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公开(公告)号：US10755863B2
公开(公告)日：2020-08-25
申请号：US16128442
申请日：2018-09-11
Inventor： Tatsuji Aoyama , Yuichiro Tsubaki
Abstract: An electrolytic capacitor includes an anode body with a dielectric layer; a solid electrolyte layer; and an electrolytic solution. The solid electrolyte layer includes a π-conjugated conductive polymer and an organic sulfonic acid. The electrolytic solution includes a solvent and an acid component, and the acid component includes a sulfuric acid. A concentration of the sulfuric acid in the electrolytic solution ranges from 2.9 ppm to 532 ppm, inclusive.
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公开(公告)号：US10079112B2
公开(公告)日：2018-09-18
申请号：US15619570
申请日：2017-06-12
Inventor： Yuichiro Tsubaki , Masahiro Kajimura
Abstract: A method for producing an electrolytic capacitor is performed in the following procedure. A solid electrolyte layer including a conductive polymer and a polyhydric alcohol is formed on an anode body on which a dielectric layer is formed. Then, the anode body on which the solid electrolyte layer is formed is impregnated with a first treatment liquid that contains an oxoacid having two or more hydroxy groups.
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公开(公告)号：US12198867B2
公开(公告)日：2025-01-14
申请号：US18222132
申请日：2023-07-14
Inventor： Yuichiro Tsubaki , Tatsuji Aoyama
Abstract: A method for manufacturing an electrolytic capacitor of the present disclosure includes first to third steps. In the first step, a capacitor element is prepared that includes an anode body on which a dielectric layer is formed. In the second step, the capacitor element is impregnated with a first treatment solution containing at least a conductive polymer and a first solvent. In the third step, the capacitor element is, after the second step, impregnated with a second treatment solution that contains a polyol compound having 3 or more hydroxyl groups per molecule.
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公开(公告)号：US12148579B2
公开(公告)日：2024-11-19
申请号：US18360528
申请日：2023-07-27
Inventor： Yuichiro Tsubaki , Tatsuji Aoyama , Kazuyo Saito , Yuji Otsuka
Abstract: An electrolytic capacitor includes a capacitor element and an electrolytic solution. The capacitor element includes: an anode body including a dielectric layer; a cathode body; and a solid electrolyte in contact with the dielectric layer. The electrolytic solution includes a solvent, a solute, and a polymer component. The solvent includes an ethylene glycol compound. The polymer component includes polyalkylene glycol. The polyalkylene glycol includes at least one of (i) a mixture of polyoxyethylene and polyoxypropylene and (ii) an oxyethylene-oxypropylene copolymer. In the polyalkylene glycol, a molar ratio m/n of oxyethylene units to oxypropylene units is greater than 1.
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公开(公告)号：US11804334B2
公开(公告)日：2023-10-31
申请号：US17892958
申请日：2022-08-22
Inventor： Yuichiro Tsubaki , Kazuyo Saito , Tatsuji Aoyama
Abstract: An electrolytic capacitor includes an anode body, a cathode body, and a conductive polymer and a liquid component that are disposed between the anode body and the cathode body. The liquid component contains an acid component, a base component, and an aromatic additive. The acid component includes at least one of an aromatic carboxylic acid and an aromatic carboxylic acid derivative. The at least one of the aromatic carboxylic acid and the aromatic carboxylic acid derivative includes at least two carboxy groups and at least one aromatic ring. A content proportion of the base component in the liquid component is more than or equal to 1% by mass. The aromatic additive includes an electron withdrawing group and an electron donating group. A content ratio of the aromatic additive contained in the liquid component is more than or equal to 50 parts by mass with respect to 100 parts by mass of the conductive polymer.
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Patent Agency Ranking
公开(公告)号：US11715605B2
公开(公告)日：2023-08-01
申请号：US17518849
申请日：2021-11-04
Inventor： Kazuyo Saito , Yuichiro Tsubaki , Tatsuji Aoyama
Abstract: An electrolytic capacitor includes a capacitor element and electrolytic solution. The capacitor element includes an anode body with an oxide film, and a solid electrolyte contacting the oxide film. The electrolytic solution contains a solvent and a solute. The solvent contains at least one selected from the group consisting of a lactone compound, a glycol compound, and a sulfone compound. The solute includes a first acid component and a base component. The first acid component includes at least one of a benzenedicarboxylic acid and a derivative of the benzenedicarboxylic acid. The base component includes at least one of an amine and an amidine. A concentration of the solute in the electrolytic solution ranges from 15% by mass to 40% by mass, inclusive. A ratio (V/Vw) of a formation voltage V of the oxide film to a rated voltage Vw of the electrolytic capacitor is less than or equal to 1.7.
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公开(公告)号：US12112900B2
公开(公告)日：2024-10-08
申请号：US17811265
申请日：2022-07-07
Inventor： Yuichiro Tsubaki , Kazuhiro Takatani , Mitsuhisa Yoshimura , Miyoko Masuda
Abstract: An electrolytic capacitor includes a capacitor element, a liquid component, a case housing the capacitor element and the liquid component, and a sealing member sealing the case. the capacitor element includes a porous sintered body including a dielectric layer, a cathode foil facing at least a part of the porous sintered body, and a conductive polymer covering at least a part of a surface of the dielectric layer. The conductive polymer is in contact with the cathode foil. And a void in the capacitor element is impregnated with the liquid component.
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公开(公告)号：US11302486B2
公开(公告)日：2022-04-12
申请号：US16833951
申请日：2020-03-30
Inventor： Yuichiro Tsubaki , Tatsuji Aoyama , Kazuyo Saito , Yuji Otsuka
Abstract: An electrolytic capacitor includes a capacitor element and an electrolytic solution. The capacitor element includes: an anode body including a dielectric layer; a cathode body; and a solid electrolyte in contact with the dielectric layer. The electrolytic solution includes a solvent, a solute, and a polymer component. The solvent includes an ethylene glycol compound. The polymer component includes polyalkylene glycol. The polyalkylene glycol includes at least one of (i) a mixture of polyoxyethylene and polyoxypropylene and (ii) an oxyethylene-oxypropylene copolymer. In the polyalkylene glycol, a molar ratio m/n of oxyethylene units to oxypropylene units is greater than 1.
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公开(公告)号：US11244792B2
公开(公告)日：2022-02-08
申请号：US16889314
申请日：2020-06-01
Inventor： Yuichiro Tsubaki , Kazuyo Saito
Abstract: An electrolytic capacitor includes an anode body, a dielectric layer disposed on a surface of the anode body, a solid electrolyte layer that is in contact with the dielectric layer, and an ion conductor that is liquid at room temperature. The solid electrolyte layer includes a conductive polymer. The ion conductor includes a solvent, an acid component, and a base component. The content proportion of the solvent in the ion conductor is more than 10% by mass and less than or equal to 60% by mass. The total content proportion of the acid component and the base component in the ion conductor is more than or equal to 40% by mass and less than 90% by mass. A melting point of the ion conductor is lower than or equal to −10° C.
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公开(公告)号：US10937599B2
公开(公告)日：2021-03-02
申请号：US16842342
申请日：2020-04-07
Inventor： Yuichiro Tsubaki , Tatsuji Aoyama
Abstract: An electrolytic capacitor includes an anode body with a dielectric layer; a solid electrolyte layer in contact with the dielectric layer; and an electrolytic solution. The solid electrolyte layer includes a π-conjugated conductive polymer and a first sulfonic acid. The electrolytic solution includes a solvent and an acid component. The solvent includes a glycol compound. And a proportion of the glycol compound in the solvent is equal to or more than 50% by mass.
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