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公开(公告)号：US08372377B2
公开(公告)日：2013-02-12
申请号：US12742408
申请日：2008-10-17
CPC分类号： C01B37/005 , B01J20/18 , C01B37/02 , C01B39/06
摘要： The invention concerns a crystalline solid designated IM-18 which has the X-ray diffraction diagram given below. Said solid has a chemical composition expressed by the empirical formula: mXO2:nGeO2:pZ2O3:qR:sF:wH2O, in which R represents one or more organic species, X represents one or more tetravalent element(s) other than germanium, Z represents at least one trivalent element and F is fluorine.
摘要翻译： 本发明涉及一种称为IM-18的结晶固体，其具有以下给出的X射线衍射图。 所述固体具有由以下经验式表示的化学组成：mXO2：nGeO2：pZ2O3：qR：sF：wH2O，其中R表示一种或多种有机物质，X表示一种或多种除锗以外的四价元素，Z表示 至少一个三价元素，F是氟。
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公开(公告)号：US20110011810A1
公开(公告)日：2011-01-20
申请号：US12742408
申请日：2008-10-17
CPC分类号： C01B37/005 , B01J20/18 , C01B37/02 , C01B39/06
摘要： The invention concerns a crystalline solid designated IM-18 which has the X-ray diffraction diagram given below. Said solid has a chemical composition expressed by the empirical formula: mXO2:nGeO2:pZ2O3:qR:sF:wH2O, in which R represents one or more organic species, X represents one or more tetravalent element(s) other than germanium, Z represents at least one trivalent element and F is fluorine.
摘要翻译： 本发明涉及一种称为IM-18的结晶固体，其具有以下给出的X射线衍射图。 所述固体具有由以下经验式表示的化学组成：mXO2：nGeO2：pZ2O3：qR：sF：wH2O，其中R表示一种或多种有机物质，X表示一种或多种除锗以外的四价元素，Z表示 至少一个三价元素，F是氟。
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公开(公告)号：US06921524B2
公开(公告)日：2005-07-26
申请号：US10792914
申请日：2004-03-05
CPC分类号： C01B37/005 , C01B39/06
摘要： The invention concerns a crystalline solid, designated IM-10, which has the X ray diffraction diagram given below. Said solid has a chemical composition, expressed as the anhydrous base, in terms of moles of oxides, in accordance with the formula XO2:mYO2:pZ2O3:qR2/nO:sF, in which R represents one or more cation(s) with valency n, X represents one or more tetravalent element(s) other than germanium, Y represents germanium, Z represents at least one trivalent element and F is fluorine.
摘要翻译： 本发明涉及一种称为IM-10的结晶固体，其具有以下给出的X射线衍射图。 所述固体具有以氧化物的摩尔数表示的无水碱的化学组成，根据式XO 2：mYO 2：pZ 2 其中R表示一个或多个具有化合价n的阳离子，X表示一个或多个四价基团 除锗以外的元素，Y表示锗，Z表示至少一个三价元素，F表示氟。
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公开(公告)号：US08124038B2
公开(公告)日：2012-02-28
申请号：US12669651
申请日：2008-06-24
CPC分类号： C01B37/00 , B01J20/10 , B01J20/18 , C01B39/48 , Y10S423/30
摘要： The invention relates to a crystallized solid, denoted by the name IM-16, which has an X-ray diffraction pattern as provided hereinafter. Said solid has a chemical composition expressed in accordance with the empirical formula mXO2:nGeO2:pZ2O3:qR:sF:wH2O, where R represents one or more organic species, X represents one or more tetravalent elements different from germanium, Z represents at least one trivalent element and F is fluorine.
摘要翻译： 本发明涉及具有如下文提供的X射线衍射图的由名称IM-16表示的结晶固体。 所述固体具有根据经验式mXO 2 :nGeO 2：pZ 2 O 3：qR：sF：wH 2 O表示的化学组成，其中R表示一种或多种有机物质，X表示一种或多种不同于锗的四价元素，Z表示至少一种 三价元素，F为氟。
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公开(公告)号：US20120041210A1
公开(公告)日：2012-02-16
申请号：US13140501
申请日：2009-11-26
申请人： Mathias Dodin , Yannick Lorgouilloux , Jean-Louis Paillaud , Philippe Caullet , Joel Patarin , Nicolas Bats
发明人： Mathias Dodin , Yannick Lorgouilloux , Jean-Louis Paillaud , Philippe Caullet , Joel Patarin , Nicolas Bats
IPC分类号： C07F7/30
摘要： The invention concerns a crystalline solid designated IM-20 which has the X-ray diffraction diagram given below. Said solid has a chemical composition expressed by the empirical formula: mXO2: nGeO2: pZ2O3: qR: sF: wH2O, in which R represents one or more organic species, X represents one or more tetravalent element(s) other than germanium, Z represents at least one trivalent element and F is fluorine.
摘要翻译： 本发明涉及一种称为IM-20的结晶固体，其具有以下给出的X射线衍射图。 所述固体具有由以下经验式表示的化学组成：mXO2：nGeO2：pZ2O3：qR：sF：wH2O，其中R表示一种或多种有机物质，X表示一种或多种除锗以外的四价元素，Z表示 至少一个三价元素，F是氟。
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公开(公告)号：US07658909B2
公开(公告)日：2010-02-09
申请号：US12062975
申请日：2008-04-04
CPC分类号： C01B39/48 , B01J20/18 , B01J29/7007 , B01J29/7415 , B01J2229/20 , B01J2229/42 , C01B37/02 , Y10S423/27
摘要： A process for preparing a beta zeolite is described, comprising at least the following steps: i) mixing, in an aqueous medium, at least one source of at least one tetravalent element X, at least one source of fluoride anions and at least one quaternary ammonium salt with formula (H3C)2—N+—(CH2CH2C(CH3)3)2; ii) treating said mixture hydrothermally until said beta zeolite is formed.
摘要翻译： 描述了制备β沸石的方法，其包括至少以下步骤：i）在水性介质中混合至少一种四价元素X的源，至少一种氟化物阴离子源和至少一种四氢呋喃 式（H3C）2 -N + - （CH2CH2C（CH3）3）2的铵盐; ii）水热处理所述混合物直至形成所述β沸石。
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17.发明申请EUO-STRUCTURAL TYPE ZEOLITE THAT CONTAINS THE N,N-DIMETHYL-N,N-DI(3,3-DIMETHYLBUTYL)AMMONIUM CATION AND ITS PROCESS FOR PREPARATION 失效含有N，N-二甲基-N，N-DI（3,3-二甲基丁基）氨基铵的EUO结构型沸石及其制备方法公开(公告)号：US20090068091A1
公开(公告)日：2009-03-12
申请号：US12062975
申请日：2008-04-04
IPC分类号： C01B39/04
CPC分类号： C01B39/48 , B01J20/18 , B01J29/7007 , B01J29/7415 , B01J2229/20 , B01J2229/42 , C01B37/02 , Y10S423/27
摘要： A process for preparing a zeolite beta is described, comprising at least the following steps: i) mixing, in an aqueous medium, at least one source of at least one tetravalent element X, at least one source of fluoride anions and at least one quaternary ammonium salt with formula (H3C)2—N+—(CH2CH2C(CH3)3)2; ii) treating said mixture hydrothermally until said zeolite beta is formed.
摘要翻译： 描述了制备沸石β的方法，其包括至少以下步骤：i）在水性介质中混合至少一种至少一种四价元素X的源，至少一种氟化物阴离子源和至少一种季铵 式（H3C）2 -N + - （CH2CH2C（CH3）3）2的铵盐; ii）水热处理所述混合物直到形成所述沸石β。
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公开(公告)号：US08101154B2
公开(公告)日：2012-01-24
申请号：US12513751
申请日：2007-10-01
CPC分类号： C01B39/06 , B01J20/10 , B01J20/18 , B01J20/22 , C01B37/005 , C01G17/00 , C01G17/006
摘要： A crystallized solid, referred to by the name IM-15, which has an X-ray diffraction diagram as provided below, is described. Said solid has a chemical composition that is expressed according to the formula mXO2:nGeO2:pZ2O3:qR:sF:wH2O, where R represents one or more organic radical(s), X represents one or more different tetravalent element(s) of germanium, Z represents at least one trivalent element, and F is fluorine.
摘要翻译： 描述具有如下所述的具有X射线衍射图的名称为IM-15的结晶固体。 所述固体具有根据式mXO 2表示的化学组成：nGeO 2：pZ 2 O 3：qR：sF：wH 2 O，其中R表示一个或多个有机基团，X表示一种或多种不同的四价元素的锗 Z表示至少一种三价元素，F表示氟。
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公开(公告)号：US20100093518A1
公开(公告)日：2010-04-15
申请号：US12513751
申请日：2007-10-01
CPC分类号： C01B39/06 , B01J20/10 , B01J20/18 , B01J20/22 , C01B37/005 , C01G17/00 , C01G17/006
摘要： A crystallized solid, referred to by the name IM-15, which has an X-ray diffraction diagram as provided below, is described. Said solid has a chemical composition that is expressed according to the formula mXO2:nGeO2:pZ2O3:qR:sF:wH2O, where R represents one or more organic radical(s), X represents one or more different tetravalent element(s) of germanium, Z represents at least one trivalent element, and F is fluorine.
摘要翻译： 描述具有如下所述的具有X射线衍射图的名称为IM-15的结晶固体。 所述固体具有根据式mXO 2表示的化学组成：nGeO 2：pZ 2 O 3：qR：sF：wH 2 O，其中R表示一个或多个有机基团，X表示一种或多种不同的四价元素的锗 Z表示至少一种三价元素，F表示氟。
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公开(公告)号：US07074385B2
公开(公告)日：2006-07-11
申请号：US10871700
申请日：2004-06-21
IPC分类号： C01B39/48
CPC分类号： C01B37/005 , C01B39/06
摘要： The invention relates to a crystallized solid, referred to by the name IM-12, which exhibits an x-ray diffraction diagram as provided below. Said solid exhibits a chemical composition that is expressed on an anhydrous base, in terms of oxide moles, by the formula XO2:m YO2:p Z2O3:q R2/nO, where R represents one or more cation(s) of valence n, X represents one or more different tetravalent element(s) of germanium, Y represents germanium, and Z represents at least one trivalent element.
摘要翻译： 本发明涉及名称为IM-12的结晶固体，其显示如下所述的x射线衍射图。 所述固体表现出化学组成，其在无水碱上以氧化物摩尔数表示，通过式XO 2：m Y 2 2：p Z 2 其中R表示一个或多个n价阳离子，X表示一个或多个不同的四价元素， 的锗，Y表示锗，Z表示至少一种三价元素。
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