HIGH-PERFORMANCE TRIPLE-CROSSLINKED POLYMER AND PREPARATION METHOD THEREOF

    公开(公告)号:US20210253805A1

    公开(公告)日:2021-08-19

    申请号:US16853785

    申请日:2020-04-21

    Abstract: A high-performance triple-crosslinked polymer and a preparation method thereof are provided. The polymer is obtained by curing and cross-linking a monomer having two epoxy groups, a cross-linking monomer and a functional monomer. The polymer contains a cross-linking network formed by covalent bonds and two types of multi-level hydrogen bonds with different strengths. The interaction strength between the covalent bonds and the two types of hydrogen bonds decreases in a gradient. The dilemma of the strength-ductility tradeoff in a high-performance polymer is overcome by forming a triple-crosslinked network with covalent bonds and multi-level hydrogen bonds with different strengths in the polymer. The dynamic and hierarchical hydrogen bonds are broken and recombined timely and continuously to concurrently maintain the complete structure of the polymer network and enable the polymer network to quickly respond to the transmission and dissipation of the external environment.

    VERTICAL GROUND HEAT EXCHANGER FOR REDUCING TEMPERATURE IN CARBONACEOUS SHALE ROCK MASS AND PREVENTING ROADBED FROST HEAVE

    公开(公告)号:US20210355639A1

    公开(公告)日:2021-11-18

    申请号:US17004013

    申请日:2020-08-27

    Inventor: Baolong ZHU Xin LI

    Abstract: A vertical ground heat exchanger for reducing the temperature in the carbonaceous shale rock mass and preventing roadbed frost heave includes a heating mechanism, a heat releasing component respectively connected to both ends of the heating mechanism and a refrigeration heat exchange mechanism. The refrigeration heat exchange mechanism is connected to the lower end of the heating mechanism through a heat transfer pipeline and communicates with the heat releasing component. The heat releasing component includes a double-layer heat exchange tube component, a gas-liquid separator and a branch tube, wherein the double-layer heat exchange tube component is respectively connected to the both ends of the heating mechanism, the gas-liquid separator is connected to the double-layer heat exchange tube component, and the branch tube is connected between the gas-liquid separator and the refrigeration heat exchange mechanism. The double-layer heat exchange tube component includes an upper bellows and a lower bellows.

    Adhesive for moss
    15.
    发明申请

    公开(公告)号:US20210347706A1

    公开(公告)日:2021-11-11

    申请号:US17381185

    申请日:2021-07-20

    Abstract: An adhesive for moss and a method for preparing the adhesive are provided, wherein the method includes steps of: adding melamine, urea, attapulgite and sepiolite powder into a ball milling tank, and adding milling balls into the ball milling tank for ball milling; then collecting ball-milled materials; adding konjac glucomannan, chitosan and collagen into water and stirring, wherein during stirring, half of the ball-milled materials are added into the water; then adding latex powder, stearic acid and ammonium zirconium carbonate, and stirring, wherein during stirring, the other half of the ball-milled materials are added into the water. The adhesive for moss can be used for bonding moss with sufficient bonding effect, which is environment-friendly and will not harm the moss; meanwhile, the konjac glucomannan, the chitosan, the collagen attapulgite and the sepiolite powder which are contained in the adhesive can provide nutrition for the moss.

    Method for comparative analysis on mechanical strength of macro-molecular polymer materials

    公开(公告)号:US11143591B2

    公开(公告)日:2021-10-12

    申请号:US16791457

    申请日:2020-02-14

    Abstract: A method for detecting or comparing mechanical strength of macro-molecular polymer materials. The detecting method has the steps of measuring the mechanical strength and the maximum value of the fluorescence absorption spectrum of each of the plurality of samples to form a curve relationship or function relationship between the maximum value of the fluorescence absorption spectrum and the mechanical strength; measuring the maximum value of the fluorescence absorption spectrum of the target material, and using the curve relationship or the function relationship to obtain the mechanical strength of the target material. The plurality of samples and the target material are both prepared from a macro-molecular polymer, and the macro-molecular polymer may be composed of disulfonate-difluorobenzophenone, hydroxyindole and difluorobenzophenone as monomers, and the sulfonate groups of the disulfonate-difluorobenzophenone have metal cations. An object of the method is to identify mechanical properties of polymer materials by fluorescence nondestructive detection.

    REVERSIBLE STRESS-RESPONSIVE MATERIAL, PREPARATION METHOD, AND USE THEREOF

    公开(公告)号:US20230391963A1

    公开(公告)日:2023-12-07

    申请号:US17891160

    申请日:2022-08-19

    CPC classification number: C08G81/024 C08F267/06

    Abstract: A reversible stress-responsive material, a preparation method, and a use thereof are provided. The reversible stress-responsive material prepared by the present disclosure has the property of real-time reversible force response at room temperature. When used with crosslinked plastic (high Tg) and rubber (low Tg) polymer materials, the reversible stress-responsive material can significantly enhance the mechanical strength and ductility of covalently cross-linked polymers. In the present disclosure, the triazolinedione (TAD)-indole click chemistry with the force-induced reversible property is used to construct a force-reversible crosslinked polymer material, and such a force-induced reversible crosslinking method can achieve the breakage and re-forming of covalent crosslinking points at room temperature in a solid state without any external stimuli other than the ambient temperature. This room-temperature force-induced reversible C—N covalent crosslinking can be regarded as an innovative approach to designing a high-toughness polymer material.

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