公开(公告)号：US5753730A

公开(公告)日：1998-05-19

申请号：US700508

申请日：1991-05-15

申请人： Teruyuki Nagata ,  Koju Okazaki ,  Tohru Miura ,  Nobuyuki Kajimoto ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa ,  Masao Imai

发明人： Teruyuki Nagata ,  Koju Okazaki ,  Tohru Miura ,  Nobuyuki Kajimoto ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa ,  Masao Imai

IPC分类号： B29C33/60 ,  C08G18/38 ,  C08G18/73 ,  C08G18/75 ,  C08G18/76 ,  C08K5/02 ,  C08K5/098 ,  C08K5/19 ,  C08K5/521 ,  C08K5/54 ,  C08L75/04 ,  G02B1/04 ,  C08K5/51

CPC分类号： B29C33/60 ,  C08G18/3863 ,  C08G18/3876 ,  C08G18/73 ,  C08G18/75 ,  C08G18/7628 ,  C08K5/02 ,  C08K5/098 ,  C08K5/19 ,  C08K5/521 ,  C08K5/54 ,  C08L75/04 ,  G02B1/041

摘要： One aspect of the present invention relates to a process for preparing plastic lenses having a high-refractive index comprising forming a mixture containing one or more polyisocyanate compounds; one or more active hydrogen compounds selected from the group consisting of a polyol compound having no sulfur atom, a polyol compound having at least one sulfur atom, and a polythiol compound having at least one sulfur atom in addition to the sulfur atom contained in mercapto group and at least one internal releasing agent and then casting and polymerizing the mixture. A second aspect of the present invention relates to a process for preparing a sulfur-containing urethane resin lens is here disclosed which comprises mixing polyisocyanate having two or more isocyanato groups, polythiol having two or more thiol groups and one or more surface active agent selected from the group consisting of fluorine-containing nonionic surface active agents, silicone-containing nonionic surface active agents, alkyl quaternary ammonium salts and acid phosphoric esters and then cast polymerizing the mixture in a mold made of a glass or a metal. Lenses prepared by the processes are also disclosed.

摘要翻译： 本发明的一个方面涉及一种制备具有高折射率的塑料透镜的方法，包括形成含有一种或多种多异氰酸酯化合物的混合物; 一种或多种选自不含硫原子的多元醇化合物的活性氢化合物，至少一个硫原子的多元醇化合物，以及巯基中含有硫原子以外还具有至少一个硫原子的多硫醇化合物 和至少一种内部脱模剂，然后浇铸和聚合该混合物。 本发明的第二方面涉及一种制备含硫聚氨酯树脂透镜的方法，其包括混合具有两个或多个异氰酸酯基的多异氰酸酯，具有两个或更多个硫醇基的多硫醇和一种或多种选自以下的表面活性剂： 由含氟非离子表面活性剂，含硅氧烷的非离子表面活性剂，烷基季铵盐和酸性磷酸酯组成的组，然后将混合物浇铸在由玻璃或金属制成的模具中。 还披露了由该方法制备的镜片。

公开(公告)号：US5021503A

公开(公告)日：1991-06-04

申请号：US311352

申请日：1989-02-15

申请人： Teruyuki Nagata ,  Koju Okazaki ,  Nobuyuki Kajimoto ,  Tohru Miura ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa

发明人： Teruyuki Nagata ,  Koju Okazaki ,  Nobuyuki Kajimoto ,  Tohru Miura ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa

IPC分类号： C08G18/34 ,  C08G18/38 ,  C08G18/77

CPC分类号： C08G18/3876 ,  C08G18/34 ,  C08G18/775

摘要： The present invention relates to resin useful in preparing plastic lenses having a high refractive index comprising reacting an aliphatic polyisocyanate compounds having at least one sulfur atom with one or more of active hydrogen compounds selected from the group consisting of a polyol, a polythiol having sulfur atoms only in a mercapto groups, and a polythiol having at least one sulfur atom other than in the mercapto groups; lenses containing the above-mentioned resin; and a method for the preparation thereof characterized by adding an internal release agent to the mixture of the above-mentioned raw materials in casting lenses from the resin; and lenses obtained by this method.

公开(公告)号：US5013496A

公开(公告)日：1991-05-07

申请号：US310388

申请日：1989-02-15

申请人： Teruyuki Nagata ,  Koju Okazaki ,  Nobuyuki Kajimoto ,  Tohru Miura ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa

发明人： Teruyuki Nagata ,  Koju Okazaki ,  Nobuyuki Kajimoto ,  Tohru Miura ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa

IPC分类号： G02B1/04 ,  B29C39/02 ,  B29K75/00 ,  B29K105/32 ,  B29L11/00 ,  C08G18/00 ,  C08G18/34 ,  C08G18/38 ,  C08G18/77 ,  C08L75/00

CPC分类号： C08G18/3876 ,  C08G18/34 ,  C08G18/775

摘要： A process for producing a plastic lens having a high refractive index and profile regularity which includes forming a mixture of one or more of sulfur-containing aromatic polyisocyanate compounds, one or more of active hydrogen compounds selected from the group consisting of polyol compounds and polythiol compounds, and at least one internal mold releasing agent. Then subjecting the resulting mixture to casting polymerization, to form the plastic lens.

公开(公告)号：US4929707A

公开(公告)日：1990-05-29

申请号：US305905

申请日：1989-02-03

申请人： Teruyuki Nagata ,  Koju Okazaki ,  Nobuyuki Kajimoto ,  Tohru Miura ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa

发明人： Teruyuki Nagata ,  Koju Okazaki ,  Nobuyuki Kajimoto ,  Tohru Miura ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa

IPC分类号： B29C33/60 ,  B29C39/02 ,  B29K75/00 ,  B29K105/32 ,  B29L11/00 ,  C08G18/30 ,  C08G18/32 ,  C08G18/38 ,  C08G18/77 ,  G02B1/04

CPC分类号： C08G18/775 ,  B29C33/60 ,  C08G18/3863 ,  G02B1/041 ,  B29K2075/00 ,  B29L2011/0016

摘要： Polyurethane base lens resins obtained by reacting one or more of sulfur-containing polyisocyanates compound with one or more of sulfur-containing polyols, and polyurethane base lenses comprising these resins are disclosed.A method for preparing polyurethane base lenses which comprises adding internal mold releasing agents to the mixture of the above polyisocyanates and polyols prior to casting polymerization is also disclosed.

公开(公告)号：US5594088A

公开(公告)日：1997-01-14

申请号：US478653

申请日：1995-06-07

申请人： Teruyuki Nagata ,  Koju Okazaki ,  Tohru Miura ,  Nobuyuki Kajimoto ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa ,  Masao Imai

发明人： Teruyuki Nagata ,  Koju Okazaki ,  Tohru Miura ,  Nobuyuki Kajimoto ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa ,  Masao Imai

IPC分类号： B29C33/60 ,  C08G18/38 ,  C08G18/73 ,  C08G18/75 ,  C08G18/76 ,  C08K5/02 ,  C08K5/098 ,  C08K5/19 ,  C08K5/521 ,  C08K5/54 ,  C08L75/04 ,  G02B1/04 ,  C08G18/32

CPC分类号： C08G18/3863 ,  B29C33/60 ,  C08G18/3876 ,  C08G18/73 ,  C08G18/75 ,  C08G18/7628 ,  C08K5/02 ,  C08K5/098 ,  C08K5/19 ,  C08K5/521 ,  C08K5/54 ,  C08L75/04 ,  G02B1/041

摘要： One aspect of the present invention relates to a process for preparing plastic lenses having a high-refractive index comprising forming a mixture containing one or more polyisocyanate compounds; one or more active hydrogen compounds selected from the group consisting of a polyol compound having no sulfur atom, a polyol compound having at least one sulfur atom, and a polythiol compound having at least one sulfur atom in addition to the sulfur atom contained in mercapto group and at least one internal releasing agent and then casting and polymerizing the mixture.A second aspect of the present invention relates to a process for preparing a sulfur-containing urethane resin lens is here disclosed which comprises mixing polyisocyanate having two or more isocyanato groups, polythiol having two or more thiol groups and one or more surface active agent selected from the group consisting of fluorine-containing nonionic surface active agents, silicone-containing nonionic surface active agents, alkyl quaternary ammonium salts and acid phosphoric esters and then cast polymerizing the mixture in a mold made of a glass or a metal. Lenses prepared by the processes are also disclosed.

摘要翻译： 本发明的一个方面涉及一种制备具有高折射率的塑料透镜的方法，包括形成含有一种或多种多异氰酸酯化合物的混合物; 一种或多种选自不含硫原子的多元醇化合物的活性氢化合物，至少一个硫原子的多元醇化合物，以及巯基中含有硫原子以外还具有至少一个硫原子的多硫醇化合物 和至少一种内部脱模剂，然后浇铸和聚合该混合物。 本发明的第二方面涉及一种制备含硫聚氨酯树脂透镜的方法，其包括混合具有两个或多个异氰酸酯基的多异氰酸酯，具有两个或多个硫醇基的多硫醇和一种或多种选自以下的表面活性剂： 由含氟非离子表面活性剂，含硅氧烷的非离子表面活性剂，烷基季铵盐和酸性磷酸酯组成的组，然后将混合物浇铸在由玻璃或金属制成的模具中。 还披露了由该方法制备的镜片。

公开(公告)号：US5126388A

公开(公告)日：1992-06-30

申请号：US648873

申请日：1991-01-31

申请人： Teruyuki Nagata ,  Koju Okazaki ,  Nobuyuki Kajimoto ,  Tohru Miura ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa

发明人： Teruyuki Nagata ,  Koju Okazaki ,  Nobuyuki Kajimoto ,  Tohru Miura ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa

IPC分类号： G02B1/04 ,  B29C39/02 ,  B29K75/00 ,  B29K105/32 ,  B29L11/00 ,  C08G18/00 ,  C08G18/34 ,  C08G18/38 ,  C08G18/77 ,  C08L75/00

CPC分类号： C08G18/3876 ,  C08G18/34 ,  C08G18/775

摘要： The present invention relates to a process for producing a plastic lens having a high refractive index and profile regularity comprising forming a mixture of one or more of sulfur-containing aromatic polyisocyanate compounds, one or more of active hydrogen compounds selected from the group consisting of polyol compounds and polythiol compounds, and at least one internal mold releasing agent, and subjecting the resulting mixture to casting polymerization, and a plastic lens obtained according to the process.

摘要翻译： 本发明涉及一种具有高折射率和轮廓规律性的塑料透镜的制造方法，包括形成一种或多种含硫芳族多异氰酸酯化合物，一种或多种活性氢化合物的混合物，所述活性氢化合物选自多元醇 化合物和多硫醇化合物，以及至少一种内部脱模剂，并将所得混合物进行浇铸聚合，以及根据该方法获得的塑料透镜。

公开(公告)号：US4946923A

公开(公告)日：1990-08-07

申请号：US310618

申请日：1989-02-15

申请人： Teruyuki Nagata ,  Koju Okazaki ,  Nobuyuki Kajimoto ,  Tohru Miura ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa

发明人： Teruyuki Nagata ,  Koju Okazaki ,  Nobuyuki Kajimoto ,  Tohru Miura ,  Yoshinobu Kanemura ,  Katsuyoshi Sasagawa

IPC分类号： B29C33/60 ,  C08G18/38 ,  C08G18/77 ,  G02B1/04

CPC分类号： C08G18/775 ,  B29C33/60 ,  C08G18/3876 ,  G02B1/041

摘要： Disclosed herein are a novel and highly refractive S-alkyl thiocarbamate base resin useful in preparing lenses and a process for producing the resin comprising reacting one or more of polyisocyanate compounds and one or more of mercapto compound having at least one hydroxyl group, a plastic lens made of the resin, and a process for making a plastic lens of high profile regularity from the resin by using internal mold releasing agents in the casting polymerization process.

公开(公告)号：US4775733A

公开(公告)日：1988-10-04

申请号：US19622

申请日：1987-02-27

申请人： Yoshinobu Kanemura ,  Masao Imai ,  Katsuyoshi Sasagawa ,  Nobuyuki Kajimoto ,  Teruyuki Nagata

发明人： Yoshinobu Kanemura ,  Masao Imai ,  Katsuyoshi Sasagawa ,  Nobuyuki Kajimoto ,  Teruyuki Nagata

IPC分类号： C08G18/72 ,  C08G18/38 ,  C08G18/76 ,  C08G18/77 ,  G02B1/04 ,  C08G18/32 ,  C08G18/34 ,  C08G18/70

CPC分类号： G02B1/04 ,  C08G18/3876 ,  C08G18/7628 ,  C08G18/773

摘要： Disclosed herein are a high-refractivity plastic lens resin obtained by polymerizing under heat at least one polyisocyanate (I): ##STR1## wherein X means a hydrogen, chlorine or bromine atom or a methyl or ethyl group, Z is a hydrogen atom or a methyl group, a stands for an integer of 1-4, b is an integer of 2-4, and a+b is not greater than 6 (a+b.ltoreq.6), with at least one polythiol (II): ##STR2## wherein R means a methyl, ethyl, chloromethyl or bromomethyl group, m stands for an integer of 0-2 and n is 4-m and/or at least one polythiol (III): ##STR3## wherein X means a hydrogen, chlorine or bromine atom or a methyl or ethyl group, Y denotes an oxygen or sulfur atom, r stands for 0 or 1, s is an integer of 0-2, p is an integer of 2-4, q is an integer of 1-4 and p+q is not greater than 6 (p+q.ltoreq.6), in such amounts that the --NCO/--SH molar ratio falls within 0.5-3.0, as well as a lens made of the above resin.

摘要翻译： 本文公开了通过在加热下聚合至少一种多异氰酸酯（I）获得的高折射率塑料透镜树脂：其中X表示氢，氯或溴原子或甲基或乙基，Z是氢 原子或甲基，a表示1-4的整数，b表示2-4的整数，a + b不大于6（a + b <6），至少有一个多硫醇（ II）：其中R表示甲基，乙基，氯甲基或溴甲基，m表示0-2的整数，n表示4-m和/或至少一个多硫醇（III）：（III）其中X表示氢，氯或溴原子或甲基或乙基，Y表示氧或硫原子，r表示0或1，s表示0-2的整数，p表示 2-4，q是1-4的整数，p + q不大于6（p + q

公开(公告)号：US4791185A

公开(公告)日：1988-12-13

申请号：US116959

申请日：1987-11-05

申请人： Yoshinobu Kanemura ,  Katsuyoshi Sasagawa ,  Masao Imai ,  Teruyuki Nagata ,  Nobuyuki Kajimoto

发明人： Yoshinobu Kanemura ,  Katsuyoshi Sasagawa ,  Masao Imai ,  Teruyuki Nagata ,  Nobuyuki Kajimoto

IPC分类号： C08G18/30 ,  C08G18/32 ,  C08G18/38 ,  G02B1/04 ,  C08G18/28 ,  C08G18/77

CPC分类号： G02B1/04 ,  C08G18/3876 ,  G02B1/041

摘要： Disclosed herein is a colorless transparent plastic lens having high refractivity and low dispersion. The lens is light, has heat resistance sufficient for post processing, and is excellent in grinding machinability and impact resistance. It is made of a sulfur-containing urethane resin, which is a polymer of a specific polythiol and a particular polyisocyanate of at least bifunctionality.

摘要翻译： 本文公开了具有高折射率和低分散性的无色透明塑料透镜。 透镜轻巧，具有足够的后处理耐热性，并且具有优良的研磨加工性和耐冲击性。 它由含硫聚氨酯树脂制成，其是特定多硫醇的聚合物和具有至少双官能度的特定多异氰酸酯。