摘要:
Semipermeable composite membranes which comprise an interpenetrating polymer network may be prepared by reacting polyethylene glycol with a toluene diisocyanate to form an isocyanate-capped polyether, thereafter admixing the isocyanate-capped polyether with a heterocyclic nitrogen-containing compound to form an interpenetrating polymer network membrane-forming composition, forming a film of the composition on a porous support backing material and curing the resultant composite in a hydrous atmosphere to generate an amine-capped polymer, and subsequently reacting a portion of the isocyanate groups present to form a substituted polyurea which will physically enter the heterocyclic nitrogen-containing compound in the membrane.
摘要:
A broad class of polymers which mimic the NAD-NADHCN couple is disclosed. These polymeric pseudocyanotransferases may be used to effect asymmetric hydrocyanation of many types of carbonyl, thiocarbonyl, and imino groups in either a batch or continuous process, with the absolute configuration of the resulting optically active product predictable from the known absolute configuration of the chiral polymer.
摘要:
Saline water containing a chlorine-containing compound in the form of free chlorine, hypochlorite, etc. which has been added as a disinfectant or antibacterial compound is desalinated by passing the saline water through a semipermeable membrane which is resistant to the chlorine. The saline water is passed through this membrane at a temperature in the range of from ambient to about 50.degree. C. and a pressure in the range of from about 1380 to about 6895 kPA (200-1000 psi). The chlorine-resistant semipermeable membrane comprises an interfacial polymerized condensation reaction product composited on a porous backing support material which has been prepared by contacting a porous support material such as polysulfone with a solution of a diaryl methylene monomer containing at least one amine radical on each aryl nucleus. The coated support material is then contacted with an organic solvent of an aromatic carboxylic acid chloride for a period of time sufficient to form an interfacial polymerized reaction product on the surface of the support material. Following this the composite is then cured at an elevated temperature to form the desired membrane.
摘要:
Apparatus and method for detecting and measuring hydrogen and gaseous compounds capable of dissociating into or combining with hydrogen ions using a solid electrolyte concentration cell. A novel proton-conducting membrane comprised of an interpenetrating polymer network serves as the solid electrolyte. A reference gas or a solid reference substance is used. For increased strength, a membrane may be composited with or utilized with a porous support.
摘要:
Chlorine-resistant semipermeable membranes which comprise an interfacial polymerization reaction product composited on a porous backing support material may be prepared by contacting a porous support material such as polysulfone with an aqueous solution of triaryl triamine. The coated support material is then contacted with an organic solvent solution of an aromatic polycarboxylic acid chloride for a period of time sufficient to form an interfacial polymerized reaction product on the surface of the support material. The resultant membrane composite may be used in separation processes such as desalination of brackish or sea water, the membrane resistant to attack by chlorine which is present in the water.
摘要:
A broad class of polymers which mimic the NAD--NADH.sub.2 couple is disclosed. These polymeric pseudohydrogenases may be used to asymmetrically reduce many types of carbonyl, thiocarbonyl, and imino groups in either a batch or continuous process, with the absolute configuration of the resulting optically active product predictable from the known absolute configuration of the chiral polymer.
摘要:
A compound having formula (I), wherein R represents C1-C18 alkyl, C5-C18 cycloalkyl, C3-C18 alkenyl or C3-C18 alkynyl; provided that, when —OR groups are in 2,2′-positions on benzene rings in formula (I), R is not methyl, ethyl, hexyl, octyl or allyl.
摘要:
The present invention involves using mechanized strategies to fabricate test samples as well as strategies for selecting sample substrates. These strategies significantly reduce the effort and the variabilities associated with making test samples and testing hair fixative compositions. The technology allows simple, rapid, inexpensive evaluation of hair fixative compositions in a way that generates consistent, reliable data. The quality of the data is high enough to facilitate easier qualitative and quantitative comparisons among compositions under investigation. In preferred modes of practice, the present invention provides a simple way to screen new polymer systems and other developmental products. Additionally, this invention can be used to generate more meaningful comparative data for customer and personal care industry presentations.
摘要:
The invention herein disclosed comprises the use of oxazolidines, nitroalcohols, nitrones, halonitroparaffins, oxazines, azaadamantanes, hexamethylenetetramine salts, nitroamines, imidazolidines, triazines, nitrooxazolidines, and imidazolidine-oxazolidine hybrids to serve as hardeners for curing phenolic resins. The hardeners and accelerators/catalysts described in the invention can be applied in any application were phenolic resins are used, including but not limited to fiber reinforced composite applications such as pultrusion, filament winding, bulk molding compound (BMC), sheet molding compounds (SMC), vacuum assisted resin transfer, prepregs, adhesives, foundry materials, abrasives, friction materials, insulation, laminates, coatings, electronics, fire resistant, and flame-retardant end uses.
摘要:
Provided are polyhydroxy-diamine compounds for use as neutralizing agents for paints and coatings. The compounds are of the formula (I): wherein R1 and R2 are as defined herein.