公开(公告)号：US4822903A

公开(公告)日：1989-04-18

申请号：US866739

申请日：1986-05-27

申请人： Roland Jacques ,  Michel Reppelin ,  Laurent Seigneurin

发明人： Roland Jacques ,  Michel Reppelin ,  Laurent Seigneurin

IPC分类号： C01B33/12 ,  B01J21/00 ,  B01J21/08 ,  B01J27/00 ,  B01J27/12 ,  B01J35/10 ,  C01B33/154 ,  C07C67/00 ,  C07C253/00 ,  C07C253/20 ,  C07C255/33 ,  C07C255/49 ,  C07C255/50 ,  C07C255/53 ,  C07C120/10

CPC分类号： B01J21/08 ,  B01J27/12 ,  B01J35/0026 ,  B01J35/1019 ,  B01J35/1047 ,  B01J35/1061 ,  C01B33/154 ,  C07C253/20

摘要： An improved fluorinated siliceous catalyst, well adapted for the catalytic synthesis of aromatic/aliphatic nitriles from their corresponding formamides, formanilides or amides, is comprised of a plurality of silica particulates, the specific surface of which ranging from about 200 to about 300 m.sup.2 /g, having a total pore volume ranging from about 1 to about 1.5 cm.sup.3 /g, with an average pore diameter ranging from about 100 to about 200 .ANG., having an exchange pH of less than about 3, and with the fluorine content thereof bonded to the silica, expressed in F.sup.31 , ranging from about 0.05 to about 2% by weight based upon the silica, and the sodium content thereof, expressed as Na.sub.2 O, being less than about 1% by weight, also based upon the silica.

摘要翻译： 一种改进的氟化硅质催化剂，其适用于从其相应的甲酰胺，甲酰苯胺或酰胺催化合成芳族/脂族腈，由多种二氧化硅微粒组成，其二氧化硅微粒的比表面积约为200-300m2 / g ，具有约1至约1.5cm 3 / g的总孔体积，平均孔径范围为约100至约200ANGSTROM，交换pH小于约3，并且其含氟量与 基于二氧化硅，以F31计，约0.05至约2重量％，以Na 2 O表示的钠含量小于约1重量％的硅石，也以二氧化硅为基准。

公开(公告)号：US4436669A

公开(公告)日：1984-03-13

申请号：US378191

申请日：1982-05-14

申请人： Roland Jacques ,  Michel Reppelin ,  Laurent Seigneurin

发明人： Roland Jacques ,  Michel Reppelin ,  Laurent Seigneurin

IPC分类号： C07B61/00 ,  B01J21/00 ,  B01J27/12 ,  C07C67/00 ,  C07C253/00 ,  C07C255/32 ,  C07C255/33 ,  C07C255/49 ,  C07C255/50 ,  C07C255/54 ,  C07C120/10

CPC分类号： B01J27/12 ,  C07C253/20

摘要： Aromatic/aliphatic nitriles having the formula:Ar--A--CN (I)wherein Ar is phenyl or substituted phenyl and A is a direct chemical bond or a hydrocarbon having from 1 to 6 carbon atoms, are conveniently prepared by heating to a temperature ranging from about 450.degree. C. to about 550.degree. C. a formamide or formanilide having the formula:Ar--A--NHCHO (II)or an amide having the formulaAr--A--CONH.sub.2 (III)in the presence of a fluorinated siliceous catalyst, said catalyst having been prepared by (i) impregnating a particulate silica containing from about 0.05 to about 2% by weight of fluorine, expressed as F.sup.- bonded to the silica, with a dilute aqueous solution of hydrofluoric acid, said hydrofluoric acid solution having a concentration in HF of less than about 5% by weight, and the ratio by weight of the hydrofluoric acid contained in said aqueous solution thereof to the silica being less than about 5%, followed by (ii) drying the catalyst thus impregnated.

摘要翻译： 具有下式的芳族/脂族腈通过加热至温度范围，方便地制备，其中Ar为苯基或取代苯基，A为直接化学键，或具有1至6个碳原子的烃 具有式Ar-A-NHCHO（II）或具有式Ar-A-CONH 2（III）的酰胺的甲酰胺或甲酰苯胺在氟化硅质催化剂存在下的约450℃至约550℃ 所述催化剂是通过以下步骤制备的：（i）用稀氢氟酸水溶液浸渍含有约0.05至约2重量％的以F-键合到二氧化硅的氟的颗粒状二氧化硅，所述氢氟酸溶液具有 HF中的浓度小于约5重量％，并且所述水溶液中所含的氢氟酸与二氧化硅的重量比小于约5％，随后（ii）干燥所浸渍的催化剂。

公开(公告)号：US4314913A

公开(公告)日：1982-02-09

申请号：US127106

申请日：1980-03-04

申请人： Jean-Yves Derrien ,  Laurent Seigneurin

发明人： Jean-Yves Derrien ,  Laurent Seigneurin

IPC分类号： B01D53/94 ,  B01D53/86 ,  B01J23/22 ,  B01J23/74 ,  B01J35/10 ,  C01F7/02 ,  B01J21/04

CPC分类号： B01J35/10 ,  B01D53/8628 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1066

摘要： Nitrogen oxides, NO.sub.x, are depleted/removed from oxygen-containing gas streams comprising same, by contacting an admixture of ammonia and such gas streams, at elevated temperatures, with a catalyst which comprises a catalytically active metallic oxide deposited on a porous alumina support, said support comprising a volume of pores having diameters larger than 1000 A in excess of 25 cm.sup.3 /100 g, a volume of pores having diameters larger than 300 A in excess of 40 cm.sup.3 /100 g, a total pore volume of from about 80 cm.sup.3 /100 g to 120 cm.sup.3 /100 g, and a surface area of less than 160 m.sup.2 /g, said catalytically active metallic oxide being an oxide of a metal selected from the group consisting of vanadium, iron and cobalt, and said catalytically active metal oxide comprising from 0.5 to 20% by weight of the catalyst.

摘要翻译： 通过在高温下将氨和这种气流的混合物与包含沉积在多孔氧化铝载体上的催化活性金属氧化物的催化剂接触，使含氧气体NO x从含氧气流中消耗/除去， 所述载体包含一定体积的孔径，其直径大于1000A，超过25cm 3 / 100g，直径大于300A的孔体积超过40cm 3 / 100g，总孔体积为约80cm 3 / 100g至120cm 3 / 100g，表面积小于160m 2 / g，所述催化活性金属氧化物是选自钒，铁和钴的金属的氧化物，所述催化活性金属 氧化物，其包含0.5至20重量％的催化剂。

公开(公告)号：US4292295A

公开(公告)日：1981-09-29

申请号：US174659

申请日：1980-08-01

申请人： Michel Pajot ,  Laurent Seigneurin

发明人： Michel Pajot ,  Laurent Seigneurin

IPC分类号： C01F7/02 ,  C01F7/30 ,  C01F7/56

CPC分类号： C01F7/30 ,  C01F7/56 ,  C01P2002/02 ,  C01P2002/72 ,  C01P2006/12

摘要： The invention relates to a new highly reactive alumina and the method of preparing it. The alumina is characterized by an amorphous structure and a specific surface of greater than 600 m.sup.2 /g. It is prepared by thermal decomposition of the double carbonate of aluminum and ammonium of the formula AlNH.sub.4 CO.sub.3 (OH).sub.2 at a temperature of between about 200.degree. and 500.degree. C.Aluminum hydroxychlorides of the formula Al.sub.2 (OH).sub.x Cl.sub.6-x can be prepared from it.

摘要翻译： 本发明涉及一种新的高活性氧化铝及其制备方法。 氧化铝的特征在于非晶结构和大于600m 2 / g的比表面积。 通过在约200℃至500℃的温度下热分解式AlNH 4 CO 3（OH）2的铝和铵的双重碳酸盐制备。可制备式Al 2（OH）x Cl 6-x的羟基氯化铝 从中。