Method for densification of sulfide solid electrolytes

    公开(公告)号:US12125974B1

    公开(公告)日:2024-10-22

    申请号:US18485902

    申请日:2023-10-12

    CPC classification number: H01M10/0562 H01M2300/0068

    Abstract: Disclosed is a sulfide-containing solid electrolyte material with an organic coating, as well as densified pellets containing this solid electrolyte material, a solid electrolyte thereof, and a solid state battery containing the solid electrolyte. According to aspects of the disclosure, the coating comprising a compound of Chemical Formula (1) or Chemical Formula (2) is formed on the surface of a sulfide-containing solid electrolyte material, e.g., the organic coating may comprise a compound having a thiol with a long hydrophobic tail, such as 1-undecanethiol. The coating provides densification of sulfide-containing solid electrolyte materials, and facilitates the ionic and lithium atomic diffusion coefficient at sulfide grain boundaries during pressing, thus achieving the densification of sulfide solid state electrolyte.

    RESISTIVE POLYMER MEMBRANES FOR ENERGY STORAGE DEVICES

    公开(公告)号:US20220013860A1

    公开(公告)日:2022-01-13

    申请号:US17282167

    申请日:2019-10-03

    Abstract: Systems and methods are disclosed for a battery that includes an anode, a separator between the anode and the cathode, a cathode, and a membrane coupled to the separator having a mixed electronic conductor and ionic conductor. A method may include casting a membrane onto a surface, dispersing carbon nanotubes in acetone to form a dispersion, adding a powder and dibutyl phthalate to the dispersion to form a polymer, and mixing the polymer. Another method may include casting a sheet of a composite, removing the sheet, and rinsing the sheet. Another method may further include casting a film, evaporating to form a dry film, and casting a mixture onto the dry film to form a bilayer membrane. Another method may further include casting a cathode, casting a CNT mixture onto the cathode, evaporating the cathode, and rinsing the cathode in ether.

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