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公开(公告)号：US20210091413A1
公开(公告)日：2021-03-25
申请号：US17033186
申请日：2020-09-25
发明人： Ping Liu , Haodong Liu
IPC分类号： H01M10/0568 , H01M10/0525 , H01M10/0567 , H01M10/0569 , H01M4/62 , H01M4/505 , H01M4/525
摘要： A rechargeable battery device, specifically a scalable 3D lithium metal anode, and a method of manufacturing the same is disclosed. The scalable 3D electrode can serve as a lithium (Li) metal host that enables stable lithium metal cycling. Furthermore, the electrode can be fabricated by coating a slurry of well mixed LiNO3, carbon black, and PVDF on a Cu foil. For example, a 3D electrode can include a binder and a plurality of additives, wherein the plurality of additives comprise at least one conductive additive and at least one solid electrolyte interface (SEI) formation additive. The conductive additive can include electronic conductors, where the conductors are selected from a group consisting of carbon black, carbon nanotubes, carbon fibers, vapor grown carbon fiber (VGCF), graphite, and graphene. The SEI formation additives are selected from a group consisting of LiNO3, RbNO3, KNO3, CsNO3, LiFSI, LiAsF6, LiF, Li2O, Li2CO3, Li3PO4, SiO2, and Li3N.
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2.发明申请公开(公告)号：US20220278378A1
公开(公告)日：2022-09-01
申请号：US17632036
申请日：2020-08-01
发明人： James Friend , An Huang , Ping Liu , Haodong Liu , Ofer Manor , Viswanathan Krishnan
摘要： A battery may include a first electrode, a second electrode, an electrolyte, and at least one acoustic device configured to generate acoustic streaming during a charging and/or a discharging of the battery. The charging of the battery may trigger cations from the first electrode to travel through the electrolyte and deposit on the second electrode while the discharging of the battery may trigger cations from the second electrode to travel through the electrolyte and deposit on the first electrode. The acoustic streaming may drive a mixing and/or a turbulent flow of the electrolyte, which may increase a charge rate and/or a discharge rate of the battery by increasing diffusion rate of cations and/or anions. The mixing and/or the turbulent flow may further prevent a formation of dendrites on the first electrode and/or the second electrode by at least homogenizing a distribution of the cations and/or anions in the electrolyte.
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公开(公告)号：US20220158235A1
公开(公告)日：2022-05-19
申请号：US17437778
申请日：2020-03-11
IPC分类号： H01M10/0565 , H01M10/0562 , H01M4/134
摘要： A solid-state battery and process of forming the same is provided. The solid-state battery includes a first metal electrode. The solid-state battery includes a first mixed conductor disposed on the first metal electrode. The first mixed conductor includes a mixture of ionic and electronic conductors. The solid-state battery includes a pure ionic conductor disposed on the first mixed conductor. The solid-state battery includes a second metal electrode disposed on top of the pure ionic conductor.
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公开(公告)号：US20210184210A1
公开(公告)日：2021-06-17
申请号：US17048467
申请日：2019-04-16
发明人： Ping Liu , Haodong Liu
摘要： Materials, designs, methods of manufacture, and devices are provided for an anode material for a rechargeable lithium-ion battery. For example, an anode material may include Li3±xV2±yO5±z. 0≤x≤7, 0≤y≤1, and z may be based on the charge resulting from Li3±x and V2±y. Also, a cell can include a lithiated anode material. The lithiated anode material may include Li3±xV2±yO5±z. The lithiated anode material may be casted on a first substrate to form a lithiated anode, having a separator stacked on the lithiated anode. The separator may include electrolytes. A cathode can be stacked on the separator. The cathode being formed by casting a cathode material on a second substrate.
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公开(公告)号：US20200176822A1
公开(公告)日：2020-06-04
申请号：US16620856
申请日：2018-06-11
发明人： Ping Liu , Byoung-Sun Lee , Xing Xing
IPC分类号： H01M10/0585 , H01M10/056 , H01M10/052 , H01M4/36 , H01M4/40 , H01M4/587 , H01M4/485 , H01M4/38
摘要： Compositions, manufacturing processes, articles of manufacture, and structures/batteries for self-forming batteries and self-healing solid electrolytes are disclosed. Example embodiments include a self-forming battery. The battery may include a first electrode material and a second electrode material. Assembly of the two electrode materials may result in a chemical reaction that forms an electrolyte layer between the two electrode materials.
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公开(公告)号：US12125979B2
公开(公告)日：2024-10-22
申请号：US17437778
申请日：2020-03-11
IPC分类号： H01M10/0565 , H01M4/134 , H01M10/0562 , H01M50/414 , H01M50/434 , H01M50/449 , H01M50/497
CPC分类号： H01M10/0565 , H01M4/134 , H01M10/0562 , H01M50/414 , H01M50/434 , H01M50/449 , H01M50/497 , H01M2300/0071 , H01M2300/008 , H01M2300/0082 , H01M2300/0094
摘要： A solid-state battery and process of forming the same is provided. The solid-state battery includes a first metal electrode. The solid-state battery includes a first mixed conductor disposed on the first metal electrode. The first mixed conductor includes a mixture of ionic and electronic conductors. The solid-state battery includes a pure ionic conductor disposed on the first mixed conductor. The solid-state battery includes a second metal electrode disposed on top of the pure ionic conductor.
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公开(公告)号：US20220013860A1
公开(公告)日：2022-01-13
申请号：US17282167
申请日：2019-10-03
发明人： Ping Liu , Matthew Gonzalez
IPC分类号： H01M50/431 , H01M50/449 , H01M50/403 , H01M10/0565
摘要： Systems and methods are disclosed for a battery that includes an anode, a separator between the anode and the cathode, a cathode, and a membrane coupled to the separator having a mixed electronic conductor and ionic conductor. A method may include casting a membrane onto a surface, dispersing carbon nanotubes in acetone to form a dispersion, adding a powder and dibutyl phthalate to the dispersion to form a polymer, and mixing the polymer. Another method may include casting a sheet of a composite, removing the sheet, and rinsing the sheet. Another method may further include casting a film, evaporating to form a dry film, and casting a mixture onto the dry film to form a bilayer membrane. Another method may further include casting a cathode, casting a CNT mixture onto the cathode, evaporating the cathode, and rinsing the cathode in ether.
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公开(公告)号：US12125974B1
公开(公告)日：2024-10-22
申请号：US18485902
申请日：2023-10-12
发明人： Ping Liu , Junghwa Hong , Mengchen Liu , Ke Zhou , Jeong Woo Oh , Min-Sang Song
IPC分类号： H01M10/0562
CPC分类号： H01M10/0562 , H01M2300/0068
摘要： Disclosed is a sulfide-containing solid electrolyte material with an organic coating, as well as densified pellets containing this solid electrolyte material, a solid electrolyte thereof, and a solid state battery containing the solid electrolyte. According to aspects of the disclosure, the coating comprising a compound of Chemical Formula (1) or Chemical Formula (2) is formed on the surface of a sulfide-containing solid electrolyte material, e.g., the organic coating may comprise a compound having a thiol with a long hydrophobic tail, such as 1-undecanethiol. The coating provides densification of sulfide-containing solid electrolyte materials, and facilitates the ionic and lithium atomic diffusion coefficient at sulfide grain boundaries during pressing, thus achieving the densification of sulfide solid state electrolyte.
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