公开(公告)号：US20050069771A1

公开(公告)日：2005-03-31

申请号：US10675695

申请日：2003-09-30

申请人： Vesselin Manev ,  Vijay Saharan

发明人： Vesselin Manev ,  Vijay Saharan

IPC分类号： H01M4/52 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/36

CPC分类号： H01M10/0525 ,  H01M4/525

摘要： A composite lithiated nickel-based positive electrode material in which the water-containing excess lithium compounds LiOH and LiHCO3 have a combined content of at least 10 times lower than the content of the water-free excess lithium compound Li2CO3. There is further provided a lithium-ion battery comprising the positive electrode material having the significantly reduced amount of LiOH and LiHCO3.

摘要翻译： 一种复合锂化镍基正极材料，其中含水过量锂化合物LiOH和LiHCO 3的组合含量比无水过量锂化合物Li 2 CO 3的含量低至少10倍。 还提供了一种锂离子电池，其包含具有显着减少量的LiOH和LiHCO 3的正极材料。

公开(公告)号：US20050069770A1

公开(公告)日：2005-03-31

申请号：US10677051

申请日：2003-09-30

申请人： Vesselin Manev ,  Yee-Ho Chia

发明人： Vesselin Manev ,  Yee-Ho Chia

IPC分类号： H01M4/13 ,  H01M4/62 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/36 ,  H01M10/42

CPC分类号： H01M4/621 ,  H01M4/13 ,  H01M4/623 ,  H01M10/0525 ,  H01M10/0565 ,  H01M2010/4292

摘要： A lithium polymer battery having a greater comonomer quantity in the polymer of the negative electrode than in the polymer of the positive electrode. The negative electrode polymer is a copolymer of a first primary monomer and 1-30 wt. % of a first comonomer, and the positive electrode is either a homopolymer of a second primary monomer or a copolymer of the second primary monomer and up to 25 wt. % of a second comonomer.

摘要翻译： 一种锂聚合物电池，其在负极聚合物中的共聚单体数量大于正极聚合物中的共聚单体数量。 负极聚合物是第一初级单体和1-30重量份的共聚物。 ％的第一共聚单体，并且正电极是第二主单体的均聚物或第二初级单体的共聚物和至多25wt。 ％的第二共聚单体。

公开(公告)号：US5961949A

公开(公告)日：1999-10-05

申请号：US871027

申请日：1997-06-06

申请人： Vesselin Manev ,  Walter Ebner ,  William Thompson ,  Stephen Dow

发明人： Vesselin Manev ,  Walter Ebner ,  William Thompson ,  Stephen Dow

IPC分类号： C01G45/00 ,  H01M2/32 ,  H01M4/04 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/50 ,  H01M4/505 ,  H01M10/052 ,  H01M10/36 ,  C01G45/12 ,  C01B13/14 ,  H01M4/58

CPC分类号： H01M4/1391 ,  C01G45/1242 ,  H01M2/32 ,  H01M4/04 ,  H01M4/0404 ,  H01M4/0416 ,  H01M4/043 ,  H01M4/0435 ,  H01M4/0471 ,  H01M4/131 ,  H01M4/505 ,  C01P2002/32 ,  C01P2004/51 ,  C01P2004/52 ,  C01P2006/40 ,  H01M10/052 ,  Y02P70/54

摘要： A novel method of preparing a highly homogenous spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compound having a predetermined mean particle size and particle size distribution for 4 V secondary lithium and lithium ion cells is provided. The method comprises mixing at least one manganese compound having a predetermined particle size distribution with at least one lithium compound wherein the manganese compound has a mean particle size of between about 1 and 15 microns and the mean particle size of the lithium compound is less than that of the manganese compound. The mixture is then fired in one or more firing steps within specific temperature ranges to form the Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compound. Preferably, at least one firing step is at a temperature of between about 700.degree. C. and 900.degree. C. The Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compounds may be used in the positive electrodes of secondary lithium and lithium ion cells to provide cells having high specific capacity, cycleability, and charge-discharge rate capability.

摘要翻译： 提供了一种制备具有预定平均粒度和4 V二次锂和锂离子电池的粒度分布的高均匀尖晶石Li1 + XMn2-XO4 + Y插层化合物的新方法。 该方法包括将至少一种具有预定粒度分布的锰化合物与至少一种锂化合物混合，其中锰化合物的平均粒度为约1至15微米，并且锂化合物的平均粒径小于 的锰化合物。 然后将混合物在特定温度范围内的一个或多个烧制步骤中烧制以形成Li1 + XMn2-XO4 + Y插层化合物。 优选地，至少一个焙烧步骤为约700℃至900℃之间的温度.Li1 + XMn2-XO4 + Y插层化合物可用于二次锂离子和锂离子电池的正电极，以提供电池 具有高比容量，循环性和充放电率能力。

公开(公告)号：US5789115A

公开(公告)日：1998-08-04

申请号：US867162

申请日：1997-06-02

申请人： Vesselin Manev ,  Walter Ebner ,  William Thompson ,  Stephen Dow

发明人： Vesselin Manev ,  Walter Ebner ,  William Thompson ,  Stephen Dow

IPC分类号： C01G45/00 ,  H01M2/32 ,  H01M4/04 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/50 ,  H01M4/505 ,  H01M10/052 ,  H01M10/36 ,  C01G45/12

CPC分类号： H01M4/1391 ,  C01G45/1242 ,  H01M2/32 ,  H01M4/04 ,  H01M4/0404 ,  H01M4/0416 ,  H01M4/043 ,  H01M4/0435 ,  H01M4/0471 ,  H01M4/131 ,  H01M4/505 ,  C01P2002/32 ,  C01P2004/51 ,  C01P2004/52 ,  C01P2006/40 ,  H01M10/052 ,  Y02P70/54

摘要： A novel method of preparing a highly homogenous spinel Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compound having a predetermined mean particle size and particle size distribution for 4 V secondary lithium and lithium ion cells is provided. The method comprises mixing at least one manganese compound having a predetermined particle size distribution with at least one lithium compound wherein the manganese compound has a mean particle size of between about 1 and 15 microns and the mean particle size of the lithium compound is less than that of the manganese compound. The mixture is then fired in one or more firing steps within specific temperature ranges to form the Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compound. Preferably, at least one firing step is at a temperature of between about 700.degree. C. and 900.degree. C. The Li.sub.1+X Mn.sub.2-X O.sub.4+Y intercalation compounds may be used in the positive electrodes of secondary lithium and lithium ion cells to provide cells having high specific capacity, cycleability, and charge-discharge rate capability.

摘要翻译： 提供了一种制备具有预定平均粒度和4 V二次锂和锂离子电池的粒度分布的高均匀尖晶石Li1 + XMn2-XO4 + Y插层化合物的新方法。 该方法包括将至少一种具有预定粒度分布的锰化合物与至少一种锂化合物混合，其中锰化合物的平均粒度为约1至15微米，并且锂化合物的平均粒径小于 的锰化合物。 然后将混合物在特定温度范围内的一个或多个烧制步骤中烧制以形成Li1 + XMn2-XO4 + Y插层化合物。 优选地，至少一个焙烧步骤为约700℃至900℃之间的温度.Li1 + XMn2-XO4 + Y插层化合物可用于二次锂离子和锂离子电池的正电极，以提供电池 具有高比容量，循环性和充放电率能力。

公开(公告)号：US20050069484A1

公开(公告)日：2005-03-31

申请号：US10675552

申请日：2003-09-30

申请人： Vesselin Manev ,  Vijay Saharan ,  Yee-Ho Chia ,  Jeffrey Roberts

发明人： Vesselin Manev ,  Vijay Saharan ,  Yee-Ho Chia ,  Jeffrey Roberts

IPC分类号： C01D15/02 ,  C01D15/08 ,  C01G53/00 ,  H01M4/04 ,  H01M4/52 ,  H01M4/525 ,  H01M6/16 ,  H01M10/0525 ,  H01M10/36 ,  C01D1/02 ,  C01G51/04 ,  C01G53/04

CPC分类号： H01M4/525 ,  C01B2203/82 ,  C01D15/02 ,  C01D15/08 ,  C01G53/42 ,  C01G53/50 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2002/88 ,  C01P2006/40 ,  H01M4/04 ,  H01M4/0404 ,  H01M4/0471 ,  H01M10/0525 ,  H01M2300/0037

摘要： A method for preparing a positive electrode material for a lithium-ion or lithium-ion polymer battery to reduce the moisture content of the positive electrode material. A lithiated transition metal oxide positive electrode material having at least one water-containing compound therein is treated to convert the water-containing compound to a water-free compound. One treatment in the method of the present invention involves exposing the positive electrode material at a temperature of 0-650° C. to a CO2-containing gas. The other treatment in the method of the present invention involves heating the positive electrode material to a temperature greater than 250° C. in the presence of an oxygen-containing gas, such as air and/or O2. The treatments may be, performed sequentially or concurrently.

摘要翻译： 一种用于制备用于锂离子或锂离子聚合物电池的正极材料以降低正极材料的含水量的方法。 处理具有至少一种含水化合物的锂化过渡金属氧化物正极材料，以将含水化合物转化为无水化合物。 在本发明的方法中的一种处理方法是将正极材料在0-650℃的温度下暴露于含CO 2的气体中。 在本发明方法中的另一种处理方法包括在含氧气体如空气和/或O 2的存在下将正极材料加热到大于250℃的温度。 治疗可以顺序或同时进行。

公开(公告)号：US06280699B1

公开(公告)日：2001-08-28

申请号：US09332644

申请日：1999-06-14

申请人： Vesselin Manev ,  Walter Ebner ,  William Thompson ,  Stephen Dow

发明人： Vesselin Manev ,  Walter Ebner ,  William Thompson ,  Stephen Dow

IPC分类号： C01G4512

CPC分类号： H01M4/1391 ,  C01G45/1242 ,  C01P2002/32 ,  C01P2004/51 ,  C01P2004/52 ,  C01P2006/40 ,  H01M2/32 ,  H01M4/04 ,  H01M4/0404 ,  H01M4/0416 ,  H01M4/043 ,  H01M4/0435 ,  H01M4/0471 ,  H01M4/131 ,  H01M4/505 ,  H01M10/052

摘要： A method of preparing a highly homogenous spinel Li1+XMn2−XO4+Y intercalation compound having a predetermined mean particle size and particle size distribution for 4 V secondary lithium and lithium ion cells is provided. The method comprises mixing at least one manganese compound having a predetermined particle size distribution with at least one lithium compound wherein the manganese compound has a mean particle size of between about 1 and 15 microns and the mean particle size of the lithium compound is less than that of the manganese compound The mixture is then fired in one or more firing steps within specific temperature ranges to form the Li1+XMn2−XO4+Y intercalation compound. Preferably, at least one firing step is at a temperature of between about 700° C. and 900° C. The Li1+XMn2−XO4+Y intercalation compounds may be used in the positive electrodes of secondary lithium and lithium ion cells to provide cells having high specific capacity, cycleability, and charge-discharge rate capability.

摘要翻译： 提供了制备具有预定平均粒径和4V二次锂和锂离子电池的粒度分布的高均匀尖晶石Li1 + XMn2-XO4 + Y插层化合物的方法。 该方法包括将至少一种具有预定粒度分布的锰化合物与至少一种锂化合物混合，其中锰化合物的平均粒度为约1至15微米，并且锂化合物的平均粒径小于 的锰化合物然后在特定温度范围内的一个或多个焙烧步骤中烧制混合物以形成Li1 + XMn2-XO4 + Y插层化合物。 优选地，至少一个焙烧步骤处于约700℃和900℃之间的温度.Li1 + XMn2-XO4 + Y插层化合物可以用于次级锂离子和锂离子电池的正极以提供电池 具有高比容量，循环性和充放电率能力。