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公开(公告)号：US5102972A
公开(公告)日：1992-04-07
申请号：US557232
申请日：1990-07-25
IPC分类号： C08G73/12
CPC分类号： C08G73/12 , C08G73/124 , C08G73/125
摘要： A class of di-ortho-substituted bismaleimides undergo uncatalyzed Michael addition with polyhydric phenols to afford chain-extended bismaleimides having a significantly wider processing window than the non-extended parent. The fully cured resins show improved fracture toughness, generally have comparable or superior dielectric constant and dielectric loss, and show no degradation in other properties such as resistance to moisture, to methylene chloride, and coefficient of thermal expansion.
摘要翻译： 一类二邻位取代的双马来酰亚胺用多元酚进行未催化的迈克尔加成以提供具有比非延伸的亲本显着更宽的加工窗口的链延伸的双马来酰亚胺。 完全固化的树脂显示出改善的断裂韧性，通常具有相当或优异的介电常数和介电损耗，并且在其它性能如耐水性，二氯甲烷和热膨胀系数方面没有降低。
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公开(公告)号：US4885091A
公开(公告)日：1989-12-05
申请号：US202850
申请日：1988-06-01
CPC分类号： C08G69/48 , B01D69/125 , B01D71/56 , C08G69/32
摘要： Chlorine-resistant semipermeable membranes which comprise an interfacial polymerized reaction product composited on a porous support backing material may be prepared by contacting a porous support material such as polysulfone with an aqueous solution of an aromatic polyamine containing a chlorine substituent on the aromatic ring such as 5-chlor-m-phenylenediamine. The coated support material is then contacted with an organic solvent solution of aromatic polycarboxylic acid chloride such as trimesoyl chloride for a period of time sufficient to form an interfacial polymerized reaction product on the surface of the support material. The resultant semipermeable membrane is then cured at curing conditions to form the desired composite. The resultant membrane composite may be used in separation processes such as desalination of brackish or sea water, the membrane being resistant to attack by chlorine which is present in the water.
摘要翻译： 包含复合在多孔载体背衬材料上的界面聚合反应产物的耐氯半透膜可以通过使诸如聚砜的多孔载体材料与芳族环上含有氯取代基的芳族多胺的水溶液接触来制备，例如5 - 氯 - 间苯二胺。 然后将涂覆的载体材料与芳族多元羧酸氯化物（例如均苯三酰氯）的有机溶剂溶液接触足以在载体材料的表面上形成界面聚合反应产物的时间。 然后将所得的半透膜在固化条件下固化以形成所需的复合材料。 所得到的膜复合物可用于分离过程，例如咸水或海水的脱盐，该膜可耐受水中存在的氯的侵蚀。
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3.发明授权
公开(公告)号：US4627859A
公开(公告)日：1986-12-09
申请号：US702172
申请日：1985-02-15
CPC分类号： C08K5/0091 , B01D69/142 , B01D71/54 , C01B13/0255 , C08G18/10 , C08L75/00 , C01B2210/0046 , C08G2270/00
摘要： Facilitated gas enrichment membrane composites which are utilized in the separation of gases or gas enrichment of a gas mixture will comprise an organometallic compound which acts as a gas carrier interdispersed in an interpenetrating polymer network matrix. The network matrix which comprises the reaction product of an isocyanate-capped polymer physically entwined with a nitrogen-containing compound will be nonacidic and hydrophobic in nature.
摘要翻译： 用于分离气体或气体混合物的气体富集的便利气体富集膜复合材料将包含有机金属化合物，其作为分散在互穿聚合物网络基质中的气体载体。 包含与含氮化合物物理缠结的异氰酸酯封端的聚合物的反应产物的网络矩阵本质上是非酸性和疏水性的。
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公开(公告)号：US4919808A
公开(公告)日：1990-04-24
申请号：US789682
申请日：1985-10-21
CPC分类号： B01D69/125 , B01J13/16
摘要： Semipermeable membranes which may be used in a variety of separation processes such as desalination, sugar separation, etc. are prepared by contacting a porous support backing material such as polysulfone with an aqueous solution of a hydrazine compound. The coated support material is then contacted with an organic solution of an aromatic polycarboxylic acid chloride whereby an interfacial polymerized condensation reaction product is formed on the surface of the support. The thus formed composite is then cured at an elevated temperature and recovered.
摘要翻译： 通过使诸如聚砜的多孔载体背衬材料与肼化合物的水溶液接触，可制备可用于各种分离方法如脱盐，糖分离等的半透膜。 然后将涂覆的载体材料与芳族多羧酸氯化物的有机溶液接触，由此在载体的表面上形成界面聚合的缩合反应产物。 然后将如此形成的复合材料在升高的温度下固化并回收。
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公开(公告)号：US4747953A
公开(公告)日：1988-05-31
申请号：US831672
申请日：1986-02-21
CPC分类号： C13K1/04 , B01D69/125 , B01D71/44 , B01D71/54 , C08G18/10 , C08L75/08 , C08G2270/00 , C08L2205/04
摘要： Semipermeable composite membranes which comprise an interpenetrating polymer network of the isocyanate-capped polymer which is the reaction product of a polyether and an isocyanate with a copolymer containing at least two saturated or unsaturated heterocyclic nitrogen-containing compounds composited on a porous backing support material may be used in various separation systems. These separation systems may include reverse osmosis, ultrafiltration, gas separation, dialysis, etc., an especially useful system being the separation of sugars.
摘要翻译： 包含异氰酸酯封端的聚合物的互穿聚合物网络的半透性复合膜，其是聚醚和异氰酸酯与含有至少两种在多孔背衬载体材料上复合的饱和或不饱和杂环含氮化合物的共聚物的反应产物，可以是 用于各种分离系统。 这些分离系统可以包括反渗透，超滤，气体分离，透析等，是分离糖的特别有用的系统。
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公开(公告)号：US4664761A
公开(公告)日：1987-05-12
申请号：US814339
申请日：1985-12-27
CPC分类号： H01M8/1023 , B01D53/228 , B01D53/326 , B01D67/0006 , B01D67/0079 , B01D69/12 , B01D69/141 , B01D71/38 , C01B3/503 , C01B3/505 , C01B3/58 , G01N27/4074 , H01M8/1007 , H01M8/1044 , H01M8/1048 , B01D2313/345 , B01D2313/365 , B01D2323/30 , B01D2325/10 , B01D67/0072 , B01D71/022 , C01B2203/0405 , C01B2203/0435 , C01B2203/048
摘要： Apparatus and method for performing an electrochemical process involving hydrogen and gaseous compounds capable of dissociating into or combining with hydrogen ions using a solid electrolyte concentration cell. Specific applications are fuel cells for producing an electrical current and separation of hydrogen from a gaseous mixture. A novel proton-conducting membrane comprised of an interpenetrating polymer network serves as the solid electrolyte. For increased strength, a membrane may be composited with or utilized with a porous support.
摘要翻译： 使用固体电解质浓度电池进行能够离解成氢离子或与氢离子结合的氢和气态化合物的电化学方法的装置和方法。 具体应用是用于产生电流和从气体混合物中分离氢的燃料电池。 由互穿聚合物网构成的新型质子传导膜用作固体电解质。 为了增加强度，膜可与多孔载体复合或与其一起使用。
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公开(公告)号：US4613440A
公开(公告)日：1986-09-23
申请号：US670187
申请日：1984-11-13
CPC分类号： B01D69/125 , B01D71/44 , B01D71/54 , C08G18/10 , C08L75/08 , C08G2270/00 , C08L2205/04
摘要： Semipermeable composite membranes which comprise an interpenetrating polymer network of the reaction product of a polyether and an isocyanate with a heterocyclic nitrogen-containing compound composited on a porous backing support material may be used in separation systems such as reverse osmosis, ultrafiltration, gas separation, dialysis, etc. The membranes of the present invention will permit the separation process to be efficient in an effective manner.
摘要翻译： 包含聚醚和异氰酸酯的反应产物的互穿聚合物网络与复合在多孔背衬支撑材料上的杂环含氮化合物的可渗透复合膜可以用于分离系统如反渗透，超滤，气体分离，透析 等等。本发明的膜将允许分离过程以有效的方式有效。
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公开(公告)号：US5025079A
公开(公告)日：1991-06-18
申请号：US377507
申请日：1989-07-10
申请人： Joseph J. Zupancic , Raymond J. Swedo , Donald R. Jamieson , Elaine F. Schumacher , Allyson J. Buehler
发明人： Joseph J. Zupancic , Raymond J. Swedo , Donald R. Jamieson , Elaine F. Schumacher , Allyson J. Buehler
IPC分类号： C08F22/40 , C08F22/36 , C08F222/40 , C08G73/00 , C08G73/12 , C08J5/04 , C08J5/24 , C08L79/00
CPC分类号： C08G73/125 , C08F222/40 , C08G73/124 , Y10T428/31721
摘要： APO-BMI is a chain-extended with certain diamines to provide thermosetting resins retaining the improved properties of APO-BMI resins, but having increased toughness in the cured resins.
摘要翻译： APO-BMI是与某些二胺链延长以提供热固性树脂，其保持了APO-BMI树脂的改进性能，但具有增加的固化树脂的韧性。
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公开(公告)号：US4772394A
公开(公告)日：1988-09-20
申请号：US898074
申请日：1986-08-20
CPC分类号： B01D69/125 , B01D71/56 , C08G69/32 , C08G69/48 , Y10T428/31536 , Y10T428/31725
摘要： Chlorine-resistant semipermeable membranes which comprise an interfacial polymerized reaction product composited on a porous support backing material may be prepared by contacting a porous support material such as polysulfone with an aqueous solution of an aromatic polyamine containing a chlorine substituent on the aromatic ring. The coated support material is then contacted with an organic solvent solution of aromatic polycarboxylic acid chloride for a period of time sufficient to form an interfacial polymerized reaction product on the surface of the support material. The resultant membrane composite may be used in separation processes such as desalination of brackish or sea water, the membrane being resistant to attack by chlorine which is present in the water.
摘要翻译： 包含复合在多孔载体背衬材料上的界面聚合反应产物的耐氯半透膜可以通过使诸如聚砜的多孔载体材料与芳族环上含有氯取代基的芳族多胺的水溶液接触来制备。 然后将涂覆的载体材料与芳族多羧酸氯化物的有机溶剂溶液接触足以在载体材料的表面上形成界面聚合反应产物的时间。 所得到的膜复合物可用于分离过程，例如咸水或海水的脱盐，该膜可耐受水中存在的氯的侵蚀。
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公开(公告)号：US4708981A
公开(公告)日：1987-11-24
申请号：US807727
申请日：1985-12-11
IPC分类号： B01D69/14 , B01D71/00 , B01D71/38 , B01D71/40 , C08L29/04 , C08L33/02 , C08L41/00 , C08L43/02
CPC分类号： B01D71/40 , B01D69/141 , B01D71/00 , B01D71/38 , Y10S525/903
摘要： Water-insoluble proton-conducting polymers which may be formed into membranes which are used in gas separation or gas sensing processes comprise an interpenetrating polymer network. This IPN is formed from the interaction between a host polymer and a guest polymer which is subsequently cross-linked or cured. The host polymer blend is formed from a phosphoric acid or sulfuric acid and a polymer or copolymer of a compound which possesses repeat units such as, for example, hydroxy ethylene, vinyl sulfonic acid, ethylene imine, etc, while the guest polymer is formed from a monofunctional monomer such as methacrylic acid and a difunctional cross-linking agent such as methylenebisacrylamide.
摘要翻译： 可以形成为用于气体分离或气体检测方法的膜的水不溶性质子导电聚合物包括互穿聚合物网络。 该IPN由主体聚合物和随后交联或固化的客体聚合物之间的相互作用形成。 主体聚合物共混物由磷酸或硫酸和具有重复单元的化合物的聚合物或共聚物形成，所述化合物具有重复单元，例如羟基乙烯，乙烯基磺酸，乙烯亚胺等，而客体聚合物由 单官能单体如甲基丙烯酸和双功能交联剂如亚甲基双丙烯酰胺。
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