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11.发明授权公开(公告)号：US07351752B2
公开(公告)日：2008-04-01
申请号：US10954212
申请日：2004-10-01
IPC分类号： C08J9/00
CPC分类号： C08J9/32 , B01J13/14 , C08J2203/14 , C08J2203/22
摘要： The present invention provides thermo-expansive microspheres comprising thermoplastic resinous shell and a blowing agent being encapsulated in the shell, the blowing agent which is a fluorine-containing C2-10 compound having ether linkage, being free of chlorine and bromine atoms and gasifying at a temperature not higher than the softening point of the thermoplastic resin; and also provides the production and application processes thereof. The thermo-expansive microspheres have preferably an average particle size ranging from 1 to 100 μm and a CV, or coefficient of variation, of particle size distribution being 30% or less, and a retaining ratio of blowing agent encapsulated being 90% or more.The thermo-expansive microspheres have low environmental loading and superior flame-retardant or flame-resistant performance, and have particle sizes distributing in narrow ranges. Those thermo-expansive microspheres and foamed hollow microspheres are suitable for applying to fire-proof paints, flame-retardant or flame-resistant thermo-insulating materials, flame-retardant or flame-resistant lightweight fillers, and flame-retardant or flame-resistant lightweight molded products, in addition to the conventional application field.
摘要翻译： 本发明提供了包含热塑性树脂壳和封装在壳中的发泡剂的热膨胀性微球，发泡剂是具有醚键的含氟C 2-10 - 化合物，不含 氯和溴原子，并且在不高于热塑性树脂的软化点的温度下气化; 并提供其生产和应用程序。 热膨胀性微球体的平均粒径优选为1〜100μm，粒径分布的CV或变异系数为30％以下，发泡剂的保持率为90％以上。 热膨胀微球具有低环境负荷和优异的阻燃或阻燃性能，并且粒度分布范围窄。 这些热膨胀微球和发泡中空微球适用于防火涂料，阻燃或阻燃绝热材料，阻燃或阻燃轻质填料，以及阻燃或阻燃轻质 模制产品，除了常规应用领域。
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公开(公告)号：US06984347B2
公开(公告)日：2006-01-10
申请号：US10923811
申请日：2004-08-24
CPC分类号： B01J13/14 , Y10T428/2987
摘要： Thermo-expansive microcapsules comprising a shell of a polymer produced by polymerizing a mixture of monomers, which comprises (I) a nitrile monomer, (II) a monomer having an unsaturated double bond and carboxyl groups in a molecule, (III) a monomer having two or more of polymerizable double bonds in a molecule, and optionally, (IV) a monomer different from and copolymerizable with the monomers (I), (II) and (III) and a blowing agent encapsulated in the shell. The volume retention of the expanded microcapsules of the thermo-expansive microcapsules is 50% or more after loaded with 15 MPa.
摘要翻译： 包含通过聚合单体混合物制备的聚合物的壳的热膨胀微胶囊，其包含（I）腈单体，（II）分子中具有不饱和双键的单体和羧基，（III）具有 分子中的两个或更多个可聚合双键，和任选地（Ⅳ）与单体（I），（II）和（III）不同且可共聚的单体和包封在壳中的发泡剂。 热膨胀微胶囊的膨胀微胶囊的体积保留率在加载15MPa后为50％以上。
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13.发明授权公开(公告)号：US07807729B2
公开(公告)日：2010-10-05
申请号：US10595910
申请日：2004-11-15
CPC分类号： C08J9/22 , B01J13/04 , B01J13/14 , C08J9/32 , C08J2203/142 , Y10T428/2985 , Y10T428/2987 , Y10T428/2991
摘要： A production process for heat-expanded microspheres includes the step of providing a gaseous fluid containing heat-expandable microspheres, which includes a shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin and have an average particle size from 1 to 100 μm. The gaseous fluid is fed through a gas-introducing tube having a dispersion nozzle on its outlet that is fixed inside a conduit having a hot gas flow flowing therethrough. A jet of the gaseous fluid is emitted through the dispersion nozzle. Further, the gaseous fluid is collided on a collision plate fixed under the dispersion nozzle so as to disperse the heat-expandable microspheres in the hot gas flow. The dispersed heat-expandable microspheres are heated in the hot gas flow at a temperature not lower than their expansion initiating temperature and thus expanded.
摘要翻译： 热膨胀微球的制造方法包括提供含有热膨胀性微球的气态流体的步骤，其包括热塑性树脂的壳和封装在其中的沸点不高于热塑性树脂的软化点的发泡剂， 平均粒径为1〜100μm。 气体流体通过其出口上具有分散喷嘴的气体导入管被供给，该出口固定在具有流过其中的热气流的管道内。 气体流体的射流通过分散喷嘴发射。 此外，气体流体在固定在分散喷嘴下方的碰撞板上碰撞，以将热膨胀性微球分散在热气流中。 分散的热膨胀性微球体在热气流中以不低于其膨胀开始温度的温度加热，从而膨胀。
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14.发明申请公开(公告)号：US20050080151A1
公开(公告)日：2005-04-14
申请号：US10954212
申请日：2004-10-01
CPC分类号： C08J9/32 , B01J13/14 , C08J2203/14 , C08J2203/22
摘要： The present invention provides thermo-expansive microspheres comprising thermoplastic resinous shell and a blowing agent being encapsulated in the shell, the blowing agent which is a fluorine-containing C2-10 compound having ether linkage, being free of chlorine and bromine atoms and gasifying at a temperature not higher than the softening point of the thermoplastic resin; and also provides the production and application processes thereof. The thermo-expansive microspheres have preferably an average particle size ranging from 1 to 100 μm and a CV, or coefficient of variation, of particle size distribution being 30% or less, and a retaining ratio of blowing agent encapsulated being 90% or more. The thermo-expansive microspheres have low environmental loading and superior flame-retardant or flame-resistant performance, and have particle sizes distributing in narrow ranges. Those thermo-expansive microspheres and foamed hollow microspheres are suitable for applying to fire-proof paints, flame-retardant or flame-resistant thermo-insulating materials, flame-retardant or flame-resistant lightweight fillers, and flame-retardant or flame-resistant lightweight molded products, in addition to the conventional application field.
摘要翻译： 本发明提供包含热塑性树脂壳和封装在壳中的发泡剂的热膨胀性微球，发泡剂是具有醚键的含氟C2-10化合物，不含氯和溴原子，并在 温度不高于热塑性树脂的软化点; 并提供其生产和应用程序。 热膨胀性微球体的平均粒径优选为1〜100μm，粒径分布的CV或变异系数为30％以下，发泡剂的保持率为90％以上。 热膨胀微球具有低环境负荷和优异的阻燃或阻燃性能，并且粒度分布范围窄。 这些热膨胀微球和发泡中空微球适用于防火涂料，阻燃或阻燃绝热材料，阻燃或阻燃轻质填料，以及阻燃或阻燃轻质 模制产品，除了常规应用领域。
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15.发明授权公开(公告)号：US07994229B2
公开(公告)日：2011-08-09
申请号：US12068430
申请日：2008-02-06
IPC分类号： C08J9/32
CPC分类号： C08J9/32 , B01J13/14 , C08J2203/14 , C08J2203/22
摘要： The present invention provides a process for producing thermo-expansive microspheres comprising a thermoplastic resinous shell and a blowing agent being encapsulated in the shell, the blowing agent which is a fluorine-containing C2-10 compound having ether linkage, being free of chlorine and bromine atoms and gasifying at a temperature not higher than the softening point of the thermoplastic resin. The thermo-expansive microspheres have preferably an average particle size ranging from 1 to 100 μm and a CV, or coefficient of variation, of particle size distribution being 30% or less, and a retaining ratio of blowing agent encapsulated being 90% or more.
摘要翻译： 本发明提供一种包含热塑性树脂壳和包封在壳中的发泡剂的热膨胀性微球的方法，发泡剂是具有醚键的含氟C2-10化合物，不含氯和溴 原子并在不高于热塑性树脂的软化点的温度下气化。 热膨胀性微球的平均粒径优选为1〜100μm，粒径分布的CV或变异系数为30％以下，发泡剂的保持率为90％以上。
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16.发明申请公开(公告)号：US20070154711A1
公开(公告)日：2007-07-05
申请号：US10595910
申请日：2004-11-15
CPC分类号： C08J9/22 , B01J13/04 , B01J13/14 , C08J9/32 , C08J2203/142 , Y10T428/2985 , Y10T428/2987 , Y10T428/2991
摘要： A production process for heat-expanded microspheres comprising the step of providing a gaseous fluid containing heat-expandable microspheres, which comprise shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin and have an average particle size from 1 to 100 μm, feeding the gaseous fluid through a gas-introducing tube having a dispersion nozzle on its outlet and being fixed inside a hot gas flow, and emitting a jet of the gaseous fluid through the dispersion nozzle; a step wherein the gaseous fluid is collided on a collision plate fixed under the dispersion nozzle so as to disperse the heat-expandable microspheres in the hot gas flow; and a step wherein the dispersed heat-expandable microspheres are heated in the hot gas flow at a temperature not lower than their expansion initiating temperature and thus expanded. The production process results in minimum difference in the variation coefficient of particle size distribution between the microspheres before and after heat-expansion, slight ratio of raw microspheres and slightly expanded microspheres contained in resultant heat-expanded microspheres, and suppressed formation of aggregated microspheres.
摘要翻译： 一种热膨胀微球的制造方法，包括以下步骤：提供包含热膨胀性微球的气态流体，其包含热塑性树脂壳和封装在其中的发泡剂，沸点不高于热塑性树脂的软化点，并具有 平均粒度为1〜100μm，通过具有分散喷嘴的气体导入管在其出口处供给气体流体并固定在热气流内，并通过分散喷嘴喷射气态流体; 其中气态流体碰撞在固定在分散喷嘴下方的碰撞板上，以将热膨胀性微球分散在热气流中; 以及在热气流中以不低于其膨胀开始温度的温度加热分散的热膨胀性微球从而膨胀的步骤。 生产过程导致热膨胀前后的微球之间的粒度分布的变异系数的差异最小，所得热膨胀微球中所含的微生物微球和微球的微小比例，抑制聚集的微球的形成。
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17.发明授权Thermo-expansive microcapsule, production process of expanded product and expanded product thereof 有权热膨胀微胶囊，膨胀产品的生产工艺及其膨胀产品公开(公告)号：US07566498B2
公开(公告)日：2009-07-28
申请号：US10539064
申请日：2003-12-24
IPC分类号： B32B5/16
CPC分类号： B01J13/14 , Y10T428/2984 , Y10T428/2987
摘要： Thermo-expansive microcapsule comprising: a polymeric shell produced by polymerizing 15 to 75 weight % of a nitrile monomer, 10 to 65 weight % of a monomer having a carboxyl group, 0.1 to 20 weight % of a monomer having an amide group and 0.1 to 20 weight % of a monomer having a cyclic structure in its side chain; and a blowing agent encapsulated in the polymeric shell.
摘要翻译： 热膨胀性微胶囊包含：通过使15〜75重量％的腈单体聚合而得到的聚合物壳，10〜65重量％的具有羧基的单体，0.1〜20重量％的具有酰胺基的单体和0.1〜 20重量％的侧链中具有环状结构的单体; 和封装在聚合物壳中的发泡剂。
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18.发明申请Thermally expandable microcapsule,process for producing molded foam, and molded foam 有权热膨胀性微囊，生产模制泡沫的方法和模塑泡沫公开(公告)号：US20060063000A1
公开(公告)日：2006-03-23
申请号：US10539064
申请日：2003-12-24
IPC分类号： B32B9/02
CPC分类号： B01J13/14 , Y10T428/2984 , Y10T428/2987
摘要： Thermo-expansive microcapsule comprising: a polymeric shell produced by polymerizing 15 to 75 weight % of a nitrile monomer, 10 to 65 weight % of a monomer having a carboxyl group, 0.1 to 20 weight % of a monomer having an amide group and 0.1 to 20 weight % of a monomer having a cyclic structure in its side chain; and a blowing agent encapsulated in the polymeric shell.
摘要翻译： 热膨胀性微胶囊包含：通过使15〜75重量％的腈单体聚合而得到的聚合物壳，10〜65重量％的具有羧基的单体，0.1〜20重量％的具有酰胺基的单体和0.1〜 20重量％的侧链中具有环状结构的单体; 和封装在聚合物壳中的发泡剂。
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19.发明授权公开(公告)号：US08247465B2
公开(公告)日：2012-08-21
申请号：US12679661
申请日：2008-10-09
CPC分类号： B01J13/14 , B01J13/18 , B01J13/20 , C08J9/32 , C08J2203/22 , Y10T428/2982 , Y10T428/2998
摘要： Heat-expandable microspheres include a shell of thermoplastic resin and core material encapsulated in the shell. The core material include a blowing agent having a boiling point not higher than the softening point of the thermoplastic resin and a gas migration inhibitor having a boiling point higher than the softening point of the thermoplastic resin. The ratio of the gas migration inhibitor to the core material is at least 1 weight percent and below 30 weight percent. The average particle size of the heat-expandable microspheres ranges from 1 to 100 micrometers.
摘要翻译： 热膨胀性微球包括热塑性树脂的外壳和包封在壳中的芯材料。 核心材料包括沸点不高于热塑性树脂的软化点的发泡剂和沸点高于热塑性树脂的软化点的气体迁移抑制剂。 气体迁移抑制剂与核心材料的比例至少为1重量％且低于30重量％。 热膨胀性微球的平均粒径为1〜100微米。
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20.发明申请公开(公告)号：US20100204349A1
公开(公告)日：2010-08-12
申请号：US12679661
申请日：2008-10-09
CPC分类号： B01J13/14 , B01J13/18 , B01J13/20 , C08J9/32 , C08J2203/22 , Y10T428/2982 , Y10T428/2998
摘要： Heat-expandable microspheres include a shell of thermoplastic resin and core material encapsulated in the shell. The core material include a blowing agent having a boiling point not higher than the softening point of the thermoplastic resin and a gas migration inhibitor having a boiling point higher than the softening point of the thermoplastic resin. The ratio of the gas migration inhibitor to the core material is at least 1 weight percent and below 30 weight percent. The average particle size of the heat-expandable microspheres ranges from 1 to 100 micrometers.
摘要翻译： 热膨胀性微球包括热塑性树脂的外壳和包封在壳中的芯材料。 核心材料包括沸点不高于热塑性树脂的软化点的发泡剂和沸点高于热塑性树脂的软化点的气体迁移抑制剂。 气体迁移抑制剂与核心材料的比例至少为1重量％且低于30重量％。 热膨胀性微球的平均粒径为1〜100微米。
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