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公开(公告)号：US20200091082A1
公开(公告)日：2020-03-19
申请号：US16558740
申请日：2019-09-03
IPC分类号： H01L23/532 , H01L23/522 , H01L21/288 , H01L21/768 , C01B32/184
摘要： The present disclosure is related to a method of fabricating a stacked nanographene structure which is assembled into quantum wires or ribbons. While it has been demonstrated that nanowires can be fabricated from various raw carbon materials including PAHs, research and industry has not produced a self-assembled nanowire produced from asphaltene materials that exhibits a metallic character and electronic structure. The following methods and materials can be used to produce new class of materials consisting of a self-assembled quantum wire out of asphaltene.
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公开(公告)号：US08480881B2
公开(公告)日：2013-07-09
申请号：US12814012
申请日：2010-06-11
CPC分类号： C10G45/24 , C07D333/76 , C10G1/00 , C10G1/002 , C10G45/28 , C10G45/30 , C10G2300/107 , C10L1/04 , C10L2200/0438 , C10L2270/026 , C10L2290/24
摘要： A method and a product made by treating a sulfur-containing hydrocarbon heavy feed, e.g., heavy crude asphaltene reduction is disclosed herein. The method comprises the steps of: mixing the sulfur-containing hydrocarbon heavy feed with a hydrogen donor solvent and an acidified silica to form a mixture and oxidizing the sulfur in the mixture at a temperature between 50° C. and 210° C., wherein the oxidation lowers the amount sulfur in the sulfur-containing hydrocarbon heavy feed by at least 90%.
摘要翻译： 本文公开了通过处理含硫烃重原料（例如重质粗沥青质还原）制备的方法和产品。 该方法包括以下步骤：将含硫烃重原料与氢供体溶剂和酸化二氧化硅混合以形成混合物并在50℃至210℃的温度下氧化混合物中的硫，其中 氧化剂将含硫烃重质原料中的硫含量降低至少90％。
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公开(公告)号：US20110017098A1
公开(公告)日：2011-01-27
申请号：US12830198
申请日：2010-07-02
CPC分类号： C02F1/281 , C02F2101/308 , C02F2103/30
摘要： The present invention describes the use of clay (palygorskite) to concurrently remove indigo dye and salts from the wastewater and subsequent conversion of recovery by-products into Maya blue, an organic-inorganic hybrid pigment with applications in the paint and coating industry. The present invention provides an attractive alternative to discharging the untreated effluent into municipal treatment plants or the environment through the production of a secondary commercial product from waste stream through a by-product synergy process.
摘要翻译： 本发明描述了使用粘土（坡缕石）同时从废水中去除靛蓝染料和盐，随后将回收副产物转化成玛雅蓝，这是在涂料和涂料工业中应用的有机 - 无机混合颜料。 本发明提供了一种有吸引力的替代方案，其通过从废物流通过副产物协同过程生产次级商业产品将未经处理的流出物排放到市政处理厂或环境中。
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公开(公告)号：US20100314286A1
公开(公告)日：2010-12-16
申请号：US12814012
申请日：2010-06-11
IPC分类号： C10L1/04 , C10G45/00 , C10G45/10 , C10G45/04 , C01B17/033
CPC分类号： C10G45/24 , C07D333/76 , C10G1/00 , C10G1/002 , C10G45/28 , C10G45/30 , C10G2300/107 , C10L1/04 , C10L2200/0438 , C10L2270/026 , C10L2290/24
摘要： A method and a product made by treating a sulfur-containing hydrocarbon heavy feed, e.g., heavy crude asphaltene reduction is disclosed herein. The method comprises the steps of: mixing the sulfur-containing hydrocarbon heavy feed with a hydrogen donor solvent and an acidified silica to form a mixture and oxidizing the sulfur in the mixture at a temperature between 50° C. and 210° C., wherein the oxidation lowers the amount sulfur in the sulfur-containing hydrocarbon heavy feed by at least 90%.
摘要翻译： 本文公开了通过处理含硫烃重原料（例如重质粗沥青质还原）制备的方法和产品。 该方法包括以下步骤：将含硫烃重原料与氢供体溶剂和酸化二氧化硅混合以形成混合物并在50℃至210℃的温度下氧化混合物中的硫，其中 氧化剂将含硫烃重质原料中的硫含量降低至少90％。
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公开(公告)号：US5186818A
公开(公告)日：1993-02-16
申请号：US743957
申请日：1991-08-12
申请人： Michel Daage , Russell R. Chianelli
发明人： Michel Daage , Russell R. Chianelli
摘要： The hydrotreating of petroleum feedstock is improved by using a layered transition metal catalyst, a mixture of such catalysts or a stocked bed of transition metal catalysts that has a selected ratio of edge to rim sites sufficient to provide a product having a predetermined sulfur and nitrogen content.In another aspect of the present invention, there is provided a method for selecting a transition metal catalyst system for use in hydrotreating nitrogen and sulfur containing feedstocks to provide a hydrotreated product having a predetermined nitrogen and sulfur content and at a predetermined reaction residence time, which method comprises: selecting the amount of sulfur and nitrogen to be removed from a given feedstock by hydrotreating to obtain a product having a predetermined nitrogen and sulfur content; determining the variation in the reaction kinetics for sulfur and nitrogen removal of the given feedstock by hydrotreating with a transition metal catalyst of varying edge to rim ratios; selecting, for a predetermined reaction residence time, that ratio from the varying edge to rim ratios of the transition metal catalyst that provides the requisite sulfur and nitrogen removal to provide the product of predetermined sulfur and nitrogen content.
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16.发明授权Hydrotreating catalysts comprising a mixture of a sulfide of a promoter metal, amorphous sulfide of trivalent chromium and microcrystalline molybdenum or tungsten sulfide 失效包含助催化剂金属硫化物，三价铬的无定形硫化物与微晶钼或硫化钨的混合物的加氢处理催化剂
公开(公告)号：US4824820A
公开(公告)日：1989-04-25
申请号：US100479
申请日：1987-09-24
IPC分类号： B01J27/047 , C10G49/04
CPC分类号： B01J27/047 , C10G49/04
摘要： A composition of matter comprising a mixture of (i) a sulfide of at least one promoter metal selected from the group consisting of Ni, Co, Mn, Cu, Zn and mixture thereof and mixtures thereof with Fe, (ii) an amorphous sulfide of trivalent chromium and (iii) microcrystallites of metal sulfide of a metal selected from the group consisting of molybdenum, tungsten and mixture thereof. These compositions have been found to be useful hydrotreating catalysts having nitrogen removal activity superior to that of commercial catalysts such as cobalt-molybdate on alumina.
摘要翻译： 一种物质组合物，其包含（i）选自Ni，Co，Mn，Cu，Zn及其混合物中的至少一种助催化剂金属的硫化物及其与Fe的混合物的混合物，（ii） 三价铬和（iii）选自钼，钨及其混合物的金属的金属硫化物的微晶。 已经发现这些组合物是具有优于在氧化铝上的商业催化剂如钼酸钴的除氮活性的有用的加氢处理催化剂。
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17.发明授权Process for preparing a supported, promoted molybdenum and/or tungsten sulfide hydroprocessing catalyst 失效制备负载，促进的钼和/或硫化钨加氢催化剂的方法
公开(公告)号：US4801570A
公开(公告)日：1989-01-31
申请号：US008008
申请日：1987-01-29
IPC分类号： B01J27/047 , B01J37/20 , C10G45/04 , C10G45/08 , B01J27/049 , B01J27/051
CPC分类号： B01J37/20 , B01J27/047 , C10G45/04 , C10G45/08
摘要： This invention relates to the preparation and use of supported, manganese sulfide promoted molybdenum and tungsten sulfide catalysts useful for hydroprocessing processes, particularly hydrotreating. These catalysts are prepared by heating a composite of support material and precursor salt under oxygen-free conditions and in the presence of sulfur, wherein said precursor salt contains a thiometallate anion of Mo, W or mixture thereof and a cation comprising one or more promoter metals which are chelated by at least one neutral, nitrogen-containing polydentate ligand, and wherein said promoter metal comprises Mn alone or a mixture of Mn with Co, Ni, Zn, Cu or mixture thereof.
摘要翻译： 本发明涉及用于加氢处理工艺，特别是加氢处理的负载型硫化锰促进的钼和硫化钨催化剂的制备和用途。 这些催化剂通过在无氧条件和硫存在下加热载体材料和前体盐的复合物而制备，其中所述前体盐含有Mo，W或其混合物的金属硫酸盐阴离子和包含一种或多种助催化剂金属的阳离子 其由至少一种中性的含氮多齿配体螯合，并且其中所述促进剂金属包含单独的Mn或Mn与Co，Ni，Zn，Cu或其混合物的混合物。
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18.发明授权Supported transition metal sulfide promoted molybdenum or tungsten sulfide catalysts and their uses for hydroprocessing 失效负载过渡金属硫化物促进了钼或硫化钨催化剂及其在加氢处理中的应用
公开(公告)号：US4755496A
公开(公告)日：1988-07-05
申请号：US44347
申请日：1987-04-30
IPC分类号： B01J27/047 , B01J37/20 , C10G45/04 , C10G45/08 , B01J31/22
CPC分类号： B01J27/047 , B01J37/20 , C10G45/04 , C10G45/08
摘要： Hydrocarbon feeds are upgraded by contacting a feed, at elevated temperature and in the presence of hydrogen, with a supported self-promoted catalyst prepared by heating a composite of support material and one or more catalyst precursor salts under oxygen-free conditions and in the presence of sulfur at a temperature of at least about 250.degree. C. The precursor salt or salts will be of the general formula (ML) (Mo.sub.y W.sub.1-y S.sub.4) wherein M comprisess one or more promoter metals selected from the group consisting essentially of Mn, Fe, Co, Ni, Zn and mixtures thereof, wherein y is any value ranging from 0 to 1 and wherein L is one or more neutral, nitrogen-containing ligands at least one of which is a chelating, polydentate ligand.
摘要翻译： 通过在升高的温度和在氢的存在下使进料接触与在无氧条件下和在存在下加热载体材料和一种或多种催化剂前体盐的复合物而制备的负载型自促进催化剂来提高烃进料 的硫在至少约250℃的温度下。前体盐或盐将具有通式（ML）（MoyW1-yS4），其中M包含一种或多种助催化剂金属，其选自基本上由Mn，Fe ，Co，Ni，Zn及其混合物，其中y是0至1的任何值，并且其中L是一种或多种中性含氮配体，其中至少一种是螯合多齿配体。
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公开(公告)号：US4622128A
公开(公告)日：1986-11-11
申请号：US656146
申请日：1984-09-28
CPC分类号： C10G45/08 , B01J23/24 , B01J27/047 , B01J37/20 , C10G45/04
摘要： Supported hydroprocessing catalysts comprising a sulfide of trivalent chromium and Mo, W or mixture thereof are obtained by compositing a preselected quantity of support material with a precursor comprising a mixture of (i) a hydrated oxide of trivalent chromium and (ii) a salt containing a thiometallate anion of Mo or W and a cation comprising the conjugate acid of at least one neutral, nitrogen-containing polydentate ligand and heating the composite in the presence of sulfur and hydrogen in an oxygen-free atmosphere. These compositions have been found to be useful hydrotreating catalysts having nitrogen removal activity superior to that of commercial catalysts derived from cobalt molybdate on alumina.
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公开(公告)号：US4508847A
公开(公告)日：1985-04-02
申请号：US552404
申请日：1983-11-16
摘要： Catalysts comprising a carbon-containing sulfide of molybdenum or tungsten are prepared by contacting, in the presence of sulfur, hydrogen and a hydrocarbon, ammonia and ammonium substituted molybdate, thiomolybdate, tungstate and thiotungstate salts at a temperature of from about 200.degree.-600.degree. C. These catalysts are useful for hydrotreating reactions. In a preferred embodiment, these catalysts will be promoted with certain transition metal sulfides, such as cobalt sulfide, which results in catalysts having greater activity than conventional catalysts such as cobaltmolybdate on alumina.
摘要翻译： 包含钼或钨的含碳硫化物的催化剂通过在硫，氢和烃，氨和铵取代的钼酸盐，硫钼酸盐，钨酸盐和硫代钨酸盐的存在下，在约200-600℃的温度下接触来制备 这些催化剂可用于加氢处理反应。 在优选的实施方案中，这些催化剂将被某些过渡金属硫化物如硫化钴促进，这导致催化剂比常规催化剂如氧化铝上的钼酸钼具有更大的活性。
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