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    Synthesis of zeolite ITQ-16 in an alkaline medium
    5.
    发明申请
    Synthesis of zeolite ITQ-16 in an alkaline medium 失效
    在碱性介质中合成沸石ITQ-16

    公开(公告)号：US20040089587A1

    公开(公告)日：2004-05-13

    申请号：US10632535

    申请日：2003-08-01

    发明人： Avelino Corma Canos ,  Teresa Navarro Villalba ,  Susana Valencia Valencia ,  Fernando Rey Garcia

    IPC分类号： C10G047/02 ,  C10G011/05 ,  C07C005/23 ,  C07C005/27 ,  C07C002/58 ,  C07C002/66 ,  C01B039/48

    CPC分类号： C10G11/05 ,  B01J29/04 ,  C01B37/005 ,  C01B39/023 ,  C01B39/08 ,  C10G47/16 ,  Y10S423/27

    摘要： The invention relates to a method for synthesizing a family of zeolite materials, grouped together under the name ITQ-16, in an OHnull medium and in the absence of fluorides and to the catalytic applications thereof. The zeolite ITQ-16 family of materials is characterized by having different proportions of distinct polymorphs A, B and C described as possible intergrowths in the Beta zeolite and, therefore, the X-ray diffraction patterns of said family are different from that described for the Beta zeolite. In its calcinated form, zeolite ITQ-16 has the following empirical formula: x(MXO2):tTO2:gGeO2:(1nullg)SiO2, wherein T is one or more elements having null4 oxidation status and different from Ge and Si; X is one or more elements having null3 oxidation status; and M can be Hnull or one or more inorganic cations with a nulln charge.

    摘要翻译： 本发明涉及一种用于合成沸石材料族的方法，该组合物以名称ITQ-16在OH-介质中并且在不存在氟化物的情况下分组在一起，并用于催化应用。 沸石ITQ-16系列材料的特征在于具有不同比例的不同的多晶型物A，B和C作为β沸石中可能的共生生长而被描述，因此，所述族的X射线衍射图不同于对于 β沸石。 沸石ITQ-16具有以下经验公式：x（MXO2）：tTO2：gGeO2：（1-g）SiO2，其中T是具有+4氧化态且不同于Ge和Si的一种或多种元素; X是具有+3氧化状态的一种或多种元素; 并且M可以是H +或一个或多个具有+ n电荷的无机阳离子。

    Synthesis of porous crystalline materials in fluoride media
    7.
    发明申请
    Synthesis of porous crystalline materials in fluoride media 失效
    氟化物介质中多孔结晶材料的合成

    公开(公告)号：US20030190282A1

    公开(公告)日：2003-10-09

    申请号：US10367292

    申请日：2003-02-14

    发明人： Kirk D. Schmitt ,  Stephen G. Casmer

    IPC分类号： C01B039/04

    CPC分类号： C01B39/48 ,  C01B37/005 ,  C01B37/02 ,  C01B39/12 ,  Y10S423/27 ,  Y10S423/33

    摘要： In a process for synthesizing a porous crystalline material, a mixture capable of forming said material is prepared wherein the mixture comprises sources of water, an oxide of a tetravalent element Y, preferably silicon, an oxide of a trivalent element X, wherein X is selected from the group consisting of aluminum, boron, gallium, iron, and indium, fluoride ions, and an organonitrogen cation RNmnull capable of directing the synthesis of said material, wherein the molar ratio of fluoride ions to organonitrogen cations RNmnull in said mixture is greater than 1.15 m but less than 2.5 m. The mixture is maintained under crystallization conditions until crystals of said material are formed and the resultant crystalline material is recovered.

    摘要翻译： 在合成多孔结晶材料的方法中，制备能够形成所述材料的混合物，其中所述混合物包含水源，四价元素Y的氧化物，优选硅，三价元素X的氧化物，其中X被选择 从由铝，硼，镓，铁和铟组成的组，氟离子和能够引导所述材料的合成的有机氮阳离子RN m +，其中氟离子与有机氮阳离子的摩尔比RN

    Zeolite ITQ-5
    8.
    发明授权
    Zeolite ITQ-5 失效
    沸石ITQ-5

    公开(公告)号：US06409986B1

    公开(公告)日：2002-06-25

    申请号：US09581877

    申请日：2000-06-19

    申请人： Miguel-Angel Camblor Fernandez ,  Avelino Corma Canos ,  Susana Valencia Valencia

    发明人： Miguel-Angel Camblor Fernandez ,  Avelino Corma Canos ,  Susana Valencia Valencia

    IPC分类号： C01B3948

    CPC分类号： B01J29/70 ,  B01J29/04 ,  B01J29/7007 ,  C01B37/005 ,  C01B39/06 ,  C01B39/08 ,  C01B39/48 ,  Y10S423/27

    摘要： The present invention relates to zeolithic materials having a characteristic X ray diffraction pattern, and its preparation method, characterized by the relatively low pH of the synthesis medium and the use of F− anions as mineralizing agent. The invention also claims the use of the obtained material in catalytic processes for the transformation of hydrocarbons and in oxidation process. The method comprises heating at 363-473° K a reaction mixture which contains a source of at least one tetravalent element T(IV), optionally a source of an element T(III), optionally H2O2, a structure director organic cation, a source of anions F− and water, the presence of alkaline cations is not necessary.

    摘要翻译： 本发明涉及具有特征X射线衍射图的沸石材料及其制备方法，其特征在于合成介质的pH值相对较低，并且使用F-阴离子作为矿化剂。 本发明还要求所获得的材料在烃转化和氧化过程的催化过程中的用途。 该方法包括在363-473°K加热反应混合物，该反应混合物含有至少一种四价元素T（IV）的源，任选的元素T（III）的源，任选的H 2 O 2，结构导向剂有机阳离子，源 的阴离子F-和水，碱性阳离子的存在是不必要的。

    Method for making molecular sieves and novel molecular sieve compositions
    9.
    发明授权
    Method for making molecular sieves and novel molecular sieve compositions 有权
    制备分子筛和新型分子筛组合物的方法

    公开(公告)号：US06350429B1

    公开(公告)日：2002-02-26

    申请号：US09465029

    申请日：1999-12-16

    申请人： Lawrence L. Murrell ,  Rudolf A. Overbeek ,  Yun-feng Chang ,  Nelleke Van Der Puil ,  Chuen Y. Yeh

    发明人： Lawrence L. Murrell ,  Rudolf A. Overbeek ,  Yun-feng Chang ,  Nelleke Van Der Puil ,  Chuen Y. Yeh

    IPC分类号： C01B3704

    CPC分类号： B01J29/035 ,  B01J29/084 ,  B01J29/40 ,  B01J29/7007 ,  B01J2229/60 ,  B01J2229/64 ,  C01B37/00 ,  C01B37/02 ,  C01B39/00 ,  C01B39/24 ,  C01B39/38 ,  C01B39/46 ,  Y10S423/21 ,  Y10S423/22 ,  Y10S423/27 ,  Y10S423/30

    摘要： This invention relates to the synthesis of large pore composite molecular sieves and to the synthetic large pore composite molecular sieves so produced. The molecular sieves of the invention have the same general utilities of the comparable molecular sieves of the prior art but have been found to be superior catalysts and absorbents. This invention relates to a hydrothermal synthesis of large pore molecular sieves from nutrients, at least one of which contains an amorphous framework-structure, and which framework-structure is essentially retained in the synthetic molecular sieve. This invention stems from a discovery that the intrinsic porosity characteristics of a nutrient that possesses an amorphous cation oxide-framework can be substantially retained in the final molecular sieve containing product formed by a hydrothermal process by carefully controlling the conditions under which the hydrothermal process is conducted. For example, the invention contemplates retention of the particle size in a final molecular sieve-containing product that corresponds with that of an amorphous cation oxide-framework nutrient used in its manufacture. This invention drives the selection of process conditions to achieve one or more of macro and meso porosity (“large pore composite porosity”) in the final molecular sieve product as a direct product of the hydrothermal reaction producing the molecular sieve. The invention allows the production of a molecular sieve that is in situ incorporated in the framework morphology of a solid cation oxide-framework used in the molecular sieve's manufacture.

    摘要翻译： 本发明涉及大孔复合分子筛的合成以及如此生产的合成大孔复合分子筛。 本发明的分子筛具有与现有技术相当的分子筛相同的通用效用，但已被发现是优异的催化剂和吸收剂。 本发明涉及从营养物质中大量分子筛的水热合成，其中至少一种含有无定形骨架结构，其中骨架结构基本上保留在合成分子筛中。 本发明源自一个发现，即通过仔细控制进行水热处理的条件，具有无定形阳离子氧化物 - 框架的营养物质的固有孔隙特性可以基本上保留在通过水热法形成的含最终分子筛的产品中 。 例如，本发明考虑到在与其制造中使用的无定形阳离子氧化物 - 骨架营养物相当的最终的含分子筛的产品中保留粒度。 本发明驱动工艺条件的选择，以实现最终分子筛产物中作为产生分子筛的水热反应的直接产物的宏观和中孔多孔性（“大孔复合孔隙率”）中的一种或多种。 本发明允许生产分子筛，其原位掺入分子筛制造中使用的固体阳离子氧化物框架的骨架形态。