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11.发明授权Method of deacidizing a gas with a fractional regeneration absorbent solution 有权使用分级再生吸收剂溶液使气体脱酸的方法公开(公告)号：US07419646B2
公开(公告)日：2008-09-02
申请号：US11264040
申请日：2005-11-02
摘要： The gaseous effluent flowing in through line 1 is contacted in absorption zone ZA with the liquid absorbent solution flowing in through line 9. The gaseous effluent depleted in acid compounds is discharged through line 2. The absorbent solution laden with acid compounds is discharged through line 3. The absorbent solution once laden with acid compounds comprises two phases: a first phase poor in acid compounds and a second phase rich in acid compounds. The two phases are separated in zone ZS. The first phase is recycled through lines 5 and 9 to absorption zone ZA. The second phase is fed through line 4 into regeneration zone ZR. In zone ZR, the acid compounds are separated from the absorbent solution. The acid compounds are discharged through line 7. The regenerated absorbent solution is recycled through lines 6 and 9 to zone ZA.
摘要翻译： 通过管线1流动的气态流出物在吸收区ZA中与液体吸收剂溶液通过管线9流动。通过管线2排出贫酸化合物的气态流出物。载有酸性化合物的吸收剂溶液通过管线3排出 一旦载有酸性化合物的吸收剂溶液包含两相：第一相酸性化合物不良，第二相富含酸化合物。 两相在区域ZS中分离。 第一阶段通过管线5和9再循环到吸收区ZA。 第二相通过管线4进入再生区ZR。 在区域ZR中，酸性化合物与吸收剂溶液分离。 酸化合物通过管线7排出。再生的吸收剂溶液通过管线6和9再循环到区域ZA。
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公开(公告)号：US20070264180A1
公开(公告)日：2007-11-15
申请号：US11746137
申请日：2007-05-09
IPC分类号： B01D53/14
CPC分类号： B01D53/1456 , B01D53/1425 , B01D53/1493 , Y02E50/343
摘要： Method of deacidizing a gaseous effluent comprising acid compounds such as H2S, mercaptans, CO2, COS, SO2, CS2. An absorbent solution comprising reactive compounds with at least two amine functions is used and the following stages are carried out: a) contacting the gaseous effluent with a first fraction of the absorbent solution, so as to obtain a gaseous effluent depleted in acid compounds and a liquid effluent laden with acid compounds, b) contacting the liquid effluent obtained in stage a) with a second fraction of absorbent solution laden with molecules more acid than the acid compounds, so as to cause formation of a first liquid phase depleted in acid compounds and of a second liquid phase enriched in acid compounds and laden with more acid molecules, c) separating the first phase from the second phase, d) regenerating the second phase so as to release a gas stream rich in acid compounds and a liquid stream poor in acid compounds and laden with more acid molecules.
摘要翻译： 使包含酸化合物如H 2 S，硫醇，CO 2，COS，SO 2，CS 2的气态流出物脱酸的方法， 2 。 使用包含具有至少两种胺官能团的反应性化合物的吸收剂溶液，并进行以下阶段：a）使气态流出物与吸收剂溶液的第一部分接触，以获得贫酸化合物和 带有酸性化合物的液体流出物，b）将a）阶段中得到的液体流出液与第二部分吸收剂溶液接触，分子比酸性化合物酸更酸，从而形成贫酸化合物的第一液相， 的第二液相富含酸性化合物并含有更多的酸分子，c）将第一相与第二相分离，d）再生第二相以释放富含酸化合物的气流和不良的 酸化合物并含有更多的酸分子。
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公开(公告)号：US20050169825A1
公开(公告)日：2005-08-04
申请号：US11014788
申请日：2004-12-20
CPC分类号： B01D53/1425 , B01D53/1475 , Y02C10/04 , Y02C10/06
摘要： The fumes flowing in through line 1 are contacted in column C1 with a solvent, at low vapour pressure, absorbing the carbon dioxide. The solvent laden with carbon dioxide is regenerated by distillation in column C2. In order to improve the regeneration operation, a gas is injected through line 11 into column C2 so that this gas carries along the carbon dioxide contained in the solvent. The carbon dioxide-rich gaseous effluent obtained at the top of column C2 can be liquefied by compression and cooling, then stored in surge tank R, which allows its transportation and possibly underground sequestration.
摘要翻译： 通过管线1流动的烟气在塔C 1中与溶剂在低蒸气压下接触，吸收二氧化碳。 用二氧化碳负载的溶剂通过柱C 2中的蒸馏再生。为了改善再生操作，将气体通过管线11注入塔C 2，使得该气体沿着溶剂中所含的二氧化碳携带。 在塔C 2顶部获得的富含二氧化碳的气态流出液可以通过压缩和冷却液化，然后储存在缓冲罐R中，这允许其运输和可能的地下封存。
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14.发明授权Process for producing alkyl esters from a vegetable or animal oil and an aliphatic monoalcohol 失效从植物油或动物油和脂肪族一元醇生产烷基酯的方法公开(公告)号：US06878837B2
公开(公告)日：2005-04-12
申请号：US10411384
申请日：2003-04-11
申请人： Laurent Bournay , Gerard Hillion , Pierre Boucot , Jean-Alain Chodorge , Charles Bronner , Alain Forestiere
发明人： Laurent Bournay , Gerard Hillion , Pierre Boucot , Jean-Alain Chodorge , Charles Bronner , Alain Forestiere
摘要： Alkyl esters of fatty acids, and high purity glycerin, are produced using a process comprising a set of transesterification reactions between a vegetable or animal oil and an aliphatic monoalcohol employing a heterogeneous catalyst, for example based on zinc aluminate, the water content in the reaction medium being controlled to a value that is below a given limiting value.
摘要翻译： 脂肪酸和高纯度甘油的烷基酯是使用包含一系列植物油或动物油与脂肪族一元醇之间的酯交换反应的方法制备的，该方法使用非均相催化剂，例如以铝酸铝为基准，反应中的水含量 介质被控制到低于给定极限值的值。
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15.发明授权Apparatus for purifying a gas containing hydrogen sulphide and sulphur dioxide 有权用于净化含有硫化氢和二氧化硫的气体的装置公开(公告)号：US06315961B1
公开(公告)日：2001-11-13
申请号：US09515329
申请日：2000-02-29
IPC分类号： B01D5334
CPC分类号： C01B17/05
摘要： A process for the production of elemental sulphur by reacting hydrogen sulphide with sulphur dioxide in a liquid reaction medium comprising an organic solvent for the two compounds, e.g., ethylene glycol, and containing at least one soluble catalytic basic compound, e.g., sodium salicylate, comprises bringing a gas mixture containing sulphur dioxide and hydrogen sulphide into contact with a co-current of the solvent containing the catalytic basic compound.
摘要翻译： 在含有两种化合物的有机溶剂（例如乙二醇）并含有至少一种可溶性催化碱性化合物（例如水杨酸钠）的液体反应介质中，使硫化氢与二氧化硫反应生成元素硫的方法包括 使含有二氧化硫和硫化氢的气体混合物与含有催化碱性化合物的溶剂的电流接触。
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公开(公告)号：US07585479B2
公开(公告)日：2009-09-08
申请号：US11746137
申请日：2007-05-09
CPC分类号： B01D53/1456 , B01D53/1425 , B01D53/1493 , Y02E50/343
摘要： A method of deacidizing a gaseous effluent including acid compounds includes the following stages: a) contacting the gaseous effluent with a first fraction of an absorbent solution containing reactive compounds with at least two amine functions, so as to obtain a gaseous effluent depleted in acid compounds and a liquid effluent laden with acid compounds, b) contacting the liquid effluent obtained in stage a) with a second fraction of absorbent solution laden with molecules more acid than the acid compounds, so as to cause formation of a first liquid phase depleted in acid compounds and a second liquid phase enriched in acid compounds and laden with more acid molecules, c) separating the first phase from the second phase, and d) regenerating the second phase so as to release a gas stream rich in acid compounds and a liquid stream poor in acid compounds and laden with more acid molecules.
摘要翻译： 使包含酸化合物的气态流出物脱酸的方法包括以下阶段：a）使气态流出物与含有具有至少两个胺官能团的反应性化合物的吸收剂溶液的第一部分接触，以获得贫酸化合物的气态流出物 和含有酸化合物的液体流出物，b）将a）阶段中得到的液体流出物与第二部分吸收剂溶液接触，分子比酸化合物酸更酸，从而形成贫酸的第一液相 化合物和富含酸化合物并含有更多酸分子的第二液相，c）将第一相与第二相分离，以及d）再生第二相以释放富含酸化合物的气流和液流 酸性化合物差，含有更多酸分子。
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17.发明申请METHOD OF DEACIDIZING A GAS BY MEANS OF AN ABSORBENT SOLUTION WITH FRACTIONATED REGENERATION THROUGH HEATING 有权通过吸热解决方案消除气体的方法，通过加热分解再生公开(公告)号：US20090199709A1
公开(公告)日：2009-08-13
申请号：US12282403
申请日：2007-03-09
CPC分类号： B01D53/229 , B01D53/1425 , B01D53/1462 , Y02C10/06 , Y02E50/343
摘要： A method of deacidizing a gaseous effluent comprising acid compounds where the gaseous effluent is contacted in C1 with an adsorbent solution so as to obtain a gaseous effluent depleted in acid compounds and an absorbent solution laden with acid compounds, the absorbent solution being selected for its property of forming two separable phases when it has absorbed an amount of acid compounds and when it is heated. The absorbent solution laden with acid compounds is then heated in E1 and E3 so as to separate two fractions: a first absorbent solution fraction depleted in acid compounds and a second absorbent solution fraction enriched in acid compounds. These two fractions are then separated in BS1. The second fraction is regenerated in C2 so as to release part of the acid compounds, and the first absorbent solution fraction and the regenerated absorbent solution are recycled as absorbent solution.
摘要翻译： 一种使含有酸性化合物的气态流出物脱酸的方法，其中气态流出物在C1中与吸附剂溶液接触，以便获得贫酸化合物的废气流出物和载有酸性化合物的吸收剂溶液，吸收剂溶液被选择用于其性质 当其吸收一定量的酸化合物和加热时形成两个可分离相。 然后将含有酸化合物的吸收剂溶液在E1和E3中加热，从而分离出两个馏分：贫酸化合物的第一吸收剂溶液馏分和富含酸化合物的第二吸收剂溶液馏分。 然后将这两个级分在BS1中分离。 第二部分在C2中再生以释放部分酸化合物，第一吸收剂部分和再生吸收剂溶液作为吸收剂溶液再循环。
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18.发明授权公开(公告)号：US07344635B2
公开(公告)日：2008-03-18
申请号：US10503807
申请日：2003-01-22
IPC分类号： C10G45/02
CPC分类号： C10G69/123 , C10G29/205
摘要： Process for desulfurization of an effluent for cracking or steam-cracking hydrocarbons, more particularly a gasoline for example for catalytic cracking that comprises the elimination of thiophenic compounds by alkylation of these compounds, followed by a distillation, a hydrocracking of said alkyl-thiophenic compounds, then a hydrodesulfurization of the effluent that is obtained from the hydrocracking zone. In a preferred embodiment, this process comprises a preliminary stage for separating the cracking or steam-cracking effluent into three fractions, and proposes sending to the alkylation stage only the intermediate fraction that is low in heavy basic nitrogen-containing compounds that are initially present in the effluents that are to be alkylated.
摘要翻译： 用于裂化或蒸汽裂解烃的流出物的脱硫方法，更具体地，例如用于催化裂解的汽油，其包括通过这些化合物的烷基化除去噻吩化合物，然后蒸馏，所述烷基 - 噻吩化合物的加氢裂化， 然后从加氢裂化区获得的流出物的加氢脱硫。 在优选的实施方案中，该方法包括用于将裂化或蒸汽裂解流出物分离成三个馏分的初步阶段，并且建议仅向最初存在于重质碱性含氮化合物中的低碱性含氮化合物的中间馏分 待烷基化的废水。
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公开(公告)号：US06281402B1
公开(公告)日：2001-08-28
申请号：US09208585
申请日：1998-12-10
申请人： Vincent Coupard , François Hugues , Dominique Commereuc , Béatrice Fischer , Pierre Boucot , Alain Forestiere
发明人： Vincent Coupard , François Hugues , Dominique Commereuc , Béatrice Fischer , Pierre Boucot , Alain Forestiere
IPC分类号： C07C604
CPC分类号： C07C6/04 , C07C2521/04 , C07C2523/36 , Y02P20/584
摘要： The present invention relates to a process for continuous metathesis or disproportionation of olefins, comprising at least 2 phases, a reaction phase a) carried out in a zone comprising at least one reactor containing at least one fixed bed of catalyst and a regeneration phase b) carried out in a zone comprising at least one reactor containing at least one fixed bed of catalyst, characterized in that at least one reactor passes from one phase to the other in alternation. In FIG. 1, the feed containing olefins traverses reactor R1 in riser mode. The feed to be treated containing olefins is introduced into reactor R1 via line 1a. In this reactor, the olefins contained in the feed undergo metathesis or disproportionation, then the effluent leaves the circuit via line 11. Simultaneously, reactor R2 is placed in catalyst regeneration phase, the different regeneration gases are introduced into reactor R2 via line 2b and leave this reactor via line 2c. Passage from the operating phase of a reactor to the catalyst regeneration phase thereof is carried out as follows: the reactor for which the catalyst is to be regenerated is isolated from the remainder of the apparatus, the hydrocarbons contained in the reactor are evacuated, then the reactor is purged. Said reactor is then connected to a regeneration loop and undergoes regeneration of its catalyst, and at the end of the regeneration phase, the reactor and the regeneration loop are purged.
摘要翻译： 本发明涉及一种烯烃的连续复分解或歧化方法，包括至少两相，在包含至少一个含有至少一个催化剂固定床和再生阶段的反应器的区域中进行的反应相a） 在包含至少一个包含至少一个催化剂固定床的反应器的区域中进行，其特征在于至少一个反应器交替地从一个相转移到另一个相。 在图 如图1所示，含有烯烃的进料以提升管方式穿过反应器R1。 待处理含烯烃的进料通过管线1a引入反应器R1。 在该反应器中，进料中所含的烯烃经过复分解或歧化，然后流出物通过管线11离开回路。同时，将反应器R2置于催化剂再生阶段，不同的再生气体通过管线2b引入反应器R2，并留下 该反应器经由管线2c。 从反应器的操作阶段到催化剂再生阶段的通过如下进行：将待再生催化剂的反应器与装置的其余部分分离，将反应器中包含的烃抽真空，然后 反应器被清除。 然后将所述反应器连接到再生回路并经历其催化剂的再生，并且在再生阶段结束时，将反应器和再生回路清除。
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20.发明授权Process for the separation of alpha-olefins by distillation of an effluent comprising ethylene and 1-butene 失效通过蒸馏出包含乙烯和1-丁烯的流出物来分离α-烯烃的方法
公开(公告)号：US5853551A
公开(公告)日：1998-12-29
申请号：US720384
申请日：1996-07-23
CPC分类号： C07C7/05
摘要： The invention concerns a process for the separation of a mixture comprising ethylene, 1-butene, alpha-olefins containing at least 6 carbon atoms per molecule and possibly heavier hydrocarbon products, the ethylene content of the mixture being in the range 30% to 70% by weight, in which separation is effected in a distillation zone to obtain an overhead fraction comprising the major portion of the ethylene present in the mixture and between 0% and 100% by weight of the 1-butene present in the mixture, the process being characterized in that the zone is also supplied with supplemental 1-butene in an amount in the range 1 to 40 times the quantity (by weight) of 1-butene present in the mixture. In a preferred implementation of the process of the invention, the mixture originates form a homogenous liquid phase ethylene oligomerisation zone.
摘要翻译： 本发明涉及一种分离包含乙烯，1-丁烯，每分子含有至少6个碳原子的α-烯烃和可能较重烃产物的混合物的混合物的方法，该混合物的乙烯含量在30％至70％的范围内， ，其中在蒸馏区中进行分离以获得包含混合物中存在的乙烯的主要部分和0重量％至100重量％的混合物中存在的1-丁烯的塔顶馏分，该方法为 其特征在于，该区域还提供了在混合物中存在的1-丁烯的量（重量）的1至40倍的量的补充的1-丁烯。 在本发明方法的优选实施方案中，混合物起始形成均相液相乙烯齐聚区。
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