摘要:
A novel bis-phosphate compound is provided which can be applied to a wide range of reactive substrates and reactions as an asymmetric reaction catalyst and can realize an asymmetric reaction affording a high yield and a high enantiomeric excess. The bis-phosphate compound has a tetraaryl skeleton represented by General Formula (1). In an asymmetric reaction, an amidodiene and an unsaturated aldehyde compound are reacted with each other in the presence of the optically active bis-phosphate compound to give an optically active amidoaldehyde. The invention allows a reaction such as an asymmetric Diels-Alder reaction to proceed efficiently, which has been difficult with conventional mono-phosphate compounds. Thus, the invention enables an industrially feasible method for the production of optically active amidoaldehydes, optically active β-amino acid derivatives, optically active diamine compounds, optically active pyrrolidine derivatives and optically active dihydropyran derivatives which are useful as products such as medicines, agricultural chemicals and chemical products as well as synthesis intermediates for such products.
摘要:
A guanidine compound having a biaryl skeleton represented by the following formula (1), which is useful as a catalyst for various asymmetric reactions. (wherein R1, R2 and R3 each independently represent a hydrogen atom, a hydrocarbon group optionally having substituent(s), or a heterocyclic group optionally having substituent(s); R4 to R15 each independently represent a hydrogen atom, a hydrocarbon group optionally having substituent(s), a heterocyclic group optionally having substituent(s), a hydroxy group, an alkoxy group optionally having substituent(s), an aryloxy group optionally having substituent(s), an acyl group, an alkoxycarbonyl group optionally having substituent(s), an aryloxycarbonyl group optionally having substituent(s), a carbamoyl group optionally having substituent(s), an alkylthiocarbonyl group optionally having substituent(s), an arylthiocarbonyl group optionally having substituent(s), a carboxyl group, an alkylthio group optionally having substituent(s), an arylthio group optionally having substituent(s), an amino group or a substituted amino group, or a substituted silyl group; or in any combination of R1 to R15, these substituents may be taken together to form a ring; and X1 to X8 represent a hydrogen atom or a nitrogen atom, provided that, in the case of a nitrogen atom, there is no substituent on X1 to X8.
摘要:
An electron-emitting device, comprising: a pair of device electrodes formed on an insulating substrate; and a conductive film formed to connect the device electrodes and having an electron-emitting portion, wherein the conductive film has a thickness of 3 nm to 50 nm and is made of precious metal and oxide of base metal, a percentage of the base metal among metals contained in the conductive film is 30 mol % or more, and the conductive film has a concentration gradient of the oxide of the base metal in a thickness direction.
摘要:
Date and time information concerning image files included in the folder is obtained, a time range from the oldest image to the newest image is calculated, and the time range is displayed with folder information. For example, data on shot dates and times recorded as associated information concerning the images or time stamps of the files are used to calculate the time range, and the date range is displayed on a folder icon or on a tab portion of the folder icon. Moreover, a file list displayed last time is stored, the stored file list is compared with a current file list, and only if the both file lists are different from each other, the date and time information is obtained for a different file to recalculate the time range. Thus, the user can infer images included in the folder to some extent and easily retrieve a desired image.
摘要:
A display apparatus is constituted by a display device including a plurality of pixels and control means for effecting a plurality of displaying operations at each pixel. Each of the displaying operation includes at least a first operation for displaying a first image at a first luminance and a second operation for displaying a second image substantially identical to the first image at a second luminance, said first and second luminances being non-zero and different from each other. One of the first and second luminances may preferably be smaller than ⅕ of the other luminance.
摘要:
Date and time information concerning image files included in the folder is obtained, a time range from the oldest image to the newest image is calculated, and the time range is displayed with folder information. For example, data on shot dates and times recorded as associated information concerning the images or time stamps of the files are used to calculate the time range, and the date range is displayed on a folder icon or on a tab portion of the folder icon. Moreover, a file list displayed last time is stored, the stored file list is compared with a current file list, and only if the both file lists are different from each other, the date and time information is obtained for a different file to recalculate the time range. Thus, the user can infer images included in the folder to some extent and easily retrieve a desired image.
摘要:
When an image processing program runs on a PC to produce a layout image in which plural selected images are inserted separately into image display frames, a CPU functions as a browser controller, a face image counter, an average number calculator, a pattern selector, a table, and an image layout section. The face image counter counts face images in each selected image. The average number calculator calculates an average number of the face images in a single selected image. Plural layout patterns of the image display frames are established in the table, which also defines the number of the image display frames and a threshold number of the face images for each layout pattern. Comparing the average number with the threshold number, the pattern selector selects the layout pattern. The image layout section inserts the selected images into the image display frames in the selected layout pattern.
摘要:
In regard to an electroconductive pattern including a high resistivity region partially, by forming a pattern with a photosensitive resin, making the pattern absorb liquid containing a metal component, and baking this, an electroconductive film of metal oxide is formed, this electroconductive film is further covered by a gas shielding layer, and portions which are not shielded are reduced selectively to be made low resistance metal film regions. Since the material which constitutes the electroconductive pattern is hardly removed, a load concerning material reuse is mitigated and material cost is reduced.
摘要:
An MPEG compression circuit records attached information (referred to as FF_PCK) at the initial address of a VOBU in which NV_PCK is to be recorded. NV_PCK is playback auxiliary information and is referred to when playing back moving images in DVD-Video format. Attached information (FF_PCK) has a data size equal to or larger than NV_PCK. FF_PCK is replaced by NV_PCK when converting MPEG2 data into DVD-Video data. As a result, it is not necessary to demultiplex and remultiplex moving image data and sound data so that data can be converted efficiently.
摘要:
In an image reproduction window, an image reproduction area in which images are reproduced, and an operating area in which a slide bar is displayed are provided. When a slider of the slide bar is moved, the number of images to be displayed in one frame in the image reproduction area is increased or decreased in accordance with a position of the slider. The number of images in one frame increases as a displacement amount of the slider increases. When the slider is moved within a range in which the number of images to be displayed in one frame does not change, only a frame change interval is changed while the number of images in one frame is unchanged.