,  C07D285/12 ,  C09K19/3068 ,  C09K19/345 ,  C09K19/3455 ,  C09K19/3463 ,  C09K19/348 ,  C09K19/3497 ,  C09K19/42

摘要： A ferroelectric chiral smectic liquid crystal composition, comprising at least one optically active compound represented by the following formula (I): ##STR1## wherein R.sub.1 denotes a linear alkyl group having 1-14 carbon atoms; R.sub.2 denotes a linear or branched alkyl group having 1-14 carbon atoms capable of having a subtituent; and X.sub.1 denotes a single bond, ##STR2## and at least one compound represented by the following formula (II): ##STR3## wherein R.sub.3 denotes a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent; R.sub.4 denotes a linear alkyl group having 1-10 carbon atoms; X.sub.2 denotes a single bond, ##STR4##

摘要翻译： 一种铁电手性近晶液晶组合物，其包含至少一种由下式（I）表示的光学活性化合物：其中R 1表示具有1-14个碳原子的直链烷基; R2表示能够具有取代基的具有1-14个碳原子的直链或支链烷基; X1表示单键，和下述式（II）表示的至少一种化合物：其中，R 3表示可具有取代基的具有1-18个碳原子的直链或支链烷基， ; R4表示具有1-10个碳原子的直链烷基; X2表示单键，

公开(公告)号：US5119219A

公开(公告)日：1992-06-02

申请号：US543415

申请日：1990-06-26

申请人： Masahiro Terada ,  Masataka Yamashita ,  Shosei Mori ,  Shinichi Nakamura ,  Kenji Shinjo ,  Kazuharu Katagiri

发明人： Masahiro Terada ,  Masataka Yamashita ,  Shosei Mori ,  Shinichi Nakamura ,  Kenji Shinjo ,  Kazuharu Katagiri

IPC分类号： G02F1/13 ,  C09K19/02 ,  G02F1/133 ,  G09G3/18 ,  G09G3/36

CPC分类号： C09K19/02 ,  G09G3/3629 ,  G09G2310/06 ,  G09G2320/041

摘要： A liquid crystal apparatus includes a chiral smectic liquid crystal showing a first and a second orientation state disposed between first and second electrodes of a liquid cell. A drive circuit applies voltages between the first and second electrodes including voltages .vertline.V.sub.S .vertline. and .vertline.V.sub.I .vertline. which provide voltages V.sub.A and V.sub.B (V.sub.B V.sub.A) satisfying the relationship of: .vertline.(V.sub.A -V.sub.B)/(V.sub.A +V.sub.B).vertline.>0.1 at 40.degree. C. V.sub.A is a minimum peak value of a voltage .vertline.V.sub.S .vertline.+.vertline.V.sub.I .vertline. (at a constant pulse width) capable of inverting the first orientation state of the chiral smectic liquid crystal into the second orientation state when a voltage pulse is applied between the first and second electrodes to cause the first orientation state of the chiral smectic liquid crystal and then the voltage .vertline.V.sub.S .vertline.+.vertline.V.sub.I .vertline. is applied between the first and second electrodes as a combination of a voltage .vertline.V.sub.S .vertline. applied to the first electrode and a voltage - V.sub.I .vertline. applied to the second electrode V.sub.B is a value of .vertline.V.sub.S .vertline.+.vertline.V.sub.I .vertline. calculated based on a maximum peak value of a voltage .vertline.V.sub.S .vertline.-.vertline.V.sub.I .vertline. capable of maintaining the first orientation state of the chiral smectic liquid crystal when a voltage pulse is applied between the first and second electrodes to cause the first orientation state and then the voltage .vertline.V.sub.S .vertline.-.vertline.V.sub.I .vertline. is applied between the first and second electrodes as a combination of a voltage .vertline.V.sub.S .vertline. applied to the first electrode and a voltage .vertline.V.sub.I .vertline. applied to the second electrode.

公开(公告)号：US5599479A

公开(公告)日：1997-02-04

申请号：US370987

申请日：1989-06-23

申请人： Kenji Shinjo ,  Takao Takiguchi ,  Hiroyuki Kitayama ,  Kazuharu Katagiri ,  Masataka Yamashita ,  Takeshi Togano ,  Masahiro Terada ,  Akio Yoshida ,  Yoshiko Kimura

发明人： Kenji Shinjo ,  Takao Takiguchi ,  Hiroyuki Kitayama ,  Kazuharu Katagiri ,  Masataka Yamashita ,  Takeshi Togano ,  Masahiro Terada ,  Akio Yoshida ,  Yoshiko Kimura

IPC分类号： C07D271/10 ,  C07D285/12 ,  C09K19/34 ,  C09K19/42 ,  C09K19/46 ,  C09K19/12 ,  C09K19/30 ,  G02F1/13

CPC分类号： C07D271/10 ,  C07D285/12 ,  C09K19/345 ,  C09K19/3455 ,  C09K19/3463 ,  C09K19/348 ,  C09K19/3497 ,  C09K19/42 ,  C09K19/46

摘要： A ferroelectric chiral smectic liquid crystal composition, comprising at least one optically active compound represented by the following formula (I): ##STR1## wherein R.sub.1 denotes a linear or branched alkyl group having 1-18 carbon atoms capable of having a subtituent; X.sub.1 denotes a single bond, ##STR2## Z denotes a single bond or ##STR3## denotes ##STR4## and n is an integer of 1-12; and at least one compound represented by the following formula (II): ##STR5## wherein R.sub.2 and R.sub.3 respectively denote a linear or branched optically inactive alkyl group having 1-18 carbon atoms capable of having an alkoxy group of 1-12 carbon atoms; X.sub.2 and X.sub.3 respectively denote a single bond, ##STR6## and p and q are respectively 0, 1 or 2 with proviso that both of p and q are not 0.

摘要翻译： 包含至少一种由下式（I）表示的光学活性化合物的铁电手性近晶液晶组合物：能够具有取代基的具有1-18个碳原子的残留的烷基; X1表示单键， Z表示单键，或表示，n表示1-12的整数。 和由下式（II）表示的至少一种化合物：其中R 2和R 3分别表示可具有1-12个烷氧基的具有1-18个碳原子的直链或支链的光学惰性烷基 碳原子 X2和X3分别表示单键，和p和q分别为0,1或2，条件是p和q均不为0。

公开(公告)号：US5269964A

公开(公告)日：1993-12-14

申请号：US710773

申请日：1991-06-05

申请人： Masataka Yamashita ,  Masahiro Terada ,  Shosei Mori ,  Kazuharu Katagiri

发明人： Masataka Yamashita ,  Masahiro Terada ,  Shosei Mori ,  Kazuharu Katagiri

IPC分类号： G02F1/13 ,  C07C43/225 ,  C07C69/75 ,  C07C69/753 ,  C07C69/773 ,  C07C69/92 ,  C07C69/94 ,  C07D239/26 ,  C07D239/28 ,  C07D239/34 ,  C07D277/20 ,  C07D277/24 ,  C07D277/30 ,  C07D417/00 ,  C09K19/34 ,  C09K19/42 ,  C09K19/46 ,  C09K19/52

CPC分类号： C09K19/46 ,  C09K19/34 ,  C09K19/42

摘要： A liquid crystal composition comprising at least one mesomorphic compound represented by the following formula (I): ##STR1## wherein R.sub.1 and R.sub.2 respectively denote a linear or branched alkyl group having 1-16 carbon atoms optionally substituted; Z.sub.1 denotes a single bond, --O--, --COO-- or --OCO--; X.sub.1 denotes halogen; and A.sub.1 denotes a single bond or ##STR2## and at least one mesomorphic compound represented by the following formula (II): ##STR3## wherein R.sub.3 and R.sub.4 respectively denote an alkyl group having 2-16 carbon atoms optionally substituted; Y.sub.1 denotes a single bond, ##STR4## Z.sub.2 and Z.sub.3 respectively denote a single bond, --O--, ##STR5## A.sub.2 and A.sub.3 respectively denote a single bond, ##STR6## X.sub.2 and X.sub.3 respectively denote hydrogen, F, Cl, Br, --CH.sub.3, --CN or --CF.sub.3 ; and k is 0 or 1 with the proviso that Z.sub.2 is a single bond when A.sub.2 is a single bond, and Z.sub.3 is a single bond when A.sub.3 is a single bond and k is 0. The liquid crystal composition is easily aligned by a simple rubbing method to provide a uniform monodomain and further provides wider driving voltage and temperature margins effective for providing a practical ferroelectric liquid crystal device.

公开(公告)号：US5268123A

公开(公告)日：1993-12-07

申请号：US834389

申请日：1992-02-12

申请人： Shosei Mori ,  Masataka Yamashita ,  Kazuharu Katagiri ,  Kenji Shinjo ,  Masahiro Terada

发明人： Shosei Mori ,  Masataka Yamashita ,  Kazuharu Katagiri ,  Kenji Shinjo ,  Masahiro Terada

IPC分类号： C09K19/34 ,  C09K19/42 ,  C09K19/44 ,  C09K19/46 ,  G02F1/13 ,  C09K19/32

CPC分类号： C09K19/46 ,  C09K19/348 ,  C09K19/3491 ,  C09K19/3497 ,  C09K19/42 ,  C09K19/44

摘要： A liquid crystal composition, comprising: at least one mesomorphic compound represented by the following formula (I): ##STR1## and at least one mesomorphic compound represented by the following formula (II):R.sup.3 --X.sup.3 --A.sup.2 --B--A.sup.3 --X.sup.4 --R.sup.4(II),The liquid crystal composition is easily aligned by a simple rubbing method to provide a uniform monodomain and further provides wider driving voltage and temperature margins effective for providing a practical ferroelectric liquid crystal device.

公开(公告)号：US5143643A

公开(公告)日：1992-09-01

申请号：US373640

申请日：1989-07-03

申请人： Takashi Iwaki ,  Kenji Shinjo ,  Akio Yoshida ,  Masataka Yamashita ,  Kazuharu Katagiri ,  Chieko Hioki ,  Takeshi Togano ,  Yoko Yamada ,  Masahiro Terada

发明人： Takashi Iwaki ,  Kenji Shinjo ,  Akio Yoshida ,  Masataka Yamashita ,  Kazuharu Katagiri ,  Chieko Hioki ,  Takeshi Togano ,  Yoko Yamada ,  Masahiro Terada

IPC分类号： C07C43/13 ,  C07C43/205 ,  C07C43/23 ,  C07D239/26 ,  C09K19/20 ,  C09K19/30 ,  C09K19/34

CPC分类号： C07D239/26 ,  C07C43/13 ,  C07C43/2055 ,  C07C43/23 ,  C09K19/2021 ,  C09K19/3068 ,  C09K19/3463

摘要： An optically active mesomorphic compound represented by the formula (III) is obtained through an optically active compound represented by the formula (I) and then through a compound represented by the formula (II), respectively, shown below. ##STR1## In the above formulas, R represents a linear, branched or cyclic saturated or unsaturated hydrocarbon group having 1-18 carbon atoms each capable of having a substituent, C* represents an asymmetric carbon atom, k is an integer of from 2 to 5, A is a releasable active group such as hydroxyl, l is 0 or 1, and when l is 1, m is 0, 1 or 2 and n is 0 or 1; R.sup.1 represents an alkyl or alkoxy group having 1-18 carbon atoms; ##STR2## respectively denote ##STR3## p, q and r are respectively 0 or 1 satisfying the relation of p+q+r.gtoreq.1.

摘要翻译： 通过式（I）表示的光学活性化合物，然后分别通过如下所示的式（II）表示的化合物获得由式（III）表示的光学活性介晶化合物。 （I）（II）（III）在上式中，R表示具有1-18个碳原子的直链，支链或环状的饱和或不饱和烃基，其能够具有 取代基，C *表示不对称碳原子，k为2〜5的整数，A为可释放的活性基团，例如羟基，l为0或1，当l为1时，m为0,1或2， n为0或1; R1表示具有1-18个碳原子的烷基或烷氧基; 分别表示 p，q和r分别为0或1，满足p + q + r> / = 1的关系。

公开(公告)号：US5709819A

公开(公告)日：1998-01-20

申请号：US592576

申请日：1996-01-26

申请人： Masataka Yamashita ,  Kazuharu Katagiri ,  Masahiro Terada ,  Shosei Mori ,  Syuji Yamada ,  Koji Noguchi

发明人： Masataka Yamashita ,  Kazuharu Katagiri ,  Masahiro Terada ,  Shosei Mori ,  Syuji Yamada ,  Koji Noguchi

IPC分类号： G02F1/13 ,  C09K19/02 ,  C09K19/34 ,  C09K19/42 ,  C09K19/44 ,  C09K19/46 ,  C09K19/30 ,  C09K19/32

CPC分类号： C09K19/46 ,  C09K19/34

摘要： A liquid crystal composition contains a mesomorphic compound represented by the following formula (A): ##STR1## wherein R.sub.1 denotes a linear or branched alkyl group having 1-18 carbon atoms; X.sub.1 denotes a single bond, --O--, --CO--O-- or --O--CO--; X.sub.2 denotes a single bond, --OCH.sub.2 --, --CO--O-- or --O--CO--; n is an integer of 3-16; and A.sub.1 denotes ##STR2## and a mesomorphic compound represented by the following formula (B): ##STR3## wherein R.sub.2 denotes a linear or branched alkyl group having 1-18 carbon atoms; X.sub.3 and X.sub.4 independently denote a single bond, --O--, --CO--O-- or --O--CO--; m is an integer of 3-16; and A.sub.2 denotes ##STR4## The liquid crystal composition may preferably be formulated as a chiral smectic liquid crystal composition. The liquid crystal composition is useful in providing a liquid crystal device using the liquid crystal composition with a good alignment characteristic, a good drive characteristic, and a high contrast ratio.

摘要翻译： 液晶组合物含有由下式（A）表示的介晶化合物：其中R 1表示具有1-18个碳原子的直链或支链烷基; X1表示单键，-O - ， - CO-O-或-O-CO-; X2表示单键，-OCH2-，-CO-O-或-O-CO-; n为3-16的整数; 和A1表示下式（B）表示的介晶化合物：其中R 2表示具有1-18个碳原子的直链或支链烷基; X3和X4独立地表示单键，-O - ， - CO-O-或-O-CO-; m为3-16的整数; 并且A2表示作为手性近晶液晶组合物配制的 e。 液晶组合物可用于提供使用具有良好的取向特性，良好的驱动特性和高对比度的液晶组合物的液晶装置。