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11.发明授权Ruthenium catalysts, their preparation and a process for preparing cycloaliphatic polyamines using these catalysts 失效钌催化剂，它们的制备和使用这些催化剂制备脂环族多胺的方法
公开(公告)号：US5663443A
公开(公告)日：1997-09-02
申请号：US384303
申请日：1995-02-03
IPC分类号： B01J23/656 , B01J27/232 , C07B61/00 , C07C209/72 , C07C211/36 , C08G59/68
CPC分类号： C08G59/686 , B01J23/6562 , C07C209/72 , C07C2101/16 , C07C2102/10
摘要： Novel ruthenium catalysts additionally contain carbonates, hydroxides and/or hydrated oxides of cerium and manganese or of manganese and/or dehydration products thereof. They can optionally be present on a support material and can be prepared by converting soluble compounds of ruthenium, cerium and manganese by treatment with alkaline compounds into insoluble compounds and optionally further treating these. Such catalysts are particularly suitable for the preparation of cycloaliphatic polyamines by hydrogenation of corresponding aromatic amines.
摘要翻译： 新型钌催化剂还含有铈和锰的碳酸盐，氢氧化物和/或水合氧化物或其锰和/或脱水产物。 它们可以任选地存在于载体材料上，并且可以通过用碱性化合物处理将可溶性钌，铈和锰化合物转化成不溶性化合物并任选进一步处理这些化合物来制备。 这种催化剂特别适用于通过相应的芳族胺的氢化制备脂环族多胺。
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12.发明授权
公开(公告)号：US5648500A
公开(公告)日：1997-07-15
申请号：US608869
申请日：1996-02-29
IPC分类号： C07D209/86 , B01J23/44 , C07B61/00 , C07C251/84 , C07D209/88
CPC分类号： C07D209/88
摘要： Substituted 1,2,3,4-tetrahydrocarbazoles of the formula ##STR1## having the meaning for R.sup.1 to R.sup.8 indicated in the description, can be prepared by catalytically hydrogenating a substituted phenol of the formula ##STR2## reacting the hydrogenation solution with a phenylhydrazine of the formula ##STR3## to give the hydrazone and cyclizing the hydrazone under acidic conditions.
摘要翻译： 可以通过催化氢化式（II）的取代的苯与式（II）的取代的苯反应来制备具有如说明书中所示的R 1至R 8的含义的式（I）的取代的1,2,3,4-四氢咔唑， 该氢化溶液与式（III）的苯肼反应得到腙并在酸性条件下使腙环化。
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公开(公告)号：US5414104A
公开(公告)日：1995-05-09
申请号：US231607
申请日：1994-04-22
申请人： Joerg-Dietrich Jentsch , Alexander Klausener , Heinz Landscheidt , Erich Wolters , Eberhard Zirngiebl
发明人： Joerg-Dietrich Jentsch , Alexander Klausener , Heinz Landscheidt , Erich Wolters , Eberhard Zirngiebl
IPC分类号： B01J27/185 , C07B61/00 , C07C68/00 , C07C69/96
CPC分类号： C07C68/00 , Y02P20/582
摘要： Dialkyl carbonates can be prepared by reaction of carbon monoxide with alkyl nitrites in a continuous gas-phase reaction using a platinum metal catalyst on a metal phosphate support and adding hydrogen halide stepwise or continuously during the course of the reaction in almost quantitative selectivity; the corresponding dialkyl oxalates are formed in such small amounts that in most cases they cannot be detected.
摘要翻译： 碳酸二烷基酯可以通过使用铂金属催化剂在金属磷酸盐载体上的连续气相反应中的一氧化碳与烷基亚硝酸盐反应来制备，并且在反应过程中以几乎定量的选择性逐步或连续地加入卤化氢; 相应的草酸二烷基酯形成量很少，在大多数情况下它们不能检测到。
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公开(公告)号：US20140012046A1
公开(公告)日：2014-01-09
申请号：US13811324
申请日：2011-07-22
CPC分类号： B01J31/0204 , B01J21/04 , B01J23/58 , C07C29/56 , C07C2601/14 , C07C35/12
摘要： The present invention relates to a process for preparing menthol isomers by selective rearrangement of stereoisomers of menthol or mixtures thereof in the presence of ruthenium-containing supported catalysts doped with or comprising alkaline earth metal alkoxides, and to the catalysts themselves.
摘要翻译： 本发明涉及通过选择性重排薄荷醇的立体异构体或其混合物在掺杂或包含碱土金属醇盐的含钌载体催化剂存在下制备薄荷醇异构体的方法，以及催化剂本身。
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公开(公告)号：US5616730A
公开(公告)日：1997-04-01
申请号：US468586
申请日：1995-06-06
IPC分类号： C07D307/60 , B01J25/02 , C07B61/00 , C07C51/567
CPC分类号： C07C51/567
摘要： Succinic anhydride (SA) can be prepared by catalytic hydrogenation of maleic anhydride (MA) with hydrogen in the liquid phase, by reacting a starting material composed of from 5 to 100% by weight of MA and from 95 to 0% by weight of SA, based on the total weight of MA and SA, at from 120.degree. to 150.degree. C. and a H.sub.2 pressure of from 10 to 150 bar over a Raney skeleton catalyst or a platinum group metal catalyst.
摘要翻译： 琥珀酸酐（SA）可以通过马来酸酐（MA）与氢气在液相中的催化氢化，通过使由5〜100重量％的MA和95〜0重量％的SA组成的原料反应来制备 基于MA和SA的总重量，在120-150℃下，在阮内骨架催化剂或铂族金属催化剂上的H 2压力为10至150巴。
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16.发明授权Polyarylene sulfide mixtures with reduced radical formation under highly accelerated weathering 失效聚芳硫醚混合物在高度加速的风化下具有减少的自由基形成
公开(公告)号：US4952624A
公开(公告)日：1990-08-28
申请号：US389267
申请日：1989-08-03
摘要： The invention relates to mixtures of polyarylene sulfides (PAS), preferably polyphenylene sulfide (PPS), and pyrenes. The mixtures show reduced radical formation under highly accelerated weathering conditions (UV irradiation).
摘要翻译： 本发明涉及聚亚芳基硫醚（PAS），优选聚苯硫醚（PPS）和芘的混合物。 混合物在高度加速的风化条件（UV照射）下显示出减少的自由基形成。
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17.发明授权Corrosion inhibitor for protecting metallic materials in strongly alkaline medium 失效用于在强碱性介质中保护金属材料的防腐蚀剂公开(公告)号：US07468158B2
公开(公告)日：2008-12-23
申请号：US10349756
申请日：2003-01-23
IPC分类号： C23F11/06
摘要： Corrosion inhibitor and method of protecting metallic materials in strongly alkaline medium by means of a corrosion inhibitor, characterized in that it contains an amine containing at least one CH group bound to the nitrogen.
摘要翻译： 腐蚀抑制剂和通过腐蚀抑制剂在强碱性介质中保护金属材料的方法，其特征在于其含有至少一个结合氮的CH基团的胺。
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18.发明授权Supported catalysts containing a platinum metal and process for preparing diaryl carbonates 失效含铂金属的载体催化剂和制备碳酸二芳基酯的方法公开(公告)号：US06548445B1
公开(公告)日：2003-04-15
申请号：US08625613
申请日：1996-03-29
申请人： Hans-Josef Buysch , Carsten Hesse , Jörg-Dietrich Jentsch , Johann Rechner , Eberhard Zirngiebl
发明人： Hans-Josef Buysch , Carsten Hesse , Jörg-Dietrich Jentsch , Johann Rechner , Eberhard Zirngiebl
IPC分类号： B01J2713
CPC分类号： B01J23/56 , C07C68/005 , C07C69/96
摘要： In the process for preparing an aromatic carbonate from an aromatic hydroxy compound, CO and O2 in the presence of a quaternary salt and a base using a platinum metal catalyst and a cocatalyst, use is advantageously made of supported catalysts containing, in the reaction-ready state, (i) a platinum metal, a platinum metal halide or a platinum metal halide complex and (ii) a metal compound acting as cocatalyst from groups IB, IIB, IIIA, IIIB, IVA, IVB, VB, VIB, VIIB, the iron group (atomic numbers 26-28) or the rare earth metals (atomic numbers 58-71) of the Periodic Table of the Elements (Mendeleev), each in an amount of 0.01-15% by weight, calculated as metal and based on the total weight of the catalyst.
摘要翻译： 在使用铂金属催化剂和助催化剂的季盐和碱的存在下，由芳族羟基化合物，CO和O 2制备芳香族碳酸酯的方法中，有利地由负载型催化剂制成， 状态，（i）铂金属，铂金属卤化物或铂金属卤化物络合物和（ii）作为IB，IIB，IIIA，IIIB，IVA，IVB，VB，VIB，VIIB族的助催化剂的金属化合物， 元素周期表（Mendeleev）的铁族（原子数26-28）或稀土金属（原子数58-71），其量为0.01-15％（重量），以金属计算，基于 催化剂的总重量。
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公开(公告)号：US5760247A
公开(公告)日：1998-06-02
申请号：US859625
申请日：1997-05-20
IPC分类号： C07D209/82 , B01J23/38 , B01J23/42 , C07D209/86 , C07D209/84 , C07C211/00
CPC分类号： C07D209/86
摘要： Diphenylamine can be dehydrocyclized on noble metal catalysts in the liquid phase at temperatures of 200.degree. to 340.degree. C. The reaction proceeds with a surprisingly high selectivity.
摘要翻译： 二苯胺可以在200-340℃的温度下在液相中的贵金属催化剂上脱氢环化。反应以令人惊讶的高选择性进行。
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公开(公告)号：US5354923A
公开(公告)日：1994-10-11
申请号：US788959
申请日：1991-11-07
CPC分类号： C07C68/06
摘要： Carbonic diesters containing at least one aromatic ester group can be prepared from carbonic diesters containing at least one aliphatic ester group by transesterification using a phenol, titanium dioxide having a surface area of at least 20 m.sup.2 /g as determined by the BET method being used as catalyst.
摘要翻译： 含有至少一个芳族酯基的碳酸二酯可以通过使用苯酚进行酯交换的碳酸二酯，通过BET法测定的表面积至少为20m 2 / g的二氧化钛作为二醇 催化剂。
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