摘要:
Liquid crystalline compounds having a comparatively high voltage holding ratio, high &Dgr;n and high &Dgr;&egr;, and excellent miscibility with known liquid crystalline compounds at low temperatures. The novel compounds have the formula (1) wherein R represents hydrogen atom or an alkyl group having 1 to 20 carbon atoms; n1 and n2 are independently 0, 1, or 2 provided that the sum of n1 and n2 is 1 or 2; ring A and ring B independently represent 1,4-phenylene, fluorine substituted 1,4-phenylene expressed by the formula (a) in the specification or 1,4-cyclohexylene provided that at least one of ring A and ring B is fluorine substituted 1,4-phenylene expressed by the formula (a); Za, Zb, and Zc independently represent single bond, —CH2CH2—, —COO—, —CF2O—, or —CH2CH2CH2CH2—; Q1, Q2, Q3, Q4, Q5, Q6, and Q7 independently represent hydrogen atom, a halogen atom, or methyl group provided that when at least one of Za, Zb, and Zc is —CH2CH2—, then Q2 is fluorine atom, and that when Za, Zb, and Zc are all single bonds, then Q1, Q2, Q3, Q4, Q5, Q6, and Q7 independently represent hydrogen atom or fluorine atom; Y represents hydrogen atom, a halogen atom, or a halogenated alkyl group having 1 to 5 carbon atoms; and each atom constituting this compound may be replaced by its isotope.
摘要:
A compound represented by the general formula (1) wherein R1 is an alkadienyl group having 4 to 10 carbon atoms in which a hydrogen atom may be substituted by a fluorine atom or the like; R2 is an alkenyl group having 2 to 10 carbon atoms in which a hydrogen atom may be substituted by a fluorine atom or the like; one or more non-adjacent methylene groups (—CH2—) in the alkadienyl group or the alkenyl group may be replaced by —O— or the like; rings A1, A2, A3 and A4 are each 1,4-cyclohexylene, 1,4-phenylene or the like in which a hydrogen atom may be substituted by a halogen atom; Z1, Z2 and Z3 are each a single bond, —CH2CH2—, —CF═CF— or the like; p and q are each 0 or 1. The above compound has a large elastic constant ratio, steep electro-optic characteristics and a little temperature dependence in a low temperature range, and so it is useful for the manufacture of a liquid crystal display device.
摘要:
The present invention provides liquid crystalline compounds having a high voltage holding ratio and a low threshold voltage, little variation of these properties depending on temperature change, high &Dgr;n, and good compatibility with other liquid crystal materials particularly under a low temperature; liquid crystal compositions containing these crystalline compounds; and liquid crystal display devices comprising these liquid crystal compositions. The liquid crystalline compounds are terphenyl derivatives represented by general formula (1): wherein R represents a straight or branched alkyl group of 1-20 carbon atoms, and any methylene groups (—CH2—) not adjacent each other in each alkyl group may be replaced by oxygen atoms; X represents halogen atom, —OCF3, —OCF2H, —CF3, —CF2H or —CFH2; Y1, Y2, Y3, Y4, Y5 and Y6 independently represents H or F, but at least two of Y1, Y2, Y3 and Y4 represent F; and any atom constituting these compounds may be substituted by its isotope.
摘要:
Provided are liquid crystalline compounds having excellent physical properties and being excellent in miscibility with other liquid crystal materials; liquid crystal compositions comprising the crystalline compound; and liquid crystal display device fabricated by using the liquid crystal composition; the liquid crystalline compounds being specific chlorobenzene derivatives expressed by the general formula (1) Ra—A1—Z1—A2&Parenopenst;Z2—A3&Parenclosest;m&Parenopenst;Z3—A4&Parenclosest;nRb (1) wherein Ra, Rb, A1 to A4, Z1 to Z3, m, and n are herein defined.
摘要:
The present invention provides liquid crystalline compounds having a very high voltage holding ratio, very little variation of these properties depending on temperature, high &Dgr;n, and good compatibility in the other liquid crystal materials particularly under a low temperature, liquid crystal compositions containing these crystalline compounds, and liquid crystal display devices constituted by using the liquid crystal compositions. The liquid crystalline compounds are represented by general formula (1): wherein R represents an alkyl, alkoxy or alkoxyalkyl group of 2-20 carbon atoms, and in each group, any 1-3 hydrogen atoms may be replaced by fluorine atoms; X shows an halogen atom or an alkyl group of 1-20 carbon atoms, any methylene groups (—CH2—) not adjacent each other in the alkyl group may be replaced by oxygen atoms, and any one or more hydrogen atoms in the alkyl group may be replaced by fluorine atoms; Z1, Z2 and Z3, each independently, represents —(CH2)2—, —(CH2)4—, —CH2O—, —OCH2—, —(CH2)3O—, —O(CH2)3— or a covalent bond; Y1-Y16 each independently represent hydrogen atoms or fluorine atoms, but at least two represent fluorine atoms; m represents 0 or 1, and any atom constituting the compound may be replaced by an isotope thereof.
摘要:
The present invention provides liquid crystalline compounds having a high voltage holding ratio and a low threshold voltage, little variation of these properties with temperature change, high &Dgr;n, and good compatibility with other liquid crystal materials particularly under a low temperature; liquid crystal compositions containing these crystalline compounds; and liquid crystal display devices made using these liquid crystal compositions. The liquid crystalline compounds are terphenyl derivatives represented by general formula (1): wherein R represents a straight or branched alkyl group of 1-20 carbon atoms, and any methylene groups (—CH2—) not adjacent each other in each alkyl group may be replaced by oxygen atoms; X is a halogen atom, —OCF3, —OCF2H, —CF3, —CF2H or —CFH2; Y1, Y2, Y3, Y4, Y5 and Y6 independently represents H or F, but at least two of Y1, Y2, Y3 and Y4 represent F; and any atom constituting these compounds may be substituted by its isotope.
摘要:
There are herein disclosed a fluorovinyl derivative compound represented by the general formula (1) and having characteristics of a liquid crystal, a liquid crystal composition, and a liquid crystal display device formed by using this composition: wherein R1 is an alkyl group having 1 to 18 carbon atoms, and a methylene group in the alkyl group may be substituted by an oxygen atom, a sulfur atom, —CH═CH— or —C≡C— and a hydrogen atom in the alkyl group may be substituted a halogen atom or a cyano group; rings A, B and C are each 1,4-cyclohexylene, 1,4-phenylene or the like in which a hydrogen atom in the ring may be substituted by a halogen atom; Z1, Z2 and Z3 are each a single bond, —CH2CH2—, —CH═CH—, —C≡C—, —CH2O—, —OCH2—, —(CH2)4—, —(CH2)3—O—, —O—(CH2)3—, —(CH2)2—CH═CH—, —CH═CH—(CH2)2—, —CF2O—, —OCF2—, —CR2═CH—, —CH═CR2— or —CF═CF—, and R2 is an alkyl group having 1 to 5 carbon atoms; X is a hydrogen atom or a fluorine atom; p and q are each 0 or 1; and m is an integer of 0 to 5.
摘要:
Liquid crystalline compounds which exhibit a negative dielectric anisotropy value, have an extremely high voltage holding ratio and a low threshold voltage, are small in their dependency on temperature, hardly exhibit smectic phase, and are excellent in miscibility with other liquid crystal materials at the same time; liquid crystal compositions comprising the compound; and liquid crystal display devices fabricated by using the liquid crystal composition are provided; the liquid crystalline compounds being specific 3,3′-difluorobiphenyl derivatives expressed by the following general formula (1):
摘要:
Liquid crystalline compounds having a wide temperature range of liquid crystal phase, a high dielectric anisotropy, and a high optical anisotropy; and liquid crystal compositions and display devices containing the composition. The liquid crystalline compounds are conjugated nitrile derivatives expressed by the formula (1) ##STR1## wherein R represents an alkyl group or a fluoroalkyl group each having 1 to 10 carbon atoms, halogen atom, or cyano group provided that in the alkyl or fluoroalkyl group, one or not-adjacent two or more methylene or fluoromethylene groups may be replaced by oxygen atom or 1,2-ethenylene group; A.sub.1, A.sub.2, A.sub.3 and A.sub.4 represent 1,4-cyclohexylene group, 1,4-phenylene in which one or two hydrogen atoms on the ring may be replaced by fluorine atom, 1,3-dioxane-2,5-diyl, or pyrimidine-2,5-diyl; B.sub.1, B.sub.2, and B.sub.3 independently represent a covalent bond, 1,2-ethylene group, 1,2-ethenylene group, 1,2-ethynylene group, carbonyloxy group, methylenoxy group, or 1,4-butylene group; m, n, and p are 0 or 1; and G represents a group expressed by the formula ##STR2##
摘要:
Liquid crystalline compounds which have excellent compatibility with other liquid crystal materials, especially at low temperatures, high voltage holding ratio, low threshold voltage, their small temperature dependency, high .DELTA.n, and broad liquid phase temperature range, the compounds being represented by formula (1)Ra--A.sub.1 --Z.sub.1 --A.sub.2 --Z.sub.2 --(--A.sub.3 --Z.sub.3 --).sub.m --A.sub.0 --Rf (1)(wherein m is 0 or 1; A.sub.0, A.sub.1, A.sub.2 and A.sub.3 represent a six-membered ring, ring A.sub.0 is 1,4-phenylene which may be substituted with 1 to 3 of F and/or Cl, rings A.sub.1, A.sub.2 and A.sub.3, independently of one another, are selected from trans-1,4-cyclohexylene, 1,4-phenylene which may be substituted with one or more halogen atoms, cyclohexene-1,4-diyl or 1,3-dioxane-2,5-diyl; Z.sub.1, Z.sub.2 and Z.sub.3 represent a bridge between the rings and independently of one another, are selected from --(CH.sub.2).sub.2 --, --(CH.sub.2).sub.4 --, --CH.sub.2 O--, --OCH.sub.2 -- bonds, one or more hydrogen atoms in these bonds being optionally substituted with a halogen atom, or a single bond (--); Rf represents --OCF.sub.2 CF.sub.2 H or --OCF.sub.2 CFHCF.sub.3 ; and Ra is a straight- or branched monovalent organic radical of 1 to 20 carbons); liquid crystal compositions comprising at least one of the compounds; and liquid crystal display devices composed of the compositions.