公开(公告)号：US08618239B2

公开(公告)日：2013-12-31

申请号：US13627374

申请日：2012-09-26

Applicant: Ticona LLC

Inventor： Steven D. Gray ,  Robert Alan Deck ,  Bing Lu

IPC: C08G64/00 ,  C08G63/02

CPC classification number: C09K19/3809 ,  C08G63/605 ,  C08G63/785 ,  C08G63/80 ,  C08G69/44

Abstract: A multi-stage process for forming a liquid crystalline polymer is provided. More particularly, the process includes acetylating one or more precursor monomers and melt-polymerizing the acetylated monomers to form a prepolymer in the form of a solid particulate material. Thereafter, the prepolymer is solid-state polymerized in a fluidized bed reactor that contains a porous surface (e.g., bed, plate, grate, etc.) on which the prepolymer is supported. While supported by this porous surface, the prepolymer can become “fluidized” with a heated stream of a gas (e.g., nitrogen). In this manner, a sufficient degree of turbulence is created to distribute heat evenly around the prepolymer and cause it to rapidly reach the target reaction temperature.

Abstract translation: 提供了一种用于形成液晶聚合物的多阶段方法。 更具体地，该方法包括乙酰化一种或多种前体单体并使乙酰化单体熔融聚合以形成固体颗粒材料形式的预聚物。 此后，预聚物在流化床反应器中固态聚合，该流化床反应器含有其上载有预聚物的多孔表面（例如床，板，格栅等）。 在由该多孔表面支撑的同时，预聚物可以用加热的气体流（例如氮气）“流化”。 以这种方式，产生足够的湍流以将热量均匀地分布在预聚物周围并使其迅速达到目标反应温度。

公开(公告)号：US20170145208A1

公开(公告)日：2017-05-25

申请号：US15352635

申请日：2016-11-16

Applicant: Ticona LLC

Inventor： Bing Lu ,  Rong Luo ,  Yuehua YU ,  Xinyu Zhao

IPC: C08L61/16

CPC classification number: C08L61/16 ,  C08G65/4012 ,  C08G2650/40 ,  C08L71/00 ,  C08L2205/12 ,  C08L67/02 ,  C08L67/04

Abstract: A polymer composition that contains a polyaryletherketone and thermotropic liquid crystalline polymer, which are melt processed in the presence of a flow modifier. The flow modifier is a functional compound that contains one or more hydroxyl functional groups.

公开(公告)号：US20140299907A1

公开(公告)日：2014-10-09

申请号：US14360016

申请日：2012-04-05

Applicant: Ticona LLC

Inventor： Bing Lu

IPC: C08K5/5333 ,  H01L33/60

CPC classification number: C08K5/5333 ,  C08K5/5317 ,  H01L33/60 ,  H01L2224/48091 ,  H01L2224/48247 ,  C08L67/02 ,  H01L2924/00014

Abstract: Polymer compositions are described that are well suited for producing reflectors for light-emitting devices, such as light-emitting diodes. In one embodiment, the polymer composition contains a polymer resin and a stabilizer comprising a phosphonate compound and/or a phosphate compound and optionally a white pigment. The polymer resin may comprise, for instance, a poly(1,4-cyclohexanedimethanol terephthalate). The phosphate stabilizer has been found to significantly improve the stability of the polymer composition without interfering with the ability of the composition to bond to other polymer materials, such as silicone resins. Silicone resins, for instance, are typically used as an encapsulant for light-emitting diode assemblies.

Abstract translation: 描述了非常适合于生产发光器件如发光二极管的反射器的聚合物组合物。 在一个实施方案中，聚合物组合物含有聚合物树脂和包含膦酸酯化合物和/或磷酸酯化合物和任选的白色颜料的稳定剂。 聚合物树脂可以包括例如聚（1,4-环己烷二甲醇对苯二甲酸酯）。 发现磷酸盐稳定剂显着提高聚合物组合物的稳定性，而不会干扰组合物与其它聚合物材料如有机硅树脂结合的能力。 硅树脂通常用作发光二极管组件的密封剂。

公开(公告)号：US20130085253A1

公开(公告)日：2013-04-04

申请号：US13627374

申请日：2012-09-26

Applicant: Ticona LLC

Inventor： Steven D. Gray ,  Robert Alan Deck ,  Bing Lu

IPC: C08G63/80 ,  B01J8/18 ,  C08G63/06

CPC classification number: C09K19/3809 ,  C08G63/605 ,  C08G63/785 ,  C08G63/80 ,  C08G69/44

Abstract: A multi-stage process for forming a liquid crystalline polymer is provided. More particularly, the process includes acetylating one or more precursor monomers and melt-polymerizing the acetylated monomers to form a prepolymer in the form of a solid particulate material. Thereafter, the prepolymer is solid-state polymerized in a fluidized bed reactor that contains a porous surface (e.g., bed, plate, grate, etc.) on which the prepolymer is supported. While supported by this porous surface, the prepolymer can become “fluidized” with a heated stream of a gas (e.g., nitrogen). In this manner, a sufficient degree of turbulence is created to distribute heat evenly around the prepolymer and cause it to rapidly reach the target reaction temperature.

Abstract translation: 提供了一种用于形成液晶聚合物的多阶段方法。 更具体地，该方法包括乙酰化一种或多种前体单体并使乙酰化单体熔融聚合以形成固体颗粒材料形式的预聚物。 此后，预聚物在流化床反应器中固态聚合，该流化床反应器含有其上载有预聚物的多孔表面（例如床，板，格栅等）。 当由该多孔表面支撑时，预聚物可以用加热的气流（例如氮气）流化。 以这种方式，产生足够的湍流以将热均匀地分布在预聚物周围并使其迅速达到目标反应温度。