Method for producing carboxylic acid esters
    13.
    发明授权
    Method for producing carboxylic acid esters 有权
    羧酸酯的制备方法

    公开(公告)号:US08901343B2

    公开(公告)日:2014-12-02

    申请号:US13140256

    申请日:2009-12-15

    IPC分类号: C07C67/08

    CPC分类号: C07C67/08 C07C69/80

    摘要: The invention relates to a method for producing carboxylic esters by converting a carboxylic acid or a carboxylic acid anhydride or a mixture thereof with an alcohol in a reaction system comprising one or more reactors, wherein reaction water is distilled as alcohol-water-azeotrope with the vapors, the vapors are at least partially condensed, the condensate is separated into an aqueous phase and an organic phase and said organic phase is supplied at least partially back into said reaction system. Components boiling lower than the alcohol are at least partially removed from said returned organic phase such as wherein components boiling lower than alcohol are evaporated and/or distilled off. An enrichment in the reaction system of by-products boiling lower than alcohol is avoided. Alcohol losses can be minimized by discharge currents.

    摘要翻译: 本发明涉及一种通过在包含一个或多个反应器的反应体系中将羧酸或羧酸酐或其混合物与醇反应来制备羧酸酯的方法,其中将反应水作为醇 - 水 - 共沸物与 蒸气,蒸气至少部分冷凝,将冷凝物分离成水相和有机相,并将所述有机相至少部分地供给至所述反应体系。 沸点低于醇的组分至少部分地从所述返回的有机相中除去,例如其中沸点低于醇的组分蒸发和/或蒸馏掉。 避免了沸点低于酒精的副产物的反应体系的富集。 酒精损失可以通过放电电流最小化。

    Electroluminescent metal complexes with nucleophilic carbene ligands
    14.
    发明授权
    Electroluminescent metal complexes with nucleophilic carbene ligands 有权
    具有亲核卡宾配体的电致发光金属络合物

    公开(公告)号:US08492749B2

    公开(公告)日:2013-07-23

    申请号:US11793513

    申请日:2005-12-14

    IPC分类号: H01L35/24

    摘要: This invention relates to electroluminescent metal complexes of the formula (I), wherein the ring A, formula (II), represents an optionally substituted aryl group which can optionally contain heteroatoms, the ring B, formula (III), represents an optionally substituted nitrogen containing aryl group, which can optionally contain further heteroatoms, or the ring A may be taken with the ring B binding to the ring A to form a ring; the group C, formula (IV), represents an acyclic carbene, or a cyclic carbene (ring C), which can optionally contain heteroatoms, the ring D, formula (V), represents an optionally substituted aryl group which can optionally contain heteroatoms, n1 is an integer of 1 to 3, m1 is an integer of 0, 1, or 2, m2 is an integer 0, or 1, M1 is a metal with an atomic weight of greater than 40, L3 is a monodentate ligand, or a bidentate ligand, Y is —C(═O)—, or —C(X1)2-, wherein X1 is hydrogen, or C1-4alkyl, especially hydrogen, and y is 0, or 1, especially 0; a process for their preparation, electronic devices comprising the metal complexes and their use in electronic devices, especially organic light emitting diodes (OLEDs), as oxygen sensitive indicators, as phosphorescent indicators in bioassays, and as catalysts.

    摘要翻译: 本发明涉及式(I)的电致发光金属络合物,其中环A,式(II)代表任选地含有杂原子的任选取代的芳基,环B,式(III)代表任选取代的氮 含有芳基,其可以任选地含有其它杂原子,或者环A可以与环B结合成环A而形成环; 式C(式Ⅳ)代表可任选地含有杂原子的无环卡宾或环卡宾(环C),环D,式(Ⅴ)代表任意取代的芳基,可任意含有杂原子, n1为1〜3的整数,m1为0,1或2的整数,m2为整数0或1,M1为原子量大于40的金属,L3为单齿配体,或 二齿配体,Y是-C(= O) - 或-C(X1)2-,其中X1是氢或C1-4烷基,特别是氢,y是0或1,特别是0; 其制备方法,包括金属络合物的电子器件及其在电子器件中的用途,特别是有机发光二极管(OLED),作为氧敏感指示剂,作为生物测定中的磷光指示剂,以及作为催化剂。

    METHOD FOR PRODUCING CARBOXYLIC ACID ESTERS
    15.
    发明申请
    METHOD FOR PRODUCING CARBOXYLIC ACID ESTERS 有权
    生产羧酸酯的方法

    公开(公告)号:US20110251420A1

    公开(公告)日:2011-10-13

    申请号:US13140256

    申请日:2009-12-15

    IPC分类号: C07C67/08

    CPC分类号: C07C67/08 C07C69/80

    摘要: The invention relates to a method for producing carboxylic esters by converting a carboxylic acid or a carboxylic acid anhydride or a mixture thereof with an alcohol in a reaction system comprising one or more reactors, wherein reaction water is distilled as alcohol-water-azeotrope with the vapors, the vapors are at least partially condensed, the condensate is separated into an aqueous phase and an organic phase and said organic phase is supplied at least partially back into said reaction system. Components boiling lower than the alcohol are at least partially removed from said returned organic phase such as wherein components boiling lower than alcohol are evaporated and/or distilled off. An enrichment in the reaction system of by-products boiling lower than alcohol is avoided. Alcohol losses can be minimized by discharge currents.

    摘要翻译: 本发明涉及一种通过在包含一个或多个反应器的反应体系中将羧酸或羧酸酐或其混合物与醇反应来制备羧酸酯的方法,其中将反应水作为醇 - 水 - 共沸物与 蒸气,蒸气至少部分冷凝,将冷凝物分离成水相和有机相,并将所述有机相至少部分提供回所述反应体系。 沸点低于醇的组分至少部分地从所述返回的有机相中除去,例如其中沸点低于醇的组分蒸发和/或蒸馏掉。 避免了沸点低于酒精的副产物的反应体系的富集。 酒精损失可以通过放电电流最小化。

    Electroluminescent Metal Complexes with Nucleophilic Carbene Ligands
    17.
    发明申请
    Electroluminescent Metal Complexes with Nucleophilic Carbene Ligands 有权
    电致发光金属络合物与亲核性碳配体

    公开(公告)号:US20110114922A1

    公开(公告)日:2011-05-19

    申请号:US11793513

    申请日:2005-12-14

    IPC分类号: H01L51/30 C07F15/00

    摘要: This invention relates to electroluminescent metal complexes of the formula (I), wherein the ring A, formula (II), represents an optionally substituted aryl group which can optionally contain heteroatoms, the ring B, formula (III), represents an optionally substituted nitrogen containing aryl group, which can optionally contain further heteroatoms, or the ring A may be taken with the ring B binding to the ring A to form a ring; the group C, formula (IV), represents an acyclic carbene, or a cyclic carbene (ring C), which can optionally contain heteroatoms, the ring D, formula (V), represents an optionally substituted aryl group which can optionally contain heteroatoms, n1 is an integer of 1 to 3, m1 is an integer of 0, 1, or 2, m2 is an integer 0, or 1, M1 is a metal with an atomic weight of greater than 40, L3 is a monodentate ligand, or a bidentate ligand, Y is —C(═O)—, or —C(X1)2-, wherein X1 is hydrogen, or C1-4alkyl, especially hydrogen, and y is 0, or 1, especially 0; a process for their preparation, electronic devices comprising the metal complexes and their use in electronic devices, especially organic light emitting diodes (OLEDs), as oxygen sensitive indicators, as phosphorescent indicators in bioassays, and as catalysts.

    摘要翻译: 本发明涉及式(I)的电致发光金属络合物,其中环A,式(II)代表任选地含有杂原子的任选取代的芳基,环B,式(III)代表任选取代的氮 含有芳基,其可以任选地含有其它杂原子,或者环A可以与环B结合成环A而形成环; 式C(式Ⅳ)代表可任选地含有杂原子的无环卡宾或环卡宾(环C),环D,式(Ⅴ)代表任意取代的可任意含有杂原子的芳基, n1为1〜3的整数,m1为0,1或2的整数,m2为整数0或1,M1为原子量大于40的金属,L3为单齿配体,或 二齿配体,Y是-C(= O) - 或-C(X1)2-,其中X1是氢或C1-4烷基,特别是氢,y是0或1,特别是0; 其制备方法,包括金属络合物的电子器件及其在电子器件中的用途,特别是有机发光二极管(OLED),作为氧敏感指示剂,作为生物测定中的磷光指示剂,以及作为催化剂。

    Polymers comprising benzotriazole for use in optical devices
    19.
    发明授权
    Polymers comprising benzotriazole for use in optical devices 失效
    包含用于光学器件的苯并三唑的聚合物

    公开(公告)号:US07750112B2

    公开(公告)日:2010-07-06

    申请号:US10553775

    申请日:2004-04-26

    IPC分类号: C08G73/00

    CPC分类号: C08G73/0666 C08G61/123

    摘要: The present invention relates to polymers comprising benzotriazole containing repeating units. Optical devices, comprising the polymers of the present invention, can show significant advantages in color purity, device efficiency and/or operational lifetime. In addition, the polymers can have good solubility characteristics and relatively high glass transition temperatures, which facilitates their fabrication into coatings and films that are relatively thin, thermally stable, and relatively free of defects.

    摘要翻译: 本发明涉及包含含有重复单元的苯并三唑的聚合物。 包含本发明聚合物的光学器件可以在色纯度,器件效率和/或使用寿命方面显示出显着的优点。 此外,聚合物可以具有良好的溶解度特性和相对较高的玻璃化转变温度,这有助于其制造成相对较薄,热稳定且相对无缺陷的涂层和薄膜。

    Sheet-processing machine with a sheet brake
    20.
    发明授权
    Sheet-processing machine with a sheet brake 失效
    带片式制动器的片材加工机

    公开(公告)号:US07168699B2

    公开(公告)日:2007-01-30

    申请号:US10735232

    申请日:2003-12-12

    IPC分类号: B65H29/68

    摘要: A sheet-processing machine includes a conveyor for transporting processed sheets at a processing speed and for releasing the sheets for braking to a depositing speed. A braking element serves for the braking of the released sheets to the depositing speed. A drive is provided for the braking element, and a drive connection is provided for connecting the drive to the braking element. Further included are an overrunning clutch in the drive connection, and a brake for retarding the braking element.

    摘要翻译: 片材加工机包括用于以处理速度输送处理过的片材并将用于制动的片材释放到沉积速度的输送机。 制动元件用于将释放的片材制动成沉积速度。 为制动元件提供驱动器,并且提供用于将驱动器连接到制动元件的驱动连接。 还包括驱动连接中的超速离合器和用于延迟制动元件的制动器。