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公开(公告)号:US09362510B2
公开(公告)日:2016-06-07
申请号:US12527437
申请日:2008-02-13
申请人: Thomas Schäfer , Peter Murer , Gisèle Baudin , Manuela Kocher , François Maike , Stephan Allenbach , Rosemarie Sift , Beat Schmidhalter
发明人: Thomas Schäfer , Peter Murer , Gisèle Baudin , Manuela Kocher , François Maike , Stephan Allenbach , Rosemarie Sift , Beat Schmidhalter
CPC分类号: H01L51/0085 , C07F15/0033 , C07F15/0086 , C09K11/06 , C09K2211/1059 , C09K2211/185 , H01L51/006 , H01L51/0081 , H01L51/0087 , H01L51/5016
摘要: This invention relates to electroluminescent metal complexes with benzotriazoles of the formula (I), a process for their preparation, electronic devices comprising the metal complexes and their use in electronic devices, especially organic light emitting diodes (OLEDs), as oxygen sensitive indicators, as phosphorescent indicators in bioassays, and as catalysts.
摘要翻译: 本发明涉及具有式(I)的苯并三唑的电致发光金属络合物,其制备方法,包含金属络合物的电子器件及其在电子器件中的用途,特别是有机发光二极管(OLED),作为氧敏感指示剂,如 生物测定中的磷光指标,以及催化剂。
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公开(公告)号:US09353065B2
公开(公告)日:2016-05-31
申请号:US12531885
申请日:2008-03-19
申请人: Thomas Schäfer , Peter Murer , Frédérique Wendeborn , Beat Schmidhalter , Kristina Bardon , Andrea Ricci , Joern Pommerehne
发明人: Thomas Schäfer , Peter Murer , Frédérique Wendeborn , Beat Schmidhalter , Kristina Bardon , Andrea Ricci , Joern Pommerehne
IPC分类号: H01J1/63 , C07D235/02 , C07D235/18 , C07D241/38 , C07D263/52 , C07D403/14 , C07D413/14 , H01L51/00 , H01L51/50
CPC分类号: C07D235/02 , C07D241/38 , C07D263/52 , C07D403/14 , C07D413/14 , H01L51/0071 , H01L51/5012
摘要: The present invention relates to compounds of the formula (I), a process for their preparation and their use in organic light emitting diodes (OLEDs), especially as host for phosphorescent compounds. The hosts may function with phosphorescent materials to provide improved efficiency, stability, manufacturability, or special characteristics of electroluminescent devices.
摘要翻译: 本发明涉及式(I)化合物,其制备方法及其在有机发光二极管(OLEDs)中的用途,特别是作为磷光化合物的主体。 主机可以与磷光材料一起工作,以提供电致发光器件的改进的效率,稳定性,可制造性或特殊特性。
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公开(公告)号:US08901343B2
公开(公告)日:2014-12-02
申请号:US13140256
申请日:2009-12-15
IPC分类号: C07C67/08
摘要: The invention relates to a method for producing carboxylic esters by converting a carboxylic acid or a carboxylic acid anhydride or a mixture thereof with an alcohol in a reaction system comprising one or more reactors, wherein reaction water is distilled as alcohol-water-azeotrope with the vapors, the vapors are at least partially condensed, the condensate is separated into an aqueous phase and an organic phase and said organic phase is supplied at least partially back into said reaction system. Components boiling lower than the alcohol are at least partially removed from said returned organic phase such as wherein components boiling lower than alcohol are evaporated and/or distilled off. An enrichment in the reaction system of by-products boiling lower than alcohol is avoided. Alcohol losses can be minimized by discharge currents.
摘要翻译: 本发明涉及一种通过在包含一个或多个反应器的反应体系中将羧酸或羧酸酐或其混合物与醇反应来制备羧酸酯的方法,其中将反应水作为醇 - 水 - 共沸物与 蒸气,蒸气至少部分冷凝,将冷凝物分离成水相和有机相,并将所述有机相至少部分地供给至所述反应体系。 沸点低于醇的组分至少部分地从所述返回的有机相中除去,例如其中沸点低于醇的组分蒸发和/或蒸馏掉。 避免了沸点低于酒精的副产物的反应体系的富集。 酒精损失可以通过放电电流最小化。
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14.
公开(公告)号:US08492749B2
公开(公告)日:2013-07-23
申请号:US11793513
申请日:2005-12-14
申请人: Roger Prétôt , Paul Adriaan Van Der Schaaf , Jemima Schmidt , Beat Schmidhalter , Thomas Schäfer , Bernd Lamatsch
发明人: Roger Prétôt , Paul Adriaan Van Der Schaaf , Jemima Schmidt , Beat Schmidhalter , Thomas Schäfer , Bernd Lamatsch
IPC分类号: H01L35/24
CPC分类号: H01L51/0067 , C07F15/0033 , C07F15/0086 , C09K11/06 , C09K2211/1029 , C09K2211/1037 , C09K2211/1059 , C09K2211/1092 , C09K2211/185 , H01L51/0071 , H01L51/0072 , H01L51/0074 , H01L51/0085 , H01L51/0087 , H01L51/5016 , H01L51/5048 , H05B33/14
摘要: This invention relates to electroluminescent metal complexes of the formula (I), wherein the ring A, formula (II), represents an optionally substituted aryl group which can optionally contain heteroatoms, the ring B, formula (III), represents an optionally substituted nitrogen containing aryl group, which can optionally contain further heteroatoms, or the ring A may be taken with the ring B binding to the ring A to form a ring; the group C, formula (IV), represents an acyclic carbene, or a cyclic carbene (ring C), which can optionally contain heteroatoms, the ring D, formula (V), represents an optionally substituted aryl group which can optionally contain heteroatoms, n1 is an integer of 1 to 3, m1 is an integer of 0, 1, or 2, m2 is an integer 0, or 1, M1 is a metal with an atomic weight of greater than 40, L3 is a monodentate ligand, or a bidentate ligand, Y is —C(═O)—, or —C(X1)2-, wherein X1 is hydrogen, or C1-4alkyl, especially hydrogen, and y is 0, or 1, especially 0; a process for their preparation, electronic devices comprising the metal complexes and their use in electronic devices, especially organic light emitting diodes (OLEDs), as oxygen sensitive indicators, as phosphorescent indicators in bioassays, and as catalysts.
摘要翻译: 本发明涉及式(I)的电致发光金属络合物,其中环A,式(II)代表任选地含有杂原子的任选取代的芳基,环B,式(III)代表任选取代的氮 含有芳基,其可以任选地含有其它杂原子,或者环A可以与环B结合成环A而形成环; 式C(式Ⅳ)代表可任选地含有杂原子的无环卡宾或环卡宾(环C),环D,式(Ⅴ)代表任意取代的芳基,可任意含有杂原子, n1为1〜3的整数,m1为0,1或2的整数,m2为整数0或1,M1为原子量大于40的金属,L3为单齿配体,或 二齿配体,Y是-C(= O) - 或-C(X1)2-,其中X1是氢或C1-4烷基,特别是氢,y是0或1,特别是0; 其制备方法,包括金属络合物的电子器件及其在电子器件中的用途,特别是有机发光二极管(OLED),作为氧敏感指示剂,作为生物测定中的磷光指示剂,以及作为催化剂。
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公开(公告)号:US20110251420A1
公开(公告)日:2011-10-13
申请号:US13140256
申请日:2009-12-15
IPC分类号: C07C67/08
摘要: The invention relates to a method for producing carboxylic esters by converting a carboxylic acid or a carboxylic acid anhydride or a mixture thereof with an alcohol in a reaction system comprising one or more reactors, wherein reaction water is distilled as alcohol-water-azeotrope with the vapors, the vapors are at least partially condensed, the condensate is separated into an aqueous phase and an organic phase and said organic phase is supplied at least partially back into said reaction system. Components boiling lower than the alcohol are at least partially removed from said returned organic phase such as wherein components boiling lower than alcohol are evaporated and/or distilled off. An enrichment in the reaction system of by-products boiling lower than alcohol is avoided. Alcohol losses can be minimized by discharge currents.
摘要翻译: 本发明涉及一种通过在包含一个或多个反应器的反应体系中将羧酸或羧酸酐或其混合物与醇反应来制备羧酸酯的方法,其中将反应水作为醇 - 水 - 共沸物与 蒸气,蒸气至少部分冷凝,将冷凝物分离成水相和有机相,并将所述有机相至少部分提供回所述反应体系。 沸点低于醇的组分至少部分地从所述返回的有机相中除去,例如其中沸点低于醇的组分蒸发和/或蒸馏掉。 避免了沸点低于酒精的副产物的反应体系的富集。 酒精损失可以通过放电电流最小化。
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公开(公告)号:US07968872B2
公开(公告)日:2011-06-28
申请号:US12309379
申请日:2007-07-18
IPC分类号: H01L51/00
CPC分类号: C07C25/22 , C07C17/263 , C07C43/225 , C07C45/004 , C07C49/215 , C07C49/255 , C07C49/697 , C07C49/753 , C08G61/10 , C08G2261/124 , C08G2261/148 , C08G2261/312 , C08G2261/314 , C08G2261/411 , C09K11/06 , C09K2211/1416 , C09K2211/1425 , C09K2211/1458 , H01L51/0035 , H01L51/0036 , H01L51/0037 , H01L51/0039 , H01L51/0043 , H01L51/0059 , H01L51/007 , H01L51/5012 , H05B33/14 , Y02E10/549 , Y10S428/917
摘要: The present invention relates to polymers comprising repeating unit(s) of the formula (I), and their use in electronic devices. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high charge carrier mobilities and high temperature stability of the emission color are observed, if the polymers according to the invention are used in polymer light emitting diodes (PLEDs).
摘要翻译: 本发明涉及包含式(I)的重复单元的聚合物及其在电子器件中的用途。 根据本发明的聚合物在有机溶剂中具有优异的溶解性和优异的成膜性能。 此外,如果根据本发明的聚合物用于聚合物发光二极管(PLED)中,则观察到高电荷载流子迁移率和发光颜色的高温稳定性。
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17.
公开(公告)号:US20110114922A1
公开(公告)日:2011-05-19
申请号:US11793513
申请日:2005-12-14
申请人: Roger Prétôt , Paul Adriaan Van Der Schaaf , Jemima Schmidt , Beat Schmidhalter , Thomas Schäfer , Bernd Lamatsch
发明人: Roger Prétôt , Paul Adriaan Van Der Schaaf , Jemima Schmidt , Beat Schmidhalter , Thomas Schäfer , Bernd Lamatsch
CPC分类号: H01L51/0067 , C07F15/0033 , C07F15/0086 , C09K11/06 , C09K2211/1029 , C09K2211/1037 , C09K2211/1059 , C09K2211/1092 , C09K2211/185 , H01L51/0071 , H01L51/0072 , H01L51/0074 , H01L51/0085 , H01L51/0087 , H01L51/5016 , H01L51/5048 , H05B33/14
摘要: This invention relates to electroluminescent metal complexes of the formula (I), wherein the ring A, formula (II), represents an optionally substituted aryl group which can optionally contain heteroatoms, the ring B, formula (III), represents an optionally substituted nitrogen containing aryl group, which can optionally contain further heteroatoms, or the ring A may be taken with the ring B binding to the ring A to form a ring; the group C, formula (IV), represents an acyclic carbene, or a cyclic carbene (ring C), which can optionally contain heteroatoms, the ring D, formula (V), represents an optionally substituted aryl group which can optionally contain heteroatoms, n1 is an integer of 1 to 3, m1 is an integer of 0, 1, or 2, m2 is an integer 0, or 1, M1 is a metal with an atomic weight of greater than 40, L3 is a monodentate ligand, or a bidentate ligand, Y is —C(═O)—, or —C(X1)2-, wherein X1 is hydrogen, or C1-4alkyl, especially hydrogen, and y is 0, or 1, especially 0; a process for their preparation, electronic devices comprising the metal complexes and their use in electronic devices, especially organic light emitting diodes (OLEDs), as oxygen sensitive indicators, as phosphorescent indicators in bioassays, and as catalysts.
摘要翻译: 本发明涉及式(I)的电致发光金属络合物,其中环A,式(II)代表任选地含有杂原子的任选取代的芳基,环B,式(III)代表任选取代的氮 含有芳基,其可以任选地含有其它杂原子,或者环A可以与环B结合成环A而形成环; 式C(式Ⅳ)代表可任选地含有杂原子的无环卡宾或环卡宾(环C),环D,式(Ⅴ)代表任意取代的可任意含有杂原子的芳基, n1为1〜3的整数,m1为0,1或2的整数,m2为整数0或1,M1为原子量大于40的金属,L3为单齿配体,或 二齿配体,Y是-C(= O) - 或-C(X1)2-,其中X1是氢或C1-4烷基,特别是氢,y是0或1,特别是0; 其制备方法,包括金属络合物的电子器件及其在电子器件中的用途,特别是有机发光二极管(OLED),作为氧敏感指示剂,作为生物测定中的磷光指示剂,以及作为催化剂。
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18.
公开(公告)号:US07820828B2
公开(公告)日:2010-10-26
申请号:US11629573
申请日:2005-06-20
CPC分类号: H01L51/0084 , C09K11/06 , C09K2211/185 , H01L51/0085 , H01L51/0087 , H01L51/5012
摘要: This invention relates to electroluminescent metal complexes with triazoles and benzotriazoles, respectively of the formula (I) a process for their preparation, electronic devices comprising the metal complexes and their use in electronic devices, especially organic light emitting diodes (OLEDs), as oxygen sensitive indicators, as phosphorescent indicators in bioassays, and as catalysts.
摘要翻译: 本发明涉及分别具有式(I)的三唑和苯并三唑的电致发光金属络合物,其制备方法,包含金属络合物的电子器件及其在电子器件中的用途,特别是有机发光二极管(OLED),作为氧敏感 指标,作为生物测定中的磷光指标,并作为催化剂。
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公开(公告)号:US07750112B2
公开(公告)日:2010-07-06
申请号:US10553775
申请日:2004-04-26
IPC分类号: C08G73/00
CPC分类号: C08G73/0666 , C08G61/123
摘要: The present invention relates to polymers comprising benzotriazole containing repeating units. Optical devices, comprising the polymers of the present invention, can show significant advantages in color purity, device efficiency and/or operational lifetime. In addition, the polymers can have good solubility characteristics and relatively high glass transition temperatures, which facilitates their fabrication into coatings and films that are relatively thin, thermally stable, and relatively free of defects.
摘要翻译: 本发明涉及包含含有重复单元的苯并三唑的聚合物。 包含本发明聚合物的光学器件可以在色纯度,器件效率和/或使用寿命方面显示出显着的优点。 此外,聚合物可以具有良好的溶解度特性和相对较高的玻璃化转变温度,这有助于其制造成相对较薄,热稳定且相对无缺陷的涂层和薄膜。
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公开(公告)号:US07168699B2
公开(公告)日:2007-01-30
申请号:US10735232
申请日:2003-12-12
申请人: Thomas Schäfer , Frank Gunschera , Carsten Kelm , Sven Kerpe , Ralf Steinmetz , Ralf Wadlinger
发明人: Thomas Schäfer , Frank Gunschera , Carsten Kelm , Sven Kerpe , Ralf Steinmetz , Ralf Wadlinger
IPC分类号: B65H29/68
CPC分类号: B65H29/686 , B65H2557/242 , B65H2801/21
摘要: A sheet-processing machine includes a conveyor for transporting processed sheets at a processing speed and for releasing the sheets for braking to a depositing speed. A braking element serves for the braking of the released sheets to the depositing speed. A drive is provided for the braking element, and a drive connection is provided for connecting the drive to the braking element. Further included are an overrunning clutch in the drive connection, and a brake for retarding the braking element.
摘要翻译: 片材加工机包括用于以处理速度输送处理过的片材并将用于制动的片材释放到沉积速度的输送机。 制动元件用于将释放的片材制动成沉积速度。 为制动元件提供驱动器,并且提供用于将驱动器连接到制动元件的驱动连接。 还包括驱动连接中的超速离合器和用于延迟制动元件的制动器。
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