ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES

    公开(公告)号:US20240059715A1

    公开(公告)日:2024-02-22

    申请号:US18347589

    申请日:2023-07-06

    Abstract: Provided are compounds comprising a first chemical moiety, wherein the first chemical moiety comprises a first heterocyclic ring or a polycyclic fused ring system comprising at least one of the first heterocyclic ring; wherein the first heterocyclic ring comprises at least one Si or Ge atom as the ring atom; wherein in the polycyclic fused ring system, the at least one of the first heterocyclic ring has at most one bond being part of an aromatic ring; wherein the compound further comprises a second chemical moiety; wherein the second chemical moiety is selected from the group consisting of triphenylene, tetraphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, dibenzofluorene, benzo[d]benzo[4,5]imidazo[1,2-a]imidazole (bimbim), indolocarbazole, indolodibenzothiophene, indolodibenzofuran, indodibenzoselenophene, indolodibenzofluorene, naphthalene, germyl, boryl, amino, pyridine, pyridazine, pyrimidine, pyrazine, triazine, imidazole, benzimidazole, and aza variants thereof; and wherein the compound is not a metal-containing compound. Also provided are formulations, OLEDs and related consumer products that utilize these compounds.

    Organic Electroluminescent Materials and Devices

    公开(公告)号:US20230389413A1

    公开(公告)日:2023-11-30

    申请号:US18360029

    申请日:2023-07-27

    Abstract: A compound of Formula I




    wherein:
    ring B is a 5-membered heterocyclic ring, or a 6-membered carbocyclic ring;
    each of X1 and X2 is independently C, CR, or N, with at least one of them being C;
    each of X3-X11 is independently C, CR, or N, with at least one of them being N, and two adjacent of X3-X7 are carbon-fused to the shown moiety through the linkage indicated by the two squiggly lines;
    Y is selected from the group consisting of O, S, Se, NR′, CR′R″, and SiR′R″;
    each of RA and RB independently represents zero, mono, or up to a maximum allowed substitution to its associated ring;
    each of R, R′, R″, RA, and RB is independently a hydrogen or a substituent selected from the group consisting of —SiR1R2R3 or —GeR1R2R3, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, with at least one of RA or RB comprising —SiR1R2R3 or —GeR1R2R3;
    each of R1, R2, and R3 is independently selected from the group consisting of alkyl, aryl group, heteroaryl group, and combinations thereof; and
    any two substituents are optionally joined or fused to form a ring where chemically feasible.

    Organic electroluminescent materials and devices

    公开(公告)号:US11557738B2

    公开(公告)日:2023-01-17

    申请号:US16786483

    申请日:2020-02-10

    Abstract: A compound of Formula I: wherein: X1-X8 are each independently C or N, wherein two adjacent X1-X8 are carbon-fused to a structure of Formula II: X9-X12 are each independently C or N; A1, A2, and A3 are each independently selected from the group consisting of O, S, Se, N, NR, CR, CRR′, SiR, SiRR′, GeR, and GeRR′, with at least one of A1 and A2 being N or NR; each occurrence of is independently a single bond or a double bond, wherein one occurrence of is a single bond and one occurrence of is a double bond; each of RA, RB, and Rc independently represents zero, mono, or up to a maximum allowed substitution to its associated ring; each of occurrence R, R′, RA, RB, and RC is independently a hydrogen or a substituent selected from the group consisting of Formula III, Formula IV, Formula V, Formula VI, Formula VII, Formula VIII, Formula IX, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, with at least one of R, R′, RA, RB, and RC comprising a group of Formula III, Formula IV, Formula V, Formula VI, Formula VII, Formula VIII, or Formula IX: each occurrence of Y1, Y2, and Y3 is independently absent, O, S, Se, NR, CRR′, SiRR′, or GeRR′; each occurrence of Ar1, and Ar2 is independently an optionally substituted aryl group or an optionally substituted heteroaryl group, wherein Ar1 and Ar2 are optionally joined or fused together to form a ring; each occurrence of X13-X20 is independently C or N, with the proviso that at least one of X13-X20 is N; each occurrence of A4 is selected from the group consisting of O, S, Se, NR, CRR′, SiRR′, and GeRR′; each occurrence of RX independently represents zero, mono, or up to a maximum allowed substitution to its associated ring; each occurrence of RX is independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; each occurrence of RY is independently a hydrogen or a substituent selected from the group consisting of Formula III, Formula IV, Formula V, Formula VI, Formula IX, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; the maximum number of N atoms that are connected to each other within a ring is two; and any two substituents are optionally joined or fused together to form a ring.

    HOST MATERIALS FOR ELECTROLUMINESCENT DEVICES

    公开(公告)号:US20200168812A1

    公开(公告)日:2020-05-28

    申请号:US16683507

    申请日:2019-11-14

    Abstract: A compound of Formula I: wherein ring A is a 5-membered or 6-membered aromatic ring; wherein RA, RB, and RC each independently represent mono to the maximum allowable substitution, or no substitution; wherein Y1 is absent or present, and when present is selected from the group consisting of a direct bond, O, S, Se, CRR′, NR, SiRR′, and BR; wherein each X1-X3 is N or CR; wherein at least one of X1-X3 is N; wherein each A1-A5 is independently C or N; wherein the maximum number of N atoms that can connect to each other within each ring is two; wherein each R1, R2, R3, and R4 is independently selected from the group consisting of alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, aryl, heteroaryl, and combinations thereof; wherein each R, R′, RA, RB, and RC is independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and wherein any two substituents may be joined or fused together to form a ring.

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