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    DIHYDROTHIOPHENE DERIVATIVES AS INSECTICIDAL COMPOUNDS
    12.
    发明申请
    DIHYDROTHIOPHENE DERIVATIVES AS INSECTICIDAL COMPOUNDS 审中-公开
    作为杀虫剂化合物的二氢苯并噻吩衍生物

    公开(公告)号：US20150272120A1

    公开(公告)日：2015-10-01

    申请号：US14441304

    申请日：2013-11-08

    Applicant: SYNGENTA PARTICIPATIONS AG

    Inventor： Myriem El Qacemi ,  Jerome Yves Cassayre ,  Guillaume Berthon ,  Girish Rawal ,  Rupesh Patre

    IPC: A01N43/10 ,  C07D333/24 ,  C07D409/12 ,  A01N43/20 ,  A01N43/653 ,  A01N43/80 ,  A01N43/40 ,  C07D333/32 ,  C07D333/48 ,  C07D409/10 ,  C07D333/40 ,  C07D413/12

    CPC classification number: A01N43/10 ,  A01N37/10 ,  A01N43/20 ,  A01N43/40 ,  A01N43/653 ,  A01N43/80 ,  C07D333/24 ,  C07D333/32 ,  C07D333/38 ,  C07D333/40 ,  C07D333/48 ,  C07D409/10 ,  C07D409/12 ,  C07D413/12

    Abstract: The present invention provides compounds of formula (I) wherein Q is Q1 or Q2 P is P0, heterocyclyl or heterocyclyl substituted by one to five Z; Y1, Y2, Y3 and Y4 are independently of each other C—H, C—R5, or nitrogen; G1 is oxygen or sulfur; R1 is hydrogen, C1-C8alkyl, C1-C8alkoxy-, C1-C8alkylcarbonyl-, or C1-C8alkoxycarbonyl-; X4 is C1-C8haloalkyl; R4 is aryl or aryl substituted by one to five R9, or heteroaryl or heteroaryl substituted by one to five R9; n is 0, 1 or 2; and Z, R2, R5 and R9 are as defined in the claims. The invention also provides methods of controlling insects, acarines, nematodes or molluscs comprising applying to a pest, to a locus of a pest, or to a plant susceptible to attack by a pest an insecticidally, acaricidally, nematicidally or molluscicidally effective amount of a compound of formula (I).

    Abstract translation: 本发明提供式（I）化合物，其中Q为Q 1或Q 2为PO，杂环基或被1至5个Z取代的杂环基; Y1，Y2，Y3和Y4彼此独立地为C-H，C-R5或氮; G1是氧或硫; R 1是氢，C 1 -C 8烷基，C 1 -C 8烷氧基 - ，C 1 -C 8烷基羰基 - 或C 1 -C 8烷氧基羰基 - X4是C1-C8卤代烷基; R4是被1至5个R9取代的芳基或芳基，或被1至5个R9取代的杂芳基或杂芳基; n为0,1或2; 并且Z，R2，R5和R9如权利要求中所定义。 本发明还提供了控制昆虫，螨虫，线虫或软体动物的方法，其包括将有害生物施用于有害生物的场所或易受害虫攻击的植物，杀虫剂，杀螨剂，杀线虫剂或杀软体动物剂有效量的化合物 的式（I）化合物。

    METHODS OF CONTROLLING INSECTS
    13.
    发明申请
    METHODS OF CONTROLLING INSECTS 有权
    控制方法

    公开(公告)号：US20150250178A1

    公开(公告)日：2015-09-10

    申请号：US14423226

    申请日：2013-08-09

    Applicant: Syngenta Participations AG

    Inventor： Myriem El Qacemi ,  Jerome Yves Cassayre

    IPC: A01N43/80 ,  C07D413/12 ,  G06Q30/00 ,  C07D261/04

    CPC classification number: A01N43/80 ,  C07D261/04 ,  C07D413/12 ,  G06Q30/018

    Abstract: The present invention provides methods comprising applying to a crop of rice plants, the locus thereof, or propagation material thereof, a compound of formula (I): wherein —B1—B2—B3— is —C═N—O—, —C═N—CH2—, —C═CH2—O— or —N—CH2—CH2—; L is a direct bond or methylene; A1 and A2 are C—H, or one of A1 and A2 is C—H and the other is N; X1 is group X R1 is C1-C4alkyl, C1-C4haloalkyl or C3-C6cycloalkyl; R2 is chlorodifluoromethyl or trifluoromethyl; each R3 is independently bromo, chloro, fluoro or trifluoromethyl; R4 is hydrogen, halogen, methyl, halomethyl or cyano; R5 is hydrogen; or R4 and R5 together form a bridging 1,3-butadiene group; p is 2 or 3. Preferably the methods are for control of stemborer, leaffolder, hoppers, Gall midge, whorl maggot, Rice bugs, and/or Black bugs.

    Abstract translation: 本发明提供了一种方法，其包括向一系列水稻植物，其基因座或其繁殖材料施用式（I）化合物：其中-B1-B2-B3-为-C = N-O-，-C = N-CH 2 - ， - C = CH 2 -O-或-N-CH 2 -CH 2 - ; L是直接键或亚甲基; A1和A2是C-H，A1和A2之一是C-H，另一个是N; X1是基团XR1是C1-C4烷基，C1-C4卤代烷基或C3-C6环烷基; R2是氯二氟甲基或三氟甲基; 每个R 3独立地是溴，氯，氟或三氟甲基; R4是氢，卤素，甲基，卤代甲基或氰基; R5是氢; 或R4和R5一起形成桥连1,3-丁二烯基团; p是2或3.优选地，这些方法用于控制stemborer，leaffolder，料斗，Gall midge，螺旋蛆，稻米虫和/或黑虫。

    METHODS OF SOIL PEST CONTROL
    14.
    发明申请
    METHODS OF SOIL PEST CONTROL 有权
    土壤病虫害控制方法

    公开(公告)号：US20150208655A1

    公开(公告)日：2015-07-30

    申请号：US14423177

    申请日：2013-08-09

    Applicant: Syngenta Participations AG

    Inventor： Myriem El Qacemi ,  Jerome Yves Cassayre ,  Benedikt Kurtz

    IPC: A01N43/80 ,  G06Q30/00

    CPC classification number: A01N43/80 ,  G06Q30/018

    Abstract: The present invention relates to methods of controlling and/or preventing soil-dwelling pests in useful plants comprising applying to the locus of the useful plant or treating plant propagation material thereof with a compound of formula (I) wherein —B1—B2—B3— is —C═N—O—, —C═N—CH2—, —C═CH2—O— or —N—CH2—CH2—; L is a direct bond or methylene; A1 and A2 are C—H, or one of A1 and A2 is C—H and the other is N; X1 is group X, formula (X) R1 is C1-C4alkyl, C1-C4aloalkyl or C3-C6cycloalkyl; R2 is chlorodifluoromethyl or trifluoromethyl; each R3 is independently bromo, chloro, fluoro or trifluoromethyl; R4 is hydrogen, halogen, methyl, halomethyl or cyano; R5 is hydrogen; or R4 and R5 together form a bridging 1,3-butadiene group; p is 2 or 3. Preferably the soil-dwelling pest is selected from corn rootworm, wireworms, grubs, in particular white grubs (e.g. Phyllophaga sp., Diloboderus sp., Popillia japonica), termites (in particular for sugar cane), subterraneous stinkbugs (e.g. Scaptocoris sp.), cutworms (e.g. agrotis sp.), millipedes (e.g. Julus sp.) and broca gigante (e.g. Telchin licus).

    Abstract translation: 本发明涉及在有用植物中控制和/或预防土壤存在害虫的方法，其包括用式（I）化合物施用于有用植物的场所或处理植物繁殖材料，其中-B1-B2-B3- 是-C≡N-O-，-C≡N-CH 2 - ， - C = CH 2 -O-或-N-CH 2 -CH 2 - ; L是直接键或亚甲基; A1和A2是C-H，A1和A2之一是C-H，另一个是N; X 1为基团X，式（X）R 1为C 1 -C 4烷基，C 1 -C 4卤烷基或C 3 -C 6环烷基; R2是氯二氟甲基或三氟甲基; 每个R 3独立地是溴，氯，氟或三氟甲基; R4是氢，卤素，甲基，卤代甲基或氰基; R5是氢; 或R4和R5一起形成桥连1,3-丁二烯基团; p为2或3.优选地，土壤有害生物选自玉米根虫，线虫，gr s，特别是白ub（如Phyllophaga sp。，Diloboderus sp。，Popillia japonica），白蚁（特别是甘蔗），subterraneous 臭椿（例如鳞翅目（Scaptocoris sp。）），夜蛾（例如ag is属），千足虫（例如茱萸属）和布鲁卡甘（例如，Telchin licus）。

    METHODS OF CONTROLLING INSECTS
    15.
    发明申请
    METHODS OF CONTROLLING INSECTS 审中-公开

    公开(公告)号：US20150189884A1

    公开(公告)日：2015-07-09

    申请号：US14422847

    申请日：2013-08-16

    Applicant: Syngenta Participations AG

    Inventor： Myriem El Qacemi ,  Jerome Yves Cassayre

    IPC: A01N43/80 ,  C07D207/08 ,  C07D413/10 ,  A01N43/653 ,  C07D403/10 ,  C07D207/20 ,  A01N43/36 ,  C07D261/04

    CPC classification number: A01N43/80 ,  A01N43/36 ,  A01N43/653 ,  C07D207/08 ,  C07D207/20 ,  C07D261/04 ,  C07D403/10 ,  C07D413/10

    Abstract: The present invention provides a method comprising applying to a crop of cotton plants, the locus thereof, or propagation material thereof, a compound of formula (I) wherein -B1-B2-B3- is —C═N—O—, —C═N—CH2—, or —N—CH2—CH2—; R1 is trifluoromethyl, difluoromethyl or chlorodifluoromethyl; R2 is group X formula (X) X2 is C—X6 or nitrogen; X1, X3 and X6 are independently hydrogen, halogen or trihalomethyl, wherein at least one of X1, X3 and X6 is not hydrogen; A is selected from A1 to A (A5) B is C—R6, CH or nitrogen; 1Y2 and Y3 are independently CH or nitrogen; wherein no more than two of Y1, Y2 and Y3 are nitrogen and wherein Y2 and Y3 are not both nitrogen; R is hydrogen, halogen, cyano, nitro, NH2, C1-C4alkyl, C1-C4haloalkyl, C3-C5 cycloalkyl, C3-C5 halocycloalkyl, C1-C2 alkoxy, or C1-C2 haloalkoxy; provided that when A is A3 or A4 R5 is not hydrogen; R6 when present together with R5 forms a —CH═CH—CH═CH-bridge; R7 is C1-C4 alkyl;) R8 is C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy(C1-C4)alkyl, C1-C4 alkylthio(C1-C4)alkyl, C1-C4 alkylsulfinyl(C1-C4)alkyl, alkylsulfonyl(C1-C4) alkyl, C3-C6 cycloalkyl, C3-C6 cycloalkyl(C1-C4)alkyl-, or tetrahydrofuranyl; R9 is C1-C4alkyl, C1-C4haloalkyl, C1-C4 alkyl-O—CH2—, C1-C4 haloalkyl-O—CH2—, C3-C6 cycloalkyl, C3-C6 cycloalkyl-CH2—, alkyl-S—CH2—, C1-C4 alkyl-S(O)—CH2—, or C1-C4 alkyl-S(O2)—CH2; each Z is independently halogen, C1-C12 alkyl or C1-C12 alkyl substituted by one to five R12, nitro, C1-C12 alkoxy or C1-C12 alkoxy substituted by one to five R12 cyano, C1-C12alkylsulfinyl, C1-C12alkylsulfonyl, C1-C12haloalkylsulfinyl, C1-C12haloalkylsulfonyl, hydroxyl or thiol; each R12 is halogen, cyano, nitro, hydroxy, C1-C8alkoxy-, C1-C8haloalkoxy-, mercapto, C1-C8alkylthio-, or C1-C8haloalkylthio; and k is 0, 1, 2 or 3. The methods are preferably for the control of Anthonomus grandis.

    INSECTICIDAL COMPOUNDS
    16.
    发明申请
    INSECTICIDAL COMPOUNDS 有权
    杀虫剂化合物

    公开(公告)号：US20150111944A1

    公开(公告)日：2015-04-23

    申请号：US14574877

    申请日：2014-12-18

    Applicant: Syngenta Participations AG ,  Syngenta Limited

    Inventor： Peter Renold ,  Jerome Yves Cassayre ,  Myriem El Qacemi ,  Jagadish Pabba ,  Thomas Pitterna

    IPC: C07D409/12 ,  C07D207/20 ,  A01N43/36

    CPC classification number: C07D409/12 ,  A01N43/36 ,  C07D207/20 ,  C07D401/04 ,  C07D403/04 ,  C07D409/14 ,  C07F7/0812

    Abstract: The invention relates to compounds of formula (I): where A1, A2, A3, A4, G, R1, R2, R3 and R4 are as defined in claim 1; or a salt or N-oxide thereof.Furthermore, the present invention relates to processes and intermediates for preparing compounds of formula (I), to insecticidal, acaricidal, nematicidal and molluscicidal compositions comprising the compounds of formula (I) and to methods of using the compounds of formula (I) to control insect, acarine, nematode and mollusc pests.

    Abstract translation: 本发明涉及式（I）化合物：其中A1，A2，A3，A4，G，R1，R2，R3和R4如权利要求1所定义; 或其盐或N-氧化物。 此外，本发明涉及制备式（I）化合物的方法和中间体，其包含式（I）化合物的杀虫，杀螨，杀线虫和杀软体动物的组合物和使用式（I）化合物控制的方法 昆虫，螨虫，线虫和软体动物害虫。

    Methods of controlling insects
    19.
    发明授权
    Methods of controlling insects 有权
    防治昆虫的方法

    公开(公告)号：US09320278B2

    公开(公告)日：2016-04-26

    申请号：US14421878

    申请日：2013-08-16

    Applicant: Syngenta Participations AG

    Inventor： Myriem El Qacemi ,  Jerome Yves Cassayre

    IPC: A01N43/80 ,  C07D261/04 ,  G06Q30/00

    CPC classification number: A01N43/80 ,  C07D261/04 ,  G06Q30/018

    Abstract: The present invention relates to methods, preferably for controlling and/or preventing infestation of boll weevil in cotton, comprising applying to a crop of cotton plants, the locus thereof, or propagation material thereof, a compound of formula (I), wherein -B1-B2-B3- is —C═N—O—, —C═N—CH2—, —C═CH—O— or —N—CH2—CH2—; L is a direct bond or methylene; A1 and A2 are C—H, or one of A1 and A2 is C—H and the other is N; X1 is group X R1 is C1-C4alkyl, C1C4aloalkyl or C3-C6cycloalkyl; R2 is chlorodifluoromethyl or trifluoromethyl; each R3 is independently bromo, chloro, fluoro or trifluoromethyl; R4 is hydrogen, halogen, methyl, halomethyl or cyano; R5 is hydrogen; or R4 and R5 together form a bridging 1,3-butadiene group; p is 2 or 3.

    Abstract translation: 本发明涉及优选用于控制和/或预防棉花中的棉铃象鼻虫感染的方法，其包括将棉花植物作物的基因座或其繁殖材料施用于式（I）化合物，其中-B1 -B2-B3-是-C≡N-O-，-C = N-CH2-， - C = OCH-O-或-N-CH2-CH2-; L是直接键合或亚甲基; A1和A2是C-H，A1和A2之一是C-H，另一个是N; X1是基团XR1是C1-C4烷基，C1C4烷基或C3-C6环烷基; R2是氯二氟甲基或三氟甲基; 每个R 3独立地是溴，氯，氟或三氟甲基; R4是氢，卤素，甲基，卤代甲基或氰基; R5是氢; 或R4和R5一起形成桥连1,3-丁二烯基团; p是2或3。

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