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    Alternated process for olefin metathesis
    1.
    发明授权
    Alternated process for olefin metathesis 有权
    烯烃复分解的交替过程

    公开(公告)号：US06281402B1

    公开(公告)日：2001-08-28

    申请号：US09208585

    申请日：1998-12-10

    申请人： Vincent Coupard ,  François Hugues ,  Dominique Commereuc ,  Béatrice Fischer ,  Pierre Boucot ,  Alain Forestiere

    发明人： Vincent Coupard ,  François Hugues ,  Dominique Commereuc ,  Béatrice Fischer ,  Pierre Boucot ,  Alain Forestiere

    IPC分类号： C07C604

    CPC分类号： C07C6/04 ,  C07C2521/04 ,  C07C2523/36 ,  Y02P20/584

    摘要： The present invention relates to a process for continuous metathesis or disproportionation of olefins, comprising at least 2 phases, a reaction phase a) carried out in a zone comprising at least one reactor containing at least one fixed bed of catalyst and a regeneration phase b) carried out in a zone comprising at least one reactor containing at least one fixed bed of catalyst, characterized in that at least one reactor passes from one phase to the other in alternation. In FIG. 1, the feed containing olefins traverses reactor R1 in riser mode. The feed to be treated containing olefins is introduced into reactor R1 via line 1a. In this reactor, the olefins contained in the feed undergo metathesis or disproportionation, then the effluent leaves the circuit via line 11. Simultaneously, reactor R2 is placed in catalyst regeneration phase, the different regeneration gases are introduced into reactor R2 via line 2b and leave this reactor via line 2c. Passage from the operating phase of a reactor to the catalyst regeneration phase thereof is carried out as follows: the reactor for which the catalyst is to be regenerated is isolated from the remainder of the apparatus, the hydrocarbons contained in the reactor are evacuated, then the reactor is purged. Said reactor is then connected to a regeneration loop and undergoes regeneration of its catalyst, and at the end of the regeneration phase, the reactor and the regeneration loop are purged.

    摘要翻译： 本发明涉及一种烯烃的连续复分解或歧化方法，包括至少两相，在包含至少一个含有至少一个催化剂固定床和再生阶段的反应器的区域中进行的反应相a） 在包含至少一个包含至少一个催化剂固定床的反应器的区域中进行，其特征在于至少一个反应器交替地从一个相转移到另一个相。 在图 如图1所示，含有烯烃的进料以提升管方式穿过反应器R1。 待处理含烯烃的进料通过管线1a引入反应器R1。 在该反应器中，进料中所含的烯烃经过复分解或歧化，然后流出物通过管线11离开回路。同时，将反应器R2置于催化剂再生阶段，不同的再生气体通过管线2b引入反应器R2，并留下 该反应器经由管线2c。 从反应器的操作阶段到催化剂再生阶段的通过如下进行：将待再生催化剂的反应器与装置的其余部分分离，将反应器中包含的烃抽真空，然后 反应器被清除。 然后将所述反应器连接到再生回路并经历其催化剂的再生，并且在再生阶段结束时，将反应器和再生回路清除。

    Process for producing an alpha olefin, a tertiary olefin and/or an ether from an unsaturated hydrocarbon cut
    3.
    发明授权
    Process for producing an alpha olefin, a tertiary olefin and/or an ether from an unsaturated hydrocarbon cut 失效
    从不饱和烃馏分制备α-烯烃，叔烯烃和/或醚的方法

    公开(公告)号：US5994594A

    公开(公告)日：1999-11-30

    申请号：US53061

    申请日：1998-04-01

    申请人： Marie-Claire Marion ,  Vincent Coupard ,  Alain Forestiere ,  Philippe Travers ,  Jean-Charles Viltard

    发明人： Marie-Claire Marion ,  Vincent Coupard ,  Alain Forestiere ,  Philippe Travers ,  Jean-Charles Viltard

    IPC分类号： C07C11/02 ,  C07C41/06 ,  C07C41/00 ,  C07C2/00 ,  C07C7/00 ,  C07C9/00

    CPC分类号： C07C11/02 ,  C07C41/06 ,  C07C41/42

    摘要： A process for producing an alpha olefin, a tertiary olefin or a tertiary alkyl ether from an unsaturated hydrocarbon cut containing at least one alpha olefin and at least one etherifiable tertiary olefin comprises synthesising at least one tertiary alkyl ether to obtain a product which is separated into a fraction (O1) which is depleted in ether and containing the alpha olefin and a fraction (E1) which is enriched in ether, followed by decomposition of at least a portion of the ether in fraction (E1) into a product (P1) containing at least one alcohol and at least one tertiary olefin, which is fractionated in a fractionation zone (C5) into a fraction (B1) containing the major portion of the tertiary olefin and a fraction (A1) containing the major portion of the alcohol.

    摘要翻译： 从含有至少一种α烯烃和至少一种可醚化叔烯烃的不饱和烃馏分中制备α-烯烃，叔烯烃或叔烷基醚的方法包括合成至少一种叔烷基醚以获得分离成 在乙醚中耗尽并含有α-烯烃的馏分（O1）和富含乙醚的馏分（E1），然后将部分（E1）中的至少一部分乙醚分解成含有 至少一种醇和至少一种叔烯烃，其在分馏区（C5）中分馏成含有主要部分的叔烯烃的级分（B1）和含有主要部分醇的级分（A1）。

    Process for producing a tertiary olefin by decomposing a tertiary alkyl ether
    4.
    发明授权
    Process for producing a tertiary olefin by decomposing a tertiary alkyl ether 失效
    通过分解叔烷基醚生产叔烯烃的方法

    公开(公告)号：US6100438A

    公开(公告)日：2000-08-08

    申请号：US26682

    申请日：1998-02-20

    申请人： Marie-Claire Marion ,  Vincent Coupard ,  Alain Forestiere ,  Philippe Travers ,  Jean-Charles Viltard

    发明人： Marie-Claire Marion ,  Vincent Coupard ,  Alain Forestiere ,  Philippe Travers ,  Jean-Charles Viltard

    IPC分类号： C07C1/20 ,  C07C11/02 ,  C07C1/00

    CPC分类号： C07C11/02 ,  C07C1/20 ,  C07C2531/025 ,  C07C2531/06

    摘要： A process for producing a tertiary olefin by decomposing a tertiary alkyl ether comprises a) decomposing at least one ether to a product containing an alcohol and a tertiary olefin, b) fractionating at least a portion of the product from a) in a fractionation zone (C1) to obtain the tertiary olefin and the alcohol, c) purifying at least a portion of the tertiary olefin obtained from step b) wherein said portion is sent to a water washing extraction zone (L1) from which a fraction (D) containing the tertiary olefin is recovered, and d) a step in which at least a portion of the fraction (D) from c) is sent to a separation zone (Co) from which a liquid aqueous fraction (Le) and a liquid hydrocarbon fraction (Lc) containing the major portion of the tertiary olefin are recovered.

    摘要翻译： 通过分解叔烷基醚来生产叔烯烃的方法包括：a）将至少一种醚分解成含有醇和叔烯烃的产物，b）在分馏区（a）中分馏至少一部分产物， C1）以获得叔烯烃和醇，c）纯化至少一部分由步骤b）获得的叔烯烃，其中所述部分被送至水洗提取区（L1），从其中含有 回收叔烯烃，d）将来自c）的馏分（D）的至少一部分送至分离区（Co）的步骤，液体含水馏分（Le）和液体烃馏分（Lc ）回收了主要部分的叔烯烃。

    Process for producing a tertiary olefin by decomposing a tertiary alkylether, comprising a first step of purification by washing with water
    5.
    发明授权
    Process for producing a tertiary olefin by decomposing a tertiary alkylether, comprising a first step of purification by washing with water 失效
    通过分解叔烷基醚生产叔烯烃的方法，包括通过用水洗涤来净化的第一步骤

    公开(公告)号：US6072095A

    公开(公告)日：2000-06-06

    申请号：US30916

    申请日：1998-02-26

    申请人： Marie-Claire Marion ,  Vincent Coupard ,  Alain Forestiere ,  Philippe Travers ,  Jean-Charles Viltard

    发明人： Marie-Claire Marion ,  Vincent Coupard ,  Alain Forestiere ,  Philippe Travers ,  Jean-Charles Viltard

    IPC分类号： C07C1/20 ,  C07C11/02 ,  C07C1/00

    CPC分类号： C07C11/02 ,  C07C1/20

    摘要： A process for producing a tertiary olefin by decomposing an ether comprises a) decomposing an ether to a product containing an alcohol and a tertiary olefin, b) purifying at least a portion of the product from a) in a water washing extraction zone (L1) to obtain an aqueous fraction (A1) containing the major portion of the alcohol and a fraction (B1) containing the major portion of the tertiary olefin, the fraction (B1) containing the tertiary olefin, water, possibly ether and light compounds and being substantially free of alcohol, and c) in which at least a portion of the fraction (B1) from b) is sent to a separation zone (Co1) from which a liquid aqueous fraction (La1) and a liquid fraction (Lb1) containing the major portion of the tertiary olefin, possibly ether and possibly light compounds, are recovered.

    摘要翻译： 通过分解醚制备叔烯烃的方法包括：a）将乙醚分解成含有醇和叔烯烃的产物，b）在水洗提取区（L1）中从a）中纯化至少一部分产物， 得到含有主要部分醇的含水馏分（A1）和含有主要部分的叔烯烃的馏分（B1），含有叔烯烃的馏分（B1），水，可能的醚和轻质化合物，并且基本上 不含醇，c）将来自b）的馏分（B1）的至少一部分送至分离区（Co1），分离区（Co1）从该分离区（Co1）中分出含有主要的液体含水馏分（La1）和液体馏分（Lb1） 回收了部分叔烯烃，可能是醚和可能的轻化合物。

    Process for the valorization of a charge of hydrocarbons and for reducing the vapour pressure of said charge
    6.
    发明申请
    Process for the valorization of a charge of hydrocarbons and for reducing the vapour pressure of said charge 有权
    用于使碳氢化合物加压并且用于降低所述电荷的蒸汽压力的方法

    公开(公告)号：US20050101821A1

    公开(公告)日：2005-05-12

    申请号：US10653426

    申请日：2003-09-03

    申请人： Patrick Briot ,  Vincent Coupard ,  Alain Forestiere ,  Eric Llido ,  Thierry Poussereau

    发明人： Patrick Briot ,  Vincent Coupard ,  Alain Forestiere ,  Eric Llido ,  Thierry Poussereau

    IPC分类号： C10L1/04 ,  C10G17/02 ,  C10G17/095 ,  C10G29/20 ,  C10G45/10 ,  C10G45/44 ,  C10G50/00 ,  C10G55/04 ,  C10G55/06 ,  C10G67/08 ,  C10G67/16 ,  C07C7/20

    CPC分类号： C10G29/205 ,  C10G50/00

    摘要： A process is described for the valorization of a charge of hydrocarbons and for reducing the vapour pressure of said charge, comprising three steps: a step a) consisting of separating said charge of hydrocarbons into a fraction (O1) comprising essentially compounds containing 5 carbon atoms, including at least 2% by weight of pentenes, a step b) consisting of placing said fraction (O1) in contact with a cut of hydrocarbons (O2) at least partly comprising hydrocarbons having a number of carbon atoms between 6 and 10, including at least 2% by weight of olefins, and a step c) consisting of separating the effluents originating from step b) into a gasoline cut (α) the upper distillation point of which is less than 100° C. and a kerosene cut (β) having a distillation range between 100° C. and 300° C.

    摘要翻译： 描述了一种用于增加烃类和降低所述电荷的蒸气压的方法，包括三个步骤：步骤a）由将所述烃分离成基本上含有5个碳原子的化合物的馏分（O1）组成的步骤 ，包括至少2重量％的戊烯，步骤b）将所述馏分（O1）与至少部分包含6至10个碳原子的烃的馏分（O 2）接触，包括 至少2重量％的烯烃，以及步骤c），其通过将来自步骤b）的流出物分离成上馏分小于100℃的汽油馏分（α）和煤油切割（β ），其蒸馏范围为100℃至300℃。

    Process for the valorization of a charge of hydrocarbons and for reducing the vapor pressure of said charge
    9.
    发明授权
    Process for the valorization of a charge of hydrocarbons and for reducing the vapor pressure of said charge 有权
    用于使碳氢化合物加压并且用于降低所述电荷的蒸汽压力的方法

    公开(公告)号：US07161052B2

    公开(公告)日：2007-01-09

    申请号：US10653426

    申请日：2003-09-03

    申请人： Patrick Briot ,  Vincent Coupard ,  Alain Forestiere ,  Eric Llido ,  Thierry Poussereau

    发明人： Patrick Briot ,  Vincent Coupard ,  Alain Forestiere ,  Eric Llido ,  Thierry Poussereau

    IPC分类号： C07C2/68 ,  C07C2/04 ,  C07C2/00

    CPC分类号： C10G29/205 ,  C10G50/00

    摘要： A process is described for the valorization of a charge of hydrocarbons and for reducing the vapour pressure of said charge, comprising three steps: a step a) consisting of separating said charge of hydrocarbons into a fraction (O1) comprising essentially compounds containing 5 carbon atoms, including at least 2% by weight of pentenes, a step b) consisting of placing said fraction (O1) in contact with a cut of hydrocarbons (O2) at least partly comprising hydrocarbons having a number of carbon atoms between 6 and 10, including at least 2% by weight of olefins, and a step c) consisting of separating the effluents originating from step b) into a gasoline cut (α) the upper distillation point of which is less than 100° C. and a kerosene cut (β) having a distillation range between 100° C. and 300° C.

    摘要翻译： 描述了一种用于增加烃类和降低所述电荷的蒸气压的方法，包括三个步骤：步骤a）由将所述烃分离成基本上含有5个碳原子的化合物的馏分（O1）组成的步骤 ，包括至少2重量％的戊烯，步骤b）将所述馏分（O1）与至少部分包含6至10个碳原子的烃的馏分（O 2）接触，包括 至少2重量％的烯烃，以及步骤c），其通过将来自步骤b）的流出物分离成上馏分小于100℃的汽油馏分（α）和煤油切割（β ），其蒸馏范围为100℃至300℃。